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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— S-ethyl N-methoxycarbonylsulfenyl thiocarbamate 1338229-24-5 C5H9NO3S2
    S-ethyl N-methoxycarbonylsulfenyl thiocarbamate
    —— 3-chloro-1-ethyl-4-(2-hydroxyphenylthio)-1H-pyrrole-2,5-dione 1403354-08-4 C12H10ClNO3S
    3-chloro-1-ethyl-4-(2-hydroxyphenylthio)-1H-pyrrole-2,5-dione
    —— 2,2'-(methylenedithio)di-phenol 100396-99-4 C13H12O2S2
    2,2'-(methylenedithio)di-phenol
    —— O-methyl N-methoxycarbonylsulfenyl carbamate 1338229-19-8 C4H7NO4S
    O-methyl N-methoxycarbonylsulfenyl carbamate
    —— 2-[(3-Cyano-6-isobutyl-2-pyridyl)sulfanyl]-2-methylpropanoic acid 696614-12-7 C14H18N2O2S
    2-[(3-Cyano-6-isobutyl-2-pyridyl)sulfanyl]-2-methylpropanoic acid
    —— Vinyl-(2-phenyl-thio-ethyl)-ether 6613-39-4 C10H12OS
    Vinyl-(2-phenyl-thio-ethyl)-ether
    —— 2-[(3-Cyano-6-propyl-2-pyridyl)sulfanyl]-2-methylpropanoic acid 696605-16-0 C13H16N2O2S
    2-[(3-Cyano-6-propyl-2-pyridyl)sulfanyl]-2-methylpropanoic acid
    —— 1-phenyl-2,2-bis(phenylthio)ethan-1-ol 13307-64-7 C20H18OS2
    1-phenyl-2,2-bis(phenylthio)ethan-1-ol
    —— 2-(Methylthiomethoxy)propan 82055-18-3 C5H12OS
    2-(Methylthiomethoxy)propan
    —— 3,3'-diaminodiphenyl sulfide 23808-29-9 C12H12N2S
    3,3'-diaminodiphenyl sulfide
    —— phenyl 2-cyclopropylphenyl sulfide 75850-33-8 C15H14S
    phenyl 2-cyclopropylphenyl sulfide
    —— tert-butyl 5-(methoxymethylthio)-2-methylpentan-2-ylcarbamate 1198225-83-0 C13H27NO3S
    tert-butyl 5-(methoxymethylthio)-2-methylpentan-2-ylcarbamate
    —— 1-[(2R,3R,5S,9S)-9-hydroxy-3-phenylsulfanyl-1-oxaspiro[4.4]nonan-2-yl]pyrimidine-2,4-dione 629666-02-0 C18H20N2O4S
    1-[(2R,3R,5S,9S)-9-hydroxy-3-phenylsulfanyl-1-oxaspiro[4.4]nonan-2-yl]pyrimidine-2,4-dione
    —— 6-amino-2,4-bis(methylthio)-pyridin-3,5-dicarbonitril 135703-42-3 C9H8N4S2
    6-amino-2,4-bis(methylthio)-pyridin-3,5-dicarbonitril
    —— 3-(4-bromophenylthio)-1,2-propanediol 59365-64-9 C9H11BrO2S
    3-(4-bromophenylthio)-1,2-propanediol
    —— 3-methylsulfanyl-1-morpholin-4-yl-5,6,7,8-tetrahydro-isoquinoline-4-carbonitrile 50865-88-8 C15H19N3OS
    3-methylsulfanyl-1-morpholin-4-yl-5,6,7,8-tetrahydro-isoquinoline-4-carbonitrile
    —— 4-bromo-2-fluoro-1-(phenylthio)benzene 882689-94-3 C12H8BrFS
    4-bromo-2-fluoro-1-(phenylthio)benzene
    —— ethyl 2,2,3-trifluoro-3-phenyl-3-(4-chlorophenylthio)propionate 1253930-97-0 C17H14ClF3O2S
    ethyl 2,2,3-trifluoro-3-phenyl-3-(4-chlorophenylthio)propionate
    —— 1-(phenylsulfanyl-methyl)-propylamine 3898-25-7 C10H15NS
    1-(phenylsulfanyl-methyl)-propylamine
    —— N-methylthiocrotonamide 80597-82-6 C5H9NS
    N-methylthiocrotonamide
    —— 6-benzyl-2,3-dihydro-7H-[1,3]thiazolo[3,2-b][1,2,4]triazin-7-one 87844-18-6 C12H11N3OS
    6-benzyl-2,3-dihydro-7H-[1,3]thiazolo[3,2-b][1,2,4]triazin-7-one
    —— ethyl 2-(4,6-dihydroxypyrimidin-2-ylthio)-2-phenylacetate 461431-94-7 C14H14N2O4S
    ethyl 2-(4,6-dihydroxypyrimidin-2-ylthio)-2-phenylacetate
    —— 2,2-bis(ethylthio)-3-phenylpropanal 76372-04-8 C13H18OS2
    2,2-bis(ethylthio)-3-phenylpropanal
    —— 3-thienyl ethoxycarbonyl(phenyl)methyl sulfide 160032-30-4 C14H14O2S2
    3-thienyl ethoxycarbonyl(phenyl)methyl sulfide
    —— sodium 2-phenyl-2-(2-pyridylthio)acetate 97522-85-5 C13H10NO2S*Na
    sodium 2-phenyl-2-(2-pyridylthio)acetate
    —— 3-<ethoxycarbonyl(phenyl)methyl>thiophene-2-carbaldehyde 160032-35-9 C15H14O3S2
    3-<ethoxycarbonyl(phenyl)methyl>thiophene-2-carbaldehyde
    —— 5-(dodecylthio)-1H-tetrazole 149475-93-4 C13H26N4S
    5-(dodecylthio)-1H-tetrazole
    —— 2-(2-Propan-2-ylsulfanylphenyl)acetic acid 74266-19-6 C11H14O2S
    2-(2-Propan-2-ylsulfanylphenyl)acetic acid
    —— ethyl 2-phenyl-2-(2-pyridylthio)acetate 97522-86-6 C15H15NO2S
    ethyl 2-phenyl-2-(2-pyridylthio)acetate
    —— N-tert-butyl-N-(furan-3-ylmethyl)-2-[2-(4-methylphenyl)sulfanylphenyl]acetamide 207349-92-6 C24H27NO2S
    N-tert-butyl-N-(furan-3-ylmethyl)-2-[2-(4-methylphenyl)sulfanylphenyl]acetamide
    —— α-Chloro-β-phenylethylphenylsulfide 89423-36-9 C14H13ClS
    α-Chloro-β-phenylethylphenylsulfide
    —— 2-propyl-2-(13,15-dioxahexadec-5-ynyl)-1,3-dithiane 928030-71-1 C21H38O2S2
    2-propyl-2-(13,15-dioxahexadec-5-ynyl)-1,3-dithiane
    —— N-benzyl-N-tert-butyl-2-[2-(4-methylphenyl)sulfanylphenyl]acetamide 207349-83-5 C26H29NOS
    N-benzyl-N-tert-butyl-2-[2-(4-methylphenyl)sulfanylphenyl]acetamide
    —— 2-(4-Acetamido-phenyl-thio)-phenyl-essigsaeure 40400-17-7 C16H15NO3S
    2-(4-Acetamido-phenyl-thio)-phenyl-essigsaeure
    —— 2-(4-Amino-phenylmercapto)-phenylessigsaeure 20904-50-1 C14H13NO2S
    2-(4-Amino-phenylmercapto)-phenylessigsaeure
    —— tert-butyl [(1S,3S)-3-(methylaminocarbonothionyl)cyclopentyl]carbamate 875899-16-4 C12H22N2O2S
    tert-butyl [(1S,3S)-3-(methylaminocarbonothionyl)cyclopentyl]carbamate
    —— 2-benzyl-5-carbethoxymethylthio-1,3,4-oxadiazole 130781-74-7 C13H14N2O3S
    2-benzyl-5-carbethoxymethylthio-1,3,4-oxadiazole
    —— tert-butyl [(1S,3R)-3-(methylaminocarbonothionyl)cyclopentyl]carbamate 875899-10-8 C12H22N2O2S
    tert-butyl [(1S,3R)-3-(methylaminocarbonothionyl)cyclopentyl]carbamate
    —— tert-butyl 2-(2-(4-bromophenylthio)phenyl)acetate 1427565-52-3 C18H19BrO2S
    tert-butyl 2-(2-(4-bromophenylthio)phenyl)acetate
    —— <2-(3-fluorophenylthio)phenyl>acetic acid 76242-88-1 C14H11FO2S
    <2-(3-fluorophenylthio)phenyl>acetic acid
    —— <2-(2-aminophenylthio)phenyl>acetic acid 54920-97-7 C14H13NO2S
    <2-(2-aminophenylthio)phenyl>acetic acid
    —— N-methyl-2-[2-(4-methylphenyl)sulfanylphenyl]-N-phenylacetamide 207349-80-2 C22H21NOS
    N-methyl-2-[2-(4-methylphenyl)sulfanylphenyl]-N-phenylacetamide
    —— N-tert-butyl-2-[2-(4-methylphenyl)sulfanylphenyl]-N-[2-(trimethylsilylmethyl)prop-2-enyl]acetamide 207350-08-1 C26H37NOSSi
    N-tert-butyl-2-[2-(4-methylphenyl)sulfanylphenyl]-N-[2-(trimethylsilylmethyl)prop-2-enyl]acetamide
    —— N-tert-butyl-N-(cyclohexen-1-ylmethyl)-2-[2-(4-methylphenyl)sulfanylphenyl]acetamide 207349-95-9 C26H33NOS
    N-tert-butyl-N-(cyclohexen-1-ylmethyl)-2-[2-(4-methylphenyl)sulfanylphenyl]acetamide
    —— N-tert-butyl-N-[(3-methoxyphenyl)methyl]-2-[2-(4-methylphenyl)sulfanylphenyl]acetamide 207349-85-7 C27H31NO2S
    N-tert-butyl-N-[(3-methoxyphenyl)methyl]-2-[2-(4-methylphenyl)sulfanylphenyl]acetamide
    —— 1-methyl-3-[2-(4-methylphenyl)sulfanylphenyl]-3H-indol-2-one 172470-07-4 C22H19NOS
    1-methyl-3-[2-(4-methylphenyl)sulfanylphenyl]-3H-indol-2-one
    —— (2-(2-methylphenylthio)phenyl)ecetic acid 107165-01-5 C15H14O2S
    (2-(2-methylphenylthio)phenyl)ecetic acid
    —— 4-[6-(3,5-di-t-butyl-4-hydroxyphenylthio)-1-methyl-1H-benzimidazole-2-ylmethoxy]benzaldehyde 223134-13-2 C30H34N2O3S
    4-[6-(3,5-di-t-butyl-4-hydroxyphenylthio)-1-methyl-1H-benzimidazole-2-ylmethoxy]benzaldehyde
    —— 6-(3,5-di-t-butyl-4-hydroxy)phenylthio-2-hydroxymethyl-1-methyl-1H-benzimidazole 223134-11-0 C23H30N2O2S
    6-(3,5-di-t-butyl-4-hydroxy)phenylthio-2-hydroxymethyl-1-methyl-1H-benzimidazole
    —— α-Ethyl-2-[(3,4-dimethoxyphenyl)thio]phenylacetic Acid 312303-34-7 C18H20O4S
    α-Ethyl-2-[(3,4-dimethoxyphenyl)thio]phenylacetic Acid