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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (S)-Ethyl 2-(6-hydroxy-2,3-dihydrobenzo[b]thiophen-3-yl)acetate 1022979-99-2 C12H14O3S
    (S)-Ethyl 2-(6-hydroxy-2,3-dihydrobenzo[b]thiophen-3-yl)acetate
    —— 3-[2-(Diethylaminomethyl)phenyl]sulfanylphenol 127906-55-2 C17H21NOS
    3-[2-(Diethylaminomethyl)phenyl]sulfanylphenol
    —— N,N-dimethyl-3-(3-methoxyphenylthio)-2-thenylamine 134478-44-7 C14H17NOS2
    N,N-dimethyl-3-(3-methoxyphenylthio)-2-thenylamine
    —— 5-Chlor-2-(3-methoxyphenylthio)-benzylchlorid 63186-38-9 C14H12Cl2OS
    5-Chlor-2-(3-methoxyphenylthio)-benzylchlorid
    —— 4-tert-Butyl-N-[5-(2-hydroxy-ethyl)-4-(3-methoxy-phenylsulfanyl)-isoxazol-3-yl]-benzenesulfonamide 302957-78-4 C22H26N2O5S2
    4-tert-Butyl-N-[5-(2-hydroxy-ethyl)-4-(3-methoxy-phenylsulfanyl)-isoxazol-3-yl]-benzenesulfonamide
    —— 1-(2-(3-methoxyphenylthio)phenyl)-2-propylamine 128958-98-5 C16H19NOS
    1-(2-(3-methoxyphenylthio)phenyl)-2-propylamine
    —— 2-(3-Methoxyphenylthio)-5-nitrobenzylalkohol 63186-35-6 C14H13NO4S
    2-(3-Methoxyphenylthio)-5-nitrobenzylalkohol
    —— [2-(3-Methoxyphenyl)sulfanylphenyl]methanamine 127905-93-5 C14H15NOS
    [2-(3-Methoxyphenyl)sulfanylphenyl]methanamine
    —— N,N-dimethyl-2-(3-hydroxyphenylthio)benzylamine 127906-18-7 C15H17NOS
    N,N-dimethyl-2-(3-hydroxyphenylthio)benzylamine
    —— N,N-dimethyl-4-(3-hydroxyphenylthio)benzylamine 141358-04-5 C15H17NOS
    N,N-dimethyl-4-(3-hydroxyphenylthio)benzylamine
    —— 3-[2-(Methylaminomethyl)phenyl]sulfanylphenol 127906-33-6 C14H15NOS
    3-[2-(Methylaminomethyl)phenyl]sulfanylphenol
    —— 2-(3-Methoxyphenyl)sulfanylbenzamide 127905-45-7 C14H13NO2S
    2-(3-Methoxyphenyl)sulfanylbenzamide
    —— 3-[2-(Aminomethyl)phenyl]sulfanylphenol 127906-44-9 C13H13NOS
    3-[2-(Aminomethyl)phenyl]sulfanylphenol
    —— N,N-diethyl-2-(3-methoxyphenyl)sulfanylbenzamide 127905-61-7 C18H21NO2S
    N,N-diethyl-2-(3-methoxyphenyl)sulfanylbenzamide
    —— 1-(2-(3-Methoxyphenylthio)phenyl)ethanol 127906-81-4 C15H16O2S
    1-(2-(3-Methoxyphenylthio)phenyl)ethanol
    —— N,N-Dimethyl-2-(3-methoxyphenylthio)benzylamine 127905-71-9 C16H19NOS
    N,N-Dimethyl-2-(3-methoxyphenylthio)benzylamine
    —— (2R)-2-amino-4-{2-chloro-4-[(3-methoxyphenyl)sulfanyl]phenyl}-2-methyl-butan-1-ol 1618092-58-2 C18H22ClNO2S
    (2R)-2-amino-4-{2-chloro-4-[(3-methoxyphenyl)sulfanyl]phenyl}-2-methyl-butan-1-ol
    —— 4-((3-methoxyphenyl)thio)aniline 747383-57-9 C13H13NOS
    4-((3-methoxyphenyl)thio)aniline
    —— (+/-)-N,N-dimethyl-1-(2-(3-hydroxyphenylthio)phenyl)ethylamine 127906-72-3 C16H19NOS
    (+/-)-N,N-dimethyl-1-(2-(3-hydroxyphenylthio)phenyl)ethylamine
    —— 3-cyano-N-(2,4-dimethoxybenzyl)-4-[(3-methoxyphenyl)thio]-N-1,2,4-thiadiazol-5-ylbenzenesulfonamide 1354917-73-9 C25H22N4O5S3
    3-cyano-N-(2,4-dimethoxybenzyl)-4-[(3-methoxyphenyl)thio]-N-1,2,4-thiadiazol-5-ylbenzenesulfonamide
    —— 2,2,2-Trifluoro-1-[4-(3-methoxyphenyl)sulfanyl-3-(2,2,2-trifluoroacetyl)naphthalen-1-yl]ethanone 142991-53-5 C21H12F6O3S
    2,2,2-Trifluoro-1-[4-(3-methoxyphenyl)sulfanyl-3-(2,2,2-trifluoroacetyl)naphthalen-1-yl]ethanone
    —— 2,4-diamino-5-methyl-6-(3'-methoxyphenylsulfanyl)furo[2,3-d]pyrimidine 1217309-59-5 C14H14N4O2S
    2,4-diamino-5-methyl-6-(3'-methoxyphenylsulfanyl)furo[2,3-d]pyrimidine
    —— 2-[1-(phenylsulfanyl)cyclopropyl]epoxide 1026510-76-8 C11H12OS
    2-[1-(phenylsulfanyl)cyclopropyl]epoxide
    —— 4-Chloro-3-(3-methoxylphenylthio)-9H-thioxanthen-9-one 1372152-33-4 C20H13ClO2S2
    4-Chloro-3-(3-methoxylphenylthio)-9H-thioxanthen-9-one
    —— 4-(3-methoxyphenylthio)benzaldehyde 141358-18-1 C14H12O2S
    4-(3-methoxyphenylthio)benzaldehyde
    —— 3-[(3-methoxyphenyl)sulfanyl]-2H-isoindole-1-carboxaldehyde 1285621-02-4 C16H13NO2S
    3-[(3-methoxyphenyl)sulfanyl]-2H-isoindole-1-carboxaldehyde
    —— 1-acetyl-3-[(3-methoxyphenyl)sulfanyl]-2H-isoindole 1285621-08-0 C17H15NO2S
    1-acetyl-3-[(3-methoxyphenyl)sulfanyl]-2H-isoindole
    —— 4-(3-Methoxyphenyl)sulfanyl-2-(trichloromethyl)quinazoline 1336930-72-3 C16H11Cl3N2OS
    4-(3-Methoxyphenyl)sulfanyl-2-(trichloromethyl)quinazoline
    —— 1-acetyl-3-[(3-methoxyphenyl)sulfanyl]-2-methyl-2H-isoindole 1285621-16-0 C18H17NO2S
    1-acetyl-3-[(3-methoxyphenyl)sulfanyl]-2-methyl-2H-isoindole
    —— 7-chloro-7-(phenylsulfanyl)dispiro[2.0.2.1]heptane 642074-91-7 C13H13ClS
    7-chloro-7-(phenylsulfanyl)dispiro[2.0.2.1]heptane
    —— 6-(sec-butoxy)-2-((3-methoxyphenyl)thio)pyrimidin-4-amine 284681-52-3 C15H19N3O2S
    6-(sec-butoxy)-2-((3-methoxyphenyl)thio)pyrimidin-4-amine
    —— tert-butyl ({4-(2-fluoropyridin-3-yl)-5-[(3-methoxyphenyl)thio]-1,3-thiazol-2-yl}methyl)methylcarbamate 1138033-81-4 C22H24FN3O3S2
    tert-butyl ({4-(2-fluoropyridin-3-yl)-5-[(3-methoxyphenyl)thio]-1,3-thiazol-2-yl}methyl)methylcarbamate
    —— 4-(3-methoxy-phenylsulfanyl)-5-nitro-thiophene-2-carboxylic acid methyl ester 631909-77-8 C13H11NO5S2
    4-(3-methoxy-phenylsulfanyl)-5-nitro-thiophene-2-carboxylic acid methyl ester
    —— (2,2-dimethyl-1,3-dithian-5-yl)methanol 1056901-08-6 C7H14OS2
    (2,2-dimethyl-1,3-dithian-5-yl)methanol
    —— 2-(4-tolylsulfanyl)-3-((phenyl)(4-tolylsulfanyl)methyl)-1H-indole 1295558-56-3 C29H25NS2
    2-(4-tolylsulfanyl)-3-((phenyl)(4-tolylsulfanyl)methyl)-1H-indole
    —— 2-phenylsulfanyl-3-((acetyl)(phenylsulfanyl)methyl)-1H-indole 1295558-75-6 C23H19NOS2
    2-phenylsulfanyl-3-((acetyl)(phenylsulfanyl)methyl)-1H-indole
    —— 2-phenylthiomethyl-2-imidazoline 65248-81-9 C10H12N2S
    2-phenylthiomethyl-2-imidazoline
    —— 5-fluoro-2-(methylthio)aniline 439291-60-8 C7H8FNS
    5-fluoro-2-(methylthio)aniline
    —— 2'-methylthio-5'-fluoro-2-(anilinomethyl)imidazoline 439291-61-9 C11H14FN3S
    2'-methylthio-5'-fluoro-2-(anilinomethyl)imidazoline
    —— 2-(3-chloro-2-methylphenyl-thiomethyl)-2-imidazoline hydrochloride 130016-17-0 C11H13ClN2S*ClH
    2-(3-chloro-2-methylphenyl-thiomethyl)-2-imidazoline hydrochloride
    —— 2-phenylsulfanyl-3-((phenyl)(phenylsulfanyl)methyl)-1H-indole 1295558-76-7 C27H21NS2
    2-phenylsulfanyl-3-((phenyl)(phenylsulfanyl)methyl)-1H-indole
    —— 3-((1H-tetrazol-5-yl)thio)-1H-indole 1569090-27-2 C9H7N5S
    3-((1H-tetrazol-5-yl)thio)-1H-indole
    —— spiro-(4H-1,3-benzodithiin-2,4'-piperidine) 136081-83-9 C12H15NS2
    spiro-(4H-1,3-benzodithiin-2,4'-piperidine)
    —— S-Methyl-N,S-diethyl-sulfoximid 35362-78-8 C5H13NOS
    S-Methyl-N,S-diethyl-sulfoximid
    —— N.S-Dimethyl-S-aethyl-sulfoximid 35362-74-4 C4H11NOS
    N.S-Dimethyl-S-aethyl-sulfoximid
    —— 4-chloro-2-(phenylthio)aniline 53692-01-6 C12H10ClNS
    4-chloro-2-(phenylthio)aniline
    —— <(1-Methylnon-2-ynyl)thio>benzene 146916-42-9 C16H22S
    <(1-Methylnon-2-ynyl)thio>benzene
    —— 2-Phenylthio-1,3-cyclohexanedione 72302-56-8 C12H12O2S
    2-Phenylthio-1,3-cyclohexanedione
    —— 4-fluoro-2-thiophenylaniline 329216-96-8 C12H10FNS
    4-fluoro-2-thiophenylaniline
    —— 4-(2-indolylthio)nicotinic acid 242491-44-7 C14H10N2O2S
    4-(2-indolylthio)nicotinic acid