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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— ethyl 2-(4,6-bis(2-cycloheptylethoxy)pyrimidin-2-ylthio)hexanoate 1231734-01-2 C30H50N2O4S
    ethyl 2-(4,6-bis(2-cycloheptylethoxy)pyrimidin-2-ylthio)hexanoate
    —— 1-Phenylsulfanyl-tetrahydro-pentalene-2,5-dione 89074-10-2 C14H14O2S
    1-Phenylsulfanyl-tetrahydro-pentalene-2,5-dione
    —— 3-ethyl-4-hex-3-ynyl-1,2-dithiete 1,1,2-trioxide 1319722-87-6 C10H14O3S2
    3-ethyl-4-hex-3-ynyl-1,2-dithiete 1,1,2-trioxide
    —— 5-ethoxymethyl-2-methylsulfanyl-pyrimidin-4-ylamine 774-75-4 C8H13N3OS
    5-ethoxymethyl-2-methylsulfanyl-pyrimidin-4-ylamine
    —— (E)-2-Methylsulfanyl-pent-2-ene 86049-93-6 C6H12S
    (E)-2-Methylsulfanyl-pent-2-ene
    —— 2-Methylsulfanyl-pent-1-ene 86049-92-5 C6H12S
    2-Methylsulfanyl-pent-1-ene
    —— (3R,4S,5S)-5-bromo-3-methyl-4-phenylsulfanyl-dihydro-furan-2-one 205815-64-1 C11H11BrO2S
    (3R,4S,5S)-5-bromo-3-methyl-4-phenylsulfanyl-dihydro-furan-2-one
    —— (Z)-2-Methylsulfanyl-pent-2-ene 86049-94-7 C6H12S
    (Z)-2-Methylsulfanyl-pent-2-ene
    —— (3aS,6aS)-3-[1-((2R,3R,4R)-4-Methyl-5-oxo-3-phenylsulfanyl-tetrahydro-furan-2-yloxy)-meth-(E)-ylidene]-3,3a,4,6a-tetrahydro-cyclopenta[b]furan-2-one 205815-50-5 C19H18O5S
    (3aS,6aS)-3-[1-((2R,3R,4R)-4-Methyl-5-oxo-3-phenylsulfanyl-tetrahydro-furan-2-yloxy)-meth-(E)-ylidene]-3,3a,4,6a-tetrahydro-cyclopenta[b]furan-2-one
    —— 3-methyl-4-phenylsulfanyl-5H-furan-2-one 117621-13-3 C11H10O2S
    3-methyl-4-phenylsulfanyl-5H-furan-2-one
    —— (3R,4R,5S)-5-bromo-3-methyl-4-phenylsulfanyl-dihydro-furan-2-one 205815-41-4 C11H11BrO2S
    (3R,4R,5S)-5-bromo-3-methyl-4-phenylsulfanyl-dihydro-furan-2-one
    —— (Z)-5,5'-Dibutyl-[2,2']bi[benzo[b]thiophenylidene]-3,3'-dione 122630-25-5 C24H24O2S2
    (Z)-5,5'-Dibutyl-[2,2']bi[benzo[b]thiophenylidene]-3,3'-dione
    —— 1,2,9-Trithiacyclopentadeca-5,12-diin 115465-39-9 C12H16S3
    1,2,9-Trithiacyclopentadeca-5,12-diin
    —— 3-Hexin-1,6-dithiol 115465-35-5 C6H10S2
    3-Hexin-1,6-dithiol
    —— 1,8-Dithiacyclotetradeca-4,11-diin-1,8-dioxid 115465-43-5 C12H16O2S2
    1,8-Dithiacyclotetradeca-4,11-diin-1,8-dioxid
    —— 13,13-Dimethyl-1,4,8,11-tetrathiadispiro[4.1.4.3]tetradecane 1,1,4,4,8,8,11,11-octaoxide 15814-66-1 C12H20O8S4
    13,13-Dimethyl-1,4,8,11-tetrathiadispiro[4.1.4.3]tetradecane 1,1,4,4,8,8,11,11-octaoxide
    —— 3-Trimethylsilyloxy-3-[1-(phenylsulfanyl)cyclohexyl]propanal 253152-15-7 C18H28O2SSi
    3-Trimethylsilyloxy-3-[1-(phenylsulfanyl)cyclohexyl]propanal
    —— methyl (phenyl 4,5-N,O-carbonylamino-5,7-N,O-DTBS-8,9-O-TIPDS-3,5-dideoxy-2-thio-D-glycero-α-D-galacto-2-nonulopyranosid)onate 1190291-15-6 C37H63NO9SSi3
    methyl (phenyl 4,5-N,O-carbonylamino-5,7-N,O-DTBS-8,9-O-TIPDS-3,5-dideoxy-2-thio-D-glycero-α-D-galacto-2-nonulopyranosid)onate
    —— 2-(2-{5'-[2-(2-Hydroxy-ethoxy)-ethyl]-4,6,4',6'-tetramethyl-5'H-[2,2']bi[[1,3]dithiolo[4,5-c]pyrrolylidene]-5-yl}-ethoxy)-ethanol 287980-46-5 C22H30N2O4S4
    2-(2-{5'-[2-(2-Hydroxy-ethoxy)-ethyl]-4,6,4',6'-tetramethyl-5'H-[2,2']bi[[1,3]dithiolo[4,5-c]pyrrolylidene]-5-yl}-ethoxy)-ethanol
    —— (3aS,5aS,8aR,8bR)-6-Eth-(Z)-ylidene-5a-methyl-octahydro-1,3-dioxa-as-indacene-2-thione 910229-09-3 C13H18O2S
    (3aS,5aS,8aR,8bR)-6-Eth-(Z)-ylidene-5a-methyl-octahydro-1,3-dioxa-as-indacene-2-thione
    —— 2,5-Diamino-4-benzylmercapto-6-<2-hydroxy-aethylamino>-pyrimidin 2879-77-8 C13H17N5OS
    2,5-Diamino-4-benzylmercapto-6-<2-hydroxy-aethylamino>-pyrimidin
    —— (E)-3-cyclopentyl-2-(6-methylsulfanylpyridin-3-yl)acrylic acid 745816-32-4 C14H17NO2S
    (E)-3-cyclopentyl-2-(6-methylsulfanylpyridin-3-yl)acrylic acid
    —— 8,10-Dichloro-5-thia-4,11-diaza-dibenzo[a,d]cycloheptene 1026055-15-1 C12H6Cl2N2S
    8,10-Dichloro-5-thia-4,11-diaza-dibenzo[a,d]cycloheptene
    —— [(Diphenyl-phosphinoyl)-phenylsulfanyl-methyl]-trimethyl-silane 87762-60-5 C22H25OPSSi
    [(Diphenyl-phosphinoyl)-phenylsulfanyl-methyl]-trimethyl-silane
    —— 6-methoxy-3-[(4-methylphenyl)thio]indole 889129-56-0 C16H15NOS
    6-methoxy-3-[(4-methylphenyl)thio]indole
    —— 3-((4-chlorophenyl)thio)-6-methoxy-1H-indole 1224875-73-3 C15H12ClNOS
    3-((4-chlorophenyl)thio)-6-methoxy-1H-indole
    —— (E)-(3-hexylnon-1-enyl)(phenyl)sulfane 1393672-37-1 C21H34S
    (E)-(3-hexylnon-1-enyl)(phenyl)sulfane
    —— (E)-2-((3-hexylnon-1-en-1-yl)thio)ethanol 1393672-41-7 C17H34OS
    (E)-2-((3-hexylnon-1-en-1-yl)thio)ethanol
    —— (E)-tert-butyl(3-hexylnon-1-en-1-yl)sulfane 1393672-39-3 C19H38S
    (E)-tert-butyl(3-hexylnon-1-en-1-yl)sulfane
    —— 2-Benzylsulfanyl-4-tert-butoxy-pyrimidine 497944-59-9 C15H18N2OS
    2-Benzylsulfanyl-4-tert-butoxy-pyrimidine
    —— 6-bromo-2,3-dihydro-7-methyl-5H-thiazolo<3,2-a>pyrimidin-5-one 111730-47-3 C7H7BrN2OS
    6-bromo-2,3-dihydro-7-methyl-5H-thiazolo<3,2-a>pyrimidin-5-one
    —— 2-Benzylsulfanyl-3-isopropyl-3H-pyrimidin-4-one 497944-65-7 C14H16N2OS
    2-Benzylsulfanyl-3-isopropyl-3H-pyrimidin-4-one
    —— 3-(phenylthio)-2,4,7,7a-tetrahydrobenzothiophene 1,1-dioxide 1268357-04-5 C14H14O2S2
    3-(phenylthio)-2,4,7,7a-tetrahydrobenzothiophene 1,1-dioxide
    —— (E)-5-Phenylsulfanyl-pent-4-enenitrile 104260-99-3 C11H11NS
    (E)-5-Phenylsulfanyl-pent-4-enenitrile
    —— 2-(4-bromophenyl)-2-(phenylsulfanyl)cyclohept-4-enone 878480-55-8 C19H17BrOS
    2-(4-bromophenyl)-2-(phenylsulfanyl)cyclohept-4-enone
    —— Allylthiocarbaminsaeure-isopropylester 76014-84-1 C7H13NOS
    Allylthiocarbaminsaeure-isopropylester
    —— (E)-3-(2-cyanovinyl)-9,10-dimethoxy-4-oxo-2-(phenylthio)-6,7-dihydro-4H-pyrido[2,1-a]isoquinoline-1-carbonitrile 1463869-15-9 C25H19N3O3S
    (E)-3-(2-cyanovinyl)-9,10-dimethoxy-4-oxo-2-(phenylthio)-6,7-dihydro-4H-pyrido[2,1-a]isoquinoline-1-carbonitrile
    —— 1-bromo-1-(methylsulfonyl)propan-2-one 1271024-83-9 C4H7BrO3S
    1-bromo-1-(methylsulfonyl)propan-2-one
    —— 2-Cyano-2-N,N-dimethylcarbamoyl-5-isopropylthio-1,3-dithiane 126832-94-8 C11H18N2OS3
    2-Cyano-2-N,N-dimethylcarbamoyl-5-isopropylthio-1,3-dithiane
    —— [4-(4,6-diamino-2-methylsulfanyl-pyrimidin-5-ylazo)-phenyl]-arsonic acid 17174-29-7 C11H13AsN6O3S
    [4-(4,6-diamino-2-methylsulfanyl-pyrimidin-5-ylazo)-phenyl]-arsonic acid
    —— 5-((4-chlorophenylthio)methyl)pyridazin-3(2H)-one 1243253-41-9 C11H9ClN2OS
    5-((4-chlorophenylthio)methyl)pyridazin-3(2H)-one
    —— 2-((4-chlorophenyl)thio)butanoic acid 155748-59-7 C10H11ClO2S
    2-((4-chlorophenyl)thio)butanoic acid
    —— 3-(3-bromo-phenylsulfanyl)-6-chloro-1H-indole 1359982-48-1 C14H9BrClNS
    3-(3-bromo-phenylsulfanyl)-6-chloro-1H-indole
    —— (-)-(S)-2-(4-Chlorothiophenoxy)butanoic acid 176021-34-4 C10H11ClO2S
    (-)-(S)-2-(4-Chlorothiophenoxy)butanoic acid
    —— ethyl 2-(p-chlorophenylthio)-2-fluorobutanoate 380859-98-3 C12H14ClFO2S
    ethyl 2-(p-chlorophenylthio)-2-fluorobutanoate
    —— Diethyl {4-[(2-amino-5-bromophenyl)thio]butyl}phosphonate 288073-37-0 C14H23BrNO3PS
    Diethyl {4-[(2-amino-5-bromophenyl)thio]butyl}phosphonate
    —— (1R<sup>*</sup>,3aS<sup>*</sup>,8b<sup>R*</sup>)-Methyl 1-<2-(2'',2''-Dimethoxyethyl)-1,3-dithian-2-yl>-1,4,5,7,8,8b-hexahydro-3H-benzo<1,2-b:3,4-c'>-difuran-3a-carboxylate 145746-32-3 C20H30O6S2
    (1R<sup>*</sup>,3aS<sup>*</sup>,8b<sup>R*</sup>)-Methyl 1-<2-(2'',2''-Dimethoxyethyl)-1,3-dithian-2-yl>-1,4,5,7,8,8b-hexahydro-3H-benzo<1,2-b:3,4-c'>-difuran-3a-carboxylate
    —— Methyl 2-<2'-tert-Butyldimethylsiloxy-1'-<2''-(2''',2'''-dimethoxyethyl)-1'',3''-dithian-2''-yl>ethoxymethyl>propenoate 145746-21-0 C21H40O6S2Si
    Methyl 2-<2'-tert-Butyldimethylsiloxy-1'-<2''-(2''',2'''-dimethoxyethyl)-1'',3''-dithian-2''-yl>ethoxymethyl>propenoate
    —— 2-[2,2-Bis(sulfanylmethyl)-1,3-dithian-5-ylidene]hydrazinecarboxamide 4085-04-5 C7H13N3OS4
    2-[2,2-Bis(sulfanylmethyl)-1,3-dithian-5-ylidene]hydrazinecarboxamide
    —— 4,6-dichloro-2-(ethylthio)pyrimidine 68498-47-5 C6H6Cl2N2S
    4,6-dichloro-2-(ethylthio)pyrimidine