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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-(4-Methoxy-phenyl)-N-(3-phenylsulfanyl-1H-indol-2-ylmethyl)-acetamide 171618-56-7 C24H22N2O2S
    N-(4-Methoxy-phenyl)-N-(3-phenylsulfanyl-1H-indol-2-ylmethyl)-acetamide
    —— 1-phenylsulfonyl-2-(2,4-dimethylbenzyl)-3-(phenylthio)-1H-indole 1150111-64-0 C29H25NO2S2
    1-phenylsulfonyl-2-(2,4-dimethylbenzyl)-3-(phenylthio)-1H-indole
    —— 1-phenylsulfonyl-2-(2,4,6-trimethylbenzyl)-3-(phenylthio)-1H-indole 1150111-66-2 C30H27NO2S2
    1-phenylsulfonyl-2-(2,4,6-trimethylbenzyl)-3-(phenylthio)-1H-indole
    —— 1-phenylsulfonyl-2-(2,5-dimethylbenzyl)-3-(phenylthio)-1H-indole 870639-67-1 C29H25NO2S2
    1-phenylsulfonyl-2-(2,5-dimethylbenzyl)-3-(phenylthio)-1H-indole
    —— 1-Benzenesulfonyl-2-(4-bromo-2,5-dimethoxy-benzyl)-3-phenylsulfanyl-1H-indole 144465-25-8 C29H24BrNO4S2
    1-Benzenesulfonyl-2-(4-bromo-2,5-dimethoxy-benzyl)-3-phenylsulfanyl-1H-indole
    —— 2-((3-aminophenyl)thio)ethanol 27122-79-8 C8H11NOS
    2-((3-aminophenyl)thio)ethanol
    —— 1-chloro-12H-quinoxalino<2,3-b><1,4>benzothiazine 110744-29-1 C14H8ClN3S
    1-chloro-12H-quinoxalino<2,3-b><1,4>benzothiazine
    —— Methylsulfinylmethylacetat 13921-25-0 C4H8O3S
    Methylsulfinylmethylacetat
    —— (1-Benzenesulfonyl-5-methoxy-3-phenylsulfanyl-1H-indol-2-ylmethyl)-phosphonic acid diethyl ester 98055-15-3 C26H28NO6PS2
    (1-Benzenesulfonyl-5-methoxy-3-phenylsulfanyl-1H-indol-2-ylmethyl)-phosphonic acid diethyl ester
    —— 3-ethyl-7,8,9,10,11,11a-hexahydro-6<i>H</i>-cycloocta[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine 60060-37-9 C12H18N4S
    3-ethyl-7,8,9,10,11,11a-hexahydro-6<i>H</i>-cycloocta[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine
    —— 6-(5-Methoxy-3-phenylsulfanyl-1H-indol-2-yl)-5H-[1,3]dioxolo[4,5-f]indole 156749-38-1 C24H18N2O3S
    6-(5-Methoxy-3-phenylsulfanyl-1H-indol-2-yl)-5H-[1,3]dioxolo[4,5-f]indole
    —— 2-Methylthio-4-methyl-imidazol 14395-85-8 C5H8N2S
    2-Methylthio-4-methyl-imidazol
    —— 1,4-bis(5-amino-6-cyano-2-oxo-thiopyrano[2,3-d]thiazolyl)benzene 1019848-49-7 C20H12N6O2S4
    1,4-bis(5-amino-6-cyano-2-oxo-thiopyrano[2,3-d]thiazolyl)benzene
    —— 2-ethylthio-2-methyl-5-phenyltetrahydrofuran 164113-08-0 C13H18OS
    2-ethylthio-2-methyl-5-phenyltetrahydrofuran
    —— 2-{[2-chloro-4-(methylsulfonyl)phenyl]thio}-4-fluorophenol 847148-90-7 C13H10ClFO3S2
    2-{[2-chloro-4-(methylsulfonyl)phenyl]thio}-4-fluorophenol
    —— 1,4-bis[6-ethoxycarbonyl-2-oxo-3,5,6,7-tetrahydro-2H-thiopyrano[2,3-d]thiazolyl]benzene 1019848-47-5 C24H24N2O6S4
    1,4-bis[6-ethoxycarbonyl-2-oxo-3,5,6,7-tetrahydro-2H-thiopyrano[2,3-d]thiazolyl]benzene
    —— Trimethylstannanylium;thiocyanate —— C4H9NSSn
    Trimethylstannanylium;thiocyanate
    —— 5-(6-methyl-2,4-dioxo-1,2,3,4-tetrahydro-3-pyrimidinyl)-methyl-2-methylsulfanyl-1,3,4-oxadiazole 445467-14-1 C9H10N4O3S
    5-(6-methyl-2,4-dioxo-1,2,3,4-tetrahydro-3-pyrimidinyl)-methyl-2-methylsulfanyl-1,3,4-oxadiazole
    —— 2-<4-(phenylthio)phenyl>ethanol 102293-53-8 C14H14OS
    2-<4-(phenylthio)phenyl>ethanol
    —— Chloro-[2-(4-phenylsulfanyl-phenyl)-ethylsulfanyl]-acetic acid ethyl ester 107291-87-2 C18H19ClO2S2
    Chloro-[2-(4-phenylsulfanyl-phenyl)-ethylsulfanyl]-acetic acid ethyl ester
    —— ethyl <4-(phenylthio)phenyl>acetate 74002-18-9 C16H16O2S
    ethyl <4-(phenylthio)phenyl>acetate
    —— 7-Phenylsulfanyl-isothiochroman-1-carboxylic acid ethyl ester 107291-95-2 C18H18O2S2
    7-Phenylsulfanyl-isothiochroman-1-carboxylic acid ethyl ester
    —— 4-(benzylthio)-1H-1,2,3-triazole —— C9H9N3S
    4-(benzylthio)-1H-1,2,3-triazole
    —— 5-Benzylsulfanyl-1H-[1,2,3]triazole 79100-69-9 C9H9N3S
    5-Benzylsulfanyl-1H-[1,2,3]triazole
    —— 4-(benzylthio)-2H-1,2,3-triazole —— C9H9N3S
    4-(benzylthio)-2H-1,2,3-triazole
    —— (3H-[1,2,3]Triazol-4-ylsulfanyl)-acetic acid methyl ester 79100-64-4 C5H7N3O2S
    (3H-[1,2,3]Triazol-4-ylsulfanyl)-acetic acid methyl ester
    —— 2-<(methylamino)(methylimino)methylthio>-4-neopentyloxypyrimidine 125189-21-1 C12H20N4OS
    2-<(methylamino)(methylimino)methylthio>-4-neopentyloxypyrimidine
    —— 4-Furan-2-yl-6-methyl-2-methylsulfanyl-nicotinonitrile 224320-84-7 C12H10N2OS
    4-Furan-2-yl-6-methyl-2-methylsulfanyl-nicotinonitrile
    —— 2-Amino-6-({[2-(4-chlorophenyl)-1,3-thiazol-4-yl]methyl}sulfanyl)-4-{2-[(2-hydroxyethyl)amino]-1,3-thiazol-5-yl}pyridine-3,5-dicarbonitrile 1187543-29-8 C22H16ClN7OS3
    2-Amino-6-({[2-(4-chlorophenyl)-1,3-thiazol-4-yl]methyl}sulfanyl)-4-{2-[(2-hydroxyethyl)amino]-1,3-thiazol-5-yl}pyridine-3,5-dicarbonitrile
    —— neopentyl 2-((3,5-dioxo-2,3,4,5-tetrahydro-1,2,4-triazin-6-yl)thio)acetate 1426059-29-1 C10H15N3O4S
    neopentyl 2-((3,5-dioxo-2,3,4,5-tetrahydro-1,2,4-triazin-6-yl)thio)acetate
    —— 4-methylthio-6-methyl-2-thienyl-5-acetylpyrimidine 189152-42-9 C12H12N2OS2
    4-methylthio-6-methyl-2-thienyl-5-acetylpyrimidine
    —— 2-azido-1-(4-methylsulfanyl-phenyl)-ethanol 1184850-61-0 C9H11N3OS
    2-azido-1-(4-methylsulfanyl-phenyl)-ethanol
    —— 4-(4-fluorophenylamino)-2-methyl-sulfanyl-pyrimidine-5-carbaldehyde 402927-91-7 C12H10FN3OS
    4-(4-fluorophenylamino)-2-methyl-sulfanyl-pyrimidine-5-carbaldehyde
    —— 2,8-di-tert-butyl-[1,4]dithilino[2,3-d:5,6-d']dipyridazine-1,9(2H,8H)-dione 1340508-96-4 C16H20N4O2S2
    2,8-di-tert-butyl-[1,4]dithilino[2,3-d:5,6-d']dipyridazine-1,9(2H,8H)-dione
    —— 9-[(4-bromophenyl)sulfanyl]-N-methoxy-N,1-dimethyl-1,4,5,6-tetrahydropyrazolo[4',3':6,7]cyclohepta[1,2-d]pyrimidine-3-carboxamide 1392050-03-1 C20H20BrN5O2S
    9-[(4-bromophenyl)sulfanyl]-N-methoxy-N,1-dimethyl-1,4,5,6-tetrahydropyrazolo[4',3':6,7]cyclohepta[1,2-d]pyrimidine-3-carboxamide
    —— 1,2-dithiacyclodecane 6573-66-6 C8H16S2
    1,2-dithiacyclodecane
    —— 2-({[2-(4-Chlorophenyl)-1,3-thiazol-4-yl]methyl}sulfanyl)-6-[(2-hydroxyethyl)amino]-4-(1,3-thiazol-5-yl)pyridine-3,5-dicarbonitrile 1187543-25-4 C22H15ClN6OS3
    2-({[2-(4-Chlorophenyl)-1,3-thiazol-4-yl]methyl}sulfanyl)-6-[(2-hydroxyethyl)amino]-4-(1,3-thiazol-5-yl)pyridine-3,5-dicarbonitrile
    —— 3,6,10,13-tetrathiapentadecane-1,15-diol 88458-56-4 C11H24O2S4
    3,6,10,13-tetrathiapentadecane-1,15-diol
    —— (R,S)-2-(4-fluorophenylthio)-7-methyl-N-(1H-pyrazol-3-yl)-7H-pyrrolo[2,3-d]pyrimidin-4-amine 1361960-91-9 C16H13FN6S
    (R,S)-2-(4-fluorophenylthio)-7-methyl-N-(1H-pyrazol-3-yl)-7H-pyrrolo[2,3-d]pyrimidin-4-amine
    —— 2-({[2-(4-Chlorophenyl)-1,3-thiazol-4-yl]methyl}sulfanyl)-6-[(3R)-3-hydroxypyrrolidin-1-yl]-4-(1,3-thiazol-5-yl)pyridine-3,5-dicarbonitrile 1187543-32-3 C24H17ClN6OS3
    2-({[2-(4-Chlorophenyl)-1,3-thiazol-4-yl]methyl}sulfanyl)-6-[(3R)-3-hydroxypyrrolidin-1-yl]-4-(1,3-thiazol-5-yl)pyridine-3,5-dicarbonitrile
    —— 2-bromo-5-[(2,5-difluorophenyl)[[6-(trifluoromethyl)pyridin-3-yl]thio]methyl]-4-methylpyridine 913091-72-2 C19H12BrF5N2S
    2-bromo-5-[(2,5-difluorophenyl)[[6-(trifluoromethyl)pyridin-3-yl]thio]methyl]-4-methylpyridine
    —— 2-(2,5-dimethylbenzylsulfanyl)-6-oxo-4-piperidin-4-yl-1,6-dihydro-pyrimidine-5-carbonitrile 1383539-75-0 C19H22N4OS
    2-(2,5-dimethylbenzylsulfanyl)-6-oxo-4-piperidin-4-yl-1,6-dihydro-pyrimidine-5-carbonitrile
    —— 4-chloro-2-(4-fluorophenylthio)-7-methyl-7H-pyrrolo[2,3-d]pyrimidine 1361960-97-5 C13H9ClFN3S
    4-chloro-2-(4-fluorophenylthio)-7-methyl-7H-pyrrolo[2,3-d]pyrimidine
    —— 2-(4-fluorophenylthio)-N-(1H-pyrazol-5-yl)-7H-pyrrolo[2,3-d]pyrimidine-4-amine 1361960-86-2 C15H11FN6S
    2-(4-fluorophenylthio)-N-(1H-pyrazol-5-yl)-7H-pyrrolo[2,3-d]pyrimidine-4-amine
    —— 2-(4-chloro-2-(4-fluorophenylthio)-7H-pyrrolo[2,3-d]pyrimidin-7-yl)-N,N-dimethylacetamide 1361961-06-9 C16H14ClFN4OS
    2-(4-chloro-2-(4-fluorophenylthio)-7H-pyrrolo[2,3-d]pyrimidin-7-yl)-N,N-dimethylacetamide
    —— tert-butyl 2-(cyclohexylsulfonyl)acetate 1504589-12-1 C12H22O4S
    tert-butyl 2-(cyclohexylsulfonyl)acetate
    —— 5-benzylmercapto-6-azauracil 4956-07-4 C10H9N3O2S
    5-benzylmercapto-6-azauracil
    —— ethyl 4-(2-Amino-phenylthio)butyrate 144879-18-5 C12H17NO2S
    ethyl 4-(2-Amino-phenylthio)butyrate
    —— 1-[(2-hydroxyethoxy)methyl]-6-(phenylthio)-2-thiothymine 125057-07-0 C14H16N2O3S2
    1-[(2-hydroxyethoxy)methyl]-6-(phenylthio)-2-thiothymine
    —— 2-(N-acetyl-N-ethylamino)thioacetamide 91188-43-1 C6H12N2OS
    2-(N-acetyl-N-ethylamino)thioacetamide