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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [3-chloro-5-(1H-imidazol-2-ylsulfanyl)-pyridin-4-yl]-methanol 1064677-27-5 C9H8ClN3OS
    [3-chloro-5-(1H-imidazol-2-ylsulfanyl)-pyridin-4-yl]-methanol
    —— 3-Amylsulfonylpropionsaeure 59358-20-2 C8H16O4S
    3-Amylsulfonylpropionsaeure
    —— 8-[3-(1-butyl-1H-imidazol-2-ylsulfanyl)-5-chloro-pyridin-4-ylmethoxy]-2-methyl-4-(2-methyl-2H-pyrazol-3-yl)-quinoline 1064669-55-1 C27H27ClN6OS
    8-[3-(1-butyl-1H-imidazol-2-ylsulfanyl)-5-chloro-pyridin-4-ylmethoxy]-2-methyl-4-(2-methyl-2H-pyrazol-3-yl)-quinoline
    —— 3-(1-butyl-1H-imidazol-2-ylsulfanyl)-5-chloro-4-chloromethyl-pyridine 1064677-31-1 C13H15Cl2N3S
    3-(1-butyl-1H-imidazol-2-ylsulfanyl)-5-chloro-4-chloromethyl-pyridine
    —— 3-(1-ethoxyethoxy)-2-methylsulfanyl-pyridine 499126-87-3 C10H15NO2S
    3-(1-ethoxyethoxy)-2-methylsulfanyl-pyridine
    —— 2-(Phenylthio)-1,3-dioxolane 19798-66-4 C9H10O2S
    2-(Phenylthio)-1,3-dioxolane
    —— 2-[(2,5-dimethylphenyl)methylthio]-6-methylpyridine-1-oxide 81167-65-9 C15H17NOS
    2-[(2,5-dimethylphenyl)methylthio]-6-methylpyridine-1-oxide
    —— 2-[(2,5-dimethylphenyl)methylthio]-5-methylpyridine 1-oxide 84950-42-5 C15H17NOS
    2-[(2,5-dimethylphenyl)methylthio]-5-methylpyridine 1-oxide
    —— 2-[(2,5-dimethylphenyl)methylthio]-4-methylpyridine-1-oxide 81167-67-1 C15H17NOS
    2-[(2,5-dimethylphenyl)methylthio]-4-methylpyridine-1-oxide
    —— 3-Chlor-5-hexylthio-1,2,4-thiadiazol 36955-37-0 C8H13ClN2S2
    3-Chlor-5-hexylthio-1,2,4-thiadiazol
    —— Methoxycarbonylsulfanyl-acetic acid methyl ester 127719-39-5 C5H8O4S
    Methoxycarbonylsulfanyl-acetic acid methyl ester
    —— N-i-Propyl-N'-s-butylthioharnstoff 54088-58-3 C8H18N2S
    N-i-Propyl-N'-s-butylthioharnstoff
    —— N-Ethyl-N'-s-butylthioharnstoff 62351-10-4 C7H16N2S
    N-Ethyl-N'-s-butylthioharnstoff
    —— 1-(sec-butyl)-3 methoxy-2-(methylsulfanyl)-1H-pyrrole 1247948-19-1 C10H17NOS
    1-(sec-butyl)-3 methoxy-2-(methylsulfanyl)-1H-pyrrole
    —— N-n-Propyl-N'-s-butylthioharnstoff 62351-13-7 C8H18N2S
    N-n-Propyl-N'-s-butylthioharnstoff
    —— 2-Methylmercapto-4.6-diaethylpyrimidin 61640-54-8 C9H14N2S
    2-Methylmercapto-4.6-diaethylpyrimidin
    —— <i>N</i>-allyl-<i>N</i>'-<i>sec</i>-butyl-thiourea 70498-36-1 C8H16N2S
    <i>N</i>-allyl-<i>N</i>'-<i>sec</i>-butyl-thiourea
    —— E-5-methylsulfonyladamantane-2-amine —— C11H19NO2S
    E-5-methylsulfonyladamantane-2-amine
    —— (Z)-2-(butylthio)-7-methyl-2,6-octadien-4-yne 89556-07-0 C13H20S
    (Z)-2-(butylthio)-7-methyl-2,6-octadien-4-yne
    —— N',N'-Bis-(3-chlor-trans-allyl)-N-sulfinyl-hydrazin 20582-08-5 C6H8Cl2N2OS
    N',N'-Bis-(3-chlor-trans-allyl)-N-sulfinyl-hydrazin
    —— 4-Benzyl-2-benzylmercapto-5-acetylimino-Δ<sup>2</sup>-1.3.4-thiodiazolin 109480-59-3 C18H17N3OS2
    4-Benzyl-2-benzylmercapto-5-acetylimino-Δ<sup>2</sup>-1.3.4-thiodiazolin
    —— O2-(methylsulfonylmethyl) 1-(isopropylamino)diazen-1-ium-1,2-diolate 1404220-38-7 C5H13N3O4S
    O2-(methylsulfonylmethyl) 1-(isopropylamino)diazen-1-ium-1,2-diolate
    —— (S)-1-(3-Methylsulfanyl-phenyl)-ethanol 666743-54-0 C9H12OS
    (S)-1-(3-Methylsulfanyl-phenyl)-ethanol
    —— 2-(methylsulfanyl)-6-(2-fluoro-6-chlorobenzyl)pyrimidin-4(3H)-one 1242134-30-0 C12H10ClFN2OS
    2-(methylsulfanyl)-6-(2-fluoro-6-chlorobenzyl)pyrimidin-4(3H)-one
    —— 2-Ethylsulfanyl-5-isopropyl-6-methyl-3H-pyrimidin-4-one 115996-83-3 C10H16N2OS
    2-Ethylsulfanyl-5-isopropyl-6-methyl-3H-pyrimidin-4-one
    —— m-Methylthio-α-methylbenzylalkohol 58114-13-9 C9H12OS
    m-Methylthio-α-methylbenzylalkohol
    —— 5-Benzyl-3-bromomethyl-6-ethyl-2,3-dihydro-thiazolo[3,2-a]pyrimidin-7-one 199852-47-6 C16H17BrN2OS
    5-Benzyl-3-bromomethyl-6-ethyl-2,3-dihydro-thiazolo[3,2-a]pyrimidin-7-one
    —— 6-Benzyl-2-(2,2-diethoxy-ethylsulfanyl)-5-ethyl-3H-pyrimidin-4-one 199851-93-9 C19H26N2O3S
    6-Benzyl-2-(2,2-diethoxy-ethylsulfanyl)-5-ethyl-3H-pyrimidin-4-one
    —— 5-Benzyl-3-ethoxy-6-ethyl-2,3-dihydro-thiazolo[3,2-a]pyrimidin-7-one 199852-15-8 C17H20N2O2S
    5-Benzyl-3-ethoxy-6-ethyl-2,3-dihydro-thiazolo[3,2-a]pyrimidin-7-one
    —— 6-amino-4-(2-furyl)-2-methylthiopyridine-3,5-dicarbonitrile 161689-60-7 C12H8N4OS
    6-amino-4-(2-furyl)-2-methylthiopyridine-3,5-dicarbonitrile
    —— 2-(methylthiomethoxy)propanal 1268389-97-4 C5H10O2S
    2-(methylthiomethoxy)propanal
    —— (E)-2-(methylthiomethoxy)non-4-en-3-one 1268389-98-5 C11H20O2S
    (E)-2-(methylthiomethoxy)non-4-en-3-one
    —— (5S,6S)-5-(4-Chloro-phenylsulfanyl)-6-methoxy-dihydro-pyran-3-one 140886-26-6 C12H13ClO3S
    (5S,6S)-5-(4-Chloro-phenylsulfanyl)-6-methoxy-dihydro-pyran-3-one
    —— (5S,6S)-6-Methoxy-5-phenylsulfanyl-dihydro-pyran-3-one 140886-22-2 C12H14O3S
    (5S,6S)-6-Methoxy-5-phenylsulfanyl-dihydro-pyran-3-one
    —— (5S,6S)-6-Methoxy-5-p-tolylsulfanyl-dihydro-pyran-3-one 140886-23-3 C13H16O3S
    (5S,6S)-6-Methoxy-5-p-tolylsulfanyl-dihydro-pyran-3-one
    —— 2-((4-(trifluorovinyl)-phenyl)thio)-tetrafluoroethyl bromide 1165890-66-3 C10H4BrF7S
    2-((4-(trifluorovinyl)-phenyl)thio)-tetrafluoroethyl bromide
    —— 6-benzyl-5-ethyl-2-[(furan-2-ylcarbonylmethyl)thio]pyrimidin-4(3H)-one 951764-41-3 C19H18N2O3S
    6-benzyl-5-ethyl-2-[(furan-2-ylcarbonylmethyl)thio]pyrimidin-4(3H)-one
    —— tert-butyl-2-{[4-({(2-furylmethyl)[6-(4-methylbenzyl)pyrimidin-4-yl]amino}methyl)phenyl]thio}-2-methylpropanoate 881687-24-7 C32H37N3O3S
    tert-butyl-2-{[4-({(2-furylmethyl)[6-(4-methylbenzyl)pyrimidin-4-yl]amino}methyl)phenyl]thio}-2-methylpropanoate
    —— 7-Benzyl-3-ethoxy-6-ethyl-2,3-dihydro-thiazolo[3,2-a]pyrimidin-5-one 199852-32-9 C17H20N2O2S
    7-Benzyl-3-ethoxy-6-ethyl-2,3-dihydro-thiazolo[3,2-a]pyrimidin-5-one
    —— N<sup>4</sup>-cyclopentyl-2-phenylpyrimidine-6-phenylmethanesulfanyl-4,5-diamine 778594-75-5 C23H26N4S
    N<sup>4</sup>-cyclopentyl-2-phenylpyrimidine-6-phenylmethanesulfanyl-4,5-diamine
    —— 2-(diethylamino)ethyl N,N'-dicyclohexylcarbamimidothioate;hydron;dichloride —— C19H39Cl2N3S
    2-(diethylamino)ethyl N,N'-dicyclohexylcarbamimidothioate;hydron;dichloride
    —— 5-Benzyl-6-ethyl-3-methoxy-2,3-dihydro-thiazolo[3,2-a]pyrimidin-7-one 199852-12-5 C16H18N2O2S
    5-Benzyl-6-ethyl-3-methoxy-2,3-dihydro-thiazolo[3,2-a]pyrimidin-7-one
    —— 6-benzyl-5-ethyl-2-[(thiophen-2-ylcarbonylmethyl)thio]pyrimidin-4(3H)-one 951764-40-2 C19H18N2O2S2
    6-benzyl-5-ethyl-2-[(thiophen-2-ylcarbonylmethyl)thio]pyrimidin-4(3H)-one
    —— 7-Benzyl-6-ethyl-3-(2-hydroxy-ethoxy)-2,3-dihydro-thiazolo[3,2-a]pyrimidin-5-one 199852-33-0 C17H20N2O3S
    7-Benzyl-6-ethyl-3-(2-hydroxy-ethoxy)-2,3-dihydro-thiazolo[3,2-a]pyrimidin-5-one
    —— N<sup>4</sup>-cyclopentyl-2-phenylpyrimidine-6-phenylmethanesulfanyl-4,5-diamine 778594-74-4 C22H24N4S
    N<sup>4</sup>-cyclopentyl-2-phenylpyrimidine-6-phenylmethanesulfanyl-4,5-diamine
    —— 2-Allylsulfanyl-6-benzyl-5-ethyl-3H-pyrimidin-4-one 199852-43-2 C16H18N2OS
    2-Allylsulfanyl-6-benzyl-5-ethyl-3H-pyrimidin-4-one
    —— tert-butyl-2-{[4-({(2-furylmethyl)[6-(3-methylbenzyl)pyrimidin-4-yl]amino}methyl)phenyl]thio}-2-methylpropanoate 881687-23-6 C32H37N3O3S
    tert-butyl-2-{[4-({(2-furylmethyl)[6-(3-methylbenzyl)pyrimidin-4-yl]amino}methyl)phenyl]thio}-2-methylpropanoate
    —— O-MTM hydroxylamine hydrochloride 41108-17-2 C2H7NOS*ClH
    O-MTM hydroxylamine hydrochloride
    —— N<sup>4</sup>-phenylmethyl-2-phenylpyrimidine-6-phenylmethanesulfanyl-4,5-diamine 778594-76-6 C24H22N4S
    N<sup>4</sup>-phenylmethyl-2-phenylpyrimidine-6-phenylmethanesulfanyl-4,5-diamine
    —— 1,3,5-Triazine-2,4-diamine, 1,6-dihydro-6,6-dimethyl-1-(4-((4-nitrophenyl)thio)phenyl)-, monohydrochloride 13413-53-1 C17H19ClN6O2S
    1,3,5-Triazine-2,4-diamine, 1,6-dihydro-6,6-dimethyl-1-(4-((4-nitrophenyl)thio)phenyl)-, monohydrochloride