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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-Chloro-4-(3,5-dimethyl-phenylsulfanyl)-5-ethyl-6-methyl-3-nitro-pyridine 175437-67-9 C16H17ClN2O2S
    2-Chloro-4-(3,5-dimethyl-phenylsulfanyl)-5-ethyl-6-methyl-3-nitro-pyridine
    —— [4-<sup>14</sup>C]-(R)-2-(2-amino-5-((S)-1-phenylethylthio)thiazolo[4,5-d]pyrimidin-7-ylamino)-4-methylpentan-1-ol 1403762-01-5 C19H25N5OS2
    [4-<sup>14</sup>C]-(R)-2-(2-amino-5-((S)-1-phenylethylthio)thiazolo[4,5-d]pyrimidin-7-ylamino)-4-methylpentan-1-ol
    —— ethyl 4-(3,5-dimethylphenylsulfanyl)-2-methyl-6-oxo-1,6-dihydropyridin-3-ylcarboxylate 1185189-75-6 C17H19NO3S
    ethyl 4-(3,5-dimethylphenylsulfanyl)-2-methyl-6-oxo-1,6-dihydropyridin-3-ylcarboxylate
    —— ethyl 2-acetyl-5-[(3,5-dimethylphenyl)thio]-5-(p-tolyl)pentanoate 1338781-70-6 C24H30O3S
    ethyl 2-acetyl-5-[(3,5-dimethylphenyl)thio]-5-(p-tolyl)pentanoate
    —— 3-amino-1-methyl-5-(2-mercaptoethylthio)-1,2,4-triazole 150366-95-3 C5H10N4S2
    3-amino-1-methyl-5-(2-mercaptoethylthio)-1,2,4-triazole
    —— phenyl 3-allyloxycarbonylamino-2,3,6-trideoxy-1-thio-L-lyxo-hexopyranoside 849071-48-3 C16H21NO4S
    phenyl 3-allyloxycarbonylamino-2,3,6-trideoxy-1-thio-L-lyxo-hexopyranoside
    —— 2-(1-acetonylthio)-5-methylthiazolo(2,3-b)-1,3,4-thiadiazolium perchlorate 122841-09-2 C8H9N2OS3*ClO4
    2-(1-acetonylthio)-5-methylthiazolo(2,3-b)-1,3,4-thiadiazolium perchlorate
    —— phenyl 3-azido-2,3,6-trideoxy-1-thio-L-lyxo-hexopyranoside 849071-47-2 C12H15N3O2S
    phenyl 3-azido-2,3,6-trideoxy-1-thio-L-lyxo-hexopyranoside
    —— 3-Phenylmercapto-acrylsaeure-chlorid 1077-15-2 C9H7ClOS
    3-Phenylmercapto-acrylsaeure-chlorid
    —— Methoxymethyl-vinyl-sulfid 4410-85-9 C4H8OS
    Methoxymethyl-vinyl-sulfid
    —— 5-chloromethyl-2,3-dihydro-7H-thiazolo<3,2-a>pyrimidin-7-one 111730-43-9 C7H7ClN2OS
    5-chloromethyl-2,3-dihydro-7H-thiazolo<3,2-a>pyrimidin-7-one
    —— 6-(4-fluorophenyl)-4-{[4-(trifluoromethyl)phenyl]thio}thieno[3,2-d]pyrimidine 1610410-47-3 C19H10F4N2S2
    6-(4-fluorophenyl)-4-{[4-(trifluoromethyl)phenyl]thio}thieno[3,2-d]pyrimidine
    —— 1-Cyclopent-1-enyl-2-methanesulfonyl-ethanone 74190-39-9 C8H12O3S
    1-Cyclopent-1-enyl-2-methanesulfonyl-ethanone
    —— 5-(4-nitro-phenylsulfanyl)-1<i>H</i>-tetrazole 91448-02-1 C7H5N5O2S
    5-(4-nitro-phenylsulfanyl)-1<i>H</i>-tetrazole
    —— 2-[(E)-2-(2-Chloro-phenyl)-vinyl]-3-phenylsulfanyl-quinoxaline 366018-64-6 C22H15ClN2S
    2-[(E)-2-(2-Chloro-phenyl)-vinyl]-3-phenylsulfanyl-quinoxaline
    —— ethyl 3-{4-cyano-5-[(2-ethoxy-2-oxoethyl)sulfanyl]-3-hydroxythiophen-2-yl}-3-oxopropanoate 1448180-44-6 C14H15NO6S2
    ethyl 3-{4-cyano-5-[(2-ethoxy-2-oxoethyl)sulfanyl]-3-hydroxythiophen-2-yl}-3-oxopropanoate
    —— 4,7,10-trioxa-1,13-dithia[13](6,6')-2,2'-bis(cyclopenta[c]pyridin-2-yl)cyclophane 1009834-83-6 C24H30N2O3S2
    4,7,10-trioxa-1,13-dithia[13](6,6')-2,2'-bis(cyclopenta[c]pyridin-2-yl)cyclophane
    —— 2-Methyl-2-(2-phenylsulfanyl-cyclopentyl)-[1,3]dioxolane 137846-59-4 C15H20O2S
    2-Methyl-2-(2-phenylsulfanyl-cyclopentyl)-[1,3]dioxolane
    —— 4-oxa-1,7-dithia[7](6,6')-2,2'-bis(cyclopenta[c]pyridine)cyclophane sulfoxide 1303611-48-4 C20H22N2O2S2
    4-oxa-1,7-dithia[7](6,6')-2,2'-bis(cyclopenta[c]pyridine)cyclophane sulfoxide
    —— 1,7-dithia[7](6,6')-2,2'-bis(cyclopenta[c]pyridine)cyclophane 1303611-46-2 C21H24N2S2
    1,7-dithia[7](6,6')-2,2'-bis(cyclopenta[c]pyridine)cyclophane
    —— 4,7,10,13-tetraoxa-1,16-dithia[16](6,6')-2,2'-bis(cyclopenta[c]pyridine-2-yl)cyclophane 1009834-84-7 C26H34N2O4S2
    4,7,10,13-tetraoxa-1,16-dithia[16](6,6')-2,2'-bis(cyclopenta[c]pyridine-2-yl)cyclophane
    —— 4,7-dioxa-1,10-dithia[10](6,6')-2,2'-bis(cyclopenta[c]pyridin-2-yl)cyclophane 1009834-82-5 C22H26N2O2S2
    4,7-dioxa-1,10-dithia[10](6,6')-2,2'-bis(cyclopenta[c]pyridin-2-yl)cyclophane
    —— 4-oxa-1,7-dithia[7](6,6')-2,2'-bis(cyclopenta[c]pyridine)cyclophane 1009834-81-4 C20H22N2OS2
    4-oxa-1,7-dithia[7](6,6')-2,2'-bis(cyclopenta[c]pyridine)cyclophane
    —— 5-(benzylthio)-3,4-cyclopenteno-6-methylpyridine 99702-57-5 C16H17NS
    5-(benzylthio)-3,4-cyclopenteno-6-methylpyridine
    —— 2-(but-3'-enyl)-2-formyl-1,3-dithiane oxime 127704-90-9 C9H15NOS2
    2-(but-3'-enyl)-2-formyl-1,3-dithiane oxime
    —— 4-(4-Chlor-benzylmercapto)-2-phenyl-5-morpholino-3-oxo-2,3-dihydro-pyridazin 5589-89-9 C21H20ClN3O2S
    4-(4-Chlor-benzylmercapto)-2-phenyl-5-morpholino-3-oxo-2,3-dihydro-pyridazin
    —— 4-Benzylmercapto-2-phenyl-5-morpholino-3-oxo-2,3-dihydro-pyridazin 5273-14-3 C21H21N3O2S
    4-Benzylmercapto-2-phenyl-5-morpholino-3-oxo-2,3-dihydro-pyridazin
    —— (5-Chloro-6-oxo-1-phenyl-1,6-dihydro-pyridazin-4-ylsulfanyl)-acetic acid ethyl ester 120929-91-1 C14H13ClN2O3S
    (5-Chloro-6-oxo-1-phenyl-1,6-dihydro-pyridazin-4-ylsulfanyl)-acetic acid ethyl ester
    —— (5-Chloro-3-oxo-2-phenyl-2,3-dihydro-pyridazin-4-ylsulfanyl)-acetic acid ethyl ester 120929-92-2 C14H13ClN2O3S
    (5-Chloro-3-oxo-2-phenyl-2,3-dihydro-pyridazin-4-ylsulfanyl)-acetic acid ethyl ester
    —— 2-phenyl-4,5-bis-phenylsulfanyl-2<i>H</i>-pyridazin-3-one 10005-39-7 C22H16N2OS2
    2-phenyl-4,5-bis-phenylsulfanyl-2<i>H</i>-pyridazin-3-one
    —— 4-chloro-2-phenyl-5-phenylsulfanyl-2<i>H</i>-pyridazin-3-one 86483-35-4 C16H11ClN2OS
    4-chloro-2-phenyl-5-phenylsulfanyl-2<i>H</i>-pyridazin-3-one
    —— α-[(5-chlorothiazolo[5,4-b]pyridin-2-yl)thio]-α-(p-chlorophenyl)acetic acid 85592-38-7 C14H8Cl2N2O2S2
    α-[(5-chlorothiazolo[5,4-b]pyridin-2-yl)thio]-α-(p-chlorophenyl)acetic acid
    —— 9-(3-formamidobenzyl)-6-phenylthio-9H-purine 136484-83-8 C19H15N5OS
    9-(3-formamidobenzyl)-6-phenylthio-9H-purine
    —— methylvinyl sulfone 19812-29-4 C6H10O2S
    methylvinyl sulfone
    —— 2-Chloro-4-(3-difluoromethylphenylthio)benzaldehyde 1006729-47-0 C14H9ClF2OS
    2-Chloro-4-(3-difluoromethylphenylthio)benzaldehyde
    —— (+/-)-(4E)-4-nonene-2-thiol 1006684-26-9 C9H18S
    (+/-)-(4E)-4-nonene-2-thiol
    —— 2-chloro-4-[3-(hydroxy)phenylthio]benzaldehyde 1023648-28-3 C13H9ClO2S
    2-chloro-4-[3-(hydroxy)phenylthio]benzaldehyde
    —— 1-methanesulfonyl-trans-2-butene 1097629-28-1 C5H10O2S
    1-methanesulfonyl-trans-2-butene
    —— 3-m-Tolylsulfanyl-thiophene 1027587-43-4 C11H10S2
    3-m-Tolylsulfanyl-thiophene
    —— 2-[1-(cyclohexyloxy)-3-(phenylthio)-2-propyn-1-yl]thiophene 1356910-94-5 C19H20OS2
    2-[1-(cyclohexyloxy)-3-(phenylthio)-2-propyn-1-yl]thiophene
    —— 2-(1-hydroxy-1-ethylbutyl)-2-methyl-1,3-dithiolane 211739-92-3 C10H20OS2
    2-(1-hydroxy-1-ethylbutyl)-2-methyl-1,3-dithiolane
    —— 2-[1-(p-chlorophenylthio)-3-(phenylsulfanyl)prop-2-ynyl]thiophene 1356911-69-7 C19H13ClS3
    2-[1-(p-chlorophenylthio)-3-(phenylsulfanyl)prop-2-ynyl]thiophene
    —— β-dichloromethylsulfonylpropionic acid 86694-66-8 C4H6Cl2O4S
    β-dichloromethylsulfonylpropionic acid
    —— ethyl β-dichloromethylsulfonylpropionate 119451-35-3 C6H10Cl2O4S
    ethyl β-dichloromethylsulfonylpropionate
    —— amide of β-dichloromethylsulfonylpropionic acid 86694-67-9 C4H7Cl2NO3S
    amide of β-dichloromethylsulfonylpropionic acid
    —— N,N'-dimethylamide of β-dichloromethylsulfonylpropionic acid 119451-23-9 C6H11Cl2NO3S
    N,N'-dimethylamide of β-dichloromethylsulfonylpropionic acid
    —— 2-<2-Chlor-aethoxy>-diaethylsulfon 90482-22-7 C6H13ClO3S
    2-<2-Chlor-aethoxy>-diaethylsulfon
    —— 2-<5-chloro-2-(4-isopropylphenylthio)phenyl>acetic acid 91528-06-2 C17H17ClO2S
    2-<5-chloro-2-(4-isopropylphenylthio)phenyl>acetic acid
    —— Ethyl 3-phenyl-3,3-bis(phenylthio)propionate 75794-13-7 C23H22O2S2
    Ethyl 3-phenyl-3,3-bis(phenylthio)propionate
    —— ethyl 2'-chloro-4'-(3-methoxyphenylthio)phenylacetate 509089-11-6 C17H17ClO3S
    ethyl 2'-chloro-4'-(3-methoxyphenylthio)phenylacetate