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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 6-phenylsulfanylhex-3-en-2-one 1415577-49-9 C12H14OS
    6-phenylsulfanylhex-3-en-2-one
    —— 6-(Carboxymethyl)-3-propyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine 1017422-92-2 C9H12N4O2S
    6-(Carboxymethyl)-3-propyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— 2-Methyl-2-[(5-nitro-2-pyridinyl)sulfanyl]-propanoic acid 952183-12-9 C9H10N2O4S
    2-Methyl-2-[(5-nitro-2-pyridinyl)sulfanyl]-propanoic acid
    —— Hexatriacontyl carbamimidothioate;hydrobromide 7509-95-7 C37H77BrN2S
    Hexatriacontyl carbamimidothioate;hydrobromide
    —— 4-(Methoxymethyl)-6-[(4-methylbenzyl)sulfanyl]-2-phenylpyrimidine 939762-12-6 C19H18N2OS
    4-(Methoxymethyl)-6-[(4-methylbenzyl)sulfanyl]-2-phenylpyrimidine
    —— Bis(1-chlorocyclopropyl) sulfone 27531-51-7 C6H8Cl2O2S
    Bis(1-chlorocyclopropyl) sulfone
    —— 2-(Prop-2-en-1-ylsulfanyl)[1,2,4]triazolo[1,5-a][1,3,5]triazin-7-amine 1011408-20-0 C7H8N6S
    2-(Prop-2-en-1-ylsulfanyl)[1,2,4]triazolo[1,5-a][1,3,5]triazin-7-amine
    —— Dotriacontyl carbamimidothioate;hydrobromide 7461-14-5 C33H69BrN2S
    Dotriacontyl carbamimidothioate;hydrobromide
    —— 5,7-diamino-3-phenyl-2-(4-methoxyphenylthio)quinoxaline 1135231-22-9 C21H18N4OS
    5,7-diamino-3-phenyl-2-(4-methoxyphenylthio)quinoxaline
    —— 2-[(2-Methylsulfanylpyrimidin-4-yl)amino]-1-phenylethanol;hydrochloride 3610-56-8 C13H16ClN3OS
    2-[(2-Methylsulfanylpyrimidin-4-yl)amino]-1-phenylethanol;hydrochloride
    —— 2-(Pyridyl)-2-thiopseudourea, N-oxide 1126-15-4 C6H7BrN3OS-
    2-(Pyridyl)-2-thiopseudourea, N-oxide
    —— N-methyl-1-[4-methyl-3-(trimethylazaniumyl)phenyl]sulfanylmethanimidate;hydroiodide —— C12H19IN2OS
    N-methyl-1-[4-methyl-3-(trimethylazaniumyl)phenyl]sulfanylmethanimidate;hydroiodide
    —— N-methyl-1-[4-(trimethylazaniumyl)phenyl]sulfanylmethanimidate;hydroiodide —— C11H17IN2OS
    N-methyl-1-[4-(trimethylazaniumyl)phenyl]sulfanylmethanimidate;hydroiodide
    —— Dimethyl(tricyclo[3.3.1.1~3,7~]decan-1-yl)sulfanium iodide 37818-84-1 C12H21IS
    Dimethyl(tricyclo[3.3.1.1~3,7~]decan-1-yl)sulfanium iodide
    —— 2-Amino-3-(methylsulfanylmethylsulfanyl)propan-1-ol;hydrochloride 61827-16-5 C5H14ClNOS2
    2-Amino-3-(methylsulfanylmethylsulfanyl)propan-1-ol;hydrochloride
    —— (3E)-3-(11,12-dihydrobenzo[d][1]benzothiocin-5-ylidene)-N,N-dimethylpropan-1-amine;hydrochloride 2178-12-3 C20H24ClNS
    (3E)-3-(11,12-dihydrobenzo[d][1]benzothiocin-5-ylidene)-N,N-dimethylpropan-1-amine;hydrochloride
    —— (3E)-3-(11,12-dihydrobenzo[d][1]benzothiocin-5-ylidene)-N-methylpropan-1-amine;hydrochloride 2178-07-6 C19H22ClNS
    (3E)-3-(11,12-dihydrobenzo[d][1]benzothiocin-5-ylidene)-N-methylpropan-1-amine;hydrochloride
    —— 1,5,6-Trimethyl-3-(methylsulfanyl)-1,2,4-triazin-1-ium iodide 35102-18-2 C7H12IN3S
    1,5,6-Trimethyl-3-(methylsulfanyl)-1,2,4-triazin-1-ium iodide
    —— N-methyl-N-[methyl-(methylsulfonylmethylidene)-oxo-lambda6-sulfanyl]methanamine 38709-87-4 C5H13NO3S2
    N-methyl-N-[methyl-(methylsulfonylmethylidene)-oxo-lambda6-sulfanyl]methanamine
    —— 38709-81-8 C6H13NO2S
    —— (2,2-Dimethyl-1,1-dioxo-1λ<sup>6</sup>-thietan-3-yl)-trimethyl-ammonium; iodide 92658-16-7 C8H18NO2S*I
    (2,2-Dimethyl-1,1-dioxo-1λ<sup>6</sup>-thietan-3-yl)-trimethyl-ammonium; iodide
    —— 2-(1-Methoxyethyl)-N,N,N-trimethyl-1,1-dioxo-1lambda~6~-thietan-3-aminium iodide 17346-39-3 C9H20INO3S
    2-(1-Methoxyethyl)-N,N,N-trimethyl-1,1-dioxo-1lambda~6~-thietan-3-aminium iodide
    —— 3-(4-Aminophenyl)sulfanylpropanoic acid;hydrochloride 30086-22-7 C9H12ClNO2S
    3-(4-Aminophenyl)sulfanylpropanoic acid;hydrochloride
    —— Bis(2-aminoethylsulfanyl)methanone;hydrochloride 13889-99-1 C5H13ClN2OS2
    Bis(2-aminoethylsulfanyl)methanone;hydrochloride
    —— 1-Dimethylamino-7-thia-bicyclo<4.2.0>octan-7,7-dioxid-methoiodid 944-08-1 C10H20NO2S*I
    1-Dimethylamino-7-thia-bicyclo<4.2.0>octan-7,7-dioxid-methoiodid
    —— 2-(3,5-Dioxo-2,3,4,5-tetrahydro-as-triazin-6-yl)-2-thiopseudourea hydrobromide 4956-09-6 C4H6BrN5O2S
    2-(3,5-Dioxo-2,3,4,5-tetrahydro-as-triazin-6-yl)-2-thiopseudourea hydrobromide
    —— 2-(3-Nitro-pyridyl-(2)-isothiuronium-chlorid 5897-92-7 C6H6N4O2S*ClH
    2-(3-Nitro-pyridyl-(2)-isothiuronium-chlorid
    —— 2-[4-(2-Aminoethyldisulfanyl)butyldisulfanyl]ethanamine;hydrochloride 92443-09-9 C8H21ClN2S4
    2-[4-(2-Aminoethyldisulfanyl)butyldisulfanyl]ethanamine;hydrochloride
    —— 5-[(4-Chlorophenyl)sulfanylmethyl]-4-(hydroxymethyl)-2-methylpyridin-3-ol;hydrochloride 92253-14-0 C14H15Cl2NO2S
    5-[(4-Chlorophenyl)sulfanylmethyl]-4-(hydroxymethyl)-2-methylpyridin-3-ol;hydrochloride
    —— 2-[2-(dimethylamino)ethylsulfonylsulfanyl]-N,N-dimethylethanamine;hydrochloride 92400-42-5 C8H21ClN2O2S2
    2-[2-(dimethylamino)ethylsulfonylsulfanyl]-N,N-dimethylethanamine;hydrochloride
    —— N,N-dimethyl-2-(2,3,4,5,6-pentachlorophenyl)sulfanylethanamine;hydrochloride 90917-26-3 C10H11Cl6NS
    N,N-dimethyl-2-(2,3,4,5,6-pentachlorophenyl)sulfanylethanamine;hydrochloride
    —— 1-(2-Phenylethyl)-2-[(2-phenylethyl)sulfanyl]pyridin-1-ium bromide 6278-00-8 C21H22BrNS
    1-(2-Phenylethyl)-2-[(2-phenylethyl)sulfanyl]pyridin-1-ium bromide
    —— 2-(2,3,3,4,5,5-Hexamethylhexan-2-yltrisulfanyl)-2,3,3,4,5,5-hexamethylhexane —— C24H50S3
    2-(2,3,3,4,5,5-Hexamethylhexan-2-yltrisulfanyl)-2,3,3,4,5,5-hexamethylhexane
    —— Di-tert-nonyl polysulfide 1135094-37-9 C18H38S3
    Di-tert-nonyl polysulfide
    —— 2,4,4-Trimethyl-1,2-bis(2,4,4-trimethylpentan-2-yltetrasulfanyl)pentane —— C24H50S8
    2,4,4-Trimethyl-1,2-bis(2,4,4-trimethylpentan-2-yltetrasulfanyl)pentane
    —— 5-Methyl-2-furyl-(4-methylthiophenyl)methanol 356552-81-3 C13H14O2S
    5-Methyl-2-furyl-(4-methylthiophenyl)methanol
    —— 4-(phenylsulfanylmethyl)-1-[[(2R,5S)-5-[(2S,5R)-5-[[4-(phenylsulfanylmethyl)triazol-1-yl]methyl]oxolan-2-yl]oxolan-2-yl]methyl]triazole 1135700-38-7 C28H32N6O2S2
    4-(phenylsulfanylmethyl)-1-[[(2R,5S)-5-[(2S,5R)-5-[[4-(phenylsulfanylmethyl)triazol-1-yl]methyl]oxolan-2-yl]oxolan-2-yl]methyl]triazole
    —— 5,5a(2)-[(6-Chloro-2,3-quinoxalinediyl)bis(thio)]bis[1,3,4-thiadiazol-2-amine] 353257-53-1 C12H7ClN8S4
    5,5a(2)-[(6-Chloro-2,3-quinoxalinediyl)bis(thio)]bis[1,3,4-thiadiazol-2-amine]
    —— potassium N,N-dimethylthiocarbamate 40033-86-1 C3H6NOS*K
    potassium N,N-dimethylthiocarbamate
    —— Sodium;2-[2-(5-chlorothiophen-2-yl)-5-(4-methylsulfanylphenyl)furan-3-yl]acetate 683251-30-1 C17H12ClO3S2*Na
    Sodium;2-[2-(5-chlorothiophen-2-yl)-5-(4-methylsulfanylphenyl)furan-3-yl]acetate
    —— (5R,6R)-5,6-bis[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]-5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiine-2-thione 957128-64-2 C15H20O4S5
    (5R,6R)-5,6-bis[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]-5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiine-2-thione
    —— OS-methyl 2-methylthioperoxybutyrate 94133-52-5 C6H12O2S
    OS-methyl 2-methylthioperoxybutyrate
    —— Ethyl carbonotrithioate 1118-64-5 C3H5S3-
    Ethyl carbonotrithioate
    —— Pyridine, 2-[(4-chloro-2-buten-1-yl)thio]-5-(trifluoromethyl)- 1344842-99-4 C10H9ClF3NS
    Pyridine, 2-[(4-chloro-2-buten-1-yl)thio]-5-(trifluoromethyl)-
    —— 2-[[2-(Methylamino)ethyl]sulfinyl]ethanol 1173400-47-9 C5H13NO2S
    2-[[2-(Methylamino)ethyl]sulfinyl]ethanol
    —— 5-amino-6-[[(4R,5R)-5-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]-2,2-dimethyl-1,3-dioxolan-4-yl]methylsulfanyl]-1H-pyrimidine-2,4-dione 952288-36-7 C15H23N3O6S
    5-amino-6-[[(4R,5R)-5-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]-2,2-dimethyl-1,3-dioxolan-4-yl]methylsulfanyl]-1H-pyrimidine-2,4-dione
    —— 4-[[(4R,5R)-5-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]-2,2-dimethyl-1,3-dioxolan-4-yl]methylsulfanyl]-2,6-dimethoxy-5-nitropyrimidine 952288-34-5 C17H25N3O8S
    4-[[(4R,5R)-5-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]-2,2-dimethyl-1,3-dioxolan-4-yl]methylsulfanyl]-2,6-dimethoxy-5-nitropyrimidine
    —— [2-(3-benzenesulfanyl-1H-indol-7-yloxy)-ethyl]-methyl-carbamic acid tert-butyl ester 706784-09-0 C22H26N2O3S
    [2-(3-benzenesulfanyl-1H-indol-7-yloxy)-ethyl]-methyl-carbamic acid tert-butyl ester
    —— 3-Methylthietan-1,1-dioxid 25903-07-5 C4H8O2S
    3-Methylthietan-1,1-dioxid
    —— 5-Chloro-2-(2-methyl-4-nitrophenyl)sulfanyl-1,3-benzothiazole 315227-75-9 C14H9ClN2O2S2
    5-Chloro-2-(2-methyl-4-nitrophenyl)sulfanyl-1,3-benzothiazole