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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-Trifluoromethyl-7H-6-p-bromophenyl-s-triazolo<3,4-b><1,3,4>thiadiazine 86628-09-3 C11H6BrF3N4S
    3-Trifluoromethyl-7H-6-p-bromophenyl-s-triazolo<3,4-b><1,3,4>thiadiazine
    —— 5-(4-chlorophenylsulfanyl)-thiazolidine-2,4-dione 204848-73-7 C9H6ClNO2S2
    5-(4-chlorophenylsulfanyl)-thiazolidine-2,4-dione
    —— 1-Butoxy-5-methyl-6-methylsulfanyl-1H-pyrimidine-2,4-dione 188484-71-1 C10H16N2O3S
    1-Butoxy-5-methyl-6-methylsulfanyl-1H-pyrimidine-2,4-dione
    —— 3-(butylthio)-5-(trifluoromethyl)-4H-1,2,4-triazol-4-amine 459211-06-4 C7H11F3N4S
    3-(butylthio)-5-(trifluoromethyl)-4H-1,2,4-triazol-4-amine
    —— 3-Trifluoromethyl-7H-6-p-chlorophenyl-s-triazolo<3,4-b><1,3,4>thiadiazine 86628-10-6 C11H6ClF3N4S
    3-Trifluoromethyl-7H-6-p-chlorophenyl-s-triazolo<3,4-b><1,3,4>thiadiazine
    —— 3-(benzylthio)-5-(trifluoromethyl)-4H-1,2,4-triazol-4-amine 426216-12-8 C10H9F3N4S
    3-(benzylthio)-5-(trifluoromethyl)-4H-1,2,4-triazol-4-amine
    —— 5-(pyridine-2-sulfanyl)-thiazolidine-2,4-dione 204848-71-5 C8H6N2O2S2
    5-(pyridine-2-sulfanyl)-thiazolidine-2,4-dione
    —— N-methyl-2-(3-pyridyl)-1,3-dithiane-2-carbothioamide 143620-10-4 C11H14N2S3
    N-methyl-2-(3-pyridyl)-1,3-dithiane-2-carbothioamide
    —— 5-(benzenesulfanyl)-thiazolidine-2,4-dione 204848-72-6 C9H7NO2S2
    5-(benzenesulfanyl)-thiazolidine-2,4-dione
    —— 4-Methylthio-5-benzylthio-6-azauracil 23449-17-4 C11H11N3OS2
    4-Methylthio-5-benzylthio-6-azauracil
    —— n,n-Bis{[(4-bromophenyl)sulfanyl]methyl}-2,4,4-trimethylpentan-2-amine 67857-79-8 C22H29Br2NS2
    n,n-Bis{[(4-bromophenyl)sulfanyl]methyl}-2,4,4-trimethylpentan-2-amine
    —— 1-dodecylsulfonyl-2-butene 78652-05-8 C16H32O2S
    1-dodecylsulfonyl-2-butene
    —— (3,5-Dioxo-2,3,4,5-tetrahydro-[1,2,4]triazin-6-ylsulfanyl)-acetic acid 88891-73-0 C5H5N3O4S
    (3,5-Dioxo-2,3,4,5-tetrahydro-[1,2,4]triazin-6-ylsulfanyl)-acetic acid
    —— 2-(((4-(methylthio)phenyl)imino)methyl)phenol 19860-04-9 C14H13NOS
    2-(((4-(methylthio)phenyl)imino)methyl)phenol
    —— 3-[(4-bromo-2,5-dimethylphenyl)thio]propanoic acid 15084-53-4 C11H13BrO2S
    3-[(4-bromo-2,5-dimethylphenyl)thio]propanoic acid
    —— N,N-dimethyl-2-hydroxythiobutanamide 52417-40-0 C6H13NOS
    N,N-dimethyl-2-hydroxythiobutanamide
    —— 4-(4-tert-butyl-phenylsulfanyl)-3-chloroaniline 87294-26-6 C16H18ClNS
    4-(4-tert-butyl-phenylsulfanyl)-3-chloroaniline
    —— bis[4-(pyridine-2-yl)pyrimidin-2-ylthio]methane 1268363-85-4 C19H14N6S2
    bis[4-(pyridine-2-yl)pyrimidin-2-ylthio]methane
    —— 5-Methyl-2-(2-methylcarbamoyl-phenylsulfanyl)-benzoic acid 198897-08-4 C16H15NO3S
    5-Methyl-2-(2-methylcarbamoyl-phenylsulfanyl)-benzoic acid
    —— 7-Chloro-2-(2-chloro-4-nitrophenyl)sulfanyl-1,3-benzothiazole 315227-28-2 C13H6Cl2N2O2S2
    7-Chloro-2-(2-chloro-4-nitrophenyl)sulfanyl-1,3-benzothiazole
    —— 2-(methylthio)-2-(phenylthio)cyclohexanone 1287313-07-8 C13H16OS2
    2-(methylthio)-2-(phenylthio)cyclohexanone
    —— 5-benzylsulfanyl-3-methoxymethyl-1,2-dihydro-pyrimido[5,4-<i>e</i>][1,2,4]triazine 30855-61-9 C14H15N5OS
    5-benzylsulfanyl-3-methoxymethyl-1,2-dihydro-pyrimido[5,4-<i>e</i>][1,2,4]triazine
    —— 5-Benzylthiopyrimido<5,4-e>as-triazin 21308-98-5 C12H9N5S
    5-Benzylthiopyrimido<5,4-e>as-triazin
    —— 6-Phenylsulfanyl-2H-[1,2,4]triazine-3,5-dione 4956-11-0 C9H7N3O2S
    6-Phenylsulfanyl-2H-[1,2,4]triazine-3,5-dione
    —— 3-tert-Butylsulfanyl-5-methyl-pyridine 18794-47-3 C10H15NS
    3-tert-Butylsulfanyl-5-methyl-pyridine
    —— (R)-5-(α-p-chlorophenylthio)acetoxy-1,1-dimethoxyhexane 158575-46-3 C16H23ClO4S
    (R)-5-(α-p-chlorophenylthio)acetoxy-1,1-dimethoxyhexane
    —— 2-methyl-5-(((3-(trifluoromethyl)thieno[3,4-b]pyrazin-2-yl)thio)methyl)-1,3,4-oxadiazole 1381779-33-4 C11H7F3N4OS2
    2-methyl-5-(((3-(trifluoromethyl)thieno[3,4-b]pyrazin-2-yl)thio)methyl)-1,3,4-oxadiazole
    —— 2-t-butylthio-3-methylpyridine 18833-87-9 C10H15NS
    2-t-butylthio-3-methylpyridine
    —— 10-nitro-8H-thiochromeno[2',3':4,5]imidazo[2,1-a]isoquinoline 1451058-45-9 C18H11N3O2S
    10-nitro-8H-thiochromeno[2',3':4,5]imidazo[2,1-a]isoquinoline
    —— 2-tert-Butylsulfanyl-5-methyl-pyridine 18794-46-2 C10H15NS
    2-tert-Butylsulfanyl-5-methyl-pyridine
    —— 7-cyano-2-hexylthio-5H-1,3,4-thiadiazolo[3,2-a]pyrimidin-5-one 112589-33-0 C12H14N4OS2
    7-cyano-2-hexylthio-5H-1,3,4-thiadiazolo[3,2-a]pyrimidin-5-one
    —— 2-(2-chloro-6-nitrophenylthio)-1-nitroimidazole 683276-71-3 C9H5ClN4O4S
    2-(2-chloro-6-nitrophenylthio)-1-nitroimidazole
    —— 7-phenyl-3-phenylsulfanylheptanoic acid hydroxyamide 193549-05-2 C19H23NO2S
    7-phenyl-3-phenylsulfanylheptanoic acid hydroxyamide
    —— 3-<3-(pentylthio)pyrazinyl>-1,2,5,6-tetrahydro-1-methylpyridine hydrochloride 138430-96-3 C15H23N3S*ClH
    3-<3-(pentylthio)pyrazinyl>-1,2,5,6-tetrahydro-1-methylpyridine hydrochloride
    —— 3.5-Dihydroxy-6-hexylmercapto-1.2.4-triazin 4956-08-5 C9H15N3O2S
    3.5-Dihydroxy-6-hexylmercapto-1.2.4-triazin
    —— 2-Chlorcyclopentyl-4-chlorphenylsulfid 99860-81-8 C11H12Cl2S
    2-Chlorcyclopentyl-4-chlorphenylsulfid
    —— 5-hydroxy-10-nitro-8H-thiochromeno[2',3':4,5]imidazo[2,1-a]isoquinoline 1451058-47-1 C18H11N3O3S
    5-hydroxy-10-nitro-8H-thiochromeno[2',3':4,5]imidazo[2,1-a]isoquinoline
    —— 7-methyl-10-nitro-8H-thiochromeno[2',3':4,5]imidazo[2,1-a]isoquinoline 1451058-48-2 C19H13N3O2S
    7-methyl-10-nitro-8H-thiochromeno[2',3':4,5]imidazo[2,1-a]isoquinoline
    —— 3.5-Dihydroxy-6-butylmercapto-1.2.4-triazin 4968-47-2 C7H11N3O2S
    3.5-Dihydroxy-6-butylmercapto-1.2.4-triazin
    —— (4-Chloro-phenylsulfanyl)-acetic acid (R)-1-methyl-5-oxo-pentyl ester 158575-47-4 C14H17ClO3S
    (4-Chloro-phenylsulfanyl)-acetic acid (R)-1-methyl-5-oxo-pentyl ester
    —— 3.5-Dihydroxy-6-cyclohexylmercapto-1.2.4-triazin 90792-89-5 C9H13N3O2S
    3.5-Dihydroxy-6-cyclohexylmercapto-1.2.4-triazin
    —— N-Methyl-thiocarbamidsaeure-chlorid 867-51-6 C2H4ClNS
    N-Methyl-thiocarbamidsaeure-chlorid
    —— 6-cyano-2-heptylthio-5H-1,3,4-thiadiazolo[3,2-a]pyrimidin-5-one 112589-32-9 C13H16N4OS2
    6-cyano-2-heptylthio-5H-1,3,4-thiadiazolo[3,2-a]pyrimidin-5-one
    —— 5-(3,5-Dichlorophenylthio)-1-ethyl-4-isopropyl-1H-imidazol-2-ylmethyl decanoylcarbamate 196406-02-7 C26H37Cl2N3O3S
    5-(3,5-Dichlorophenylthio)-1-ethyl-4-isopropyl-1H-imidazol-2-ylmethyl decanoylcarbamate
    —— 1,7-diperfluorohexyl-4-[(hydrothio)methyl]heptane 1334164-80-5 C20H16F26S
    1,7-diperfluorohexyl-4-[(hydrothio)methyl]heptane
    —— 7-(2-Chloro-4-fluoro-phenylsulfanyl)-2-methylsulfanyl-thiazolo[4,5-b]pyridine-6-carbonitrile 905435-06-5 C14H7ClFN3S3
    7-(2-Chloro-4-fluoro-phenylsulfanyl)-2-methylsulfanyl-thiazolo[4,5-b]pyridine-6-carbonitrile
    —— 5-(Pyridin-2-ylsulfanylmethyl)-5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiine-2-thione 569649-46-3 C11H9NS6
    5-(Pyridin-2-ylsulfanylmethyl)-5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiine-2-thione
    —— (R)-2-Amino-2-(2-(methylthio)phenyl)ethan-1-ol 1212933-22-6 C9H13NOS
    (R)-2-Amino-2-(2-(methylthio)phenyl)ethan-1-ol
    —— methyl 4,6-dimethyl-2-(phenylthio)benzoate 102736-34-5 C16H16O2S
    methyl 4,6-dimethyl-2-(phenylthio)benzoate
    —— 5-Methylmercapto-2-methyl-s-triazolo<3,4-b>-1,3,4-thiadiazol 14778-91-7 C5H6N4S2
    5-Methylmercapto-2-methyl-s-triazolo<3,4-b>-1,3,4-thiadiazol