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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— Isothiocyanic acid, 1,4-cyclohexylene-, dimethylene ester 29647-03-8 C10H14N2S2
    Isothiocyanic acid, 1,4-cyclohexylene-, dimethylene ester
    —— Tin(4+) dipropane-1,2-bis(thiolate) 7191-35-7 C6H12S4Sn
    Tin(4+) dipropane-1,2-bis(thiolate)
    —— Diethylthiocarbamic acid S-2-chloroallyl ester S-oxide 71387-21-8 C8H14ClNO2S
    Diethylthiocarbamic acid S-2-chloroallyl ester S-oxide
    —— Methylvinylensulfon 14491-01-1 C3H4O2S
    Methylvinylensulfon
    —— p-Toluidine, N-methyl-alpha-phenyl-thio- 13641-21-9 C14H15NS
    p-Toluidine, N-methyl-alpha-phenyl-thio-
    —— 2-((2-Chloro-1,1,2-trifluoroethyl)thio)-2-methylpropane 111959-97-8 C6H10ClF3S
    2-((2-Chloro-1,1,2-trifluoroethyl)thio)-2-methylpropane
    —— 2,8-Bis-(α-phenyl-thiobenzyl)-cyclooctanon 52186-08-0 C34H34OS2
    2,8-Bis-(α-phenyl-thiobenzyl)-cyclooctanon
    —— 2-Propanone, 3-((4-butylphenyl)thio)-1,1,1-trifluoro- 99541-30-7 C13H15F3OS
    2-Propanone, 3-((4-butylphenyl)thio)-1,1,1-trifluoro-
    —— Pentasulfide, bis(2,2,4-trimethylpentyl) 78718-06-6 C16H34S5
    Pentasulfide, bis(2,2,4-trimethylpentyl)
    —— 4-amino-6-chloro-2-ethylamino-5-methylthio-pyrimidine 78415-50-6 C7H11ClN4S
    4-amino-6-chloro-2-ethylamino-5-methylthio-pyrimidine
    —— O,O-Dimethyl S-((2-methyl-1,3-dithiolan-2-yl)methyl)phosphorodithioate 1012-62-0 C7H15O2PS4
    O,O-Dimethyl S-((2-methyl-1,3-dithiolan-2-yl)methyl)phosphorodithioate
    —— Di-tert-tetradecyl disulphide 29962-83-2 C28H58S2
    Di-tert-tetradecyl disulphide
    —— N-Isopropyl-<2-methyl-2-propyl-3-thiocarbamoyloxy-propyl>-carbamat 1444-06-0 C12H24N2O3S
    N-Isopropyl-<2-methyl-2-propyl-3-thiocarbamoyloxy-propyl>-carbamat
    —— Einecs 249-087-9 28573-66-2 C17H20Cl3N2O2SZn+
    Einecs 249-087-9
    —— 2,2'-Thio-bis-<4-(1,1,3,3-tetramethyl-butyl)phenolato>-Ni(II) 27574-34-1 C28H40O2S*Ni
    2,2'-Thio-bis-<4-(1,1,3,3-tetramethyl-butyl)phenolato>-Ni(II)
    —— 10H-Pyrido(3,2-b)(1,4)benzothiazine-10-carbothioic acid, S-(2-(4-(2-hydroxyethyl)piperazinyl)ethyl) ester, dihydrochloride 35805-99-3 C20H26Cl2N4O2S2
    10H-Pyrido(3,2-b)(1,4)benzothiazine-10-carbothioic acid, S-(2-(4-(2-hydroxyethyl)piperazinyl)ethyl) ester, dihydrochloride
    —— thiol acetic acid —— CH2O2S
    thiol acetic acid
    —— Ethyl 2-(ethylsulfanyl)-6-methylpyrimidin-4-yl ethylphosphonate 25537-46-6 C11H19N2O3PS
    Ethyl 2-(ethylsulfanyl)-6-methylpyrimidin-4-yl ethylphosphonate
    —— Thiocyanic acid, (12-aminododecyl) ester 64047-97-8 C13H26N2S
    Thiocyanic acid, (12-aminododecyl) ester
    —— Phosphorodithioic acid, S-(((o-chlorophenyl)thio)methyl) O,O-dimethyl ester 64050-57-3 C9H12ClO2PS3
    Phosphorodithioic acid, S-(((o-chlorophenyl)thio)methyl) O,O-dimethyl ester
    —— Pyridinium, 1-(2-hydroxyethyl)-4-(phenylthio)-, bromide 71173-83-6 C13H14BrNOS
    Pyridinium, 1-(2-hydroxyethyl)-4-(phenylthio)-, bromide
    —— 3-(2-carbamimidoylsulfanylethylsulfanyl)propyl carbamimidothioate;hydron;dichloride —— C7H18Cl2N4S3
    3-(2-carbamimidoylsulfanylethylsulfanyl)propyl carbamimidothioate;hydron;dichloride
    —— 14-carbamimidoylsulfanyltetradecyl carbamimidothioate;hydron;bromide —— C16H35BrN4S2
    14-carbamimidoylsulfanyltetradecyl carbamimidothioate;hydron;bromide
    —— S-(((3-Chlorophenyl)thio)methyl) O,O-dimethyl phosphorodithioate 64050-56-2 C9H12ClO2PS3
    S-(((3-Chlorophenyl)thio)methyl) O,O-dimethyl phosphorodithioate
    —— 1,3,4-Thiadiazol-2-amine, 5-((4-aminophenyl)thio)- 64070-79-7 C8H8N4S2
    1,3,4-Thiadiazol-2-amine, 5-((4-aminophenyl)thio)-
    —— 11-carbamimidoylsulfanylundecyl carbamimidothioate;hydron;dibromide —— C13H30Br2N4S2
    11-carbamimidoylsulfanylundecyl carbamimidothioate;hydron;dibromide
    —— Sulfonium, dimethyl(2-((10H-pyrido(3,2-b)(1,4)benzothiazin-10-yl)carbonyloxy)ethyl)-, iodide 64036-96-0 C16H17IN2O2S2
    Sulfonium, dimethyl(2-((10H-pyrido(3,2-b)(1,4)benzothiazin-10-yl)carbonyloxy)ethyl)-, iodide
    —— 1-(Carbamimidoylsulfanyl)-2-methoxyethane hydrobromide 64039-34-5 C4H11BrN2OS
    1-(Carbamimidoylsulfanyl)-2-methoxyethane hydrobromide
    —— Pseudourea, 2-hexadecyl-1,3-dimethyl-2-thio-, hydrochloride 64039-31-2 C19H41ClN2S
    Pseudourea, 2-hexadecyl-1,3-dimethyl-2-thio-, hydrochloride
    —— 5-(N'-acetylcarbamimidoyl)sulfanylpentyl N'-acetylcarbamimidothioate;hydron;dichloride —— C11H22Cl2N4O2S2
    5-(N'-acetylcarbamimidoyl)sulfanylpentyl N'-acetylcarbamimidothioate;hydron;dichloride
    —— 2-(N,N-Dimethylaminopropyl)-4,4'-dichlorodiphenyl sulfide hydrochloride 63979-98-6 C17H20Cl3NS
    2-(N,N-Dimethylaminopropyl)-4,4'-dichlorodiphenyl sulfide hydrochloride
    —— Sulfide, bis(2-amino-5-chlorophenyl), hydrochloride, hydrate 63979-93-1 C12H13Cl3N2OS
    Sulfide, bis(2-amino-5-chlorophenyl), hydrochloride, hydrate
    —— Ammonium, diisopropylmethyl(2-(10H-pyrido(3,2-b)(1,4)benzothiazin-10-yl)carbonyloxyethyl)-, iodide 63977-43-5 C21H28IN3O2S
    Ammonium, diisopropylmethyl(2-(10H-pyrido(3,2-b)(1,4)benzothiazin-10-yl)carbonyloxyethyl)-, iodide
    —— 2-(4-chlorophenyl)sulfanyl-N,N-dimethylpropan-1-amine;hydron;chloride —— C11H17Cl2NS
    2-(4-chlorophenyl)sulfanyl-N,N-dimethylpropan-1-amine;hydron;chloride
    —— 2-[bis(2-methylpropyl)amino]ethyl carbamimidothioate;hydron;dichloride —— C11H27Cl2N3S
    2-[bis(2-methylpropyl)amino]ethyl carbamimidothioate;hydron;dichloride
    —— hydron;10-(N,N,N'-trimethylcarbamimidoyl)sulfanyldecyl N,N,N'-trimethylcarbamimidothioate;dibromide —— C18H40Br2N4S2
    hydron;10-(N,N,N'-trimethylcarbamimidoyl)sulfanyldecyl N,N,N'-trimethylcarbamimidothioate;dibromide
    —— [Amino-[10-[amino(azaniumylidene)methyl]sulfanyldecylsulfanyl]methylidene]azanium;dibromide —— C12H28Br2N4S2
    [Amino-[10-[amino(azaniumylidene)methyl]sulfanyldecylsulfanyl]methylidene]azanium;dibromide
    —— Methyl-phosphonothioic acid O-(2-ethylsulfanyl-6-methyl-pyrimidin-4-yl) ester O-methyl ester 63815-54-3 C9H15N2O2PS2
    Methyl-phosphonothioic acid O-(2-ethylsulfanyl-6-methyl-pyrimidin-4-yl) ester O-methyl ester
    —— Pseudourea, 2-thio-, 4-amino-4-carboxy-n-butyl-, dibromide 63679-72-1 C6H15Br2N3O2S
    Pseudourea, 2-thio-, 4-amino-4-carboxy-n-butyl-, dibromide
    —— 1,3-Diethyl-2-hexadecyl-2-thiopseudourea hydrochloride 63680-38-6 C21H45ClN2S
    1,3-Diethyl-2-hexadecyl-2-thiopseudourea hydrochloride
    —— [Amino-[4-[amino(azaniumylidene)methyl]sulfanylbut-2-ynylsulfanyl]methylidene]azanium;dichloride —— C6H12Cl2N4S2
    [Amino-[4-[amino(azaniumylidene)methyl]sulfanylbut-2-ynylsulfanyl]methylidene]azanium;dichloride
    —— 1-Pyrrolidinepropanamine, N-(4-chloro-2-((4-chlorophenyl)thio)phenyl)-, monohydrochloride, hemihydrate 63716-99-4 C38H48Cl6N4OS2
    1-Pyrrolidinepropanamine, N-(4-chloro-2-((4-chlorophenyl)thio)phenyl)-, monohydrochloride, hemihydrate
    —— Pyridine, 4-(3-(phenylthio)propyl)-, hydrochloride 63681-08-3 C14H16ClNS
    Pyridine, 4-(3-(phenylthio)propyl)-, hydrochloride
    —— [Amino(2-azaniumylethylsulfanyl)methylidene]-ethylazanium;diacetate 63679-86-7 C9H21N3O4S
    [Amino(2-azaniumylethylsulfanyl)methylidene]-ethylazanium;diacetate
    —— 2-Decyl-1,3-diethyl-2-thiopseudourea hydriodide 63680-31-9 C15H33IN2S
    2-Decyl-1,3-diethyl-2-thiopseudourea hydriodide
    —— N,N'-dimethyl(dodecylsulfanyl)methanimidamide hydrobromide 63680-50-2 C15H33BrN2S
    N,N'-dimethyl(dodecylsulfanyl)methanimidamide hydrobromide
    —— 1,3-Dimethyl-2-tetradecyl-2-thiopseudourea hydrochloride 63680-47-7 C17H37ClN2S
    1,3-Dimethyl-2-tetradecyl-2-thiopseudourea hydrochloride
    —— 2-Decyl-1,3-diethyl-2-thiopseudourea hydrobromide 63680-32-0 C15H33BrN2S
    2-Decyl-1,3-diethyl-2-thiopseudourea hydrobromide
    —— Pseudourea, 1,3-diethyl-2-hexadecyl-2-thio-, hydrobromide 63680-37-5 C21H45BrN2S
    Pseudourea, 1,3-diethyl-2-hexadecyl-2-thio-, hydrobromide
    —— hydron;tetradecyl N,N'-dimethylcarbamimidothioate;bromide —— C17H37BrN2S
    hydron;tetradecyl N,N'-dimethylcarbamimidothioate;bromide