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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-Methylthio-6-phenyl-thiazolo<4,5-d>-ν-triazin-7(6H)-on 94099-83-9 C11H8N4OS2
    2-Methylthio-6-phenyl-thiazolo<4,5-d>-ν-triazin-7(6H)-on
    —— 3,3'-Bis-ethylsulfanyl-[1,1']bi[bicyclo[1.1.1]pentyl] 115092-68-7 C14H22S2
    3,3'-Bis-ethylsulfanyl-[1,1']bi[bicyclo[1.1.1]pentyl]
    —— 1-Phenylthio-1-trimethylsilyloxy-ethan 40110-37-0 C11H18OSSi
    1-Phenylthio-1-trimethylsilyloxy-ethan
    —— Butyl-<4-butylmercapto-3-methyl-benzyl>-sulfid 97833-72-2 C16H26S2
    Butyl-<4-butylmercapto-3-methyl-benzyl>-sulfid
    —— 3,5-Dichlorobis(methylthio)pyridin 51230-89-8 C7H7Cl2NS2
    3,5-Dichlorobis(methylthio)pyridin
    —— 876300-91-3 C20H17N3O2S
    —— 1-[3-(4-methyl-5-oxo-2,5-dihydrofuran-2-yl)-propyl]-5-phenylsulfanyl-pyrrolidin-2-one 849208-89-5 C18H21NO3S
    1-[3-(4-methyl-5-oxo-2,5-dihydrofuran-2-yl)-propyl]-5-phenylsulfanyl-pyrrolidin-2-one
    —— (3-Nitro-pyridyl-(2)-mercapto)-aceton 5898-30-6 C8H8N2O3S
    (3-Nitro-pyridyl-(2)-mercapto)-aceton
    —— [(E)-2-(4-Chloro-phenylsulfanyl)-vinyl]-phosphonodithioic acid S,S-dipropyl ester 23480-14-0 C14H20ClOPS3
    [(E)-2-(4-Chloro-phenylsulfanyl)-vinyl]-phosphonodithioic acid S,S-dipropyl ester
    —— 50596-07-1 C13H19N2O2PS
    —— 2-Benzylsulfanyl-1-methyl-1H-imidazole; hydrochloride 50968-71-3 C11H12N2S*ClH
    2-Benzylsulfanyl-1-methyl-1H-imidazole; hydrochloride
    —— 3-Methyl-thiobutyric acid S-(2-chloro-3-diisopropylcarbamoylsulfanyl-propyl) ester 38456-69-8 C15H28ClNO2S2
    3-Methyl-thiobutyric acid S-(2-chloro-3-diisopropylcarbamoylsulfanyl-propyl) ester
    —— 5-(pyrimidin-2-ylthio)-2H-benzimidazole-2-spirocyclohexane 141421-24-1 C16H16N4S
    5-(pyrimidin-2-ylthio)-2H-benzimidazole-2-spirocyclohexane
    —— N-[2-(4,5-dichloro-2-nitrophenyl)sulfanyl-4-methylphenyl]formamide 500898-71-5 C14H10Cl2N2O3S
    N-[2-(4,5-dichloro-2-nitrophenyl)sulfanyl-4-methylphenyl]formamide
    —— 4,5-dichloro-<i>N</i>-(4-trifluoromethylsulfanyl-phenyl)-1<i>H</i>-imidazole-2-carboximidic acid 4-trifluoromethylsulfanyl-anilide 64737-99-1 C18H10Cl2F6N4S2
    4,5-dichloro-<i>N</i>-(4-trifluoromethylsulfanyl-phenyl)-1<i>H</i>-imidazole-2-carboximidic acid 4-trifluoromethylsulfanyl-anilide
    —— o-Tolyl-N,N-dimethyl-thiocarbamoyl-trithiocarbonat 17210-31-0 C11H13NS4
    o-Tolyl-N,N-dimethyl-thiocarbamoyl-trithiocarbonat
    —— <i>N</i><sup>4</sup>,<i>N</i><sup>4</sup>-dimethyl-2-methylsulfanyl-pyrimidine-4,5,6-triyltriamine 154-20-1 C7H13N5S
    <i>N</i><sup>4</sup>,<i>N</i><sup>4</sup>-dimethyl-2-methylsulfanyl-pyrimidine-4,5,6-triyltriamine
    —— 37107-89-4 C21H24O3S2
    —— 2-((4-bromophenyl)thio)-5-methyltetrahydrofuran 1451371-71-3 C11H13BrOS
    2-((4-bromophenyl)thio)-5-methyltetrahydrofuran
    —— 1-methyl-2-(γ-picolylmercapto)imidazole 87008-57-9 C10H11N3S
    1-methyl-2-(γ-picolylmercapto)imidazole
    —— N,N'-bis[(2-(hexylthio)phenyl)methylene]-1,2-ethanediamine 261361-40-4 C28H40N2S2
    N,N'-bis[(2-(hexylthio)phenyl)methylene]-1,2-ethanediamine
    —— 4-(2-ethylsulfanyl-4,5-dimethyl-thiazolium-3-yl)-1-methyl-pyridinium; iodide 63317-11-3 C13H18N2S2*2I
    4-(2-ethylsulfanyl-4,5-dimethyl-thiazolium-3-yl)-1-methyl-pyridinium; iodide
    —— 2-chloro-1-(1-ethoxy-ethylsulfanyl)-propane 92349-41-2 C7H15ClOS
    2-chloro-1-(1-ethoxy-ethylsulfanyl)-propane
    —— 6-endo-hydroxymethyl-4-exo-phenylthiobicyclo<3.1.0>hex-2-ene 75758-80-4 C13H14OS
    6-endo-hydroxymethyl-4-exo-phenylthiobicyclo<3.1.0>hex-2-ene
    —— 1ax-Isothiocyanato-2-ax-thiocyanato-4-eq-tert-butyl-cyclohexan 62444-45-5 C12H18N2S2
    1ax-Isothiocyanato-2-ax-thiocyanato-4-eq-tert-butyl-cyclohexan
    —— ((E)-2-Methanesulfonyl-vinyl)-trimethyl-silane 64489-04-9 C6H14O2SSi
    ((E)-2-Methanesulfonyl-vinyl)-trimethyl-silane
    —— 8-methoxy-7-phenylthio-2,3,4,5-tetrahydro-1H-3-benzazepine 119018-77-8 C17H19NOS
    8-methoxy-7-phenylthio-2,3,4,5-tetrahydro-1H-3-benzazepine
    —— 7-methoxy-4-methyl-2-propylsulfanyl-4<i>H</i>-thiazolo[4,5-<i>b</i>]pyridin-5-one 71109-63-2 C11H14N2O2S2
    7-methoxy-4-methyl-2-propylsulfanyl-4<i>H</i>-thiazolo[4,5-<i>b</i>]pyridin-5-one
    —— 2-(naphthalen-2-ylthio)benzo[d]oxazole 1158999-50-8 C17H11NOS
    2-(naphthalen-2-ylthio)benzo[d]oxazole
    —— Lithium; (4E,6E)-2,4-dimethyl-octa-4,6-dienoate 99427-13-1 C10H15O2*Li
    Lithium; (4E,6E)-2,4-dimethyl-octa-4,6-dienoate
    —— 2-(4-chlorobenzylthio)-6-(2-methylpropyl)-4-(phenylthio)pyrimidine-5-carbonitrile 1402215-06-8 C22H20ClN3S2
    2-(4-chlorobenzylthio)-6-(2-methylpropyl)-4-(phenylthio)pyrimidine-5-carbonitrile
    —— N2,N4-bis(4-(methylthio)phenyl)pentane-2,4-diimine 1361138-36-4 C19H22N2S2
    N2,N4-bis(4-(methylthio)phenyl)pentane-2,4-diimine
    —— 9-{[3-(2-methylphenyl)quinoxalin-2-yl]methyl}-9H-purin-6-amine 1365616-93-8 C21H17N7
    9-{[3-(2-methylphenyl)quinoxalin-2-yl]methyl}-9H-purin-6-amine
    —— N,N,4,4-Tetramethyl-2-pentinthioamid 124235-20-7 C9H15NS
    N,N,4,4-Tetramethyl-2-pentinthioamid
    —— (S)-2-(2-(benzylsulfanyl)-6-methylpyrimidin-4-ylamino)-3-methylbutan-1-ol 1035913-50-8 C17H23N3OS
    (S)-2-(2-(benzylsulfanyl)-6-methylpyrimidin-4-ylamino)-3-methylbutan-1-ol
    —— 5-{[(4-chlorophenyl)methyl]sulfanyl}-1-(pyrrolidin-2-ylmethyl)-1H-1,2,3,4-tetrazole hydrochloride 1209836-44-1 C13H17Cl2N5S
    5-{[(4-chlorophenyl)methyl]sulfanyl}-1-(pyrrolidin-2-ylmethyl)-1H-1,2,3,4-tetrazole hydrochloride
    —— 3-Hydroxy-6-phenylthiopyridazin 66089-78-9 C10H8N2OS
    3-Hydroxy-6-phenylthiopyridazin
    —— 123702-20-5 C4GeN4S4
    —— 2-bromo-3-(hexylthio)thiophene 1309469-55-3 C10H15BrS2
    2-bromo-3-(hexylthio)thiophene
    —— (2-(2,5-dimethoxyphenylthio)benzylideneamino)-N-3-methylguanidine 1147093-15-9 C17H20N4O2S
    (2-(2,5-dimethoxyphenylthio)benzylideneamino)-N-3-methylguanidine
    —— Methyl-carbamic acid 3,5-dimethyl-4-(2-trifluoromethyl-phenylsulfanyl)-phenyl ester 52145-43-4 C17H16F3NO2S
    Methyl-carbamic acid 3,5-dimethyl-4-(2-trifluoromethyl-phenylsulfanyl)-phenyl ester
    —— 2-methanesulfonyl-2-methylsulfanyl-propane 67658-95-1 C5H12O2S2
    2-methanesulfonyl-2-methylsulfanyl-propane
    —— Z-1-cyclopropyl-5-methoxy-4-p-tolylthiopent-4-en-1-one 128672-61-7 C16H20O2S
    Z-1-cyclopropyl-5-methoxy-4-p-tolylthiopent-4-en-1-one
    —— 1-(4-chloro-2-(methylthio)pyrimidin-5-yl)-2-(2-chloro-6-fluorophenyl)ethanone 1431324-49-0 C13H9Cl2FN2OS
    1-(4-chloro-2-(methylthio)pyrimidin-5-yl)-2-(2-chloro-6-fluorophenyl)ethanone
    —— 3-{5-[3-Methyl-5-methylsulfanyl-3H-[1,3,4]thiadiazol-(2Z)-ylidene]-4-oxo-2-thioxo-thiazolidin-3-yl}-propionic acid 21015-78-1 C10H11N3O3S4
    3-{5-[3-Methyl-5-methylsulfanyl-3H-[1,3,4]thiadiazol-(2Z)-ylidene]-4-oxo-2-thioxo-thiazolidin-3-yl}-propionic acid
    —— N-{2-[(2-cyanophenyl)sulfanyl]phenyl}-5-(2-hydroxyphenyl)-3-pyridin-3-yl-4,5-dihydro-1H-pyrazole-1-carboxamide 1035234-05-9 C28H21N5O2S
    N-{2-[(2-cyanophenyl)sulfanyl]phenyl}-5-(2-hydroxyphenyl)-3-pyridin-3-yl-4,5-dihydro-1H-pyrazole-1-carboxamide
    —— Phenyl-N,N-diethyl-thiocarbamoyl-trithiocarbonat 19378-31-5 C12H15NS4
    Phenyl-N,N-diethyl-thiocarbamoyl-trithiocarbonat
    —— 76685-61-5 C22H34OS2
    —— 2-(4-Aethoxy-phenylmercapto)-benzoesaeure 5588-49-8 C15H14O3S
    2-(4-Aethoxy-phenylmercapto)-benzoesaeure
    —— 1-(6-chloro-pyridin-3-ylmethyl)-6-methoxy-3-(2-nitro-phenylsulfanyl)-1H-indole 691400-48-3 C21H16ClN3O3S
    1-(6-chloro-pyridin-3-ylmethyl)-6-methoxy-3-(2-nitro-phenylsulfanyl)-1H-indole