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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— Acetanilide, 2-(diethylamino)-N-methyl-4'-(phenylthio)-, oxalate, hydrate (4:4:1) 77711-43-4 C21H26N2O5S
    Acetanilide, 2-(diethylamino)-N-methyl-4'-(phenylthio)-, oxalate, hydrate (4:4:1)
    —— 2,4,6-trithiaheptane 2,2-dioxide 197845-95-7 C4H10O2S3
    2,4,6-trithiaheptane 2,2-dioxide
    —— 2-[{(methylsulfonyl)methyl}sulfanyl]ethanol 68483-74-9 C4H10O3S2
    2-[{(methylsulfonyl)methyl}sulfanyl]ethanol
    —— (5-Benzyl-2-thienylthio)-acetic Acid 58386-04-2 C13H12O2S2
    (5-Benzyl-2-thienylthio)-acetic Acid
    —— 1-Piperidineacetamide, N-methyl-N-(p-(phenylthio)phenyl)-, oxalate 77711-47-8 C22H26N2O5S
    1-Piperidineacetamide, N-methyl-N-(p-(phenylthio)phenyl)-, oxalate
    —— [5-(p-Chlorophenyl)-2-thienylthio]-acetic Acid 58386-03-1 C12H9ClO2S2
    [5-(p-Chlorophenyl)-2-thienylthio]-acetic Acid
    —— Acetic acid 3-[4-(3,5-dimethyl-phenylsulfanyl)-5-nitro-6-oxo-1,6-dihydro-pyridin-2-yl]-propyl ester 175437-64-6 C18H20N2O5S
    Acetic acid 3-[4-(3,5-dimethyl-phenylsulfanyl)-5-nitro-6-oxo-1,6-dihydro-pyridin-2-yl]-propyl ester
    —— 2-Methylthio-4-phenylthiophene 72814-47-2 C11H10S2
    2-Methylthio-4-phenylthiophene
    —— 3-chloro-4-(napthalen-2-ylsulfanyl)-phenylamine 76590-40-4 C16H12ClNS
    3-chloro-4-(napthalen-2-ylsulfanyl)-phenylamine
    —— 1-(Dimethylamino)-5-(phenylthio)-3,4-pyrazoldicarbonsaeure-dimethylester 79489-82-0 C15H17N3O4S
    1-(Dimethylamino)-5-(phenylthio)-3,4-pyrazoldicarbonsaeure-dimethylester
    —— 2-methyl-5-(methylthio)-3-phenylfuran 84735-61-5 C12H12OS
    2-methyl-5-(methylthio)-3-phenylfuran
    —— 6-Methylsulfanyl-4-phenyl-pyran-2-one 128951-26-8 C12H10O2S
    6-Methylsulfanyl-4-phenyl-pyran-2-one
    —— 4-tosyl-2-p-tolylthio-5-chloro-1,3-thiazole 557773-57-6 C17H14ClNO2S3
    4-tosyl-2-p-tolylthio-5-chloro-1,3-thiazole
    —— 4-(3-hydroxypropane-1-thio)-2,6-bis(1,3-dioxolan-2-yl)pyridine 656826-69-6 C14H19NO5S
    4-(3-hydroxypropane-1-thio)-2,6-bis(1,3-dioxolan-2-yl)pyridine
    —— 4,5-diphenyl-3-methoxycarbonyl-6-methylthio-2-pyrone 77022-26-5 C20H16O4S
    4,5-diphenyl-3-methoxycarbonyl-6-methylthio-2-pyrone
    —— 3-cyano-6-ethylthio-4,5-diphenyl-2-pyrone 77022-30-1 C20H15NO2S
    3-cyano-6-ethylthio-4,5-diphenyl-2-pyrone
    —— bisbenzo[b]thieno[2,3-b:3',2'-e]-1,4-dithiin 19676-55-2 C16H8S4
    bisbenzo[b]thieno[2,3-b:3',2'-e]-1,4-dithiin
    —— (+/-)-2-Methyl-octylisothiocyanat 91351-15-4 C10H19NS
    (+/-)-2-Methyl-octylisothiocyanat
    —— 3,3'-thiobis(benzo[b]thiophene) 20896-21-3 C16H10S3
    3,3'-thiobis(benzo[b]thiophene)
    —— bromomethyl methyl sulfone 78967-61-0 C2H5BrO2S
    bromomethyl methyl sulfone
    —— 3-(thien-2-yl)-5-(4,4-difluorobut-3-enylthio)isoxazole 172932-81-9 C11H9F2NOS2
    3-(thien-2-yl)-5-(4,4-difluorobut-3-enylthio)isoxazole
    —— 4-Aza-phenothiazin-10-carbonsaeure-1-diaethylamino-propylester-3 100195-68-4 C19H23N3O2S
    4-Aza-phenothiazin-10-carbonsaeure-1-diaethylamino-propylester-3
    —— N-[1-(1,1-dioxido-2(R)-thietanyl)cyclohexyl]-2-methyl-2-propane-(S)-sulfinamide 865469-61-0 C13H25NO3S2
    N-[1-(1,1-dioxido-2(R)-thietanyl)cyclohexyl]-2-methyl-2-propane-(S)-sulfinamide
    —— 5-cyclohexyl-4-(phenylthiomethyl)penta-2(Z),4(Z)-dienoic acid diethylamide 1415313-09-5 C22H31NOS
    5-cyclohexyl-4-(phenylthiomethyl)penta-2(Z),4(Z)-dienoic acid diethylamide
    —— 6-ethoxycarbonylmethylenethio-1-methyluracil 193196-38-2 C9H12N2O4S
    6-ethoxycarbonylmethylenethio-1-methyluracil
    —— 6-phenyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thidiazine 22184-39-0 C10H8N4S
    6-phenyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thidiazine
    —— 1,4-dimethyl-5-(1-methyl-5-methylthiopyrrol-2-oyl)pyrrole-2-acetic acid 86187-06-6 C15H18N2O3S
    1,4-dimethyl-5-(1-methyl-5-methylthiopyrrol-2-oyl)pyrrole-2-acetic acid
    —— ethyl 1-methyl-5-(methylthio)pyrrole-2-acetate 121192-95-8 C10H15NO2S
    ethyl 1-methyl-5-(methylthio)pyrrole-2-acetate
    —— 6-methoxycarbonylmethylenethio-1-methyluracil 193196-39-3 C8H10N2O4S
    6-methoxycarbonylmethylenethio-1-methyluracil
    —— 2-benzyl-2,3-dihydrobenzo[b]thiophene 1398124-09-8 C15H14S
    2-benzyl-2,3-dihydrobenzo[b]thiophene
    —— 2-(4-Trifluoromethylsulfanyl-benzyl)-malonic acid diethyl ester 29805-57-0 C15H17F3O4S
    2-(4-Trifluoromethylsulfanyl-benzyl)-malonic acid diethyl ester
    —— 4-chloro-2-{[4-(methylsulfonyl) phenyl]thio}phenol 847148-23-6 C13H11ClO3S2
    4-chloro-2-{[4-(methylsulfonyl) phenyl]thio}phenol
    —— N-ethyl-N-(2-hydroxycyclohexyl)-4-(1-methyl-1,2,3,4-tetrazol-5-yl)thio-butyramide 80464-16-0 C14H25N5O2S
    N-ethyl-N-(2-hydroxycyclohexyl)-4-(1-methyl-1,2,3,4-tetrazol-5-yl)thio-butyramide
    —— 9-isothiocyanatopupukeanane 693259-26-6 C16H25NS
    9-isothiocyanatopupukeanane
    —— N-Furfuryl-4-(1-methyl-1,2,3,4-tetrazol-5-yl)thio-butyramide 80464-03-5 C11H15N5O2S
    N-Furfuryl-4-(1-methyl-1,2,3,4-tetrazol-5-yl)thio-butyramide
    —— 1-Methyl-5-[3-(5-methyl-1,3,4-oxadiazol-2-yl)thiopropyl]thio-1,2,3,4-tetrazole 80086-85-7 C8H12N6OS2
    1-Methyl-5-[3-(5-methyl-1,3,4-oxadiazol-2-yl)thiopropyl]thio-1,2,3,4-tetrazole
    —— N-Ethyl-N-(pyridin-2-yl)-4-(1-methyl-1,2,3,4-tetrazol-5-yl)thio-butyramide 80464-10-4 C13H18N6OS
    N-Ethyl-N-(pyridin-2-yl)-4-(1-methyl-1,2,3,4-tetrazol-5-yl)thio-butyramide
    —— 1-Methyl-5-[3-(pyridin-4-yl)thiopropyl]thio-1,2,3,4-tetrazole 80087-02-1 C10H13N5S2
    1-Methyl-5-[3-(pyridin-4-yl)thiopropyl]thio-1,2,3,4-tetrazole
    —— 2-(4-Ethylsulfanyl-phenylsulfanyl)-N-hydroxy-acetamidine 79506-78-8 C10H14N2OS2
    2-(4-Ethylsulfanyl-phenylsulfanyl)-N-hydroxy-acetamidine
    —— 1-Methyl-5-[3-(N-ethyl-N-cyclopentylcarbonylamino)propyl]thio-1,2,3,4-tetrazole 80085-45-6 C13H23N5OS
    1-Methyl-5-[3-(N-ethyl-N-cyclopentylcarbonylamino)propyl]thio-1,2,3,4-tetrazole
    —— Pyridinium-2,3,4,5-tetrakis(trifluormethylthio)pyrrolidid 87840-90-2 C5H5N*C8HF12NS4
    Pyridinium-2,3,4,5-tetrakis(trifluormethylthio)pyrrolidid
    —— 2'-Brom-2-amino-4-methoxy-diphenylsulfid 4726-28-7 C13H12BrNOS
    2'-Brom-2-amino-4-methoxy-diphenylsulfid
    —— (S)-1-Amino-pentane-2-thiol 791048-55-0 C5H13NS
    (S)-1-Amino-pentane-2-thiol
    —— 3-Chloro-2-isopropylsulfanyl-propionaldehyde 132279-10-8 C6H11ClOS
    3-Chloro-2-isopropylsulfanyl-propionaldehyde
    —— 2-tert-Butylsulfanyl-3-chloro-propionaldehyde 132279-12-0 C7H13ClOS
    2-tert-Butylsulfanyl-3-chloro-propionaldehyde
    —— 3-chloro-2-(phenylthio)propanal 132279-09-5 C9H9ClOS
    3-chloro-2-(phenylthio)propanal
    —— 2,3-Bis-tert-butylsulfanyl-propionaldehyde 132279-16-4 C11H22OS2
    2,3-Bis-tert-butylsulfanyl-propionaldehyde
    —— 2,3-bis(phenylthio)propanal 132279-13-1 C15H14OS2
    2,3-bis(phenylthio)propanal
    —— N-ethyl-N-cyclohexyl-5-(1-methyl-1,2,3,4-tetrazol-5-yl)thio-valeramide 80472-73-7 C15H27N5OS
    N-ethyl-N-cyclohexyl-5-(1-methyl-1,2,3,4-tetrazol-5-yl)thio-valeramide
    —— bis-(2-isopropyl-6-methyl-pyrimidin-4-yl)-sulfide 2463-82-3 C16H22N4S
    bis-(2-isopropyl-6-methyl-pyrimidin-4-yl)-sulfide