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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(7-iodo-2,3-dihydrobenzo[b][1,4]dioxin-6-ylthio)-1-(pent-4-ynyl)-1H-imidazo[4,5-c]pyridin-4-amine 1061316-67-3 C19H17IN4O2S
    2-(7-iodo-2,3-dihydrobenzo[b][1,4]dioxin-6-ylthio)-1-(pent-4-ynyl)-1H-imidazo[4,5-c]pyridin-4-amine
    —— 2-chloro-4-fluoro-1-methylsulfanylbenzene 917761-33-2 C7H6ClFS
    2-chloro-4-fluoro-1-methylsulfanylbenzene
    —— 6-Phenylsulfanyl-1,4,4a,8a-tetrahydro-1,4-methano-naphthalene-5,8-dione 95333-41-8 C17H14O2S
    6-Phenylsulfanyl-1,4,4a,8a-tetrahydro-1,4-methano-naphthalene-5,8-dione
    —— N,N,N',N'-Tetrakis-[2-(4-chloro-phenylsulfanyl)-ethyl]-succinamide 61455-09-2 C36H36Cl4N2O2S4
    N,N,N',N'-Tetrakis-[2-(4-chloro-phenylsulfanyl)-ethyl]-succinamide
    —— 2H,3H-benzo<1,2-b:4,3:b'>bisthiete 220398-60-7 C8H6S2
    2H,3H-benzo<1,2-b:4,3:b'>bisthiete
    —— 5-bromo-3-methyl-6-phenylthiouracil 81077-92-1 C11H9BrN2O2S
    5-bromo-3-methyl-6-phenylthiouracil
    —— (3,3-Dimethyl-2-phenylsulfanylmethyl-cyclohex-1-enyl)-methanol 81054-02-6 C16H22OS
    (3,3-Dimethyl-2-phenylsulfanylmethyl-cyclohex-1-enyl)-methanol
    —— 1,5-dithia-spiro[5.5]undecan-8-ol 68972-10-1 C9H16OS2
    1,5-dithia-spiro[5.5]undecan-8-ol
    —— cobalt(2+);tetrathiocyanate —— C4CoN4S4-2
    cobalt(2+);tetrathiocyanate
    —— 3-(5-methyl-1,3,4-thiadiazol-2-mercapto)-propionitrile 132432-21-4 C6H7N3S2
    3-(5-methyl-1,3,4-thiadiazol-2-mercapto)-propionitrile
    —— 1-(methylthio)oct-2-ene 91944-69-3 C9H18S
    1-(methylthio)oct-2-ene
    —— 6,6-dimethyl-2-phenylthiomethyl-1-cyclohexencarboxaldehyde 126087-75-0 C16H20OS
    6,6-dimethyl-2-phenylthiomethyl-1-cyclohexencarboxaldehyde
    —— 1-methoxy-1-(phenylthio)-1,3-pentadiene 93500-44-8 C12H14OS
    1-methoxy-1-(phenylthio)-1,3-pentadiene
    —— 1-Methyl-3-methylmercapto-1,2,4-triazolon (5) 53065-41-1 C4H7N3OS
    1-Methyl-3-methylmercapto-1,2,4-triazolon (5)
    —— 5-Mercaptomethyldihydro-1,2,4-triazolon-3 53065-40-0 C3H5N3OS
    5-Mercaptomethyldihydro-1,2,4-triazolon-3
    —— <i>N</i>-ethyl-4-(4-nitro-phenylsulfanyl)-aniline 5786-51-6 C14H14N2O2S
    <i>N</i>-ethyl-4-(4-nitro-phenylsulfanyl)-aniline
    —— (1R,2R)-1-(R)-1,4-Dioxa-spiro[4.5]dec-2-yl-2-methoxy-2-phenylsulfanyl-ethanol 134678-19-6 C17H24O4S
    (1R,2R)-1-(R)-1,4-Dioxa-spiro[4.5]dec-2-yl-2-methoxy-2-phenylsulfanyl-ethanol
    —— tert-Butyl-{(Z)-1-tert-butyl-3-[1-(methoxy-phenylsulfanyl-methyl)-heptyloxy]-propenyloxy}-dimethyl-silane 200347-28-0 C28H50O3SSi
    tert-Butyl-{(Z)-1-tert-butyl-3-[1-(methoxy-phenylsulfanyl-methyl)-heptyloxy]-propenyloxy}-dimethyl-silane
    —— (E)-1-methoxy-3-methyl-1-(phenylthio)but-1-ene 93500-48-2 C12H16OS
    (E)-1-methoxy-3-methyl-1-(phenylthio)but-1-ene
    —— (1-Methoxy-heptylsulfanyl)-benzene 89423-38-1 C14H22OS
    (1-Methoxy-heptylsulfanyl)-benzene
    —— (1-Methoxy-4-methyl-pent-3-enylsulfanyl)-benzene 116204-90-1 C13H18OS
    (1-Methoxy-4-methyl-pent-3-enylsulfanyl)-benzene
    —— 5H,7H-Dibenzo<b,g><1,5>dithiocin 6-oxide 103896-92-0 C14H12OS2
    5H,7H-Dibenzo<b,g><1,5>dithiocin 6-oxide
    —— (2R,4aR,5S,7R,8aR,9aS,10aR)-5-(tert-Butyl-dimethyl-silanyloxy)-7-[2-(tert-butyl-diphenyl-silanyloxymethyl)-allyl]-3,3-bis-ethylsulfanyl-10a-methyl-decahydro-1,8,10-trioxa-anthracene-2-carbaldehyde 807616-67-7 C43H66O6S2Si2
    (2R,4aR,5S,7R,8aR,9aS,10aR)-5-(tert-Butyl-dimethyl-silanyloxy)-7-[2-(tert-butyl-diphenyl-silanyloxymethyl)-allyl]-3,3-bis-ethylsulfanyl-10a-methyl-decahydro-1,8,10-trioxa-anthracene-2-carbaldehyde
    —— Cyclohexyl-phenylsulfanyl-acetaldehyde 115205-38-4 C14H18OS
    Cyclohexyl-phenylsulfanyl-acetaldehyde
    —— Acetic acid 2-furan-3-yl-2-phenylsulfanyl-ethyl ester 117770-29-3 C14H14O3S
    Acetic acid 2-furan-3-yl-2-phenylsulfanyl-ethyl ester
    —— N-(2-fluoro-4-phenylsulphanylphenyl)-2-hydroxy-2-methylpropanamide 252016-95-8 C16H16FNO2S
    N-(2-fluoro-4-phenylsulphanylphenyl)-2-hydroxy-2-methylpropanamide
    —— o-decylthioaniline 141945-26-8 C16H27NS
    o-decylthioaniline
    —— 1-methoxy-2-phenyl-1-(phenylthio)-2-propanol 78614-66-1 C16H18O2S
    1-methoxy-2-phenyl-1-(phenylthio)-2-propanol
    —— 2-(4-bromo-phenylsulfanyl)benzoic acid benzyl ester 1005513-47-2 C20H15BrO2S
    2-(4-bromo-phenylsulfanyl)benzoic acid benzyl ester
    —— α-Methoxy-aethyl-phenyl-sulfid 10429-09-1 C9H12OS
    α-Methoxy-aethyl-phenyl-sulfid
    —— 3-mercapto-5,5-dimethyl-2-cyclohexenethione 73705-06-3 C8H12S2
    3-mercapto-5,5-dimethyl-2-cyclohexenethione
    —— 1-Methoxy-4-methyl-1-phenylsulfanylpentan-2-ol 200347-22-4 C13H20O2S
    1-Methoxy-4-methyl-1-phenylsulfanylpentan-2-ol
    —— 2-methyl-2-<3'(1,3-dithiolanyl)octyl>thiazolidine 156000-20-3 C14H27NS3
    2-methyl-2-<3'(1,3-dithiolanyl)octyl>thiazolidine
    —— diethyl 2,5-bis(o-hexylthioanilino)-3,6-dihydroterephthalate 141945-27-9 C36H50N2O4S2
    diethyl 2,5-bis(o-hexylthioanilino)-3,6-dihydroterephthalate
    —— diethyl 2,5-bis(o-decylthioanilino)-3,6-dihydroterephthalate 141945-29-1 C44H66N2O4S2
    diethyl 2,5-bis(o-decylthioanilino)-3,6-dihydroterephthalate
    —— 3-({2-[(1-benzofuran-2-ylsulfonyl)amino]-4-chlorophenyl}sulfanyl)benzoic acid 1451261-80-5 C21H14ClNO5S2
    3-({2-[(1-benzofuran-2-ylsulfonyl)amino]-4-chlorophenyl}sulfanyl)benzoic acid
    —— 1-(2-Aminobenzyl)-5-(3,5-dichlorophenylthio)-2-(2-carbamoyloxyethyl)-4-isopropyl-1H-imidazole 178980-38-6 C22H24Cl2N4O2S
    1-(2-Aminobenzyl)-5-(3,5-dichlorophenylthio)-2-(2-carbamoyloxyethyl)-4-isopropyl-1H-imidazole
    —— 2-pentyl-2-<3'(1,3-dithiolanyl)butyl>thiazolidine 156000-19-0 C14H27NS3
    2-pentyl-2-<3'(1,3-dithiolanyl)butyl>thiazolidine
    —— N-[2-[(2,4-difluorophenyl)thio]-4-oxo-6-phenylthieno[2,3-d]pyrimidin-3(4H)-yl]methanesulfonamide 1415720-12-5 C19H13F2N3O3S3
    N-[2-[(2,4-difluorophenyl)thio]-4-oxo-6-phenylthieno[2,3-d]pyrimidin-3(4H)-yl]methanesulfonamide
    —— N-[2-[(2,4-difluorophenyl)thio]-4-oxothieno[3,2-d]pyrimidin-3(4H)-yl]methanesulfonamide 1018471-33-4 C13H9F2N3O3S3
    N-[2-[(2,4-difluorophenyl)thio]-4-oxothieno[3,2-d]pyrimidin-3(4H)-yl]methanesulfonamide
    —— 2-(2-Carbamoyloxyethyl)-5-(3,5-dichlorophenylthio)-4-isopropyl-1-(o-nitrobenzyl)-1H-imidazole 178980-65-9 C22H22Cl2N4O4S
    2-(2-Carbamoyloxyethyl)-5-(3,5-dichlorophenylthio)-4-isopropyl-1-(o-nitrobenzyl)-1H-imidazole
    —— methyl 3-((4-chloro-2-nitrophenyl)thio)benzoate 1451261-92-9 C14H10ClNO4S
    methyl 3-((4-chloro-2-nitrophenyl)thio)benzoate
    —— 1-(3-Aminobenzyl)-5-(3,5-dichlorophenylthio)-2-(2-carbamoyloxyethyl)-4-isopropyl-1H-imidazole 178980-36-4 C22H24Cl2N4O2S
    1-(3-Aminobenzyl)-5-(3,5-dichlorophenylthio)-2-(2-carbamoyloxyethyl)-4-isopropyl-1H-imidazole
    —— (1SR,2RS)-2-methyl-1-(phenylthiomethyl)cyclooctanol 125335-00-4 C16H24OS
    (1SR,2RS)-2-methyl-1-(phenylthiomethyl)cyclooctanol
    —— 5-(3,5-Dichlorophenylthio)-2-(2-hydroxyethyl)-4-isopropyl-1-m-nitrobenzyl-1H-imidazole 178980-68-2 C21H21Cl2N3O3S
    5-(3,5-Dichlorophenylthio)-2-(2-hydroxyethyl)-4-isopropyl-1-m-nitrobenzyl-1H-imidazole
    —— 5-(3,5-Dichlorophenylthio)-2-(2-hydroxyethyl)-4-isopropyl-1-o-nitrobenzyl-1H-imidazole 178980-67-1 C21H21Cl2N3O3S
    5-(3,5-Dichlorophenylthio)-2-(2-hydroxyethyl)-4-isopropyl-1-o-nitrobenzyl-1H-imidazole
    —— 8-methyl-1-(phenylthiomethyl)cyclooctene 125335-12-8 C16H22S
    8-methyl-1-(phenylthiomethyl)cyclooctene
    —— 2-(3-(1-carboxy-1-methyl(ethylsulfanyl))-phenylsulfanyl)-2-methylpropanoic acid 694520-72-4 C14H18O4S2
    2-(3-(1-carboxy-1-methyl(ethylsulfanyl))-phenylsulfanyl)-2-methylpropanoic acid
    —— 4,4'Thiobis-(2-methyl-6-tert.-butylanisol) 54519-54-9 C24H34O2S
    4,4'Thiobis-(2-methyl-6-tert.-butylanisol)
    —— (S)-3-((S)-1-Methyl-2-oxo-cyclohexyl)-2-phenylsulfanyl-propionic acid methyl ester 118664-20-3 C17H22O3S
    (S)-3-((S)-1-Methyl-2-oxo-cyclohexyl)-2-phenylsulfanyl-propionic acid methyl ester