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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-allyloxy-1,1-difluoro-2-(2'-methoxyethoxymethoxy)-4,4-[1,3]dithian-2-ylhepta-1,6-diene 864532-95-6 C17H26F2O4S2
    3-allyloxy-1,1-difluoro-2-(2'-methoxyethoxymethoxy)-4,4-[1,3]dithian-2-ylhepta-1,6-diene
    —— 4,4-difluoro-7-([1,3]dithian-2-yl)-5-(2'-methoxyethoxymethoxy)deca-1,5Z,9-trien-3-ol 864532-98-9 C17H26F2O4S2
    4,4-difluoro-7-([1,3]dithian-2-yl)-5-(2'-methoxyethoxymethoxy)deca-1,5Z,9-trien-3-ol
    —— 1,1'-(Hexa-2,4-diyne-1,6-diyldisulfanediyl)bis(4-methylbenzene) 75368-08-0 C20H18S2
    1,1'-(Hexa-2,4-diyne-1,6-diyldisulfanediyl)bis(4-methylbenzene)
    —— 2-(6-chloro-2-methylsulfanyl-pyrimidin-4-yl-amino)-ethanol 932046-82-7 C7H10ClN3OS
    2-(6-chloro-2-methylsulfanyl-pyrimidin-4-yl-amino)-ethanol
    —— bis(1,2-tributylstannyl)-3-p-tolylthiopropene 155197-75-4 C34H64SSn2
    bis(1,2-tributylstannyl)-3-p-tolylthiopropene
    —— (2E,6E)-2,7-Dimethyl-1,8-bis(phenylthio)octa-2,6-diene 128243-73-2 C22H26S2
    (2E,6E)-2,7-Dimethyl-1,8-bis(phenylthio)octa-2,6-diene
    —— tert-butyl N-[(2S)-2-(1,3-benzodithiol-2-yl)-3-hydroxypropyl]-N-methylcarbamate 1333204-00-4 C16H23NO3S2
    tert-butyl N-[(2S)-2-(1,3-benzodithiol-2-yl)-3-hydroxypropyl]-N-methylcarbamate
    —— 3-(3-(tert-butylthio)pyridin-2-yl)propanenitrile 1147849-33-9 C12H16N2S
    3-(3-(tert-butylthio)pyridin-2-yl)propanenitrile
    —— 2-(3-(tert-butylthio)pyridin-2-yl)ethanamine 1147849-29-3 C11H18N2S
    2-(3-(tert-butylthio)pyridin-2-yl)ethanamine
    —— phosphoric acid diethyl ester 5-ethylsulfanyl-1-methyl-6-oxo-1,6-dihydro-pyridazin-4-yl ester 37839-90-0 C11H19N2O5PS
    phosphoric acid diethyl ester 5-ethylsulfanyl-1-methyl-6-oxo-1,6-dihydro-pyridazin-4-yl ester
    —— 1,3,5-tris(phenylthio)benzene 3379-62-2 C24H18S3
    1,3,5-tris(phenylthio)benzene
    —— (5-bromo-1,3-phenylene)bis(methylsulfane) 149428-38-6 C8H9BrS2
    (5-bromo-1,3-phenylene)bis(methylsulfane)
    —— 3.5-dibromophenyl 4-tert-butylphenyl sulphide 135049-37-5 C16H16Br2S
    3.5-dibromophenyl 4-tert-butylphenyl sulphide
    —— 5-cyano-2-methyl-6-methylthio-1-phenylpyrimidin-4(1H)-one 111479-75-5 C13H11N3OS
    5-cyano-2-methyl-6-methylthio-1-phenylpyrimidin-4(1H)-one
    —— 5-cyano-2-methyl-6-methylthio-3-phenylpyrimidin-4(3H)-one 111479-74-4 C13H11N3OS
    5-cyano-2-methyl-6-methylthio-3-phenylpyrimidin-4(3H)-one
    —— tert-butyl-2-({4-[((2-methoxyethyl){2-[3-methylphenyl]pyrimidin-4-yl}amino)methyl]phenyl}-thio)-2-methylpropanoate 881687-39-4 C29H37N3O3S
    tert-butyl-2-({4-[((2-methoxyethyl){2-[3-methylphenyl]pyrimidin-4-yl}amino)methyl]phenyl}-thio)-2-methylpropanoate
    —— 2-Methylamino-aethyl-2-methylamino-aethanthiolsulfonat 90993-34-3 C6H16N2O2S2
    2-Methylamino-aethyl-2-methylamino-aethanthiolsulfonat
    —— 4-(2,6-Dinitro-4-trifluoromethyl-phenylsulfanyl)-phenylamine 128730-87-0 C13H8F3N3O4S
    4-(2,6-Dinitro-4-trifluoromethyl-phenylsulfanyl)-phenylamine
    —— Aethyl-N-vinylformimidat 30698-08-9 C5H9NS
    Aethyl-N-vinylformimidat
    —— 1,1,3-(trisphenylthio)propane 69519-81-9 C21H20S3
    1,1,3-(trisphenylthio)propane
    —— 1-Methoxy-1-phenylthio-2-propin 13864-98-7 C10H10OS
    1-Methoxy-1-phenylthio-2-propin
    —— 4,6-dichloro-2-[(2,3-difluorobenzyl)thio]pyrimidine-5-carbaldehyde oxime 666752-62-1 C12H7Cl2F2N3OS
    4,6-dichloro-2-[(2,3-difluorobenzyl)thio]pyrimidine-5-carbaldehyde oxime
    —— Triacontyl carbamimidothioate 5249-97-8 C31H64N2S
    Triacontyl carbamimidothioate
    —— (S)-4-[2'-(4''-Hydroxybutyl)-1',3'-dithian-2'-yl]butane-1,3-diol 319911-64-3 C12H24O3S2
    (S)-4-[2'-(4''-Hydroxybutyl)-1',3'-dithian-2'-yl]butane-1,3-diol
    —— tert-butyl {2-[(3-{2-[2-(tetrahydro-2H-pyran-2-yloxy)ethoxy]phenyl}[1,2,4]triazolo[4,3-a]pyridin-6-yl)thio]benzyl}carbamate 1344738-23-3 C31H36N4O5S
    tert-butyl {2-[(3-{2-[2-(tetrahydro-2H-pyran-2-yloxy)ethoxy]phenyl}[1,2,4]triazolo[4,3-a]pyridin-6-yl)thio]benzyl}carbamate
    —— ethyl 2-phenylthiobut-2-enoate 77873-90-6 C12H14O2S
    ethyl 2-phenylthiobut-2-enoate
    —— 4-(2-tetrahydropyranyloxyethylthio)-bromobenzene 1349856-50-3 C13H17BrO2S
    4-(2-tetrahydropyranyloxyethylthio)-bromobenzene
    —— 2-[2-(2-bromophenylsulfanyl)ethoxy]tetrahydropyran 863579-25-3 C13H17BrO2S
    2-[2-(2-bromophenylsulfanyl)ethoxy]tetrahydropyran
    —— 5-t-Butylsulfonylpent-1-en 64818-54-8 C9H18O2S
    5-t-Butylsulfonylpent-1-en
    —— 3-(4-Pentenylthio)-1-propanol 143144-51-8 C8H16OS
    3-(4-Pentenylthio)-1-propanol
    —— p-chlorophenyl α-fluoropropargyl sulfide 349146-78-7 C9H6ClFS
    p-chlorophenyl α-fluoropropargyl sulfide
    —— {6-[2-amino-4-fluoro-5-(1-methyl-1H-imidazol-2-ylsulfanyl)-benzoylamino]-pyridin-3-yl}-methyl-phosphinic acid isopropyl ester 1119778-30-1 C20H23FN5O3PS
    {6-[2-amino-4-fluoro-5-(1-methyl-1H-imidazol-2-ylsulfanyl)-benzoylamino]-pyridin-3-yl}-methyl-phosphinic acid isopropyl ester
    —— 1-Chloro-4-[6-(4-chlorophenyl)sulfanylhexa-2,4-diynylsulfanyl]benzene 75354-78-8 C18H12Cl2S2
    1-Chloro-4-[6-(4-chlorophenyl)sulfanylhexa-2,4-diynylsulfanyl]benzene
    —— 1-Chloro-4-prop-1-ynylsulfanyl-benzene 85143-30-2 C9H7ClS
    1-Chloro-4-prop-1-ynylsulfanyl-benzene
    —— p-chlorophenyl α-fluoroallenyl sulfide 349146-83-4 C9H6ClFS
    p-chlorophenyl α-fluoroallenyl sulfide
    —— (2-Phenylsulfanyl-pyrrol-1-yl)-acetic acid 214270-54-9 C12H11NO2S
    (2-Phenylsulfanyl-pyrrol-1-yl)-acetic acid
    —— (2-Phenylsulfanyl-pyrrol-1-yl)-selenoacetic acid Se-methyl ester 214270-55-0 C13H13NOSSe
    (2-Phenylsulfanyl-pyrrol-1-yl)-selenoacetic acid Se-methyl ester
    —— 10-Cyan-decylisothiocyanat 108488-82-0 C12H20N2S
    10-Cyan-decylisothiocyanat
    —— 3-(Ethylthio)propyl 4-pentenyl sulfide 143144-41-6 C10H20S2
    3-(Ethylthio)propyl 4-pentenyl sulfide
    —— 2-[2,3-bis(isopropylthio)benzyl]pyrimidine 332101-38-9 C17H22N2S2
    2-[2,3-bis(isopropylthio)benzyl]pyrimidine
    —— 2-[2,3-bis(isopropylthio)benzyl]pyridine 332101-34-5 C18H23NS2
    2-[2,3-bis(isopropylthio)benzyl]pyridine
    —— 2,3-bis(isopropylthio)-1-[2-(N-tert-butoxycarbonylamino)ethyl]benzene 165283-79-4 C19H31NO2S2
    2,3-bis(isopropylthio)-1-[2-(N-tert-butoxycarbonylamino)ethyl]benzene
    —— n-Butyl-propinyl-(2)-sulfon 15259-73-1 C7H12O2S
    n-Butyl-propinyl-(2)-sulfon
    —— S-isopropylisothiourea 6913-17-3 C4H10N2S
    S-isopropylisothiourea
    —— N,N,3,3-Tetramethyl-2-thioxobutansaeurethioamid 74128-99-7 C8H15NS2
    N,N,3,3-Tetramethyl-2-thioxobutansaeurethioamid
    —— 3,3-bis((2'-hydroxyethyl)thio)cyclobutanecarbonitrile 125331-82-0 C9H15NO2S2
    3,3-bis((2'-hydroxyethyl)thio)cyclobutanecarbonitrile
    —— 3-(4'-methylthiophenyl)-4-(4'-fluorophenyl)thiophene 157671-90-4 C17H13FS2
    3-(4'-methylthiophenyl)-4-(4'-fluorophenyl)thiophene
    —— 8-oxa-5-thiaspiro<3.4>octane-2-carbonitrile 906633-25-8 C7H9NOS
    8-oxa-5-thiaspiro<3.4>octane-2-carbonitrile
    —— N-(3,5-Bis-methylsulfanyl-[1,2,4]triazol-4-yl)-2,4-dimethyl-benzamidine 86663-48-1 C13H17N5S2
    N-(3,5-Bis-methylsulfanyl-[1,2,4]triazol-4-yl)-2,4-dimethyl-benzamidine
    —— N,N-3,3-Tetramethyl-2-oxobutansaeurethioamid 60166-89-4 C8H15NOS
    N,N-3,3-Tetramethyl-2-oxobutansaeurethioamid