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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-(4-(4-(4-methoxyphenylthio)pyrimidin-2-ylamino)phenyl)acrylamide 1042122-92-8 C20H18N4O2S
    N-(4-(4-(4-methoxyphenylthio)pyrimidin-2-ylamino)phenyl)acrylamide
    —— 2-methyl-2,3-dithiocyanatobutane 62444-35-3 C7H10N2S2
    2-methyl-2,3-dithiocyanatobutane
    —— (S)-2-amino-3-methyl-1-thiophenylbutane 156358-28-0 C11H17NS
    (S)-2-amino-3-methyl-1-thiophenylbutane
    —— Deca-(p-tolylthio)biphenyl 58554-05-5 C82H70S10
    Deca-(p-tolylthio)biphenyl
    —— cobalt(2+);2-methoxycarbonylbenzenethiolate 307502-96-1 C16H14CoO4S2
    cobalt(2+);2-methoxycarbonylbenzenethiolate
    —— 2,3-dihydro-5-methylthio-1,4-dithiin 106691-49-0 C5H8S3
    2,3-dihydro-5-methylthio-1,4-dithiin
    —— 3-(naphthalen-1-ylthio)-1H-indole 139461-62-4 C18H13NS
    3-(naphthalen-1-ylthio)-1H-indole
    —— O-ethyl S-(1-cyclohexyl-2-nitroethyl) dithiocarbonate 1252060-80-2 C11H19NO3S2
    O-ethyl S-(1-cyclohexyl-2-nitroethyl) dithiocarbonate
    —— 2-acetonyl-1-(1-naphthylthio)isoquinolinium iodide 112107-66-1 C22H18NOS*I
    2-acetonyl-1-(1-naphthylthio)isoquinolinium iodide
    —— 3-chloro-4-((trifluoromethyl)thio)phenol 774-72-1 C7H4ClF3OS
    3-chloro-4-((trifluoromethyl)thio)phenol
    —— Dimethyl-dithiocarbamic acid (E)-1-methyl-pent-2-enyl ester 53282-09-0 C9H17NS2
    Dimethyl-dithiocarbamic acid (E)-1-methyl-pent-2-enyl ester
    —— 2-Methyl-3-phenylsulfanylmethyl-octane-2,3-diol 144424-60-2 C16H26O2S
    2-Methyl-3-phenylsulfanylmethyl-octane-2,3-diol
    —— 6-methoxy-3-(2-nitro-phenylsulfanyl)-1-pyridin-4-ylmethyl-1H-indole 691400-45-0 C21H17N3O3S
    6-methoxy-3-(2-nitro-phenylsulfanyl)-1-pyridin-4-ylmethyl-1H-indole
    —— phenyl N-benzylsulfonyloxyethanimidothioate 1390629-05-6 C15H15NO3S2
    phenyl N-benzylsulfonyloxyethanimidothioate
    —— N-[2-(4-amino-7-cyclopentyl-7H-pyrrolo[2,3-d]pyrimidin-5-ylsulfanyl)-phenyl]-2,4-difluoro-benzenesulfonamide 717898-26-5 C23H21F2N5O2S2
    N-[2-(4-amino-7-cyclopentyl-7H-pyrrolo[2,3-d]pyrimidin-5-ylsulfanyl)-phenyl]-2,4-difluoro-benzenesulfonamide
    —— 1-Isothiocyanato-4-phenylsulfanylmethyl-benzene 42498-13-5 C14H11NS2
    1-Isothiocyanato-4-phenylsulfanylmethyl-benzene
    —— (4-{4-[3-(4-butoxyphenyl)-1-(3-phenylpropyl)ureido]phenylsulphanyl}phenyl)acetic acid 735314-22-4 C34H36N2O4S
    (4-{4-[3-(4-butoxyphenyl)-1-(3-phenylpropyl)ureido]phenylsulphanyl}phenyl)acetic acid
    —— (4-{3-[3-(4-methoxyphenyl)-1-phenethylureido]phenylsulphanyl}phenyl)acetic acid 735313-01-6 C30H28N2O4S
    (4-{3-[3-(4-methoxyphenyl)-1-phenethylureido]phenylsulphanyl}phenyl)acetic acid
    —— (Z)-2-acetoxy-1-phenylthiopropene 123630-58-0 C11H12O2S
    (Z)-2-acetoxy-1-phenylthiopropene
    —— cis-di-chloro(CH2CCH3CH2SCH2CCH3CH2)2palladium(II) 127162-12-3 C16H28Cl2PdS2
    cis-di-chloro(CH2CCH3CH2SCH2CCH3CH2)2palladium(II)
    —— 3-acetoxy-1-p-tolylthio-3-phenylthio-2-propanone 96028-60-3 C18H18O3S2
    3-acetoxy-1-p-tolylthio-3-phenylthio-2-propanone
    —— (Z)-3-[5-(4-Acetylamino-phenylsulfanyl)-furan-2-yl]-2-cyano-acrylic acid methyl ester 56656-74-7 C17H14N2O4S
    (Z)-3-[5-(4-Acetylamino-phenylsulfanyl)-furan-2-yl]-2-cyano-acrylic acid methyl ester
    —— 2-(4-Amino-5,6,7,8-tetrahydro-naphthalen-1-ylsulfanyl)-benzoic acid 50536-97-5 C17H17NO2S
    2-(4-Amino-5,6,7,8-tetrahydro-naphthalen-1-ylsulfanyl)-benzoic acid
    —— 6-chloro-<i>N</i>'-[2-(4-dimethylamino-6-methoxy-[1,3,5]triazin-2-ylsulfanyl)-phenyl]-<i>N</i>,<i>N</i>-dimethyl-[1,3,5]triazine-2,4-diamine 50803-10-6 C17H20ClN9OS
    6-chloro-<i>N</i>'-[2-(4-dimethylamino-6-methoxy-[1,3,5]triazin-2-ylsulfanyl)-phenyl]-<i>N</i>,<i>N</i>-dimethyl-[1,3,5]triazine-2,4-diamine
    —— 3-(6-chloro-2-methyl-1H-indol-3-ylsulfanyl)-2-methoxy-benzoic acid ethyl ester 1359981-27-3 C19H18ClNO3S
    3-(6-chloro-2-methyl-1H-indol-3-ylsulfanyl)-2-methoxy-benzoic acid ethyl ester
    —— Bis-(p-phenylthiobenzoyl)-ethylen 59344-90-0 C28H20O2S2
    Bis-(p-phenylthiobenzoyl)-ethylen
    —— 3-(6-chloro-2-ethyl-1H-indol-3-ylsulfanyl)-benzoic acid methyl ester 1359982-36-7 C18H16ClNO2S
    3-(6-chloro-2-ethyl-1H-indol-3-ylsulfanyl)-benzoic acid methyl ester
    —— 2-(1-Methyl-1H-imidazol-2-ylsulfanyl)-acetamide; hydrochloride 50970-53-1 C6H9N3OS*ClH
    2-(1-Methyl-1H-imidazol-2-ylsulfanyl)-acetamide; hydrochloride
    —— N3-methyl-1-(2-methylsulfanyl-6-phenylamino-pyrimidin-4-yl)-1H-[1,2,4]triazole-3,5-diamine 700811-17-2 C14H16N8S
    N3-methyl-1-(2-methylsulfanyl-6-phenylamino-pyrimidin-4-yl)-1H-[1,2,4]triazole-3,5-diamine
    —— 2-(4-chloro-2-methyl-phenylsulfanyl)-butyric acid 100126-84-9 C11H13ClO2S
    2-(4-chloro-2-methyl-phenylsulfanyl)-butyric acid
    —— (ethoxy-methylsulfanyl-methylene)-carbamic acid ethyl ester 51291-79-3 C7H13NO3S
    (ethoxy-methylsulfanyl-methylene)-carbamic acid ethyl ester
    —— 5-amino-2-(3-pyridinyl)-7-methylthiothiazolo[5,4-d]pyrimidine 1245317-76-3 C11H9N5S2
    5-amino-2-(3-pyridinyl)-7-methylthiothiazolo[5,4-d]pyrimidine
    —— 2-(p-Tolylmercapto)-3,5,7-trideutero-tropon 50702-28-8 C14H12OS
    2-(p-Tolylmercapto)-3,5,7-trideutero-tropon
    —— 2-acetoxy-4-acetyl-1-(4'-methoxyphenylthio)-1-cyclohexene 65173-92-4 C17H20O4S
    2-acetoxy-4-acetyl-1-(4'-methoxyphenylthio)-1-cyclohexene
    —— (E)-1-(2-Allyl-[1,3]dithian-2-yl)-4-isopropyl-hexa-3,5-dien-1-ol 75266-70-5 C16H26OS2
    (E)-1-(2-Allyl-[1,3]dithian-2-yl)-4-isopropyl-hexa-3,5-dien-1-ol
    —— 3-[6-chloro-1-(1-isopropyl-1H-pyrazol-4-yl)-2-methyl-1H-indol-3-ylsulfanyl]-benzoic acid ethyl ester 1359980-70-3 C24H24ClN3O2S
    3-[6-chloro-1-(1-isopropyl-1H-pyrazol-4-yl)-2-methyl-1H-indol-3-ylsulfanyl]-benzoic acid ethyl ester
    —— 3-acetyl-2-isopropoxy-5-methylsulfanyl-2,3-dihydro-[1,3,4,2]thiadiazaphosphole 72107-76-7 C7H13N2O2PS2
    3-acetyl-2-isopropoxy-5-methylsulfanyl-2,3-dihydro-[1,3,4,2]thiadiazaphosphole
    —— 5-((1-methyl-1H-imidazol-2-yl)thio)-N-(4-methylthiazol-2-yl)-2-nitrobenzamide 1146340-70-6 C15H13N5O3S2
    5-((1-methyl-1H-imidazol-2-yl)thio)-N-(4-methylthiazol-2-yl)-2-nitrobenzamide
    —— 1-Acetonyl-2-(phenylmercapto)-5-methyl-pyridinium 97175-52-5 C15H16NOS*I
    1-Acetonyl-2-(phenylmercapto)-5-methyl-pyridinium
    —— 2-Bromo-3,4-dimethylphenyl-3-amino-4 pyridinylsulfide 239791-60-7 C13H13BrN2S
    2-Bromo-3,4-dimethylphenyl-3-amino-4 pyridinylsulfide
    —— 1337470-54-8 C12H16N2O2S
    —— 2,5-bis(4-tolylthio)-3-thiophenecarboxaldehyde 1385822-45-6 C19H16OS3
    2,5-bis(4-tolylthio)-3-thiophenecarboxaldehyde
    —— 2-bromo-2-butyl-1-[difluoro-1-(methylsulfonyl)methyl]pentane 881744-32-7 C11H21BrF2O2S
    2-bromo-2-butyl-1-[difluoro-1-(methylsulfonyl)methyl]pentane
    —— 2-cyclopropylmethyl-1,3,4,4a,5,10a-hexahydro-2<i>H</i>-thiochromeno[2,3-<i>c</i>]pyridin-5-ol 24232-50-6 C16H21NOS
    2-cyclopropylmethyl-1,3,4,4a,5,10a-hexahydro-2<i>H</i>-thiochromeno[2,3-<i>c</i>]pyridin-5-ol
    —— 4-<(3-cyano-4-nitrophenyl)thio>benzoic acid methyl ester 74761-56-1 C15H10N2O4S
    4-<(3-cyano-4-nitrophenyl)thio>benzoic acid methyl ester
    —— 2-<2-<1,3-dimethyl-2-<(phenylthio)methyl>-2-cyclohexen-1-yl>>acetaldehyde 98127-16-3 C17H22OS
    2-<2-<1,3-dimethyl-2-<(phenylthio)methyl>-2-cyclohexen-1-yl>>acetaldehyde
    —— 3-phenyl-1-phenylthio-propene 29736-81-0 C15H14S
    3-phenyl-1-phenylthio-propene
    —— 5-Benzyl-2-methylsulfanyl-4-trimethylsilanyloxy-pyrimidine 173208-27-0 C15H20N2OSSi
    5-Benzyl-2-methylsulfanyl-4-trimethylsilanyloxy-pyrimidine
    —— hexakis(3-methoxy-1-phenylthio)benzene 113087-90-4 C48H42O6S6
    hexakis(3-methoxy-1-phenylthio)benzene
    —— 1-deoxy-4,5-O-isopropylidene-D-erythro-2-pentulose trimethylene dithioacetal 83657-27-6 C11H20O3S2
    1-deoxy-4,5-O-isopropylidene-D-erythro-2-pentulose trimethylene dithioacetal