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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-[2'-(tert-butylsulfanyl)phenyl]-4-phenylbutan-2-one 765292-71-5 C20H24OS
    1-[2'-(tert-butylsulfanyl)phenyl]-4-phenylbutan-2-one
    —— 2-[2'-(tert-butylsulfanyl)phenyl]-1,3-dithiane 765292-68-0 C14H20S3
    2-[2'-(tert-butylsulfanyl)phenyl]-1,3-dithiane
    —— S-<2-Ethyl-butyl>-thiophenol 13921-07-8 C12H18S
    S-<2-Ethyl-butyl>-thiophenol
    —— Bis(2-methyl-2-propenyl) sulfoxide 90112-55-3 C8H14OS
    Bis(2-methyl-2-propenyl) sulfoxide
    —— 1,1,1,3,3,3-hexafluoropropan-2-yl 3-((2-aminophenyl)thio)-3-phenylpropanoate 1443456-10-7 C18H15F6NO2S
    1,1,1,3,3,3-hexafluoropropan-2-yl 3-((2-aminophenyl)thio)-3-phenylpropanoate
    —— (R)-3-((2-aminophenyl)thio)-N,N-dimethyl-3-phenylpropanethioamide 1402449-09-5 C17H20N2S2
    (R)-3-((2-aminophenyl)thio)-N,N-dimethyl-3-phenylpropanethioamide
    —— (Z)-1,4-bis(ethylsulfanyl)but-2-ene 90224-13-8 C8H16S2
    (Z)-1,4-bis(ethylsulfanyl)but-2-ene
    —— 2-(neopentylsulfonyl)acetic acid 1391715-40-4 C7H14O4S
    2-(neopentylsulfonyl)acetic acid
    —— 1-bromo-2-methyl-3-(methylthio)benzene 871352-93-1 C8H9BrS
    1-bromo-2-methyl-3-(methylthio)benzene
    —— 7-bromobenzo[b]thiophen-3(2H)-one 72002-05-2 C8H5BrOS
    7-bromobenzo[b]thiophen-3(2H)-one
    —— 2H,3H,4H-pyrido[3,2-e][1,3]thiazin-4-one 118966-15-7 C7H6N2OS
    2H,3H,4H-pyrido[3,2-e][1,3]thiazin-4-one
    —— (2E)-2-[1-(Phenylsulfanyl)propan-2-ylidene]hydrazine-1-carboxamide 5042-49-9 C10H13N3OS
    (2E)-2-[1-(Phenylsulfanyl)propan-2-ylidene]hydrazine-1-carboxamide
    —— Tert-butyl 2-(4,5-dimethyl-1,3-dithiol-2-ylidene)-4,6-dimethyl-[1,3]dithiolo[4,5-c]pyrrole-5-carboxylate 188014-43-9 C17H21NO2S4
    Tert-butyl 2-(4,5-dimethyl-1,3-dithiol-2-ylidene)-4,6-dimethyl-[1,3]dithiolo[4,5-c]pyrrole-5-carboxylate
    —— 2-(4,5-dimethyl-1,3-dithiol-2-ylidene)-4,6-dimethyl-5H-[1,3]dithiolo[4,5-c]pyrrole 188014-42-8 C12H13NS4
    2-(4,5-dimethyl-1,3-dithiol-2-ylidene)-4,6-dimethyl-5H-[1,3]dithiolo[4,5-c]pyrrole
    —— 3-phenyl-N-phenylmethoxy-3-phenylsulfanylpropanamide 851228-39-2 C22H21NO2S
    3-phenyl-N-phenylmethoxy-3-phenylsulfanylpropanamide
    —— N',N'-Bis-(3-chlor-cis-allyl)-N-sulfinyl-hydrazin 20582-07-4 C6H8Cl2N2OS
    N',N'-Bis-(3-chlor-cis-allyl)-N-sulfinyl-hydrazin
    —— (S)-N-(1-phenylethyl)-3-(phenylthio)propanamide 496944-31-1 C17H19NOS
    (S)-N-(1-phenylethyl)-3-(phenylthio)propanamide
    —— dimethyl (2S)-2-hydroxy-2-[(4-methylphenyl)sulfenylmethyl]hexanedioate 1067938-41-3 C16H22O5S
    dimethyl (2S)-2-hydroxy-2-[(4-methylphenyl)sulfenylmethyl]hexanedioate
    —— N-((1S)-1-phenylethyl)-2-(2-pyridinylsulfanyl)-(4R)-4-(1H-pyrrol-1-yl)heptanamide 415696-78-5 C24H29N3OS
    N-((1S)-1-phenylethyl)-2-(2-pyridinylsulfanyl)-(4R)-4-(1H-pyrrol-1-yl)heptanamide
    —— (E)-1-(3-((3-(morpholinomethyl)quinolin-6-yl)thio)[1,2,4]triazolo[4,3-a]pyridin-6-yl)ethanone O-(2-hydroxyethyl) oxime 1427473-57-1 C24H26N6O3S
    (E)-1-(3-((3-(morpholinomethyl)quinolin-6-yl)thio)[1,2,4]triazolo[4,3-a]pyridin-6-yl)ethanone O-(2-hydroxyethyl) oxime
    —— methyl (5S)-6-amino-5-hydroxy-5-[(4-methylphenyl)sulfenylmethyl]-6-oxohexanoate 1067938-30-0 C15H21NO4S
    methyl (5S)-6-amino-5-hydroxy-5-[(4-methylphenyl)sulfenylmethyl]-6-oxohexanoate
    —— thiacyclopentadeca-3,13-diyne-1,1-dioxide 514853-64-6 C14H20O2S
    thiacyclopentadeca-3,13-diyne-1,1-dioxide
    —— 7-(1-hydroxy-2-methylthioethyl)-2,2-dimethyl-3-oxa-7-phenylthio-1-azabicyclo<4.2.0>octan-8-one 98827-08-8 C17H23NO3S2
    7-(1-hydroxy-2-methylthioethyl)-2,2-dimethyl-3-oxa-7-phenylthio-1-azabicyclo<4.2.0>octan-8-one
    —— 2,5-bis-methylsulfanyl-3,4-dihydro-2<i>H</i>-pyran-2-carbaldehyde 64199-32-2 C8H12O2S2
    2,5-bis-methylsulfanyl-3,4-dihydro-2<i>H</i>-pyran-2-carbaldehyde
    —— 1-[(2-hydroxy-2-phenyl-1-phenylsulfanyl)ethyl]cyclohexanol 253797-51-2 C20H24O2S
    1-[(2-hydroxy-2-phenyl-1-phenylsulfanyl)ethyl]cyclohexanol
    —— 1-Chloro-1-octylsulfonylsulfanyloctane 92807-04-0 C16H33ClO2S2
    1-Chloro-1-octylsulfonylsulfanyloctane
    —— 2,5-bis-(1,1-dimethyl-propylsulfanyl)-3,4-dihydro-2<i>H</i>-pyran-2-carbaldehyde 64199-35-5 C16H28O2S2
    2,5-bis-(1,1-dimethyl-propylsulfanyl)-3,4-dihydro-2<i>H</i>-pyran-2-carbaldehyde
    —— (1,1-dimethyl-propylsulfanyl)-acetaldehyde 64199-30-0 C7H14OS
    (1,1-dimethyl-propylsulfanyl)-acetaldehyde
    —— 2-Formyl-2,5-diisobutylthio-2,3-dihydro-4H-pyran 64199-34-4 C14H24O2S2
    2-Formyl-2,5-diisobutylthio-2,3-dihydro-4H-pyran
    —— isobutylsulfanyl-acetaldehyde 64199-29-7 C6H12OS
    isobutylsulfanyl-acetaldehyde
    —— 2-fluoro-5-phenylthiopyridine 344781-88-0 C11H8FNS
    2-fluoro-5-phenylthiopyridine
    —— 6-methyl-3-(2-methylphenyl)-2-methylthio-4(3H)-pyrimidinone 89069-38-5 C13H14N2OS
    6-methyl-3-(2-methylphenyl)-2-methylthio-4(3H)-pyrimidinone
    —— 3-(4-methylphenyl)-2-methylthio-4(3H)-pyrimidinone 89069-26-1 C12H12N2OS
    3-(4-methylphenyl)-2-methylthio-4(3H)-pyrimidinone
    —— 9-Thiabicyclo[6.2.0]deca-1(8), 9,9-dioxide 20452-34-0 C9H12O2S
    9-Thiabicyclo[6.2.0]deca-1(8), 9,9-dioxide
    —— Trimethoxy-p-tolylthiomethyl-silan 70615-95-1 C11H18O3SSi
    Trimethoxy-p-tolylthiomethyl-silan
    —— phenyl(trimethoxysilylmethyl)sulfide 57557-71-8 C10H16O3SSi
    phenyl(trimethoxysilylmethyl)sulfide
    —— (E)-1-(3-(3-(morpholinomethyl)quinolin-6-ylthio)[1,2,4]triazolo[4,3-a]pyridin-6-yl)ethanone oxime 1427473-56-0 C22H22N6O2S
    (E)-1-(3-(3-(morpholinomethyl)quinolin-6-ylthio)[1,2,4]triazolo[4,3-a]pyridin-6-yl)ethanone oxime
    —— 2-[(Z)-2-propan-2-ylsulfonylethenyl]sulfonylpropane 93114-10-4 C8H16O4S2
    2-[(Z)-2-propan-2-ylsulfonylethenyl]sulfonylpropane
    —— 2,4-dimethoxy-6,4'-dimethyldiphenyl thioether 1296142-89-6 C16H18O2S
    2,4-dimethoxy-6,4'-dimethyldiphenyl thioether
    —— 2-Hexyl-2-propyl-1,3-dithiolane 90692-04-9 C12H24S2
    2-Hexyl-2-propyl-1,3-dithiolane
    —— 2-Hexyl-2-propyl-1,3-dithiane 74327-18-7 C13H26S2
    2-Hexyl-2-propyl-1,3-dithiane
    —— 10-undecenedithioic acid 131264-71-6 C11H20S2
    10-undecenedithioic acid
    —— 9-decenyl 10-undecenedithioate 131264-73-8 C21H38S2
    9-decenyl 10-undecenedithioate
    —— methyl 2-fluoro-4-[7-(quinolin-6-ylthio)imidazo[1,2-b][1,2,4]triazin-2-yl]benzoate 1029712-86-4 C22H14FN5O2S
    methyl 2-fluoro-4-[7-(quinolin-6-ylthio)imidazo[1,2-b][1,2,4]triazin-2-yl]benzoate
    —— 3-(Phenylthio)-2-piperidone 104261-03-2 C11H13NOS
    3-(Phenylthio)-2-piperidone
    —— cis-1,2-bis(Ethylsulfonyl)ethen 15383-59-2 C6H12O4S2
    cis-1,2-bis(Ethylsulfonyl)ethen
    —— (4-methylphenyl) (1Z)-N-hydroxy-2-methylpropanimidothioate 713-77-9 C11H15NOS
    (4-methylphenyl) (1Z)-N-hydroxy-2-methylpropanimidothioate
    —— 2-chloro-N-methyl-N-(2-phenylcyclohex-2-en-1-yl)-2-phenylsulfanylacetamide 147949-58-4 C21H22ClNOS
    2-chloro-N-methyl-N-(2-phenylcyclohex-2-en-1-yl)-2-phenylsulfanylacetamide
    —— 20-mercapto-eicosane-1-ol 149340-92-1 C20H42OS
    20-mercapto-eicosane-1-ol
    —— 3-bromo-2,5-bis(methylthio)thiophene 152570-31-5 C6H7BrS3
    3-bromo-2,5-bis(methylthio)thiophene