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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (4R,5S,SS)-7,7-Dimethyl-4-(tert-butylsulfinyl)bicyclo[3.3.0]oct-1-en-3-one 389842-85-7 C14H22O2S
    (4R,5S,SS)-7,7-Dimethyl-4-(tert-butylsulfinyl)bicyclo[3.3.0]oct-1-en-3-one
    —— (S)-trans-1-(tert-Butylsulfinyl)-4,4-dimethyl-1-hepten-6-yne 245367-16-2 C13H22OS
    (S)-trans-1-(tert-Butylsulfinyl)-4,4-dimethyl-1-hepten-6-yne
    —— 2,6,6-trimethyl-1-(phenylthiomethyl)cyclohex-1-ene 56691-73-7 C16H22S
    2,6,6-trimethyl-1-(phenylthiomethyl)cyclohex-1-ene
    —— 2-methyl-2-<3'(1,3-dithiolanyl)pentyl>thiazolidine 156000-12-3 C11H21NS3
    2-methyl-2-<3'(1,3-dithiolanyl)pentyl>thiazolidine
    —— but-3-yne-2-thiol 1220112-14-0 C4H6S
    but-3-yne-2-thiol
    —— Z-3-(Methylthio)-2,2-dimethyl-3-hepten-5-in 61809-23-2 C10H16S
    Z-3-(Methylthio)-2,2-dimethyl-3-hepten-5-in
    —— 6,6-Dimethyl-5-(methylsulfanyl)hept-4-en-2-yne 84770-49-0 C10H16S
    6,6-Dimethyl-5-(methylsulfanyl)hept-4-en-2-yne
    —— tert-Butyl<2,2,2-trifluor-1-(trifluormethyl)ethyl>sulfon 102150-27-6 C7H10F6O2S
    tert-Butyl<2,2,2-trifluor-1-(trifluormethyl)ethyl>sulfon
    —— 1-n-butylthio-2-butene 3001-22-7 C8H16S
    1-n-butylthio-2-butene
    —— O-[(E)-but-2-enyl] N-methylcarbamothioate 188400-04-6 C6H11NOS
    O-[(E)-but-2-enyl] N-methylcarbamothioate
    —— O-methyl S-t-butyl dithiocarbonate 82810-50-2 C6H12OS2
    O-methyl S-t-butyl dithiocarbonate
    —— β-Methyl-β-carbomethoxy-ethyl-<pyridyl-(2)>-sulfid 91012-43-0 C10H13NO2S
    β-Methyl-β-carbomethoxy-ethyl-<pyridyl-(2)>-sulfid
    —— 4-(4-chlorophenyl)-3-cyano-2-ethylthiothiophene 116526-43-3 C13H10ClNS2
    4-(4-chlorophenyl)-3-cyano-2-ethylthiothiophene
    —— Methyl 1-(2-acetyloxyethoxymethyl)-5-(2-methylphenyl)sulfanyl-1,2,4-triazole-3-carboxylate 1237741-54-6 C16H19N3O5S
    Methyl 1-(2-acetyloxyethoxymethyl)-5-(2-methylphenyl)sulfanyl-1,2,4-triazole-3-carboxylate
    —— Methyl 1-(2-acetyloxyethoxymethyl)-5-[4-(trifluoromethyl)phenyl]sulfanyl-1,2,4-triazole-3-carboxylate 1237741-65-9 C16H16F3N3O5S
    Methyl 1-(2-acetyloxyethoxymethyl)-5-[4-(trifluoromethyl)phenyl]sulfanyl-1,2,4-triazole-3-carboxylate
    —— Methyl 1-(2-acetyloxyethoxymethyl)-5-(4-methoxyphenyl)sulfanyl-1,2,4-triazole-3-carboxylate 1237741-59-1 C16H19N3O6S
    Methyl 1-(2-acetyloxyethoxymethyl)-5-(4-methoxyphenyl)sulfanyl-1,2,4-triazole-3-carboxylate
    —— 2-[3,6-Bis(2-methylpropyl)pyrazin-2-yl]sulfanylethanol 1283166-90-4 C14H24N2OS
    2-[3,6-Bis(2-methylpropyl)pyrazin-2-yl]sulfanylethanol
    —— N-[2-[3,6-bis(2-methylpropyl)pyrazin-2-yl]sulfanylethyl]acetamide 1283166-78-8 C16H27N3OS
    N-[2-[3,6-bis(2-methylpropyl)pyrazin-2-yl]sulfanylethyl]acetamide
    —— Methyl 1-(2-acetyloxyethoxymethyl)-5-(4-tert-butylphenyl)sulfanyl-1,2,4-triazole-3-carboxylate 1237741-67-1 C19H25N3O5S
    Methyl 1-(2-acetyloxyethoxymethyl)-5-(4-tert-butylphenyl)sulfanyl-1,2,4-triazole-3-carboxylate
    —— Methyl 1-(2-acetyloxyethoxymethyl)-5-(4-chlorophenyl)sulfanyl-1,2,4-triazole-3-carboxylate 1237741-66-0 C15H16ClN3O5S
    Methyl 1-(2-acetyloxyethoxymethyl)-5-(4-chlorophenyl)sulfanyl-1,2,4-triazole-3-carboxylate
    —— Methyl 1-(2-acetyloxyethoxymethyl)-5-[2-(trifluoromethyl)phenyl]sulfanyl-1,2,4-triazole-3-carboxylate 1237741-63-7 C16H16F3N3O5S
    Methyl 1-(2-acetyloxyethoxymethyl)-5-[2-(trifluoromethyl)phenyl]sulfanyl-1,2,4-triazole-3-carboxylate
    —— Methyl 1-(2-acetyloxyethoxymethyl)-5-(3-fluorophenyl)sulfanyl-1,2,4-triazole-3-carboxylate 1237741-61-5 C15H16FN3O5S
    Methyl 1-(2-acetyloxyethoxymethyl)-5-(3-fluorophenyl)sulfanyl-1,2,4-triazole-3-carboxylate
    —— Methyl 1-(2-acetyloxyethoxymethyl)-5-[3-(trifluoromethyl)phenyl]sulfanyl-1,2,4-triazole-3-carboxylate 1237741-64-8 C16H16F3N3O5S
    Methyl 1-(2-acetyloxyethoxymethyl)-5-[3-(trifluoromethyl)phenyl]sulfanyl-1,2,4-triazole-3-carboxylate
    —— (3S,2S)-(-)-t-butyl 3-hydroxy-3-phenyl-2-thiophenoxypropionate 277318-40-8 C19H22O3S
    (3S,2S)-(-)-t-butyl 3-hydroxy-3-phenyl-2-thiophenoxypropionate
    —— N-[5-[[5-[(4-Acetylpiperazin-1-yl)carbonyl]-2,4-dimethylphenyl]thio]thiazol-2-yl]-4-(1,1-dimethylethyl)benzamide 439574-55-7 C29H34N4O3S2
    N-[5-[[5-[(4-Acetylpiperazin-1-yl)carbonyl]-2,4-dimethylphenyl]thio]thiazol-2-yl]-4-(1,1-dimethylethyl)benzamide
    —— Unii-O5LR0V4ple 1029125-06-1 C15H17FN2S
    Unii-O5LR0V4ple
    —— tetra(ethylthiomethyl)methane 65654-52-6 C13H28S4
    tetra(ethylthiomethyl)methane
    —— tetrakis (hexylsulphonylmethyl)methane 84466-50-2 C29H60O8S4
    tetrakis (hexylsulphonylmethyl)methane
    —— 2,6,10-trichlorodibenzo[d,g][1,3,6,2]dioxathiaphosphocin 6-sulfide 378782-15-1 C12H6Cl3O2PS2
    2,6,10-trichlorodibenzo[d,g][1,3,6,2]dioxathiaphosphocin 6-sulfide
    —— 1,3-bis-dodecylmercapto-2,2-bis-(dodecylmercapto-methyl)-propane 105198-24-1 C53H108S4
    1,3-bis-dodecylmercapto-2,2-bis-(dodecylmercapto-methyl)-propane
    —— Tetrakis-(phenylthiomethyl)-methan 16873-35-1 C29H28S4
    Tetrakis-(phenylthiomethyl)-methan
    —— N-Cyclopropyl-4-[(4-methylphenyl)thio]-2-pyrimidinamine 1158760-02-1 C14H15N3S
    N-Cyclopropyl-4-[(4-methylphenyl)thio]-2-pyrimidinamine
    —— 1-thiophenyl-5-trimethylsilyl-pent-4-yn-2-ol 158070-22-5 C14H20OSSi
    1-thiophenyl-5-trimethylsilyl-pent-4-yn-2-ol
    —— 2-methyl-6-(phenylthio)-N-(quinolin-8-yl)benzamide 1404616-67-6 C23H18N2OS
    2-methyl-6-(phenylthio)-N-(quinolin-8-yl)benzamide
    —— (2R)-3-(phenylthio)-1,2-propanediol 118206-03-4 C9H12O2S
    (2R)-3-(phenylthio)-1,2-propanediol
    —— (Z)-1-thiophenyl-5-trimethylsilyl-2-trimethylsilyloxyhex-4-ene 158070-30-5 C18H32OSSi2
    (Z)-1-thiophenyl-5-trimethylsilyl-2-trimethylsilyloxyhex-4-ene
    —— ({3-[(Prop-2-en-1-yl)oxy]prop-1-en-1-yl}sulfanyl)benzene 63540-09-0 C12H14OS
    ({3-[(Prop-2-en-1-yl)oxy]prop-1-en-1-yl}sulfanyl)benzene
    —— 2-chloro-3-phenylthiopropan-1-ol 144363-38-2 C9H11ClOS
    2-chloro-3-phenylthiopropan-1-ol
    —— 4-Aza-phenothiazin-10-carbonsaeure-dimethylamino-aethylester 408521-21-1 C16H17N3O2S
    4-Aza-phenothiazin-10-carbonsaeure-dimethylamino-aethylester
    —— 5-phenylthiomethyl-3-phenylselenotetrahydrofuran-2-one 112233-30-4 C17H16O2SSe
    5-phenylthiomethyl-3-phenylselenotetrahydrofuran-2-one
    —— 3-Methyl-2-[(phenylsulfanyl)methyl]-4-pentenal 63540-21-6 C13H16OS
    3-Methyl-2-[(phenylsulfanyl)methyl]-4-pentenal
    —— 1-chloromethyl-2-(phenylthio)ethyl methoxymethyl ether 112091-39-1 C11H15ClO2S
    1-chloromethyl-2-(phenylthio)ethyl methoxymethyl ether
    —— 3-(2-methylprop-2-enoxy)prop-1-enylsulfanylbenzene 63540-11-4 C13H16OS
    3-(2-methylprop-2-enoxy)prop-1-enylsulfanylbenzene
    —— 8-methyl-1-(phenylthio)-7-nonen-2-ol 173912-28-2 C16H24OS
    8-methyl-1-(phenylthio)-7-nonen-2-ol
    —— methyl [3-bromo-4-(cyclopropylsulfanyl)phenyl]acetate 1174229-43-6 C12H13BrO2S
    methyl [3-bromo-4-(cyclopropylsulfanyl)phenyl]acetate
    —— (E)-1-(1-Propylsulfanyl-propyldisulfanyl)-propene 137363-95-2 C9H18S3
    (E)-1-(1-Propylsulfanyl-propyldisulfanyl)-propene
    —— 6-[5-(4-Methylphenyl)furan-2-yl]-3-[(4-methylsulfanylphenyl)methyl]-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazole 1144110-92-8 C22H18N4OS2
    6-[5-(4-Methylphenyl)furan-2-yl]-3-[(4-methylsulfanylphenyl)methyl]-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazole
    —— [3-bromo-4-(cyclopropylsulfanyl)phenyl]acetic acid 1174229-42-5 C11H11BrO2S
    [3-bromo-4-(cyclopropylsulfanyl)phenyl]acetic acid
    —— (Z)-1-propenyl propyl trisulfide 23838-26-8 C6H12S3
    (Z)-1-propenyl propyl trisulfide
    —— 4-Diisopropylamino-7-methylmercapto-1H-imidazo<4,5-d>pyridazin 3438-75-3 C12H19N5S
    4-Diisopropylamino-7-methylmercapto-1H-imidazo<4,5-d>pyridazin