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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— Methyl 3-methyl-2-oxo-4-phenylsulfanylcyclopent-3-ene-1-carboxylate 71847-64-8 C14H14O3S
    Methyl 3-methyl-2-oxo-4-phenylsulfanylcyclopent-3-ene-1-carboxylate
    —— (2-Oxo-3-phenylsulfanyloxolan-3-yl) acetate 62675-06-3 C12H12O4S
    (2-Oxo-3-phenylsulfanyloxolan-3-yl) acetate
    —— (Methoxy-methylsulfanylmethyl)sulfanylbenzene 60565-52-8 C9H12OS2
    (Methoxy-methylsulfanylmethyl)sulfanylbenzene
    —— 2-Isobutyl-5-thiahex-1-en 67173-71-1 C9H18S
    2-Isobutyl-5-thiahex-1-en
    —— 3-Methylthio-5-cyano-6-aminoisothiazolo<4,5-b>pyrazin 67209-13-6 C7H5N5S2
    3-Methylthio-5-cyano-6-aminoisothiazolo<4,5-b>pyrazin
    —— 4-Butyl-2,6-bis-methylsulfanyl-pyrimidine 116137-68-9 C10H16N2S2
    4-Butyl-2,6-bis-methylsulfanyl-pyrimidine
    —— 1-Ethoxycarbonyl-1-<thien-3-yl-mercapto>-ethan 90534-54-6 C9H12O2S2
    1-Ethoxycarbonyl-1-<thien-3-yl-mercapto>-ethan
    —— 7,9,9-Trimethyl-1,4-dithiaspiro[4.5]dec-6-ene-8-carbaldehyde 62641-97-8 C12H18OS2
    7,9,9-Trimethyl-1,4-dithiaspiro[4.5]dec-6-ene-8-carbaldehyde
    —— Ethyl 2-({4-chloro-6-[(2,3-dimethylphenyl)amino]pyrimidin-2-yl}sulfanyl)-2-phenylacetate 916482-38-7 C22H22ClN3O2S
    Ethyl 2-({4-chloro-6-[(2,3-dimethylphenyl)amino]pyrimidin-2-yl}sulfanyl)-2-phenylacetate
    —— [(3-Ethyl-2,2-dimethyl-cyclopropyl)-methoxy-methylsulfanyl]-benzene 54337-65-4 C15H22OS
    [(3-Ethyl-2,2-dimethyl-cyclopropyl)-methoxy-methylsulfanyl]-benzene
    —— dithiocarbonic acid <i>O</i>-ethyl ester-<i>S</i>-<i>m</i>-tolyl ester 63468-45-1 C10H12OS2
    dithiocarbonic acid <i>O</i>-ethyl ester-<i>S</i>-<i>m</i>-tolyl ester
    —— 1-(3-{[(4-Chlorophenyl)methyl]sulfanyl}-4-cyano-1,2-thiazol-5-yl)-3-methylurea 900525-29-3 C13H11ClN4OS2
    1-(3-{[(4-Chlorophenyl)methyl]sulfanyl}-4-cyano-1,2-thiazol-5-yl)-3-methylurea
    —— 2-Amino-6-({[2-(4-chlorophenyl)-1,3-thiazol-4-yl]methyl}thio)-4-(4-hydroxypiperidin-1-yl)pyridine-3,5-dicarbonitrile 1030619-35-2 C22H19ClN6OS2
    2-Amino-6-({[2-(4-chlorophenyl)-1,3-thiazol-4-yl]methyl}thio)-4-(4-hydroxypiperidin-1-yl)pyridine-3,5-dicarbonitrile
    —— 2-(4-Chlorophenyl)sulfanyl-2-(4-methylphenyl)ethanol 1045855-22-8 C15H15ClOS
    2-(4-Chlorophenyl)sulfanyl-2-(4-methylphenyl)ethanol
    —— 2-amino-6-[({2-[(4-fluorophenyl)amino]-1,3-thiazol-4-yl}methyl)thio]-4-piperidin-4-ylpyridine-3,5-dicarbonitrile 1030622-59-3 C22H20FN7S2
    2-amino-6-[({2-[(4-fluorophenyl)amino]-1,3-thiazol-4-yl}methyl)thio]-4-piperidin-4-ylpyridine-3,5-dicarbonitrile
    —— rac-2-({[2-(4-chlorophenyl)-1,3-thiazol-4-yl]methyl}thio)-4-(tetrahydro-2H-pyran-2-yl)pyridine-3,5-dicarbonitrile 1030622-80-0 C22H17ClN4OS2
    rac-2-({[2-(4-chlorophenyl)-1,3-thiazol-4-yl]methyl}thio)-4-(tetrahydro-2H-pyran-2-yl)pyridine-3,5-dicarbonitrile
    —— 2-amino-6-({[2-(4-chlorophenyl)-1,3-thiazol-4-yl]methyl}thio)-4-(tetrahydro-2H-pyran-2-yl)-pyridine-3,5-dicarbonitrile 1030622-68-4 C22H18ClN5OS2
    2-amino-6-({[2-(4-chlorophenyl)-1,3-thiazol-4-yl]methyl}thio)-4-(tetrahydro-2H-pyran-2-yl)-pyridine-3,5-dicarbonitrile
    —— 2-amino-6-({[2-(4-chlorophenyl)-1,3-thiazol-4-yl]methyl}thio)-4-[1-(3-hydroxypropyl)piperidin-4-yl]pyridine-3,5-dicarbonitrile 1030622-66-2 C25H25ClN6OS2
    2-amino-6-({[2-(4-chlorophenyl)-1,3-thiazol-4-yl]methyl}thio)-4-[1-(3-hydroxypropyl)piperidin-4-yl]pyridine-3,5-dicarbonitrile
    —— 2-amino-6-({[2-(4-chlorophenyl)-1,3-thiazol-4-yl]methyl}thio)-4-(tetrahydro-2H-pyran-2-yl)-pyridine-3,5-dicarbonitrile 1030622-69-5 C22H18ClN5OS2
    2-amino-6-({[2-(4-chlorophenyl)-1,3-thiazol-4-yl]methyl}thio)-4-(tetrahydro-2H-pyran-2-yl)-pyridine-3,5-dicarbonitrile
    —— 3-fluoro-N-(2-hydroxy-2-phenylpentyl)-4-(2-(5-(methoxymethyl)pyridin-2-ylamino)thiazol-5-ylthio)picolinamide 1034922-24-1 C27H28FN5O3S2
    3-fluoro-N-(2-hydroxy-2-phenylpentyl)-4-(2-(5-(methoxymethyl)pyridin-2-ylamino)thiazol-5-ylthio)picolinamide
    —— 2,4-diamino-5-isopropyl-6-(4'-methoxyphenylsulfanyl)-7H-pyrrolo[2,3-d]pyrimidine 1043925-17-2 C16H19N5OS
    2,4-diamino-5-isopropyl-6-(4'-methoxyphenylsulfanyl)-7H-pyrrolo[2,3-d]pyrimidine
    —— 2,4-diamino-5-propyl-6-(4'-methoxyphenylsulfanyl)-7H-pyrrolo[2,3-d]pyrimidine 1043925-09-2 C16H19N5OS
    2,4-diamino-5-propyl-6-(4'-methoxyphenylsulfanyl)-7H-pyrrolo[2,3-d]pyrimidine
    —— 2,4-diamino-5-isopropyl-6-(2',5'-dimethoxyphenylsulfanyl)-7H-pyrrolo[2,3-d]pyrimidine 1043925-18-3 C17H21N5O2S
    2,4-diamino-5-isopropyl-6-(2',5'-dimethoxyphenylsulfanyl)-7H-pyrrolo[2,3-d]pyrimidine
    —— 2,4-diamino-5-isopropyl-6-(phenylsulfanyl)-7H-pyrrolo[2,3-d]pyrimidine 1043925-16-1 C15H17N5S
    2,4-diamino-5-isopropyl-6-(phenylsulfanyl)-7H-pyrrolo[2,3-d]pyrimidine
    —— 2,4-diamino-5-propyl-6-(2',5'-dimethoxyphenylsulfanyl)-7H-pyrrolo[2,3-d]pyrimidine 1043925-10-5 C17H21N5O2S
    2,4-diamino-5-propyl-6-(2',5'-dimethoxyphenylsulfanyl)-7H-pyrrolo[2,3-d]pyrimidine
    —— 2,4-diamino-5-propyl-6-(phenylsulfanyl)-7H-pyrrolo[2,3-d]pyrimidine 1043925-08-1 C15H17N5S
    2,4-diamino-5-propyl-6-(phenylsulfanyl)-7H-pyrrolo[2,3-d]pyrimidine
    —— (5S)-3-((R)-2-(tert-butyldimethylsilyloxy)-9-((2S,5S)-5-((4S,7S)-2,2-diisopropyl-7-((2S,5R)-5-((S)-1-(methoxymethoxy)undecyl)-tetrahydrofuran-2-yl)-1,3,2-dioxasilepan-4-yl)-tetrahydrofuran-2-yl)nonyl)-5-methyl-3-phenylthio-dihydrofuran-2(3H)-one 1033883-57-6 C57H102O9SSi2
    (5S)-3-((R)-2-(tert-butyldimethylsilyloxy)-9-((2S,5S)-5-((4S,7S)-2,2-diisopropyl-7-((2S,5R)-5-((S)-1-(methoxymethoxy)undecyl)-tetrahydrofuran-2-yl)-1,3,2-dioxasilepan-4-yl)-tetrahydrofuran-2-yl)nonyl)-5-methyl-3-phenylthio-dihydrofuran-2(3H)-one
    —— 4-chloro-6-cyclopropyl-2-(methylsulfanyl)pyrimidine 21573-00-2 C8H9ClN2S
    4-chloro-6-cyclopropyl-2-(methylsulfanyl)pyrimidine
    —— Diphenyl-[[3-(phenylsulfanylmethyl)phenyl]methyl]phosphane 1046780-45-3 C26H23PS
    Diphenyl-[[3-(phenylsulfanylmethyl)phenyl]methyl]phosphane
    —— 4-[2-(7-ethyl-[1,8]naphthyridin-4-ylamino)-4-methylphenylsulfanyl]-phenol 943719-31-1 C23H21N3OS
    4-[2-(7-ethyl-[1,8]naphthyridin-4-ylamino)-4-methylphenylsulfanyl]-phenol
    —— 1-(1,5-Dithiaspiro[5.5]undecan-9-yl)ethanone 1025389-80-3 C11H18OS2
    1-(1,5-Dithiaspiro[5.5]undecan-9-yl)ethanone
    —— 2-(N-(2-(benzylsulfanyl)-6-methylpyrimidin-4-yl)-N-methylamino)ethanol 1035913-52-0 C15H19N3OS
    2-(N-(2-(benzylsulfanyl)-6-methylpyrimidin-4-yl)-N-methylamino)ethanol
    —— 2-(2-(benzylsulfanyl)-6-methylpyrimidin-4-yloxy)-N-methylethanamine 1035913-38-2 C15H19N3OS
    2-(2-(benzylsulfanyl)-6-methylpyrimidin-4-yloxy)-N-methylethanamine
    —— 4-(3-(phenylthio)propyl)-6,7-dihydro-5H-cyclopenta[c]pyridine 1028832-48-5 C17H19NS
    4-(3-(phenylthio)propyl)-6,7-dihydro-5H-cyclopenta[c]pyridine
    —— 3-ethoxycarbonyl-5-(3-phenylthiopropyl)-1,2,4-triazine 1028832-44-1 C15H17N3O2S
    3-ethoxycarbonyl-5-(3-phenylthiopropyl)-1,2,4-triazine
    —— 3-(methylthio)-2,5-bis(3-thienyl)pyrrole 1020208-98-3 C13H11NS3
    3-(methylthio)-2,5-bis(3-thienyl)pyrrole
    —— O-[(E)-6-oxohept-2-enyl] azetidine-1-carbothioate 1018479-22-5 C11H17NO2S
    O-[(E)-6-oxohept-2-enyl] azetidine-1-carbothioate
    —— N<sup>1</sup>-[(E)-3-(dihydroxyphosphinyl)-prop-2-enyl]-5-(phenylthio)uracil 1023339-93-6 C13H13N2O5PS
    N<sup>1</sup>-[(E)-3-(dihydroxyphosphinyl)-prop-2-enyl]-5-(phenylthio)uracil
    —— Thiopyrano(4,3-c)pyrazole, 2,3,3a,4,6,7-hexahydro-7-(o-methylbenzylidene)-2-(3-(4-methyl-1-piperazinyl)propyl)-3-o-tolyl-, maleate 102367-50-0 C33H42N4O5S
    Thiopyrano(4,3-c)pyrazole, 2,3,3a,4,6,7-hexahydro-7-(o-methylbenzylidene)-2-(3-(4-methyl-1-piperazinyl)propyl)-3-o-tolyl-, maleate
    —— Bis-<5,5,5-trichlor-pentyl>-sulfid 14146-66-8 C10H16Cl6S
    Bis-<5,5,5-trichlor-pentyl>-sulfid
    —— {6-fluoro-3-[2-fluoro-4-(morpholine-4-sulfonyl)phenylsulfanyl]-2-methylindolizin-1-yl}acetic acid 1036713-43-5 C21H20F2N2O5S2
    {6-fluoro-3-[2-fluoro-4-(morpholine-4-sulfonyl)phenylsulfanyl]-2-methylindolizin-1-yl}acetic acid
    —— 6H-Pyrimido(4,5-b)(1,4)benzothiazine-4,9-diamine, 7,8-dihydro-7,7-dimethyl-N(sup 4)-(1-methylethyl)-N(sup 9)-pentyl-, monohydrobromide 103291-39-0 C20H32BrN5S
    6H-Pyrimido(4,5-b)(1,4)benzothiazine-4,9-diamine, 7,8-dihydro-7,7-dimethyl-N(sup 4)-(1-methylethyl)-N(sup 9)-pentyl-, monohydrobromide
    —— 6H-Pyrimido(4,5-b)(1,4)benzothiazine-4,9-diamine, 7,8-dihydro-7,7-dimethyl-N(sup 9)-(phenylmethyl)-, monohydrobromide 103291-31-2 C19H22BrN5S
    6H-Pyrimido(4,5-b)(1,4)benzothiazine-4,9-diamine, 7,8-dihydro-7,7-dimethyl-N(sup 9)-(phenylmethyl)-, monohydrobromide
    —— Sulfonium, hexamethylenebis(dimethyl-, diiodide 94982-30-6 C10H24I2S2
    Sulfonium, hexamethylenebis(dimethyl-, diiodide
    —— 6H-Pyrimido(4,5-b)(1,4)benzothiazine-4,9-diamine, 7,8-dihydro-N(sup 9)-heptyl-N(sup 4),7,7-trimethyl-, monohydrobromide 103291-35-6 C20H32BrN5S
    6H-Pyrimido(4,5-b)(1,4)benzothiazine-4,9-diamine, 7,8-dihydro-N(sup 9)-heptyl-N(sup 4),7,7-trimethyl-, monohydrobromide
    —— 6H-Pyrimido(4,5-b)(1,4)benzothiazine-4,9-diamine, 7,8-dihydro-7,7-dimethyl-N(sup 9)-hexyl-, monohydrobromide 103291-29-8 C18H28BrN5S
    6H-Pyrimido(4,5-b)(1,4)benzothiazine-4,9-diamine, 7,8-dihydro-7,7-dimethyl-N(sup 9)-hexyl-, monohydrobromide
    —— 6H-Pyrimido(4,5-b)(1,4)benzothiazine-4,9-diamine, 7,8-dihydro-N(sup 9)-pentyl-N(sup 4),7,7-trimethyl-, monohydrobromide 103291-34-5 C18H28BrN5S
    6H-Pyrimido(4,5-b)(1,4)benzothiazine-4,9-diamine, 7,8-dihydro-N(sup 9)-pentyl-N(sup 4),7,7-trimethyl-, monohydrobromide
    —— 6H-Pyrimido(4,5-b)(1,4)benzothiazine-4,9-diamine, 7,8-dihydro-N(sup 9)-butyl-7,7-dimethyl-N(sup 4)-(1-methylethyl)-, monohydrobromide, hydrate 103291-38-9 C19H32BrN5OS
    6H-Pyrimido(4,5-b)(1,4)benzothiazine-4,9-diamine, 7,8-dihydro-N(sup 9)-butyl-7,7-dimethyl-N(sup 4)-(1-methylethyl)-, monohydrobromide, hydrate
    —— S-(2-(Diisobutylamino)ethyl)pseudothiourea dihydrobromide 102612-82-8 C11H27Br2N3S
    S-(2-(Diisobutylamino)ethyl)pseudothiourea dihydrobromide
    —— 2-Methyl-2-propyl-1,3-propanediol carbamate isopropylthiocarbamate 91565-32-1 C12H24N2O3S
    2-Methyl-2-propyl-1,3-propanediol carbamate isopropylthiocarbamate