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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(5-Methylsulfanyl-thiophen-3-yl)-1-(tetrahydro-pyran-2-yloxy)-propan-2-ol 159615-90-4 C13H20O3S2
    2-(5-Methylsulfanyl-thiophen-3-yl)-1-(tetrahydro-pyran-2-yloxy)-propan-2-ol
    —— C,C,C-Trifluoro-N-(2-m-tolylsulfanyl-phenyl)-methanesulfonamide 62705-77-5 C14H12F3NO2S2
    C,C,C-Trifluoro-N-(2-m-tolylsulfanyl-phenyl)-methanesulfonamide
    —— <i>S</i>-hexadecyl-isothiourea; hydriodide 20204-43-7 C17H36N2S*HI
    <i>S</i>-hexadecyl-isothiourea; hydriodide
    —— C,C,C-Trifluoro-N-(2-o-tolylsulfanyl-phenyl)-methanesulfonamide 62676-81-7 C14H12F3NO2S2
    C,C,C-Trifluoro-N-(2-o-tolylsulfanyl-phenyl)-methanesulfonamide
    —— <2-Nitro-phenyl>-<m-tolyl>-sulfid 92903-56-5 C13H11NO2S
    <2-Nitro-phenyl>-<m-tolyl>-sulfid
    —— 5-p-Tolylsulfanyl-thiophene-2-sulfonic acid amide 63031-80-1 C11H11NO2S3
    5-p-Tolylsulfanyl-thiophene-2-sulfonic acid amide
    —— 5-(4-tert-Butyl-phenylsulfanyl)-thiophene-2-sulfonic acid amide 63032-18-8 C14H17NO2S3
    5-(4-tert-Butyl-phenylsulfanyl)-thiophene-2-sulfonic acid amide
    —— 5-(Naphthalen-2-ylsulfanyl)-thiophene-2-sulfonic acid amide 63032-10-0 C14H11NO2S3
    5-(Naphthalen-2-ylsulfanyl)-thiophene-2-sulfonic acid amide
    —— 5-(4-Methylsulfanyl-phenylsulfanyl)-thiophene-2-sulfonic acid amide 63031-87-8 C11H11NO2S4
    5-(4-Methylsulfanyl-phenylsulfanyl)-thiophene-2-sulfonic acid amide
    —— 5-(4-Methoxy-phenylsulfanyl)-thiophene-2-sulfonic acid amide 77893-72-2 C11H11NO3S3
    5-(4-Methoxy-phenylsulfanyl)-thiophene-2-sulfonic acid amide
    —— 5-(4-Fluoro-phenylsulfanyl)-thiophene-2-sulfonic acid amide 63031-85-6 C10H8FNO2S3
    5-(4-Fluoro-phenylsulfanyl)-thiophene-2-sulfonic acid amide
    —— 5-(3-Fluoro-phenylsulfanyl)-thiophene-2-sulfonic acid amide 63032-19-9 C10H8FNO2S3
    5-(3-Fluoro-phenylsulfanyl)-thiophene-2-sulfonic acid amide
    —— 3-(5-methylsulfanyl-[1,3,4]thiadiazol-2-yl)-pyridine 28534-83-0 C8H7N3S2
    3-(5-methylsulfanyl-[1,3,4]thiadiazol-2-yl)-pyridine
    —— 4-(phenyl(phenylthio)methyl)morpholine 51643-92-6 C17H19NOS
    4-(phenyl(phenylthio)methyl)morpholine
    —— 6-[(2-chloro-6-fluorophenyl)ethyl]-2-propylthiopyrimidin-4(3H)-one 1613669-02-5 C15H16ClFN2OS
    6-[(2-chloro-6-fluorophenyl)ethyl]-2-propylthiopyrimidin-4(3H)-one
    —— 3,5-dimethyl-4-(3'-iso-propyl-4'-methoxyphenylsulfanyl)anisole 852949-58-7 C19H24O2S
    3,5-dimethyl-4-(3'-iso-propyl-4'-methoxyphenylsulfanyl)anisole
    —— d7-propyl-thiocarbamic acid S-methyl ester 1218931-82-8 C5H11NOS
    d7-propyl-thiocarbamic acid S-methyl ester
    —— 7-phenylthiomethyl-1,4-dioxaspiro<4,5>decane 163068-98-2 C15H20O2S
    7-phenylthiomethyl-1,4-dioxaspiro<4,5>decane
    —— (S)-6-[(2-chloro-6-fluorophenyl)ethyl]-5-methyl-2-isopropylthiopyrimidin-4(3H)-one 1613669-36-5 C16H18ClFN2OS
    (S)-6-[(2-chloro-6-fluorophenyl)ethyl]-5-methyl-2-isopropylthiopyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)ethyl]-2-sec-butylthiopyrimidin-4(3H)-one 1613669-31-0 C16H18ClFN2OS
    6-[(2-chloro-6-fluorophenyl)ethyl]-2-sec-butylthiopyrimidin-4(3H)-one
    —— (R,R)-6-[1-(2-chloro-6-fluorophenyl)ethyl]-5-methyl-2-sec-butylthio-pyrimidin-4(3H)-one 1613669-37-6 C17H20ClFN2OS
    (R,R)-6-[1-(2-chloro-6-fluorophenyl)ethyl]-5-methyl-2-sec-butylthio-pyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)ethyl]-2-cyclopentylthiopyrimidin-4(3H)-one 1613669-05-8 C17H18ClFN2OS
    6-[(2-chloro-6-fluorophenyl)ethyl]-2-cyclopentylthiopyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)methyl]-2-propylthiopyrimidin-4(3H)-one 1613668-92-0 C14H14ClFN2OS
    6-[(2-chloro-6-fluorophenyl)methyl]-2-propylthiopyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)methyl]-5-methyl-2-sec-butylthiopyrimidin-4(3H)-one 1613668-98-6 C16H18ClFN2OS
    6-[(2-chloro-6-fluorophenyl)methyl]-5-methyl-2-sec-butylthiopyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)ethyl]-5-methyl-2-butylthiopyrimidin-4(3H)-one 1613669-09-2 C17H20ClFN2OS
    6-[(2-chloro-6-fluorophenyl)ethyl]-5-methyl-2-butylthiopyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)methyl]-2-sec-butylthiopyrimidin-4(3H)-one 1613668-93-1 C15H16ClFN2OS
    6-[(2-chloro-6-fluorophenyl)methyl]-2-sec-butylthiopyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)ethyl]-2-sec-butylthiopyrimidin-4(3H)-one 1613669-33-2 C16H18ClFN2OS
    6-[(2-chloro-6-fluorophenyl)ethyl]-2-sec-butylthiopyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)ethyl]-5-ethyl-2-propylthiopyrimidin-4(3H)-one 1613669-12-7 C17H20ClFN2OS
    6-[(2-chloro-6-fluorophenyl)ethyl]-5-ethyl-2-propylthiopyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)methyl]-5-methyl-2-propylthiopyrimidin-4(3H)-one 1613668-97-5 C15H16ClFN2OS
    6-[(2-chloro-6-fluorophenyl)methyl]-5-methyl-2-propylthiopyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)ethyl]-5-methyl-2-isopropylthiopyrimidin-4(3H)-one 1613669-06-9 C16H18ClFN2OS
    6-[(2-chloro-6-fluorophenyl)ethyl]-5-methyl-2-isopropylthiopyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)methyl]-2-butylthiopyrimidin-4(3H)-one 1613668-94-2 C15H16ClFN2OS
    6-[(2-chloro-6-fluorophenyl)methyl]-2-butylthiopyrimidin-4(3H)-one
    —— 6-[1-(2-chloro-6-fluorophenyl)ethyl]-5-methyl-2-sec-butylthio-pyrimidin-4(3H)-one 1613669-38-7 C17H20ClFN2OS
    6-[1-(2-chloro-6-fluorophenyl)ethyl]-5-methyl-2-sec-butylthio-pyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)ethyl]-5-ethyl-2-isopropylthiopyrimidin-4(3H)-one 1613669-11-6 C17H20ClFN2OS
    6-[(2-chloro-6-fluorophenyl)ethyl]-5-ethyl-2-isopropylthiopyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)methyl]-5-methyl-2-isopropylthiopyrimidin-4(3H)-one 1613668-96-4 C15H16ClFN2OS
    6-[(2-chloro-6-fluorophenyl)methyl]-5-methyl-2-isopropylthiopyrimidin-4(3H)-one
    —— (S,S)-6-[1-(2-chloro-6-fluorophenyl)ethyl]-5-methyl-2-sec-butylthio-pyrimidin-4(3H)-one 1613669-39-8 C17H20ClFN2OS
    (S,S)-6-[1-(2-chloro-6-fluorophenyl)ethyl]-5-methyl-2-sec-butylthio-pyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)ethyl]-5-methyl-2-propylthiopyrimidin-4(3H)-one 1613669-07-0 C16H18ClFN2OS
    6-[(2-chloro-6-fluorophenyl)ethyl]-5-methyl-2-propylthiopyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)ethyl]-2-sec-butylthiopyrimidin-4(3H)-one 1613669-32-1 C16H18ClFN2OS
    6-[(2-chloro-6-fluorophenyl)ethyl]-2-sec-butylthiopyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)ethyl]-2-sec-butylthiopyrimidin-4(3H)-one 1613669-34-3 C16H18ClFN2OS
    6-[(2-chloro-6-fluorophenyl)ethyl]-2-sec-butylthiopyrimidin-4(3H)-one
    —— 6-[1-(2-chloro-6-fluorophenyl)ethyl]-5-methyl-2-sec-butylthio-pyrimidin-4(3H)-one 1613669-40-1 C17H20ClFN2OS
    6-[1-(2-chloro-6-fluorophenyl)ethyl]-5-methyl-2-sec-butylthio-pyrimidin-4(3H)-one
    —— (R)-6-[(2-chloro-6-fluorophenyl)ethyl]-5-methyl-2-isopropylthiopyrimidin-4(3H)-one 1613669-35-4 C16H18ClFN2OS
    (R)-6-[(2-chloro-6-fluorophenyl)ethyl]-5-methyl-2-isopropylthiopyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)methyl]-5-methyl-2-butylthiopyrimidin-4(3H)-one 1613668-99-7 C16H18ClFN2OS
    6-[(2-chloro-6-fluorophenyl)methyl]-5-methyl-2-butylthiopyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)ethyl]-5-ethyl-2-cyclopentylthiopyrimidin-4(3H)-one 1613669-15-0 C19H22ClFN2OS
    6-[(2-chloro-6-fluorophenyl)ethyl]-5-ethyl-2-cyclopentylthiopyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)ethyl]-2-isopropylthiopyrimidin-4(3H)-one 1613669-01-4 C15H16ClFN2OS
    6-[(2-chloro-6-fluorophenyl)ethyl]-2-isopropylthiopyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)methyl]-2-cyclopentylthiopyrimidin-4(3H)-one 1613668-95-3 C16H16ClFN2OS
    6-[(2-chloro-6-fluorophenyl)methyl]-2-cyclopentylthiopyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)ethyl]-5-ethyl-2-sec-butylthiopyrimidin-4(3H)-one 1613669-13-8 C18H22ClFN2OS
    6-[(2-chloro-6-fluorophenyl)ethyl]-5-ethyl-2-sec-butylthiopyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)ethyl]-5-ethyl-2-butylthiopyrimidin-4(3H)-one 1613669-14-9 C18H22ClFN2OS
    6-[(2-chloro-6-fluorophenyl)ethyl]-5-ethyl-2-butylthiopyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)methyl]-5-methyl-2-cyclopentylpyrimidin-4(3H)-one 1613669-00-3 C17H18ClFN2OS
    6-[(2-chloro-6-fluorophenyl)methyl]-5-methyl-2-cyclopentylpyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)ethyl]-2-butylthiopyrimidin-4(3H)-one 1613669-04-7 C16H18ClFN2OS
    6-[(2-chloro-6-fluorophenyl)ethyl]-2-butylthiopyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)ethyl]-5-methyl-2-cyclopentylthiopyrimidin-4(3H)-one 1613669-10-5 C18H20ClFN2OS
    6-[(2-chloro-6-fluorophenyl)ethyl]-5-methyl-2-cyclopentylthiopyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)methyl]-2-isopropylthiopyrimidin-4(3H)-one 1613668-91-9 C14H14ClFN2OS
    6-[(2-chloro-6-fluorophenyl)methyl]-2-isopropylthiopyrimidin-4(3H)-one