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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-(2-allylazetidine-1-yl)-2,2-dimethylpropane-1-thione 1228452-92-3 C11H19NS
    1-(2-allylazetidine-1-yl)-2,2-dimethylpropane-1-thione
    —— (cyclohexyl-N-thio)-1,2-ethylenediamine 959755-05-6 C9H19N3S
    (cyclohexyl-N-thio)-1,2-ethylenediamine
    —— (cyclohexyl-N-thio)-1,2-propanediamine 959755-07-8 C10H21N3S
    (cyclohexyl-N-thio)-1,2-propanediamine
    —— 1-(2-butylazetidin-1-yl)-2,2-dimethylpropane-1-thione 1228452-94-5 C12H23NS
    1-(2-butylazetidin-1-yl)-2,2-dimethylpropane-1-thione
    —— 2-methanesulfonyl-acrylic acid methyl ester 73017-61-5 C5H8O4S
    2-methanesulfonyl-acrylic acid methyl ester
    —— 5-[(3-bromophenyl)thio]-4-(2-fluoropyridin-3-yl)thiophene-2-carbaldehyde 1138034-20-4 C16H9BrFNOS2
    5-[(3-bromophenyl)thio]-4-(2-fluoropyridin-3-yl)thiophene-2-carbaldehyde
    —— 4-bromo-5-[(3-fluorophenyl)thio]thiophene-2-carbaldehyde 1138032-95-7 C11H6BrFOS2
    4-bromo-5-[(3-fluorophenyl)thio]thiophene-2-carbaldehyde
    —— 3-benzylmercapto-4-methyl-1,2,4-triazole 81678-27-5 C10H11N3S
    3-benzylmercapto-4-methyl-1,2,4-triazole
    —— 6-Methyl-2-methylsulfanyl-1,3-oxazin-4-one 93700-30-2 C6H7NO2S
    6-Methyl-2-methylsulfanyl-1,3-oxazin-4-one
    —— 4-chloro-2-(4-fluorophenylthio)-7-(2-methoxyethyl)-7H-pyrrolo[2,3-d]pyrimidine 1361961-01-4 C15H13ClFN3OS
    4-chloro-2-(4-fluorophenylthio)-7-(2-methoxyethyl)-7H-pyrrolo[2,3-d]pyrimidine
    —— (5R)-3-(4-methylthiophenyl)-5-methanesulfonyloxymethyloxazolidin-2-one 1102257-76-0 C12H15NO5S2
    (5R)-3-(4-methylthiophenyl)-5-methanesulfonyloxymethyloxazolidin-2-one
    —— 1,3-Dichlor-propanthiol-(2) 16621-51-5 C3H6Cl2S
    1,3-Dichlor-propanthiol-(2)
    —— N-Isobutyl-N'-sek.-butyl-thioharnstoff 74177-91-6 C9H20N2S
    N-Isobutyl-N'-sek.-butyl-thioharnstoff
    —— Thiopropionsaeure-isobutylamid 5827-76-9 C7H15NS
    Thiopropionsaeure-isobutylamid
    —— amino (NZ)-N-[(3-methyl-4-methylsulfanylphenyl)methylidene]carbamimidothioate 5408-41-3 C10H13N3S2
    amino (NZ)-N-[(3-methyl-4-methylsulfanylphenyl)methylidene]carbamimidothioate
    —— [1-(2-butyl-1,3-dithian-2-yl)-4,4,4-tris(methylthio)butan-2-yloxy]trimethylsilane 1216983-35-5 C18H38OS5Si
    [1-(2-butyl-1,3-dithian-2-yl)-4,4,4-tris(methylthio)butan-2-yloxy]trimethylsilane
    —— 1,1-Dimethyl-2-(2,2,2-trifluoro-1-((2,2,2-trifluoro-N,N-dimethylethanehydrazonoyl)dithio)ethylidene)hydrazine 4503-67-7 C8H12F6N4S2
    1,1-Dimethyl-2-(2,2,2-trifluoro-1-((2,2,2-trifluoro-N,N-dimethylethanehydrazonoyl)dithio)ethylidene)hydrazine
    —— 1-Fluoro-4-[(3,5-difluorophenyl)sulfanylmethyl]benzene 1443314-20-2 C13H9F3S
    1-Fluoro-4-[(3,5-difluorophenyl)sulfanylmethyl]benzene
    —— 2-amino-2-(phenylthio)midazo<1,2-a>pyridine 76911-31-4 C13H11N3S
    2-amino-2-(phenylthio)midazo<1,2-a>pyridine
    —— 6-[(E)-3-oxodec-1-enyl]sulfanyl-2H-1,2,4-triazine-3,5-dione 80037-04-3 C13H19N3O3S
    6-[(E)-3-oxodec-1-enyl]sulfanyl-2H-1,2,4-triazine-3,5-dione
    —— O-methyl O-octyl thiocarbonate 1051374-75-4 C10H20O2S
    O-methyl O-octyl thiocarbonate
    —— methyl 5-(phenylthio)imidazo[1,2-a]pyridine-2-carbamate 76911-32-5 C15H13N3O2S
    methyl 5-(phenylthio)imidazo[1,2-a]pyridine-2-carbamate
    —— 3-amino-5-(phenylthio)imidazo<1,2-a>pyridine 79508-14-8 C13H11N3S
    3-amino-5-(phenylthio)imidazo<1,2-a>pyridine
    —— 6-[[(4R,5R)-5-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]-2,2-dimethyl-1,3-dioxolan-4-yl]methylsulfanyl]-5-nitro-1H-pyrimidine-2,4-dione 952288-35-6 C15H21N3O8S
    6-[[(4R,5R)-5-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]-2,2-dimethyl-1,3-dioxolan-4-yl]methylsulfanyl]-5-nitro-1H-pyrimidine-2,4-dione
    —— 2,2,N-trimethylthiopropanamide 5260-01-5 C6H13NS
    2,2,N-trimethylthiopropanamide
    —— 6-methylsulfanyl-5-nitro-1H-pyrimidine-2,4-dione 1451885-57-6 C5H5N3O4S
    6-methylsulfanyl-5-nitro-1H-pyrimidine-2,4-dione
    —— methyl ester of 2-N-methylamino-1-cyclopentene-1-dithiocarboxylic acid 34281-25-9 C8H13NS2
    methyl ester of 2-N-methylamino-1-cyclopentene-1-dithiocarboxylic acid
    —— (E)-5-isothiocyanatooct-3-ene 87656-59-5 C9H15NS
    (E)-5-isothiocyanatooct-3-ene
    —— 5-methyl-2-(phenylthio)-2-(trimethylsilylmethyl)hexanenitrile 77412-11-4 C17H27NSSi
    5-methyl-2-(phenylthio)-2-(trimethylsilylmethyl)hexanenitrile
    —— (6Z,9Z,28Z,31Z)-heptatriaconta-6,9,28,31-tetraene-19-thiol 1226780-13-7 C37H68S
    (6Z,9Z,28Z,31Z)-heptatriaconta-6,9,28,31-tetraene-19-thiol
    —— 5-methyl-2-(phenylthio)-2-(trimethylsilylmethyl)hexan-1-ol 77412-19-2 C17H30OSSi
    5-methyl-2-(phenylthio)-2-(trimethylsilylmethyl)hexan-1-ol
    —— methyl 5-methyl-2-phenylthio-2-prop-2-enylhexan-2-oate 109542-10-1 C17H24O2S
    methyl 5-methyl-2-phenylthio-2-prop-2-enylhexan-2-oate
    —— 5-methyl-1-(phenylthio)-2-(trimethylsilylmethyl)hex-2-ene 77412-06-7 C17H28SSi
    5-methyl-1-(phenylthio)-2-(trimethylsilylmethyl)hex-2-ene
    —— 6-methyl-3-(phenylthio)-3-(trimethylsilylmethyl)heptan-2-ol 77412-03-4 C18H32OSSi
    6-methyl-3-(phenylthio)-3-(trimethylsilylmethyl)heptan-2-ol
    —— N-[2-({7-[3-(Diethylamino)propoxy]-6-methoxy-4-quinolyl}sulfanyl)-1,3-thiazol-5-yl]-N'-(4-fluorophenyl)urea 417715-51-6 C27H30FN5O3S2
    N-[2-({7-[3-(Diethylamino)propoxy]-6-methoxy-4-quinolyl}sulfanyl)-1,3-thiazol-5-yl]-N'-(4-fluorophenyl)urea
    —— 3-[2-(3-fluoro-phenylsulfanyl)-phenyl]-propionic acid 791642-73-4 C15H13FO2S
    3-[2-(3-fluoro-phenylsulfanyl)-phenyl]-propionic acid
    —— N,N-Diethyl-N-[3-({6-methoxy-4-[(5-nitro-1,3-thiazol-2-yl)sulfanyl]-7-quinolyl}oxy)propyl]amine 417722-37-3 C20H24N4O4S2
    N,N-Diethyl-N-[3-({6-methoxy-4-[(5-nitro-1,3-thiazol-2-yl)sulfanyl]-7-quinolyl}oxy)propyl]amine
    —— 4-Methylsulfanyl-6-propyl-1H-pyrimidin-2-one 175354-51-5 C8H12N2OS
    4-Methylsulfanyl-6-propyl-1H-pyrimidin-2-one
    —— 2-nitro-5-(3-hydroxyphenylthio)-p-xylene 1374025-94-1 C14H13NO3S
    2-nitro-5-(3-hydroxyphenylthio)-p-xylene
    —— Tris-methylthiomethyl-amin 82971-98-0 C6H15NS3
    Tris-methylthiomethyl-amin
    —— 5-phenylthio-6-azaoxindole 136888-39-6 C13H10N2OS
    5-phenylthio-6-azaoxindole
    —— cyclobutyl(p-tolyl)sulfane 16769-08-7 C11H14S
    cyclobutyl(p-tolyl)sulfane
    —— 2,2'-di(phenylthio)diethylselenide 55110-85-5 C16H18S2Se
    2,2'-di(phenylthio)diethylselenide
    —— 2-Ethenylselanylethylsulfanylbenzene 90053-42-2 C10H12SSe
    2-Ethenylselanylethylsulfanylbenzene
    —— 1-thia-4-selenacyclohexadiene 290-82-4 C4H4SSe
    1-thia-4-selenacyclohexadiene
    —— 2-(methylthio)-4-(4-methyl-3-pentenyl)furan 84735-64-8 C11H16OS
    2-(methylthio)-4-(4-methyl-3-pentenyl)furan
    —— 1-Fluoro-4-[(3-fluorophenyl)sulfanylmethyl]benzene 1443351-96-9 C13H10F2S
    1-Fluoro-4-[(3-fluorophenyl)sulfanylmethyl]benzene
    —— 2-bromo-5-isopropylsulfanyl-pyridine 1349770-67-7 C8H10BrNS
    2-bromo-5-isopropylsulfanyl-pyridine
    —— 2-methylthio-5-methyl-6-[1-(4-fluorophenyl)-1-hydroxymethyl]-4(3H)-pyrimidinone 948859-53-8 C13H13FN2O2S
    2-methylthio-5-methyl-6-[1-(4-fluorophenyl)-1-hydroxymethyl]-4(3H)-pyrimidinone
    —— 6,6-Bis(phenylsulfanyl)hex-4-ynylbenzene 114245-27-1 C24H22S2
    6,6-Bis(phenylsulfanyl)hex-4-ynylbenzene