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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1,3,5-trithiepane 81451-19-6 C4H8S3
    1,3,5-trithiepane
    —— 1,1-bis(chloromethylthio)methane 129965-42-0 C3H6Cl2S2
    1,1-bis(chloromethylthio)methane
    —— (4-(tert-butyl)-2,6-dimethylphenyl)(phenyl)sulfane 1421690-04-1 C18H22S
    (4-(tert-butyl)-2,6-dimethylphenyl)(phenyl)sulfane
    —— 2-aminoethanethiol t-butyl disulfide hydrochloride —— C6H15NS2*ClH
    2-aminoethanethiol t-butyl disulfide hydrochloride
    —— [6-fluoro-3-(4-methanesulfonylphenylsulfanyl)-2-methylindolizin-1-yl]acetic acid 917760-90-8 C18H16FNO4S2
    [6-fluoro-3-(4-methanesulfonylphenylsulfanyl)-2-methylindolizin-1-yl]acetic acid
    —— 6-methyl-4-(5-methylfuran-2-yl)-2-ethylsulfanylpyridine-3-carbonitrile 1353091-94-7 C14H14N2OS
    6-methyl-4-(5-methylfuran-2-yl)-2-ethylsulfanylpyridine-3-carbonitrile
    —— (4RS,6RS)-4-Hydroxy-1-oxa-7-thiaspiro<5.5>undecan-10-one 144617-18-5 C9H14O3S
    (4RS,6RS)-4-Hydroxy-1-oxa-7-thiaspiro<5.5>undecan-10-one
    —— 4-(methylthio)-N,N,3-trimethylaniline 70611-07-3 C10H15NS
    4-(methylthio)-N,N,3-trimethylaniline
    —— 4-tert-butyl-1-(methylthio)cyclohexene 86050-02-4 C11H20S
    4-tert-butyl-1-(methylthio)cyclohexene
    —— 1-Methyl-2-methylsulfanyl-cyclohexene 86049-99-2 C8H14S
    1-Methyl-2-methylsulfanyl-cyclohexene
    —— 1-bromo-5-methylthiopentane 115412-78-7 C6H13BrS
    1-bromo-5-methylthiopentane
    —— Pentafluor-dithiopropionsaeure-methylester 1542-26-3 C4H3F5S2
    Pentafluor-dithiopropionsaeure-methylester
    —— 2-(1-hydroxy-2,2-bis(methylsulfanyl)ethyl)cyclohexanone 408500-55-0 C10H18O2S2
    2-(1-hydroxy-2,2-bis(methylsulfanyl)ethyl)cyclohexanone
    —— 7-phenylthio-2-heptene 99390-03-1 C13H18S
    7-phenylthio-2-heptene
    —— 4-Amino-5H-pyrimido<4,5-b><1,4>thiazin-on-(6<7H>) 120267-09-6 C6H6N4OS
    4-Amino-5H-pyrimido<4,5-b><1,4>thiazin-on-(6<7H>)
    —— N-[2-(3-isopropyl-[1,2,4]triazolo[4,3-a]pyridin-6-ylsulfanyl)-benzyl]-acetamide 745827-36-5 C18H20N4OS
    N-[2-(3-isopropyl-[1,2,4]triazolo[4,3-a]pyridin-6-ylsulfanyl)-benzyl]-acetamide
    —— 3,7-dithianonane-3-oxide 126526-64-5 C7H16OS2
    3,7-dithianonane-3-oxide
    —— 1-Phenyl-7-(thiazol-2-ylsulfanyl)-[1,2,4]triazolo[4,3-a]quinoline 944924-43-0 C19H12N4S2
    1-Phenyl-7-(thiazol-2-ylsulfanyl)-[1,2,4]triazolo[4,3-a]quinoline
    —— Dicyclopropyl-[2-(1-phenyl-[1,2,4]triazolo[4,3-a]quinolin-7-ylsulfanyl)-thiazol-5-yl]-methanol 944924-30-5 C26H22N4OS2
    Dicyclopropyl-[2-(1-phenyl-[1,2,4]triazolo[4,3-a]quinolin-7-ylsulfanyl)-thiazol-5-yl]-methanol
    —— 2,6-dithiaoctane 2-oxide 126526-62-3 C6H14OS2
    2,6-dithiaoctane 2-oxide
    —— 1,2-Bis-methyldisulfanyl-ethane 80641-43-6 C4H10S4
    1,2-Bis-methyldisulfanyl-ethane
    —— 2-((4-bis(4-bromophenylthio)methyl)phenylmethylthio)-5-nitropyridine 866249-14-1 C25H18Br2N2O2S3
    2-((4-bis(4-bromophenylthio)methyl)phenylmethylthio)-5-nitropyridine
    —— 4-(phenylthio-methyl)-piperidine hydrochloride 875282-60-3 C12H17NS*ClH
    4-(phenylthio-methyl)-piperidine hydrochloride
    —— 1-{2'-[bis(3"-isopropylpyrazol-1"-yl)methyl]phenylsulfanyl}-2-bromoethane 1027064-65-8 C21H27BrN4S
    1-{2'-[bis(3"-isopropylpyrazol-1"-yl)methyl]phenylsulfanyl}-2-bromoethane
    —— [3-chloro-5-(thiazol-2-ylsulfanyl)-pyridin-4-yl]-methanol 1064678-63-2 C9H7ClN2OS2
    [3-chloro-5-(thiazol-2-ylsulfanyl)-pyridin-4-yl]-methanol
    —— (6-ethoxy-2-methylsulfanyl-5-nitro-pyrimidin-4-yl)-ethyl-amine 58288-98-5 C9H14N4O3S
    (6-ethoxy-2-methylsulfanyl-5-nitro-pyrimidin-4-yl)-ethyl-amine
    —— 2-amino-5-chloro-3-cyano-6-thiocyanopyrazine 97780-03-5 C6H2ClN5S
    2-amino-5-chloro-3-cyano-6-thiocyanopyrazine
    —— 6-chloro-2-[(phenylmethyl)thio]-4,5-pyrimidinediamine 354582-79-9 C11H11ClN4S
    6-chloro-2-[(phenylmethyl)thio]-4,5-pyrimidinediamine
    —— bis-(2-amino-ethyl)-sulfoxide; dihydrobromide 105596-04-1 2BrH*C4H12N2OS
    bis-(2-amino-ethyl)-sulfoxide; dihydrobromide
    —— 2-[[(2,3-difluorophenyl)methyl]thio]-6-[[(1R)-2-hydroxy-1-methylethyl]amino]-5-(4-pyridinylthio)-4-pyrimidinol 666752-76-7 C19H18F2N4O2S2
    2-[[(2,3-difluorophenyl)methyl]thio]-6-[[(1R)-2-hydroxy-1-methylethyl]amino]-5-(4-pyridinylthio)-4-pyrimidinol
    —— 1-[2-[[(2,3-difluorophenyl)methyl]thio]-4-hydroxy-6-[[(1R)-2-hydroxy-1-methylethyl]amino]-5-pyrimidinyl]-4(1H)-pyridinethione 666752-75-6 C19H18F2N4O2S2
    1-[2-[[(2,3-difluorophenyl)methyl]thio]-4-hydroxy-6-[[(1R)-2-hydroxy-1-methylethyl]amino]-5-pyrimidinyl]-4(1H)-pyridinethione
    —— 4,6-dichloro-2-(benzylthio)-5-pyrimidinamine 1440512-67-3 C11H9Cl2N3S
    4,6-dichloro-2-(benzylthio)-5-pyrimidinamine
    —— 2-[(2,3-difluorobenzyl)thio]-5-fluoro-6-{[(1R)-2-hydroxy-1-methylethyl]amino}pyrimidin-4-ol 666752-99-4 C14H14F3N3O2S
    2-[(2,3-difluorobenzyl)thio]-5-fluoro-6-{[(1R)-2-hydroxy-1-methylethyl]amino}pyrimidin-4-ol
    —— 2-[(3-fluorobenzyl)thio]-5-fluoro-6-{[(1R)-2-hydroxy-1-methylethyl]amino}pyrimidin-4-ol 666753-02-2 C14H15F2N3O2S
    2-[(3-fluorobenzyl)thio]-5-fluoro-6-{[(1R)-2-hydroxy-1-methylethyl]amino}pyrimidin-4-ol
    —— [[4-amino-2,6-bis[[(2,3-difluorophenyl)methyl]thio]-5-pyrimidinyl]amino]acetonitrile 415920-31-9 C20H15F4N5S2
    [[4-amino-2,6-bis[[(2,3-difluorophenyl)methyl]thio]-5-pyrimidinyl]amino]acetonitrile
    —— O-{4-[5-fluoro-3-(4-methoxytetrahydropyran-4-yl)phenylthio]benzyl}hydroxylamine 153581-66-9 C19H22FNO3S
    O-{4-[5-fluoro-3-(4-methoxytetrahydropyran-4-yl)phenylthio]benzyl}hydroxylamine
    —— 4,6-Dihydroxy-5-nitro-2-[(phenylmethyl)thio]pyrimidine 354582-76-6 C11H9N3O4S
    4,6-Dihydroxy-5-nitro-2-[(phenylmethyl)thio]pyrimidine
    —— 5-chloro-2-[[(2,3-difluorophenyl)methyl]thio]-6-[[(1R)-2-hydroxy-1-methylethyl]amino]-4-pyrimidinol 666752-66-5 C14H14ClF2N3O2S
    5-chloro-2-[[(2,3-difluorophenyl)methyl]thio]-6-[[(1R)-2-hydroxy-1-methylethyl]amino]-4-pyrimidinol
    —— 2-[(4-fluorobenzyl)thio]-5-fluoro-6-{[(1R)-2-hydroxy-1-methylethyl]amino}pyrimidin-4-ol 666753-04-4 C14H15F2N3O2S
    2-[(4-fluorobenzyl)thio]-5-fluoro-6-{[(1R)-2-hydroxy-1-methylethyl]amino}pyrimidin-4-ol
    —— 2-[[(2,3-difluorophenyl)methyl]thio]-6-[[(1R)-2-hydroxy-1-methylethyl]amino]-5-nitro-4-pyrimidinol 666752-70-1 C14H14F2N4O4S
    2-[[(2,3-difluorophenyl)methyl]thio]-6-[[(1R)-2-hydroxy-1-methylethyl]amino]-5-nitro-4-pyrimidinol
    —— 2-[[(2,3-difluorophenyl)methyl]thio]-6-[[(1R)-2-hydroxy-1-methylethyl]amino]-5-(1H-imidazol-2-ylthio)-4-pyrmidinol 666752-73-4 C17H17F2N5O2S2
    2-[[(2,3-difluorophenyl)methyl]thio]-6-[[(1R)-2-hydroxy-1-methylethyl]amino]-5-(1H-imidazol-2-ylthio)-4-pyrmidinol
    —— 2-(benzylthio)-5-chloro-6-{[(1R)-2-hydroxy-1-methylethyl]amino}-4-pyrimidinol 666752-52-9 C14H16ClN3O2S
    2-(benzylthio)-5-chloro-6-{[(1R)-2-hydroxy-1-methylethyl]amino}-4-pyrimidinol
    —— 2-[[(2,3-difluorophenyl)methyl]thio]-6-[[(1R)-2-hydroxy-1-methylethyl]amino]-5-[(4-methyl-4H-1,2,4-triazol-3-yl)thio]-4-pyrimidinol 666752-78-9 C17H18F2N6O2S2
    2-[[(2,3-difluorophenyl)methyl]thio]-6-[[(1R)-2-hydroxy-1-methylethyl]amino]-5-[(4-methyl-4H-1,2,4-triazol-3-yl)thio]-4-pyrimidinol
    —— pentanedithioic acid ethyl ester 13831-09-9 C7H14S2
    pentanedithioic acid ethyl ester
    —— 6-[2-(methylsulfinyl)ethyl]fulvene 1467737-18-3 C9H12OS
    6-[2-(methylsulfinyl)ethyl]fulvene
    —— 5-methyl-2-methylthiopyrimidin-4-amine 54308-64-4 C6H9N3S
    5-methyl-2-methylthiopyrimidin-4-amine
    —— 3-methylsulfanyl-2-methylsulfanylmethylprop-1-ene 96694-05-2 C6H12S2
    3-methylsulfanyl-2-methylsulfanylmethylprop-1-ene
    —— (Z)-(4S)-2,2-dimethoxy-4-<2'-<4''-(methylphenyl)thio>-2'-nitroethenyl>-1,3-dioxolane 150640-12-3 C14H17NO4S
    (Z)-(4S)-2,2-dimethoxy-4-<2'-<4''-(methylphenyl)thio>-2'-nitroethenyl>-1,3-dioxolane
    —— Cyclohex-2-enecarbothioic acid S-pyridin-2-yl ester 159389-41-0 C12H13NOS
    Cyclohex-2-enecarbothioic acid S-pyridin-2-yl ester
    —— 2-Amino-6-({[2-(4-chlorophenyl)-1,3-thiazol-4-yl]methyl}sulfanyl)-4-[1-(3-hydroxypropyl)-1H-pyrazol-3-yl]pyridine-3,5-dicarbonitrile 1187543-17-4 C23H18ClN7OS2
    2-Amino-6-({[2-(4-chlorophenyl)-1,3-thiazol-4-yl]methyl}sulfanyl)-4-[1-(3-hydroxypropyl)-1H-pyrazol-3-yl]pyridine-3,5-dicarbonitrile