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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-Propyl-N-thiocarbamoylmethyl-acetamide 115172-98-0 C7H14N2OS
    N-Propyl-N-thiocarbamoylmethyl-acetamide
    —— N-Acetyl-sarkosinthioamid 91188-40-8 C5H10N2OS
    N-Acetyl-sarkosinthioamid
    —— 4-((S)-2-hydroxy-propylamino)-2-methylsulfanyl-pyrimidine-5-carbaldehyde 851885-70-6 C9H13N3O2S
    4-((S)-2-hydroxy-propylamino)-2-methylsulfanyl-pyrimidine-5-carbaldehyde
    —— 5-Butyl-6-propyl-2,3-dihydro-[1,4]dithiine 134255-44-0 C11H20S2
    5-Butyl-6-propyl-2,3-dihydro-[1,4]dithiine
    —— 2-((4-bromophenyl)thio)-4-nitroaniline 1418195-44-4 C12H9BrN2O2S
    2-((4-bromophenyl)thio)-4-nitroaniline
    —— 1-(2-Hydroxy-ethoxymethyl)-6-phenylsulfanyl-2-thioxo-2,3-dihydro-1H-pyrimidin-4-one 125057-06-9 C13H14N2O3S2
    1-(2-Hydroxy-ethoxymethyl)-6-phenylsulfanyl-2-thioxo-2,3-dihydro-1H-pyrimidin-4-one
    —— 2-((4-fluorophenyl)thio)-4-nitroaniline 1418195-45-5 C12H9FN2O2S
    2-((4-fluorophenyl)thio)-4-nitroaniline
    —— 5-Bromo-1-(2-hydroxy-ethoxymethyl)-6-phenylsulfanyl-1H-pyrimidine-2,4-dione 123027-55-4 C13H13BrN2O4S
    5-Bromo-1-(2-hydroxy-ethoxymethyl)-6-phenylsulfanyl-1H-pyrimidine-2,4-dione
    —— 5-Chloro-1-(2-hydroxy-ethoxymethyl)-6-phenylsulfanyl-1H-pyrimidine-2,4-dione 123027-54-3 C13H13ClN2O4S
    5-Chloro-1-(2-hydroxy-ethoxymethyl)-6-phenylsulfanyl-1H-pyrimidine-2,4-dione
    —— 4-nitro-2-(m-tolylthio)aniline 1443147-79-2 C13H12N2O2S
    4-nitro-2-(m-tolylthio)aniline
    —— 5-(3'-bromo-5'-methoxy-2'-oxotetrafuran-4'-yl)-5-ethylthio-4-(pyrrolidin-1-yl)furan-2(5H)-one 134295-05-9 C15H20BrNO5S
    5-(3'-bromo-5'-methoxy-2'-oxotetrafuran-4'-yl)-5-ethylthio-4-(pyrrolidin-1-yl)furan-2(5H)-one
    —— 5-(4-Adamantan-1-yl-5-methylsulfanyl-4H-[1,2,4]triazol-3-yl)-4-methyl-[1,2,3]thiadiazole 318467-45-7 C16H21N5S2
    5-(4-Adamantan-1-yl-5-methylsulfanyl-4H-[1,2,4]triazol-3-yl)-4-methyl-[1,2,3]thiadiazole
    —— N,N''-(1R,2R)-1,2-cyclohexanediylbis[N'-tricyclo[3.3.1.1(3,7)]dec-1-ylthiourea] 1082952-48-4 C28H44N4S2
    N,N''-(1R,2R)-1,2-cyclohexanediylbis[N'-tricyclo[3.3.1.1(3,7)]dec-1-ylthiourea]
    —— N,N''-1,3-cyclohexanediylbis[N'-tricyclo[3.3.1.1(3,7)]dec-1-ylthiourea] 1082952-55-3 C28H44N4S2
    N,N''-1,3-cyclohexanediylbis[N'-tricyclo[3.3.1.1(3,7)]dec-1-ylthiourea]
    —— N-(adamantan-1-yl)ethanethioamide 78027-74-4 C12H19NS
    N-(adamantan-1-yl)ethanethioamide
    —— N,N',N''-(nitrilotri-2,1-ethanediyl)tris[N'''-tricyclo-[3.3.1.1(3,7)] dec-1-ylurea] 1384100-88-2 C39H63N7S3
    N,N',N''-(nitrilotri-2,1-ethanediyl)tris[N'''-tricyclo-[3.3.1.1(3,7)] dec-1-ylurea]
    —— (2-MeSC6H4)SnBu3 203195-90-8 C19H34SSn
    (2-MeSC6H4)SnBu3
    —— 5,11-Epoxy-dipyrido<2,3-b:2',3'-f><1,5>dithiocine 62349-89-7 C12H8N2OS2
    5,11-Epoxy-dipyrido<2,3-b:2',3'-f><1,5>dithiocine
    —— 5-acetyl-6-methylthiouracil 136411-39-7 C7H8N2O3S
    5-acetyl-6-methylthiouracil
    —— ethyl-N'-(3H-pyrido[2,3-b][1,4]thiazin-2-yl)hydrazinecarboxylate 639825-94-8 C10H12N4O2S
    ethyl-N'-(3H-pyrido[2,3-b][1,4]thiazin-2-yl)hydrazinecarboxylate
    —— 2-(2-Carboxy-phenylmercapto)-chinolin 92795-28-3 C16H11NO2S
    2-(2-Carboxy-phenylmercapto)-chinolin
    —— cyclohexyl(phenylthio)(trimethylsilyl)methane 89656-95-1 C16H26SSi
    cyclohexyl(phenylthio)(trimethylsilyl)methane
    —— 4-(3,5-dimethylphenylsulfanyl)-3-iodo-6-methyl-5-(1H-pyrrol-2-ylmethyl)pyridin-2(1H)-one 1185190-40-2 C19H19IN2OS
    4-(3,5-dimethylphenylsulfanyl)-3-iodo-6-methyl-5-(1H-pyrrol-2-ylmethyl)pyridin-2(1H)-one
    —— {1-[4-(3,5-dimethylphenylsulfanyl)-5-iodo-2-methyl-6-oxo-1,6-dihydropyridin-3-ylmethyl]-5-methyl-1H-[1,2,4]triazol-3-yl}acetonitrile 1185190-42-4 C20H20IN5OS
    {1-[4-(3,5-dimethylphenylsulfanyl)-5-iodo-2-methyl-6-oxo-1,6-dihydropyridin-3-ylmethyl]-5-methyl-1H-[1,2,4]triazol-3-yl}acetonitrile
    —— 2-amino-4-ethoxy-6-methylthio-5-pyrimidinecarbonitrile 136062-56-1 C8H10N4OS
    2-amino-4-ethoxy-6-methylthio-5-pyrimidinecarbonitrile
    —— 4-(3,5-dimethylphenylsulfanyl)-3-iodo-6-methyl-5-(3-phenyl-[1,2,4]triazol-4-ylmethyl)pyridin-2(1H)-one 1185190-97-9 C23H21IN4OS
    4-(3,5-dimethylphenylsulfanyl)-3-iodo-6-methyl-5-(3-phenyl-[1,2,4]triazol-4-ylmethyl)pyridin-2(1H)-one
    —— 4-(3,5-dimethylphenylsulfanyl)-3-iodo-6-methyl-5-pyrrol-1-ylmethylpyridin-2(1H)-one 1027050-89-0 C19H19IN2OS
    4-(3,5-dimethylphenylsulfanyl)-3-iodo-6-methyl-5-pyrrol-1-ylmethylpyridin-2(1H)-one
    —— 4-(3,5-dimethylphenylsulfanyl)-5-ethylthiomethyl-3-iodo-6-methyl-pyridin-2(1H)-one 1026632-31-4 C17H20INOS2
    4-(3,5-dimethylphenylsulfanyl)-5-ethylthiomethyl-3-iodo-6-methyl-pyridin-2(1H)-one
    —— 4-(3,5-dimethylphenylsulfanyl)-3-iodo-6-methyl-5-(3-phenyl-[1,2,4]triazol-1-ylmethyl)pyridin-2(1H)-one 1185190-44-6 C23H21IN4OS
    4-(3,5-dimethylphenylsulfanyl)-3-iodo-6-methyl-5-(3-phenyl-[1,2,4]triazol-1-ylmethyl)pyridin-2(1H)-one
    —— 4-(3,5-dimethylphenylsulfanyl)-5-(furan-2-ylmethylthiomethyl)-3-iodo-6-methyl-pyridin-2(1H)-one 1185190-10-6 C20H20INO2S2
    4-(3,5-dimethylphenylsulfanyl)-5-(furan-2-ylmethylthiomethyl)-3-iodo-6-methyl-pyridin-2(1H)-one
    —— 4-(3,5-dimethylphenylsulfanyl)-5-imidazol-1-ylmethyl-3-iodo-6-methylpyridin-2(1H)-one 1026737-26-7 C18H18IN3OS
    4-(3,5-dimethylphenylsulfanyl)-5-imidazol-1-ylmethyl-3-iodo-6-methylpyridin-2(1H)-one
    —— 4-(3,5-dimethylphenylsulfanyl)-3-iodo-6-methyl-5-[1,2,4]triazol-1-ylmethylpyridin-2(1H)-one 1026892-50-1 C17H17IN4OS
    4-(3,5-dimethylphenylsulfanyl)-3-iodo-6-methyl-5-[1,2,4]triazol-1-ylmethylpyridin-2(1H)-one
    —— 4-(3,5-dimethylphenylsulfanyl)-3-iodo-5-[2-(2-methoxyethyl)morpholin-4-ylmethyl]-6-methylpyridin-2(1H)-one 1185190-61-7 C22H29IN2O3S
    4-(3,5-dimethylphenylsulfanyl)-3-iodo-5-[2-(2-methoxyethyl)morpholin-4-ylmethyl]-6-methylpyridin-2(1H)-one
    —— 4-(3,5-dimethylphenylsulfanyl)-5-(3-furan-2-yl-5-methyl-[1,2,4]triazol-1-ylmethyl)-3-iodo-6-methylpyridin-2(1H)-one 1185190-35-5 C22H21IN4O2S
    4-(3,5-dimethylphenylsulfanyl)-5-(3-furan-2-yl-5-methyl-[1,2,4]triazol-1-ylmethyl)-3-iodo-6-methylpyridin-2(1H)-one
    —— 1-[4-(3,5-dimethylphenylsulfanyl)-5-iodo-2-methyl-6-oxo-1,6-dihydropyridin-3-ylmethyl]-1H-pyrrole-2-carbonitrile 1185190-22-0 C20H18IN3OS
    1-[4-(3,5-dimethylphenylsulfanyl)-5-iodo-2-methyl-6-oxo-1,6-dihydropyridin-3-ylmethyl]-1H-pyrrole-2-carbonitrile
    —— 3,4-dihydro-2H,6H-pyrimido[1,2-c]pyrido[3,2-e][1,3]thiazine-6-imine 1394235-65-4 C10H10N4S
    3,4-dihydro-2H,6H-pyrimido[1,2-c]pyrido[3,2-e][1,3]thiazine-6-imine
    —— 5-hydroxymethyl-3-iodo-6-methyl-4-(3,5-dimethylphenylsulfanyl)pyridin-2(1H)-one 1185189-86-9 C15H16INO2S
    5-hydroxymethyl-3-iodo-6-methyl-4-(3,5-dimethylphenylsulfanyl)pyridin-2(1H)-one
    —— 2,2-diethyl-[1,3]dithiane-1,1,3,3-tetraoxide 69490-00-2 C8H16O4S2
    2,2-diethyl-[1,3]dithiane-1,1,3,3-tetraoxide
    —— <2,7-<sup>2</sup>H2>tropothione 114735-40-9 C7H6S
    <2,7-<sup>2</sup>H2>tropothione
    —— 3,3'''-(1,16-dithia-4,7,10,13-tetraoxa-1,16-hexadecanediyl)-2,2':5',2'':5'':2'''-quaterthiophene 499793-39-4 C26H28O4S6
    3,3'''-(1,16-dithia-4,7,10,13-tetraoxa-1,16-hexadecanediyl)-2,2':5',2'':5'':2'''-quaterthiophene
    —— 5,8-dimethoxy-6-(phenylthio)tetralin 87923-75-9 C18H20O2S
    5,8-dimethoxy-6-(phenylthio)tetralin
    —— 3,3'''''-(1,16-dithia-4,7,10,13-tetraoxa-1,16-hexadecanediyl)-2,2':5',2'':5'':2''':5''',2'''':5'''',2'''''-sexithiophene 499793-41-8 C34H32O4S8
    3,3'''''-(1,16-dithia-4,7,10,13-tetraoxa-1,16-hexadecanediyl)-2,2':5',2'':5'':2''':5''',2'''':5'''',2'''''-sexithiophene
    —— 1-(2-aminopropyldisulfanyl)propan-2-amine;hydron;dichloride —— C6H18Cl2N2S2
    1-(2-aminopropyldisulfanyl)propan-2-amine;hydron;dichloride
    —— 1217446-21-3 C15H22S4
    —— (4,5-Dihydro-1H-imidazol-2-yl)-[4-(2-methoxy-phenylsulfanyl)-phenyl]-amine 677343-40-7 C16H17N3OS
    (4,5-Dihydro-1H-imidazol-2-yl)-[4-(2-methoxy-phenylsulfanyl)-phenyl]-amine
    —— 4'-Isopropoxy-4-aminodiphenylsulfid 62248-49-1 C15H17NOS
    4'-Isopropoxy-4-aminodiphenylsulfid
    —— 4'-Isopropyl-4-aminodiphenylsulfid 62248-50-4 C15H17NS
    4'-Isopropyl-4-aminodiphenylsulfid
    —— (4,5-Dihydro-1H-imidazol-2-yl)-[4-(4-methoxy-phenylsulfanyl)-phenyl]-amine 677343-08-7 C16H17N3OS
    (4,5-Dihydro-1H-imidazol-2-yl)-[4-(4-methoxy-phenylsulfanyl)-phenyl]-amine
    —— (4,5-Dihydro-1H-imidazol-2-yl)-[4-(4-ethoxy-phenylsulfanyl)-phenyl]-amine 677343-44-1 C17H19N3OS
    (4,5-Dihydro-1H-imidazol-2-yl)-[4-(4-ethoxy-phenylsulfanyl)-phenyl]-amine
    —— 4-[2-(pyridin-4-ylsulfanyl)-phenylcarbamoyl]-piperidine-1-carboxylic acid tert-butyl ester 919118-82-4 C22H27N3O3S
    4-[2-(pyridin-4-ylsulfanyl)-phenylcarbamoyl]-piperidine-1-carboxylic acid tert-butyl ester