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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 6-Amino-5-ethylsulfanyl-4-methyl-2-oxo-1,2-dihydro-pyridine-3-carbonitrile 89110-38-3 C9H11N3OS
    6-Amino-5-ethylsulfanyl-4-methyl-2-oxo-1,2-dihydro-pyridine-3-carbonitrile
    —— (p-Tolyl)[[(1R,6S)-6beta-(3-acetoxypropyl)bicyclo[4.1.0]heptan]-1beta-yl] sulfide —— C19H26O2S
    (p-Tolyl)[[(1R,6S)-6beta-(3-acetoxypropyl)bicyclo[4.1.0]heptan]-1beta-yl] sulfide
    —— 3-<(1S,6R)-6-(p-tolylthio)bicyclo<4.1.0>hept-1-yl>propyl acetate 139590-74-2 C19H26O2S
    3-<(1S,6R)-6-(p-tolylthio)bicyclo<4.1.0>hept-1-yl>propyl acetate
    —— <<2-(Methylthio)phenyl>methyl>phenylphosphinsaeure-methylester 122278-86-8 C15H17O2PS
    <<2-(Methylthio)phenyl>methyl>phenylphosphinsaeure-methylester
    —— 3-<(1S,6S)-6-(p-tolylthio)(5,5-(2)H2)bicyclo<4.1.0>hept-1-yl>propyl acetate 139590-80-0 C19H26O2S
    3-<(1S,6S)-6-(p-tolylthio)(5,5-(2)H2)bicyclo<4.1.0>hept-1-yl>propyl acetate
    —— 3-<(1S)-1-methyl-2-(p-tolylthio)cyclohex-2-en-1-yl>propyl acetate 139590-77-5 C19H26O2S
    3-<(1S)-1-methyl-2-(p-tolylthio)cyclohex-2-en-1-yl>propyl acetate
    —— 4-[2-(4-chlorophenylthio)-2,2-difluoroethyl]oxazolidin-2-one 1355214-08-2 C11H10ClF2NO2S
    4-[2-(4-chlorophenylthio)-2,2-difluoroethyl]oxazolidin-2-one
    —— 4-[2,2-difluoro-2-(phenylthio)ethyl]oxazolidin-2-one 1355213-96-5 C11H11F2NO2S
    4-[2,2-difluoro-2-(phenylthio)ethyl]oxazolidin-2-one
    —— 1-methylsulfonyl-3-methylthio-5-(1H-1,2,4-triazolamine) 122652-06-6 C4H8N4O2S2
    1-methylsulfonyl-3-methylthio-5-(1H-1,2,4-triazolamine)
    —— 5-methoxycarbonylethylthio-1,2,3-thiadiazole 69893-90-9 C6H8N2O2S2
    5-methoxycarbonylethylthio-1,2,3-thiadiazole
    —— (3S,4R,1'R)-2-(α-methylbenzyl)-3-phenyl-4-(phenylsulfenyl)-1,2-thiazetidine 1,1-dioxide 218460-70-9 C22H21NO2S2
    (3S,4R,1'R)-2-(α-methylbenzyl)-3-phenyl-4-(phenylsulfenyl)-1,2-thiazetidine 1,1-dioxide
    —— 5-Difluoromethylthio-3-phenylisoxazole 126767-48-4 C10H7F2NOS
    5-Difluoromethylthio-3-phenylisoxazole
    —— (3R,4S,1'R)-2-(α-methylbenzyl)-3-phenyl-4-(phenylsulfenyl)-1,2-thiazetidine 1,1-dioxide 218460-57-2 C22H21NO2S2
    (3R,4S,1'R)-2-(α-methylbenzyl)-3-phenyl-4-(phenylsulfenyl)-1,2-thiazetidine 1,1-dioxide
    —— N-(4-(4-(2H-1,2,4-triazol-3-ylamino)-6-chloropyrimidin-2-ylthio)phenyl)-3,3,3-trifluoropropanamide 1079394-23-2 C15H11ClF3N7OS
    N-(4-(4-(2H-1,2,4-triazol-3-ylamino)-6-chloropyrimidin-2-ylthio)phenyl)-3,3,3-trifluoropropanamide
    —— 2-methoxy-1-phenylthio-3-butene 82578-08-3 C11H14OS
    2-methoxy-1-phenylthio-3-butene
    —— [5-Chloro-2-(4-chloro-phenylsulfanyl)-phenyl]-methanol 13420-69-4 C13H10Cl2OS
    [5-Chloro-2-(4-chloro-phenylsulfanyl)-phenyl]-methanol
    —— 3-chloro-6-[(4'-chlorophenyl)-thio]-benzyl chloride 14359-50-3 C13H9Cl3S
    3-chloro-6-[(4'-chlorophenyl)-thio]-benzyl chloride
    —— N-(4-(4-(3-amino-1H-1,2,4-triazol-1-yl)-6-chloropyrimidin-2-ylthio)phenyl)-3,3,3-trifluoropropanamide 1079394-24-3 C15H11ClF3N7OS
    N-(4-(4-(3-amino-1H-1,2,4-triazol-1-yl)-6-chloropyrimidin-2-ylthio)phenyl)-3,3,3-trifluoropropanamide
    —— ((Z)-3-Methoxy-but-2-enylsulfanyl)-benzene 79631-61-1 C11H14OS
    ((Z)-3-Methoxy-but-2-enylsulfanyl)-benzene
    —— 7-bromo-9-(4-ethylpiperazin-1-yl)pyrrolo[2,1-b][1,3]benzothiazepine 395073-87-7 C18H20BrN3S
    7-bromo-9-(4-ethylpiperazin-1-yl)pyrrolo[2,1-b][1,3]benzothiazepine
    —— 7-bromo-9,10-dihydropyrrolo[2,1-b][1,3]benzothiazepin-9-one 256950-35-3 C12H8BrNOS
    7-bromo-9,10-dihydropyrrolo[2,1-b][1,3]benzothiazepin-9-one
    —— (+/-)-7-bromo-9,10-dihydro-9-hydroxypyrrolo[2,1-b][1,3]benzothiazepine 256950-36-4 C12H10BrNOS
    (+/-)-7-bromo-9,10-dihydro-9-hydroxypyrrolo[2,1-b][1,3]benzothiazepine
    —— 7-bromo-9-(4-methylpiperazin-1-yl)pyrrolo[2,1-b][1,3]benzothiazepine 395073-86-6 C17H18BrN3S
    7-bromo-9-(4-methylpiperazin-1-yl)pyrrolo[2,1-b][1,3]benzothiazepine
    —— (+/-)-7,9-dibromo-9,10-dihydropyrrolo[2,1-b][1,3]benzothiazepine 256950-37-5 C12H9Br2NS
    (+/-)-7,9-dibromo-9,10-dihydropyrrolo[2,1-b][1,3]benzothiazepine
    —— 1-Hentriacontanethiol 5340-24-9 C31H64S
    1-Hentriacontanethiol
    —— (4,5-difluoro-2-(2-(hydroxymethyl)phenylthio)phenyl)methanol 1062599-56-7 C14H12F2O2S
    (4,5-difluoro-2-(2-(hydroxymethyl)phenylthio)phenyl)methanol
    —— 4-furan-2-yl-6-methylsulfanyl-pyrimidin-2-ylamine 357285-91-7 C9H9N3OS
    4-furan-2-yl-6-methylsulfanyl-pyrimidin-2-ylamine
    —— 9-Benzyl-7-bromo-1,4-dithia-spiro[4.5]dec-6-ene 106225-79-0 C15H17BrS2
    9-Benzyl-7-bromo-1,4-dithia-spiro[4.5]dec-6-ene
    —— 4-chloro-6-difluoromethoxy-2-methylthiopyrimidine 111810-90-3 C6H5ClF2N2OS
    4-chloro-6-difluoromethoxy-2-methylthiopyrimidine
    —— 3-cyclohexylmethoxy-5-methylsulfanyl-isothiazole-4-carbonitrile 651305-70-3 C12H16N2OS2
    3-cyclohexylmethoxy-5-methylsulfanyl-isothiazole-4-carbonitrile
    —— 1-isopropyl-7-(methylmercapto)-3,4-dihydropyrimido[4,5-d]pyrimidin-2(1H)-one 251371-24-1 C10H14N4OS
    1-isopropyl-7-(methylmercapto)-3,4-dihydropyrimido[4,5-d]pyrimidin-2(1H)-one
    —— 2-Hexyl isothiocyanate 5334-87-2 C7H13NS
    2-Hexyl isothiocyanate
    —— 2-(dimethylamino)ethyl 3-[(4-hydroxyphenyl)sulfanyl]-2-methylpropanoate 1069086-82-3 C14H21NO3S
    2-(dimethylamino)ethyl 3-[(4-hydroxyphenyl)sulfanyl]-2-methylpropanoate
    —— 1-methyl-5-methylthio-3-trifluoromethyl-1H-1,2,4-triazole 51856-19-0 C5H6F3N3S
    1-methyl-5-methylthio-3-trifluoromethyl-1H-1,2,4-triazole
    —— 1-(pentane-1-sulfonyl)-propan-2-one 92334-75-3 C8H16O3S
    1-(pentane-1-sulfonyl)-propan-2-one
    —— 5-methylsulfanyl-[1,2,4]triazole-3,4-diyldiamine 55055-08-8 C3H7N5S
    5-methylsulfanyl-[1,2,4]triazole-3,4-diyldiamine
    —— (4,5-diamino-4<i>H</i>-[1,2,4]triazol-3-ylmercapto)-acetic acid 118769-03-2 C4H7N5O2S
    (4,5-diamino-4<i>H</i>-[1,2,4]triazol-3-ylmercapto)-acetic acid
    —— ethyl (2-methylthio-4-thiazolyl)acetate 117491-75-5 C8H11NO2S2
    ethyl (2-methylthio-4-thiazolyl)acetate
    —— 2-Phenylsulfanyl-cyclooctanone oxime 189755-40-6 C14H19NOS
    2-Phenylsulfanyl-cyclooctanone oxime
    —— 2-(5-methylthio)-5-(6-morpholinopyrazin-2-yl)[1,3,4]thiadiazole 865440-77-3 C11H13N5OS2
    2-(5-methylthio)-5-(6-morpholinopyrazin-2-yl)[1,3,4]thiadiazole
    —— 4-[2-(3,5-Dichlorophenyl)sulfanyl-5-nitrophenyl]sulfonylthiomorpholine 1253498-77-9 C16H14Cl2N2O4S3
    4-[2-(3,5-Dichlorophenyl)sulfanyl-5-nitrophenyl]sulfonylthiomorpholine
    —— 3-(5-Methylsulfanyl-[1,3,4]thiadiazol-2-yl)-propylamine; hydrochloride 140440-10-4 C6H11N3S2*ClH
    3-(5-Methylsulfanyl-[1,3,4]thiadiazol-2-yl)-propylamine; hydrochloride
    —— {4-[(2-amino-2-oxoethyl)thio]phenyl}boronic acid 1032825-15-2 C8H10BNO3S
    {4-[(2-amino-2-oxoethyl)thio]phenyl}boronic acid
    —— ({4-[(1R)-3-Oxocyclopentyl]phenyl}thio)acetic acid ethyl ester 1211474-19-9 C15H18O3S
    ({4-[(1R)-3-Oxocyclopentyl]phenyl}thio)acetic acid ethyl ester
    —— {[4-(3-Oxo-1-cyclopenten-1-yl)phenyl]thio}acetic acid ethyl ester 1211474-18-8 C15H16O3S
    {[4-(3-Oxo-1-cyclopenten-1-yl)phenyl]thio}acetic acid ethyl ester
    —— 5-Ethylsulfanyl-6-methyl-3-nitro-1H-pyridin-2-one 139548-62-2 C8H10N2O3S
    5-Ethylsulfanyl-6-methyl-3-nitro-1H-pyridin-2-one
    —— N,N-dimethyl-5-(4-fluorophenyl)-4-[4-(methylthio)phenyl]-2-thenylamine 140403-62-9 C20H20FNS2
    N,N-dimethyl-5-(4-fluorophenyl)-4-[4-(methylthio)phenyl]-2-thenylamine
    —— 5-(3,5-dichlorophenylthio)-1-isopropyl-3-(4-methoxybenzyl)-1,3-dihydro-2-imidazolone-4-carboxaldehyde 431880-77-2 C21H20Cl2N2O3S
    5-(3,5-dichlorophenylthio)-1-isopropyl-3-(4-methoxybenzyl)-1,3-dihydro-2-imidazolone-4-carboxaldehyde
    —— 2-amino-5-[(3,5-dichlorophenyl)sulfanyl]-6-methylthieno[2,3-d]pyrimidin-4(3H)-one 1059126-69-0 C13H9Cl2N3OS2
    2-amino-5-[(3,5-dichlorophenyl)sulfanyl]-6-methylthieno[2,3-d]pyrimidin-4(3H)-one
    —— 1,3-Bis[(2-hydroxyethyl)thio]butane 5335-14-8 C8H18O2S2
    1,3-Bis[(2-hydroxyethyl)thio]butane