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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-(4-fluoro-phenylsulfanyl)-4-methyl-furazan 5-oxide 63435-83-6 C9H7FN2O2S
    3-(4-fluoro-phenylsulfanyl)-4-methyl-furazan 5-oxide
    —— 3-(4-fluoro-phenylsulfanyl)-4-methyl-furazan 63435-92-7 C9H7FN2OS
    3-(4-fluoro-phenylsulfanyl)-4-methyl-furazan
    —— 4-(4-fluorophenylsulfanyl)-3-hydroxy-2-pyrone 881171-81-9 C11H7FO3S
    4-(4-fluorophenylsulfanyl)-3-hydroxy-2-pyrone
    —— (Dimethyl-lambda4-sulfanylidene)urea 55871-39-1 C3H8N2OS
    (Dimethyl-lambda4-sulfanylidene)urea
    —— (3-chloro-benzyl)-(4-fluoro-phenyl)-sulfide 588-55-6 C13H10ClFS
    (3-chloro-benzyl)-(4-fluoro-phenyl)-sulfide
    —— diphenyl[2-(phenylthio)phenyl]bismuthane 1319745-97-5 C24H19BiS
    diphenyl[2-(phenylthio)phenyl]bismuthane
    —— 4,6-Diaminopyrimido<4,5-b>-1,4-thiazin 55383-58-9 C6H7N5S
    4,6-Diaminopyrimido<4,5-b>-1,4-thiazin
    —— 2,5-dibromo-3-(butylsulfanyl)thiophene 161405-99-8 C8H10Br2S2
    2,5-dibromo-3-(butylsulfanyl)thiophene
    —— 3-(4-methoxyphenylthio)cinnoline 121346-70-1 C15H12N2OS
    3-(4-methoxyphenylthio)cinnoline
    —— (S)-1,1,1-trifluoro-2-<(methoxymethyl)oxy>-3-methyl-4-phenylthio-2-trifluoromethylbutane 156078-73-8 C14H16F6O2S
    (S)-1,1,1-trifluoro-2-<(methoxymethyl)oxy>-3-methyl-4-phenylthio-2-trifluoromethylbutane
    —— 2-Amino-6-(4-chloro-phenyl)-3,7-dihydro-pyrimido[4,5-b][1,4]thiazin-4-one 77903-13-0 C12H9ClN4OS
    2-Amino-6-(4-chloro-phenyl)-3,7-dihydro-pyrimido[4,5-b][1,4]thiazin-4-one
    —— 5-methylsulfanyl-6-phenylsulfanyl-2<i>H</i>-[1,2,4]triazin-3-one 32330-98-6 C10H9N3OS2
    5-methylsulfanyl-6-phenylsulfanyl-2<i>H</i>-[1,2,4]triazin-3-one
    —— (4,4,4-trifluorobutylsulfonyl)acetonitrile 1097630-73-3 C6H8F3NO2S
    (4,4,4-trifluorobutylsulfonyl)acetonitrile
    —— <(Fluoromethyl)sulfonyl>methane 94404-44-1 C2H5FO2S
    <(Fluoromethyl)sulfonyl>methane
    —— (3-(trifluoromethyl)-3,4,4,4-pentafluorobutylsulfonyl)acetonitrile 1097630-68-6 C7H6F7NO2S
    (3-(trifluoromethyl)-3,4,4,4-pentafluorobutylsulfonyl)acetonitrile
    —— 4-hydrazino-5<i>H</i>-pyrimido[4,5-<i>b</i>][1,4]thiazin-6-one hydrazone 55383-68-1 C6H9N7S
    4-hydrazino-5<i>H</i>-pyrimido[4,5-<i>b</i>][1,4]thiazin-6-one hydrazone
    —— 6-ethylsulfanyl-5-methylsulfanyl-2<i>H</i>-[1,2,4]triazin-3-one 32331-15-0 C6H9N3OS2
    6-ethylsulfanyl-5-methylsulfanyl-2<i>H</i>-[1,2,4]triazin-3-one
    —— 3-methylthiohexa-1,2,5-triene 162573-17-3 C7H10S
    3-methylthiohexa-1,2,5-triene
    —— 3-Dimethylamino-<2,3>bithietan-1,1,1',1'-tetroxid 5583-80-2 C8H15NO4S2
    3-Dimethylamino-<2,3>bithietan-1,1,1',1'-tetroxid
    —— 4-Hydroxy-2-(2-phenylsulfanylethyl)-5-(2,4,6-trimethylphenyl)-2,3-dihydropyran-6-one 1612830-28-0 C22H24O3S
    4-Hydroxy-2-(2-phenylsulfanylethyl)-5-(2,4,6-trimethylphenyl)-2,3-dihydropyran-6-one
    —— (2-fluorobenzyl)(p-tolyl)sulfane 887079-00-7 C14H13FS
    (2-fluorobenzyl)(p-tolyl)sulfane
    —— 6-amino-2-[[(2-fluorophenyl)methyl]thio]-4-pyrimidinol 354582-82-4 C11H10FN3OS
    6-amino-2-[[(2-fluorophenyl)methyl]thio]-4-pyrimidinol
    —— 4-Phenyl-2-phenylthiocyclohex-2-enone 391858-25-6 C18H16OS
    4-Phenyl-2-phenylthiocyclohex-2-enone
    —— 2-Methyl-7-methylthiooxazolo<5,4-d>pyrimidin 33360-25-7 C7H7N3OS
    2-Methyl-7-methylthiooxazolo<5,4-d>pyrimidin
    —— 2-[2-(2-azido-ethoxy)ethylsulfonyl]ethanol 1303532-01-5 C6H13N3O4S
    2-[2-(2-azido-ethoxy)ethylsulfonyl]ethanol
    —— 5-Hydrazino-6-phenylthio-as-triazin-3(2H)-on 32331-03-6 C9H9N5OS
    5-Hydrazino-6-phenylthio-as-triazin-3(2H)-on
    —— 1h-Imidazole, 5,5'-thiobis[1-methyl-4-nitro- 13755-68-5 C8H8N6O4S
    1h-Imidazole, 5,5'-thiobis[1-methyl-4-nitro-
    —— N-(4-(8-(5-methyl-1H-pyrazol-3-ylamino)imidazo[1,2-a]pyrazin-6-ylthio)phenyl)cyclopropane carboxamide 883734-21-2 C20H19N7OS
    N-(4-(8-(5-methyl-1H-pyrazol-3-ylamino)imidazo[1,2-a]pyrazin-6-ylthio)phenyl)cyclopropane carboxamide
    —— 1,1,2-trifluoro-2-chloro-2'-bromodiethyl thioether 61810-45-5 C4H5BrClF3S
    1,1,2-trifluoro-2-chloro-2'-bromodiethyl thioether
    —— 2,3'-Bithiethan-tetroxid 17471-12-4 C6H10O4S2
    2,3'-Bithiethan-tetroxid
    —— 5-Amino-6-methylthio-as-triazin-3(2H)-on 31697-23-1 C4H6N4OS
    5-Amino-6-methylthio-as-triazin-3(2H)-on
    —— methyl 2-(4-cyclopropanecarboxamido-phenylsulfanyl)-5-nitro-6-(5-methylpyrazol-3-ylamino)-4-pyrimidinecarboxylate 888020-13-1 C20H19N7O5S
    methyl 2-(4-cyclopropanecarboxamido-phenylsulfanyl)-5-nitro-6-(5-methylpyrazol-3-ylamino)-4-pyrimidinecarboxylate
    —— N-[4-[4-[4-(aminomethyl)piperidin-1-yl]-6-[(5-methyl-1H-pyrazol-3-yl)amino]pyrimidin-2-yl]sulfanylphenyl]cyclopropanecarboxamide 1152262-47-9 C24H30N8OS
    N-[4-[4-[4-(aminomethyl)piperidin-1-yl]-6-[(5-methyl-1H-pyrazol-3-yl)amino]pyrimidin-2-yl]sulfanylphenyl]cyclopropanecarboxamide
    —— N-(4-(5-(5-methyl-1H-pyrazol-3-ylamino)imidazo[1,2-f]pyrimidin-7-ylthio)phenyl)cyclopropane carboxamide 883734-14-3 C20H19N7OS
    N-(4-(5-(5-methyl-1H-pyrazol-3-ylamino)imidazo[1,2-f]pyrimidin-7-ylthio)phenyl)cyclopropane carboxamide
    —— N-(4-(5-(5-methyl-1H-pyrazol-3-ylamino)-[1,2,4]triazolo[1,5-f]pyrimidin-7-ylthio)phenyl)cyclopropane carboxamide 883734-19-8 C19H18N8OS
    N-(4-(5-(5-methyl-1H-pyrazol-3-ylamino)-[1,2,4]triazolo[1,5-f]pyrimidin-7-ylthio)phenyl)cyclopropane carboxamide
    —— 4-Amino-3-methyl-2-methylthio-6-oxo-3,6-dihydropyrimidin 29877-80-3 C6H9N3OS
    4-Amino-3-methyl-2-methylthio-6-oxo-3,6-dihydropyrimidin
    —— N-[4-[[4-(1H-imidazol-2-ylamino)-6-phenyl-1,3,5-triazin-2-yl]sulfanyl]phenyl]cyclopropanecarboxamide 1258423-45-8 C22H19N7OS
    N-[4-[[4-(1H-imidazol-2-ylamino)-6-phenyl-1,3,5-triazin-2-yl]sulfanyl]phenyl]cyclopropanecarboxamide
    —— N-(4-(2-ethyl-5-(5-methyl-1H-pyrazol-3-ylamino)imidazo[1,2-c]pyrimidin-7-ylthio)phenyl)cyclopropanecarboxamide 883737-15-3 C22H23N7OS
    N-(4-(2-ethyl-5-(5-methyl-1H-pyrazol-3-ylamino)imidazo[1,2-c]pyrimidin-7-ylthio)phenyl)cyclopropanecarboxamide
    —— 1,4,8,12-Tetrathiadispiro[4.1.57.15]tridecan-6-one 1018781-79-7 C9H12OS4
    1,4,8,12-Tetrathiadispiro[4.1.57.15]tridecan-6-one
    —— (Z)-5-(3-Nitro-4-((2,3,5,6-tetrafluoro-4-(trifluoromethyl)phenyl)thio) benzylidene)-2-thioxothiazolidin-4-one 21 1489285-12-2 C17H5F7N2O3S3
    (Z)-5-(3-Nitro-4-((2,3,5,6-tetrafluoro-4-(trifluoromethyl)phenyl)thio) benzylidene)-2-thioxothiazolidin-4-one 21
    —— N-(4-(5-(5-Methyl-1H-pyrazol-3-ylamino)imidazo[1,2-a]pyrimidin-7-ylthio)phenyl)-cyclopropane carboxamide 883734-23-4 C20H19N7OS
    N-(4-(5-(5-Methyl-1H-pyrazol-3-ylamino)imidazo[1,2-a]pyrimidin-7-ylthio)phenyl)-cyclopropane carboxamide
    —— 2,4-diamino-5-methyl-6-(2',3',5',6'-tetrafluoro-4'-trifluoromethylphenylsulfanyl)furo[2,3-d]pyrimidine 1217309-57-3 C14H7F7N4OS
    2,4-diamino-5-methyl-6-(2',3',5',6'-tetrafluoro-4'-trifluoromethylphenylsulfanyl)furo[2,3-d]pyrimidine
    —— 2-(2-Methylsulfonylethyl)guanidine 1149763-47-2 C4H11N3O2S
    2-(2-Methylsulfonylethyl)guanidine
    —— octanedithioamide 157122-35-5 C8H16N2S2
    octanedithioamide
    —— 2-(3,5-Bis-trifluoromethyl-phenylsulfanyl)-benzaldehyde 643763-23-9 C15H8F6OS
    2-(3,5-Bis-trifluoromethyl-phenylsulfanyl)-benzaldehyde
    —— 3-Isobutylsulfinyl-propionsaeure 7318-61-8 C7H14O3S
    3-Isobutylsulfinyl-propionsaeure
    —— 2,3,5,6-tetrafluorothioanisole 1480-02-0 C7H4F4S
    2,3,5,6-tetrafluorothioanisole
    —— 2-amino-5-phenyl-3-(3,5-bis-trifluoromethylphenyl)thiopyrazine 1262118-45-5 C18H11F6N3S
    2-amino-5-phenyl-3-(3,5-bis-trifluoromethylphenyl)thiopyrazine
    —— (2-chloroethylsulfanyl)-2,3,5,6-tetrafluorobenzene 111873-89-3 C8H5ClF4S
    (2-chloroethylsulfanyl)-2,3,5,6-tetrafluorobenzene
    —— heptyl vinyl sulfone 30719-65-4 C9H18O2S
    heptyl vinyl sulfone