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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2Z,4Z)-3,4-bis(benzenesulfenyl)-6,6-dimethylhepta-2,4-dienal diethyl acetal 647010-54-6 C25H32O2S2
    (2Z,4Z)-3,4-bis(benzenesulfenyl)-6,6-dimethylhepta-2,4-dienal diethyl acetal
    —— 3-Methylmercapto-5H-<1,2,4>triazolo<5,1-c><1,2,4>triazol 13728-27-3 C4H5N5S
    3-Methylmercapto-5H-<1,2,4>triazolo<5,1-c><1,2,4>triazol
    —— (E)-5-ethoxy-6,6,7,7,7-pentafluoro-1-phenyl-4-phenylsulfanylhept-4-en-1-yn-3-ol 236121-36-1 C21H17F5O2S
    (E)-5-ethoxy-6,6,7,7,7-pentafluoro-1-phenyl-4-phenylsulfanylhept-4-en-1-yn-3-ol
    —— (E)-5-ethoxy-6,6,7,7,7-pentafluoro-2,2-dimethyl-4-phenylsulfanylhept-4-en-3-ol 236121-34-9 C17H21F5O2S
    (E)-5-ethoxy-6,6,7,7,7-pentafluoro-2,2-dimethyl-4-phenylsulfanylhept-4-en-3-ol
    —— (E)-3-ethoxy-4,4,5,5,5-pentafluoro-1-phenyl-2-phenylsulfanylpent-2-en-1-ol 236121-35-0 C19H17F5O2S
    (E)-3-ethoxy-4,4,5,5,5-pentafluoro-1-phenyl-2-phenylsulfanylpent-2-en-1-ol
    —— (E)-2-ethoxy-3-(methylthio)-1,1,1-trifluoroprop-2-ene 236121-26-9 C6H9F3OS
    (E)-2-ethoxy-3-(methylthio)-1,1,1-trifluoroprop-2-ene
    —— 1-<2-(methoxymethyl)-1,3-dithian-2-yl>-3-methylbutan-2-one 144712-22-1 C11H20O2S2
    1-<2-(methoxymethyl)-1,3-dithian-2-yl>-3-methylbutan-2-one
    —— 3-Methyl-2-(phenylsulfanyl)cycloheptanone 108592-70-7 C14H18OS
    3-Methyl-2-(phenylsulfanyl)cycloheptanone
    —— (Z,3R)-3-methoxymethoxy-1-nitro-3-phenyl-1-phenylsulfanylpropene 169137-46-6 C17H17NO4S
    (Z,3R)-3-methoxymethoxy-1-nitro-3-phenyl-1-phenylsulfanylpropene
    —— 1-Nitro-1-phenylthio-heptan 59906-57-9 C13H19NO2S
    1-Nitro-1-phenylthio-heptan
    —— [2,2']Bi[benzo[b][1,3]dithiolo[4,5-e][1,4]dithiinylidene] 136058-19-0 C18H8S8
    [2,2']Bi[benzo[b][1,3]dithiolo[4,5-e][1,4]dithiinylidene]
    —— 1-Nitro-1-phenylthio-1-heptene 132364-57-9 C13H17NO2S
    1-Nitro-1-phenylthio-1-heptene
    —— (Z)-<2-nitro-2-(phenylthio)ethenyl>benzene 116272-76-5 C14H11NO2S
    (Z)-<2-nitro-2-(phenylthio)ethenyl>benzene
    —— 5-butyl-4,5-dihydro-3-(phenylthio)isoxazole 116502-97-7 C13H17NOS
    5-butyl-4,5-dihydro-3-(phenylthio)isoxazole
    —— (Z)-tert-butyl 1-propenyl sulfone 69113-45-7 C7H14O2S
    (Z)-tert-butyl 1-propenyl sulfone
    —— (E/Z)-tert-butyl 1-propenyl sulfone 105962-15-0 C7H14O2S
    (E/Z)-tert-butyl 1-propenyl sulfone
    —— 2-methyl-2-propyl 1'-propenyl sulfoxide 232265-53-1 C7H14OS
    2-methyl-2-propyl 1'-propenyl sulfoxide
    —— 2-methyl-2-propyl (E)-1'-propenyl sulfoxide 69113-53-7 C7H14OS
    2-methyl-2-propyl (E)-1'-propenyl sulfoxide
    —— 9-hexyl-6-(1-methyl-1H-tetrazol-5-ylthio)-9H-purine 1384277-46-6 C13H18N8S
    9-hexyl-6-(1-methyl-1H-tetrazol-5-ylthio)-9H-purine
    —— Phenylmercapto-cyan-acetamid 22805-16-9 C9H8N2OS
    Phenylmercapto-cyan-acetamid
    —— S-Octyl butylthiocarbamate 92412-00-5 C13H27NOS
    S-Octyl butylthiocarbamate
    —— 3,3-Bis-(2-hydroxy-ethylsulfanyl)-propionic acid methyl ester 164725-69-3 C8H16O4S2
    3,3-Bis-(2-hydroxy-ethylsulfanyl)-propionic acid methyl ester
    —— methyl 2-(5-bromo-4-ethoxy-6-ethyl-7H-pyrrolo[2,3-d]pyrimidin-2-ylthio)thiazole-4-carboxylate 1275599-13-7 C15H15BrN4O3S2
    methyl 2-(5-bromo-4-ethoxy-6-ethyl-7H-pyrrolo[2,3-d]pyrimidin-2-ylthio)thiazole-4-carboxylate
    —— methyl 2-(4-ethoxy-6-ethyl-7H-pyrrolo[2,3-d]pyrimidin-2-ylthio)thiazole-4-carboxylate 1275607-85-6 C15H16N4O3S2
    methyl 2-(4-ethoxy-6-ethyl-7H-pyrrolo[2,3-d]pyrimidin-2-ylthio)thiazole-4-carboxylate
    —— 2,3-dichloro-4-<(4-nitrophenyl)sulfenyl>phenetole 87181-25-7 C14H11Cl2NO3S
    2,3-dichloro-4-<(4-nitrophenyl)sulfenyl>phenetole
    —— 2,3-dichloro-4-<(4-nitrophenyl)sulfenyl>phenol 87181-27-9 C12H7Cl2NO3S
    2,3-dichloro-4-<(4-nitrophenyl)sulfenyl>phenol
    —— 4.5-Bis-(4-chlor-benzylmercapto)-2-phenyl-3-oxo-2.3-dihydro-pyridazin 5273-35-8 C24H18Cl2N2OS2
    4.5-Bis-(4-chlor-benzylmercapto)-2-phenyl-3-oxo-2.3-dihydro-pyridazin
    —— 1,4,7,10-Tetraoxa-15lambda6-thiacyclononadeca-12,17-diyne 15,15-dioxide 155015-38-6 C14H20O6S
    1,4,7,10-Tetraoxa-15lambda6-thiacyclononadeca-12,17-diyne 15,15-dioxide
    —— 1,1,4-trichloro-1-(phenylthio)-3,3,-dimethyl-2-butanone 146679-15-4 C12H13Cl3OS
    1,1,4-trichloro-1-(phenylthio)-3,3,-dimethyl-2-butanone
    —— Methanaminium, N-[(dimethylamino)(methylthio)methylene]-N-methyl- 54496-81-0 C6H15N2S+
    Methanaminium, N-[(dimethylamino)(methylthio)methylene]-N-methyl-
    —— 2-chloro-1-phenylthioethyl isocyanate 85212-30-2 C9H8ClNOS
    2-chloro-1-phenylthioethyl isocyanate
    —— N,N-dipropylcarbamothioate;nickel(2+) 47116-64-3 C14H28N2NiO2S2
    N,N-dipropylcarbamothioate;nickel(2+)
    —— 3-({4-[2-(diethylamino)ethoxy]phenyl}thio)-N-(3-methyl-1,2,4-thiadiazol-5-yl)-6-[(4-methyl-4H-1,2,4-triazol-3-yl)thio]pyridine-2-carboxamide 1018966-32-9 C24H28N8O2S3
    3-({4-[2-(diethylamino)ethoxy]phenyl}thio)-N-(3-methyl-1,2,4-thiadiazol-5-yl)-6-[(4-methyl-4H-1,2,4-triazol-3-yl)thio]pyridine-2-carboxamide
    —— S-3-(phenylthio)propyl-N,N-diethylthiolcarbamate 62850-35-5 C14H21NOS2
    S-3-(phenylthio)propyl-N,N-diethylthiolcarbamate
    —— Aethyl-(1-trichlormethyl-vinyl)-sulfon 98698-72-7 C5H10O2S
    Aethyl-(1-trichlormethyl-vinyl)-sulfon
    —— 2-Methylsulfonylhept-1-ene 98698-73-8 C8H16O2S
    2-Methylsulfonylhept-1-ene
    —— N,N-Diethylperfluorbutanthioamid 61881-10-5 C8H10F7NS
    N,N-Diethylperfluorbutanthioamid
    —— (Z)-1-phenylthio-2-butyl-3-phenyl-3-hydroxy-1-propene 1251831-17-0 C19H22OS
    (Z)-1-phenylthio-2-butyl-3-phenyl-3-hydroxy-1-propene
    —— chloromethyl 2-thienyl sulfide 131673-98-8 C5H5ClS2
    chloromethyl 2-thienyl sulfide
    —— 3-Methylene-2-pentyl-2,3-dihydrobenzo<b>thiophene-2-ol 146916-46-3 C14H18OS
    3-Methylene-2-pentyl-2,3-dihydrobenzo<b>thiophene-2-ol
    —— N,N-diethyl-2-[(1-pyridin-2-ylimidazol-2-yl)sulfanylmethyl]aniline 117323-04-3 C19H22N4S
    N,N-diethyl-2-[(1-pyridin-2-ylimidazol-2-yl)sulfanylmethyl]aniline
    —— 2,2-dimethyl-6-methylene-1-phenylthiomethylcyclohexane 88218-61-5 C16H22S
    2,2-dimethyl-6-methylene-1-phenylthiomethylcyclohexane
    —— N,N-diethyl-2-[[1-(3-methoxypyridin-2-yl)imidazol-2-yl]sulfanylmethyl]aniline 117323-02-1 C20H24N4OS
    N,N-diethyl-2-[[1-(3-methoxypyridin-2-yl)imidazol-2-yl]sulfanylmethyl]aniline
    —— 6-azido-2,3-dihydrobenzo<b>thiophen 89536-43-6 C8H7N3S
    6-azido-2,3-dihydrobenzo<b>thiophen
    —— γ-Isothiocyanatoallylchlorid 76855-03-3 C4H4ClNS
    γ-Isothiocyanatoallylchlorid
    —— 3-(phenylthiomethyl)pent-3-enoic acid 108378-65-0 C12H14O2S
    3-(phenylthiomethyl)pent-3-enoic acid
    —— 2,3-Dimethyl-4-phenylthio-2,5-dihydrothiophene 1,1-Dioxide 110026-90-9 C12H14O2S2
    2,3-Dimethyl-4-phenylthio-2,5-dihydrothiophene 1,1-Dioxide
    —— 1-Phenylthiooctan-2-on 71221-50-6 C14H20OS
    1-Phenylthiooctan-2-on
    —— 2-((E)-2,6-dimethyl-hepta-1,5-dienyl)-2-(3-methyl-but-2-enyl)-[1,3]dithiane 69301-62-8 C18H30S2
    2-((E)-2,6-dimethyl-hepta-1,5-dienyl)-2-(3-methyl-but-2-enyl)-[1,3]dithiane
    —— 4-Pyrimidinamine, 2-(butylthio)-6-(2-naphthalenylthio)- 284681-96-5 C18H19N3S2
    4-Pyrimidinamine, 2-(butylthio)-6-(2-naphthalenylthio)-