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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4-Fluor-2-methylthiothiophen 32431-73-5 C5H5FS2
    4-Fluor-2-methylthiothiophen
    —— 3,3-Dimethyl-5-(phenylsulfanyl)oxolan-2-one 144500-38-9 C12H14O2S
    3,3-Dimethyl-5-(phenylsulfanyl)oxolan-2-one
    —— 4-cyano-4-thioethyl (1'-ethoxy) hepta-1,6-diene 135986-76-4 C12H19NOS
    4-cyano-4-thioethyl (1'-ethoxy) hepta-1,6-diene
    —— 1-Butylmercapto-2-phenylmercapto-propan 6839-05-0 C13H20S2
    1-Butylmercapto-2-phenylmercapto-propan
    —— 3-Methyl-1-methylsulfanylcyclopentene 70871-33-9 C7H12S
    3-Methyl-1-methylsulfanylcyclopentene
    —— 4-chlorobutyl 4,4,5,5,5-pentafluoropentyl sulphide 199730-57-9 C9H14ClF5S
    4-chlorobutyl 4,4,5,5,5-pentafluoropentyl sulphide
    —— 1,1,1,2,2-Pentafluoro-2-(2-iodo-ethylsulfanyl)-ethane 1206523-87-6 C4H4F5IS
    1,1,1,2,2-Pentafluoro-2-(2-iodo-ethylsulfanyl)-ethane
    —— 3-(2-Aminoethyl)thietane 1,1-dioxide 1352242-98-8 C5H11NO2S
    3-(2-Aminoethyl)thietane 1,1-dioxide
    —— 2,6-Anhydro-3-deoxy-L-erythro-hex-2-enonothioamide 136590-79-9 C6H9NO3S
    2,6-Anhydro-3-deoxy-L-erythro-hex-2-enonothioamide
    —— Dnlmctzrkphjfk-uhfffaoysa- 103698-11-9 C9H12N2O2S
    Dnlmctzrkphjfk-uhfffaoysa-
    —— (1S,4R,5S,6S)-5-chloro-6-phenylsulfanylbicyclo[2.2.1]hept-2-ene 71040-90-9 C13H13ClS
    (1S,4R,5S,6S)-5-chloro-6-phenylsulfanylbicyclo[2.2.1]hept-2-ene
    —— 2-ethanesulfonyl-1,1-dimethoxy-ethane 71185-74-5 C6H14O4S
    2-ethanesulfonyl-1,1-dimethoxy-ethane
    —— 1,1,1,3,3,3-Hexafluoro-2-[phenylsulfanyl(triphenylstannyl)methyl]propan-2-ol 147102-04-3 C28H22F6OSSn
    1,1,1,3,3,3-Hexafluoro-2-[phenylsulfanyl(triphenylstannyl)methyl]propan-2-ol
    —— 1-chloro-cis,trans-3,5-dimethyl-trans,trans-3,4-dihydroxy-trans-2-(phenylthio)cyclohexane 3,4-acetonide 81939-87-9 C17H23ClO2S
    1-chloro-cis,trans-3,5-dimethyl-trans,trans-3,4-dihydroxy-trans-2-(phenylthio)cyclohexane 3,4-acetonide
    —— 1-chloro-trans,cis-3,5-dimethyl-cis,cis-3,4-dihydroxy-trans-2-(phenylthio)cyclohexane 3,4-acetonide 81939-82-4 C17H23ClO2S
    1-chloro-trans,cis-3,5-dimethyl-cis,cis-3,4-dihydroxy-trans-2-(phenylthio)cyclohexane 3,4-acetonide
    —— cis,trans-3,5-dimethyl-trans,trans-3,4-dihydroxy-1-mercapto-trans-2-(phenylthio)cyclohexane 3,4-acetonide 81939-88-0 C17H24O2S2
    cis,trans-3,5-dimethyl-trans,trans-3,4-dihydroxy-1-mercapto-trans-2-(phenylthio)cyclohexane 3,4-acetonide
    —— phenylthio-6-O-tert-butyldimethylsilyl-2,3-dideoxy-4-O-(1-imino-1-trichloromethyl)-α-D-threo-hex-2-enopyranoside 177263-31-9 C20H28Cl3NO3SSi
    phenylthio-6-O-tert-butyldimethylsilyl-2,3-dideoxy-4-O-(1-imino-1-trichloromethyl)-α-D-threo-hex-2-enopyranoside
    —— (Z)-1-ethoxy-4-phenylthio-1-butene 124224-91-5 C12H16OS
    (Z)-1-ethoxy-4-phenylthio-1-butene
    —— (5-methylthio-1,3,4-thiadiazol-2-yl)methylamine 933693-22-2 C4H7N3S2
    (5-methylthio-1,3,4-thiadiazol-2-yl)methylamine
    —— 4-chloro-5H,6H,7H-pyrimido[4,5-b][1,4]thiazin-6-one 20015-70-7 C6H4ClN3OS
    4-chloro-5H,6H,7H-pyrimido[4,5-b][1,4]thiazin-6-one
    —— 2-isopropyl-2-methyl-propane-1,3-dithiol 56472-21-0 C7H16S2
    2-isopropyl-2-methyl-propane-1,3-dithiol
    —— 2-(1,1,1-Trifluoropropan-2-yl)propane-1,3-dithiol 130624-22-5 C6H11F3S2
    2-(1,1,1-Trifluoropropan-2-yl)propane-1,3-dithiol
    —— 3-Brom-exo-4-phenyl-endo-6-(phenylthio)bicyclo<3.1.1>hept-2-en 102870-52-0 C19H17BrS
    3-Brom-exo-4-phenyl-endo-6-(phenylthio)bicyclo<3.1.1>hept-2-en
    —— 3-Brom-endo-6-(phenylthio)bicyclo<3.1.1>hept-3-en-endo-2-ol 102870-53-1 C13H13BrOS
    3-Brom-endo-6-(phenylthio)bicyclo<3.1.1>hept-3-en-endo-2-ol
    —— 3-Chlor-endo-6-(phenylthio)bicyclo<3.1.1>hept-3-en-endo-2-ol 102870-56-4 C13H13ClOS
    3-Chlor-endo-6-(phenylthio)bicyclo<3.1.1>hept-3-en-endo-2-ol
    —— 1,2-bis(4-chlorophenyl)-1-[N'-methyl-N-(6-methyl-3-methylsulfanyl-5-oxo-1,2,4-triazin-4-yl)carbamimidoyl]-3-(6-methyl-3-methylsulfanyl-5-oxo-1,2,4-triazin-4-yl)guanidine 118458-64-3 C25H25Cl2N11O2S2
    1,2-bis(4-chlorophenyl)-1-[N'-methyl-N-(6-methyl-3-methylsulfanyl-5-oxo-1,2,4-triazin-4-yl)carbamimidoyl]-3-(6-methyl-3-methylsulfanyl-5-oxo-1,2,4-triazin-4-yl)guanidine
    —— 2-[1'-(Phenylsulfanyl)cyclohexyl]tetrahydropyran 165748-36-7 C17H24OS
    2-[1'-(Phenylsulfanyl)cyclohexyl]tetrahydropyran
    —— 1,2-bis(4-fluorophenyl)-1-[N'-methyl-N-(6-methyl-3-methylsulfanyl-5-oxo-1,2,4-triazin-4-yl)carbamimidoyl]-3-(6-methyl-3-methylsulfanyl-5-oxo-1,2,4-triazin-4-yl)guanidine 132658-69-6 C25H25F2N11O2S2
    1,2-bis(4-fluorophenyl)-1-[N'-methyl-N-(6-methyl-3-methylsulfanyl-5-oxo-1,2,4-triazin-4-yl)carbamimidoyl]-3-(6-methyl-3-methylsulfanyl-5-oxo-1,2,4-triazin-4-yl)guanidine
    —— 1-(Ethylsulfanyl)pentadecane 64919-20-6 C17H36S
    1-(Ethylsulfanyl)pentadecane
    —— N-(2-Amino-1,3,4-thiadiazol-5-ylthioacetyl)methylcarbamate 141722-20-5 C6H8N4O3S2
    N-(2-Amino-1,3,4-thiadiazol-5-ylthioacetyl)methylcarbamate
    —— (6R,7S)-5-Methyl-3-methylsulfanyl-5,6,7,8-tetrahydro-pyrazino[2,3-e][1,2,4]triazine-6,7-diol 106776-44-7 C7H11N5O2S
    (6R,7S)-5-Methyl-3-methylsulfanyl-5,6,7,8-tetrahydro-pyrazino[2,3-e][1,2,4]triazine-6,7-diol
    —— Methyl 5-methoxy-2,6,6-trimethyl-1-cyclohexene dithiocarboxylate 111916-94-0 C12H20OS2
    Methyl 5-methoxy-2,6,6-trimethyl-1-cyclohexene dithiocarboxylate
    —— Methyl α-dithiocyclogeranate 111916-92-8 C11H18S2
    Methyl α-dithiocyclogeranate
    —— 2-(ethylthio)-8,8-dimethylbicyclo<3.2.1>octa-2,6-diene 108712-27-2 C12H18S
    2-(ethylthio)-8,8-dimethylbicyclo<3.2.1>octa-2,6-diene
    —— (octadecylmercapto-[1,3,4]thiadiazol-2-ylmercapto)-acetic acid 102944-91-2 C22H40N2O2S3
    (octadecylmercapto-[1,3,4]thiadiazol-2-ylmercapto)-acetic acid
    —— [4-chloro-6-(4-chloro-benzylamino)-pyrimidin-2-ylsulfanyl]-acetic acid 50892-37-0 C13H11Cl2N3O2S
    [4-chloro-6-(4-chloro-benzylamino)-pyrimidin-2-ylsulfanyl]-acetic acid
    —— 1,5-Di-(2-chlorethylsulfonyl)-pentan 53061-08-8 C9H18Cl2O4S2
    1,5-Di-(2-chlorethylsulfonyl)-pentan
    —— 1-[3,5-Dichloro-4-(2,4,5-trichloro-phenylsulfanyl)-phenyl]-3-methyl-urea 54456-82-5 C14H9Cl5N2OS
    1-[3,5-Dichloro-4-(2,4,5-trichloro-phenylsulfanyl)-phenyl]-3-methyl-urea
    —— 2,5-dimethyl-3-furfurylthio-pyrazine 59021-10-2 C11H12N2OS
    2,5-dimethyl-3-furfurylthio-pyrazine
    —— 1-[4-(2,5-Dimethoxy-phenylsulfanyl)-3,5-dimethyl-phenyl]-3-methyl-urea 54456-79-0 C18H22N2O3S
    1-[4-(2,5-Dimethoxy-phenylsulfanyl)-3,5-dimethyl-phenyl]-3-methyl-urea
    —— [5,6-bis-(4-methylsulfanyl-phenyl)-[1,2,4]triazin-3-yl]-dimethyl-amine 59663-49-9 C19H20N4S2
    [5,6-bis-(4-methylsulfanyl-phenyl)-[1,2,4]triazin-3-yl]-dimethyl-amine
    —— [2-(5-methyl-1,3,4-thiadiazolyl)thio]-acetyl chloride 50918-27-9 C5H5ClN2OS2
    [2-(5-methyl-1,3,4-thiadiazolyl)thio]-acetyl chloride
    —— 6H-Pyrimido[1,2-c][1,3,5]benzothiadiazepine, hydrochloride 60877-22-7 C11H9N3S*ClH
    6H-Pyrimido[1,2-c][1,3,5]benzothiadiazepine, hydrochloride
    —— N-{4-[4-(3-Propyl-ureido)-phenylsulfanyl]-phenyl}-acetamide 54457-10-2 C18H21N3O2S
    N-{4-[4-(3-Propyl-ureido)-phenylsulfanyl]-phenyl}-acetamide
    —— 1-Methyl-3-(4-p-tolylsulfanyl-phenyl)-urea 54456-59-6 C15H16N2OS
    1-Methyl-3-(4-p-tolylsulfanyl-phenyl)-urea
    —— 1-[4-(4-Chloro-phenylsulfanyl)-phenyl]-3-propyl-urea 54457-32-8 C16H17ClN2OS
    1-[4-(4-Chloro-phenylsulfanyl)-phenyl]-3-propyl-urea
    —— 1-[4-(4-Chloro-phenylsulfanyl)-3,5-dimethyl-phenyl]-3-propyl-urea 54456-80-3 C18H21ClN2OS
    1-[4-(4-Chloro-phenylsulfanyl)-3,5-dimethyl-phenyl]-3-propyl-urea
    —— 1-[4-(4-tert-Butyl-phenylsulfanyl)-3,5-dichloro-phenyl]-3-methyl-urea 54456-77-8 C18H20Cl2N2OS
    1-[4-(4-tert-Butyl-phenylsulfanyl)-3,5-dichloro-phenyl]-3-methyl-urea
    —— 1-[4-(2,6-Dimethoxy-phenylsulfanyl)-phenyl]-3-methyl-urea 54456-89-2 C16H18N2O3S
    1-[4-(2,6-Dimethoxy-phenylsulfanyl)-phenyl]-3-methyl-urea
    —— 1-[3,5-Dichloro-4-(4-nitro-phenylsulfanyl)-phenyl]-3-methyl-urea 54456-86-9 C14H11Cl2N3O3S
    1-[3,5-Dichloro-4-(4-nitro-phenylsulfanyl)-phenyl]-3-methyl-urea