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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1,1-dioxo-N-(1-phenylethyl)-7-(trifluoromethyl)-1lambda6,4,2-benzodithiazin-3-imine 1429321-54-9 C16H13F3N2O2S2
    1,1-dioxo-N-(1-phenylethyl)-7-(trifluoromethyl)-1lambda6,4,2-benzodithiazin-3-imine
    —— N-butan-2-yl-1,1-dioxo-7-(trifluoromethyl)-1lambda6,4,2-benzodithiazin-3-imine 1429321-51-6 C12H13F3N2O2S2
    N-butan-2-yl-1,1-dioxo-7-(trifluoromethyl)-1lambda6,4,2-benzodithiazin-3-imine
    —— 3-(methylthio)-5-phenylisoxazole 73112-00-2 C10H9NOS
    3-(methylthio)-5-phenylisoxazole
    —— 4,6-bis[2-(diisopropoxyphosphorylmethoxy)ethoxy]-2-(methylsulfanyl)pyrimidine 1160513-01-8 C23H44N2O10P2S
    4,6-bis[2-(diisopropoxyphosphorylmethoxy)ethoxy]-2-(methylsulfanyl)pyrimidine
    —— tert-butyl-2-[(4-{[(2-chloropyrimidin-4-yl)(2-methoxyethyl)amino]methyl}phenyl)thio]-2-methyl-propanoate 881687-37-2 C22H30ClN3O3S
    tert-butyl-2-[(4-{[(2-chloropyrimidin-4-yl)(2-methoxyethyl)amino]methyl}phenyl)thio]-2-methyl-propanoate
    —— tert-butyl-2-({4-[((2-methoxyethyl){2-[3-chlorophenyl]pyrimidin-4-yl}amino)methyl]phenyl}-thio)-2-methylpropanoate 881687-40-7 C28H34ClN3O3S
    tert-butyl-2-({4-[((2-methoxyethyl){2-[3-chlorophenyl]pyrimidin-4-yl}amino)methyl]phenyl}-thio)-2-methylpropanoate
    —— 2-[2-(3-methoxypropylamino)benzylthio]imidazole 134017-61-1 C14H19N3OS
    2-[2-(3-methoxypropylamino)benzylthio]imidazole
    —— (<i>E</i>)-4,4'-dichloro-[2,2']bi[benzo[<i>b</i>]thiophenylidene]-3,3'-dione 62025-39-2 C16H6Cl2O2S2
    (<i>E</i>)-4,4'-dichloro-[2,2']bi[benzo[<i>b</i>]thiophenylidene]-3,3'-dione
    —— hydron;phenylsulfanylmethyl carbamimidothioate;iodide —— C8H11IN2S2
    hydron;phenylsulfanylmethyl carbamimidothioate;iodide
    —— 1,5-Bis(phenylthio)-2,2,3,3,4,4-hexamethyl-2,3,4-trisilapentane 253589-52-5 C20H32S2Si3
    1,5-Bis(phenylthio)-2,2,3,3,4,4-hexamethyl-2,3,4-trisilapentane
    —— 3-(1-methyl-1H-tetrazol-5-ylthio)propionyl chloride 93211-21-3 C5H7ClN4OS
    3-(1-methyl-1H-tetrazol-5-ylthio)propionyl chloride
    —— O-t-Butyl-t-butylsulfonat 30223-18-8 C8H18OS
    O-t-Butyl-t-butylsulfonat
    —— Methyl-thiocarbamic acid O-tert-butyl ester 14128-39-3 C6H13NOS
    Methyl-thiocarbamic acid O-tert-butyl ester
    —— 2-(2-Methyl-1,3-dithian-2-yl)propanal 1130279-42-3 C8H14OS2
    2-(2-Methyl-1,3-dithian-2-yl)propanal
    —— 4-methylthiobenzaldehyde ethylene acetal 180143-69-5 C10H12O2S
    4-methylthiobenzaldehyde ethylene acetal
    —— 5-[[(2,3-Difluorophenyl)methyl]thio]-N7-(2-fluoroethyl)thiazolo[4,5-d]pyrimidine-2,7-diamine 259101-58-1 C14H12F3N5S2
    5-[[(2,3-Difluorophenyl)methyl]thio]-N7-(2-fluoroethyl)thiazolo[4,5-d]pyrimidine-2,7-diamine
    —— 5-fluoro-2-(2-nitro-phenylsulfanyl)-benzoic acid ethyl ester 1201672-74-3 C15H12FNO4S
    5-fluoro-2-(2-nitro-phenylsulfanyl)-benzoic acid ethyl ester
    —— 6-Piperidomethyl-4-dimethylaminopyrimido<4,5-b>(1,4)thiazine 80949-15-1 C14H21N5S
    6-Piperidomethyl-4-dimethylaminopyrimido<4,5-b>(1,4)thiazine
    —— 1-(4-<i>tert</i>-butyl-phenylsulfanyl)-2-nitro-benzene 3169-88-8 C16H17NO2S
    1-(4-<i>tert</i>-butyl-phenylsulfanyl)-2-nitro-benzene
    —— 5-(3,5-dichlorophenylthio)-1,2-dimethyl-4-isopropyl-1H-imidazole 178978-90-0 C14H16Cl2N2S
    5-(3,5-dichlorophenylthio)-1,2-dimethyl-4-isopropyl-1H-imidazole
    —— hydron;4-N,7,7-trimethyl-6,8-dihydropyrimido[4,5-b][1,4]benzothiazine-4,9-diamine;bromide —— C13H18BrN5S
    hydron;4-N,7,7-trimethyl-6,8-dihydropyrimido[4,5-b][1,4]benzothiazine-4,9-diamine;bromide
    —— (4-methoxymethylsulfanyl-phenyl)-acetic acid methyl ester 588939-32-6 C11H14O3S
    (4-methoxymethylsulfanyl-phenyl)-acetic acid methyl ester
    —— 6H-Pyrimido(4,5-b)(1,4)benzothiazine, 7,8-dihydro-9-amino-7,7-dimethyl-4-(dimethylamino)-, hydrobromide 80761-73-5 C14H20BrN5S
    6H-Pyrimido(4,5-b)(1,4)benzothiazine, 7,8-dihydro-9-amino-7,7-dimethyl-4-(dimethylamino)-, hydrobromide
    —— (+-)-N,N-Dimethyl-11H-dibenzo(b,e)(1,4)oxathiepin-11-ethanamine hydrochloride 81320-47-0 C17H20ClNOS
    (+-)-N,N-Dimethyl-11H-dibenzo(b,e)(1,4)oxathiepin-11-ethanamine hydrochloride
    —— 4-Amino-2,5,6-tris(phenylsulfanyl)benzene-1,3-dicarbonitrile 1429124-27-5 C26H17N3S3
    4-Amino-2,5,6-tris(phenylsulfanyl)benzene-1,3-dicarbonitrile
    —— 2-{[5-(3,5-Dichlorophenylthio)-1-ethyl-4-isopropyl-1H-imidazol-2-yl]methoxy}ethyl Acetate 178979-52-7 C19H24Cl2N2O3S
    2-{[5-(3,5-Dichlorophenylthio)-1-ethyl-4-isopropyl-1H-imidazol-2-yl]methoxy}ethyl Acetate
    —— 6-chloro-2-[(2,3-difluorobenzyl)thio]-N-{(1R)-1-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]ethyl}pyrimidin-4-amine 1204707-82-3 C18H20ClF2N3O2S
    6-chloro-2-[(2,3-difluorobenzyl)thio]-N-{(1R)-1-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]ethyl}pyrimidin-4-amine
    —— [2-t-butyldimethylsilyloxymethyl-5-(3-chlorophenylthio)-1-methyl-1H-imidazol-4-yl]methanol 178982-09-7 C18H27ClN2O2SSi
    [2-t-butyldimethylsilyloxymethyl-5-(3-chlorophenylthio)-1-methyl-1H-imidazol-4-yl]methanol
    —— Methyl-formamidomethyl-sulfid 28918-56-1 C3H7NOS
    Methyl-formamidomethyl-sulfid
    —— 5-chloro-2,4'-dinitrodiphenylsulfide 158143-79-4 C12H7ClN2O4S
    5-chloro-2,4'-dinitrodiphenylsulfide
    —— 3,26-dithia-10,19-diazahexacyclo[16.8.0.02,11.04,9.012,17.020,25]hexacosa-1,4,6,8,10,12(17),13,15,18,20,22,24-dodecaen-13-amine 107209-11-0 C22H13N3S2
    3,26-dithia-10,19-diazahexacyclo[16.8.0.02,11.04,9.012,17.020,25]hexacosa-1,4,6,8,10,12(17),13,15,18,20,22,24-dodecaen-13-amine
    —— N,N-Dimethyl-11H-dibenzo(b,e)(1,4)dithiepin-11-propanamine oxalate 81890-73-5 C20H23NO4S2
    N,N-Dimethyl-11H-dibenzo(b,e)(1,4)dithiepin-11-propanamine oxalate
    —— <i>N'</i>-[4-chloro-2-(4-chloro-phenylsulfanyl)-phenyl]-<i>N,N</i>-dimethyl-propanediyldiamine 132319-19-8 C17H20Cl2N2S
    <i>N'</i>-[4-chloro-2-(4-chloro-phenylsulfanyl)-phenyl]-<i>N,N</i>-dimethyl-propanediyldiamine
    —— Thiazolo(4,5-c)pyridazine, 6,7-dihydro-3-methyl- 82608-20-6 C6H7N3S
    Thiazolo(4,5-c)pyridazine, 6,7-dihydro-3-methyl-
    —— 2-(5-(3,5-Dichlorophenylthio)-4-isopropyl-1-methyl-1H-imidazol-2-ylmethoxy)ethyl acetate 178979-50-5 C18H22Cl2N2O3S
    2-(5-(3,5-Dichlorophenylthio)-4-isopropyl-1-methyl-1H-imidazol-2-ylmethoxy)ethyl acetate
    —— tert-butyl 4-[({2-[(2,3-difluorobenzyl)thio]-6-methoxypyrimidin-4-yl}amino)sulfonyl]-1,4-diazepane-1-carboxylate 878387-76-9 C22H29F2N5O5S2
    tert-butyl 4-[({2-[(2,3-difluorobenzyl)thio]-6-methoxypyrimidin-4-yl}amino)sulfonyl]-1,4-diazepane-1-carboxylate
    —— tert-butyl {(3S)-1-[({2-[(2,3-difluorobenzyl)thio]-6-methoxypyrimidin-4-yl}amino)sulfonyl]pyrrolidin-3-yl}carbamate 878387-52-1 C21H27F2N5O5S2
    tert-butyl {(3S)-1-[({2-[(2,3-difluorobenzyl)thio]-6-methoxypyrimidin-4-yl}amino)sulfonyl]pyrrolidin-3-yl}carbamate
    —— N-{2-[(2,3-difluorobenzyl)thio]-6-methoxypyrimidin-4-yl}-3-hydroxy-3-methylazetidine-1-sulfonamide 878387-81-6 C16H18F2N4O4S2
    N-{2-[(2,3-difluorobenzyl)thio]-6-methoxypyrimidin-4-yl}-3-hydroxy-3-methylazetidine-1-sulfonamide
    —— 4-[3,5-difluoro-4-(methylthio)-phenyl]-5-methyl-3-phenylisoxazole 473299-56-8 C17H13F2NOS
    4-[3,5-difluoro-4-(methylthio)-phenyl]-5-methyl-3-phenylisoxazole
    —— tert-butyl {(3R)-1-[({2-[(2,3-difluorobenzyl)thio]-6-methoxypyrimidin-4-yl}amino)sulfonyl]pyrrolidin-3-yl}carbamate 878387-55-4 C21H27F2N5O5S2
    tert-butyl {(3R)-1-[({2-[(2,3-difluorobenzyl)thio]-6-methoxypyrimidin-4-yl}amino)sulfonyl]pyrrolidin-3-yl}carbamate
    —— 4-(3-Bromo-phenylsulfanyl)-5-nitro-thiophene-2-carboxylic acid methyl ester 631909-27-8 C12H8BrNO4S2
    4-(3-Bromo-phenylsulfanyl)-5-nitro-thiophene-2-carboxylic acid methyl ester
    —— Phenyl-3-(2-nitro-5-carbonsaeuremethylester)-thienylsulfid 31845-06-4 C12H9NO4S2
    Phenyl-3-(2-nitro-5-carbonsaeuremethylester)-thienylsulfid
    —— 4-(5-Bromo-pyridin-3-ylsulfanyl)-5-nitro-thiophene-2-carboxylic acid methyl ester 631909-98-3 C11H7BrN2O4S2
    4-(5-Bromo-pyridin-3-ylsulfanyl)-5-nitro-thiophene-2-carboxylic acid methyl ester
    —— 6-chloro-2-[(2,3-difluorobenzyl)thio]-N-{(1R)-1-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]ethyl}pyrimidin-4-amine 1204707-80-1 C18H20ClF2N3O2S
    6-chloro-2-[(2,3-difluorobenzyl)thio]-N-{(1R)-1-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]ethyl}pyrimidin-4-amine
    —— 6-chloro-2-[(2,3-difluorobenzyl)thio]-N-{(1S)-1-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]ethyl}pyrimidin-4-amine 1204707-86-7 C18H20ClF2N3O2S
    6-chloro-2-[(2,3-difluorobenzyl)thio]-N-{(1S)-1-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]ethyl}pyrimidin-4-amine
    —— tert-butyl {1-[({2-[(2,3-difluorobenzyl)thio]-6-methoxypyrimidin-4-yl}amino)sulfonyl]azetidin-3-yl}carbamate 878387-79-2 C20H25F2N5O5S2
    tert-butyl {1-[({2-[(2,3-difluorobenzyl)thio]-6-methoxypyrimidin-4-yl}amino)sulfonyl]azetidin-3-yl}carbamate
    —— 6-chloro-2-[(2,3-difluorobenzyl)thio]-N-{(1S)-1-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]ethyl}pyrimidin-4-amine 1204707-88-9 C18H20ClF2N3O2S
    6-chloro-2-[(2,3-difluorobenzyl)thio]-N-{(1S)-1-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]ethyl}pyrimidin-4-amine
    —— 3-chloro-6,7-dihydro[1,4]oxathiino[2,3-c]pyridazine 943026-18-4 C6H5ClN2OS
    3-chloro-6,7-dihydro[1,4]oxathiino[2,3-c]pyridazine
    —— 2-[(2,3-difluorobenzyl)thio]pyrimidine-4,6-diol 654073-28-6 C11H8F2N2O2S
    2-[(2,3-difluorobenzyl)thio]pyrimidine-4,6-diol
    —— 6,7-dihydro[1,4]oxathiino[3,2-c]pyridazine-3-carbaldehyde 943026-23-1 C7H6N2O2S
    6,7-dihydro[1,4]oxathiino[3,2-c]pyridazine-3-carbaldehyde