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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— Bis-<(1,2,3,4-thiatriazol-5-yl)-thio>-methan 1482-28-6 C3H2N6S4
    Bis-<(1,2,3,4-thiatriazol-5-yl)-thio>-methan
    —— 4-Ethylthio-3-methylfuroxan 49739-33-5 C5H8N2O2S
    4-Ethylthio-3-methylfuroxan
    —— 3-Ethylthio-4-methylfurazan 49739-34-6 C5H8N2OS
    3-Ethylthio-4-methylfurazan
    —— 3-Ethylthio-4-methylfuroxan 49739-35-7 C5H8N2O2S
    3-Ethylthio-4-methylfuroxan
    —— Bis-(3-Chlor-4-carboxamidoisothiazol-5-yl)-sulfid 1028-53-1 C8H4Cl2N4O2S3
    Bis-(3-Chlor-4-carboxamidoisothiazol-5-yl)-sulfid
    —— 2,3,6,7-tetrahydro-[1,4]oxathiino[2,3-<i>d</i>]pyridazine-5,8-dione 30125-35-0 C6H6N2O3S
    2,3,6,7-tetrahydro-[1,4]oxathiino[2,3-<i>d</i>]pyridazine-5,8-dione
    —— 2-(2-Bromophenyl)sulfanyl-3-(trifluoromethyl)aniline 24025-13-6 C13H9BrF3NS
    2-(2-Bromophenyl)sulfanyl-3-(trifluoromethyl)aniline
    —— 3-<Pyridyl-(2)-mercapto>-pentan-dion-(2,4) 67302-31-2 C10H11NO2S
    3-<Pyridyl-(2)-mercapto>-pentan-dion-(2,4)
    —— 2-[(4-Fluorophenyl)methylsulfanyl]pyrimidine-4,5-diamine 124732-07-6 C11H11FN4S
    2-[(4-Fluorophenyl)methylsulfanyl]pyrimidine-4,5-diamine
    —— 2'-Aethoxycarbonyl-3,4-dimethoxy-diphenylsulfid 17313-61-0 C17H18O4S
    2'-Aethoxycarbonyl-3,4-dimethoxy-diphenylsulfid
    —— 1.6-Dibrom-dipyridazo<4,5-b;4,5-e>-1.4-dithiin 13616-19-8 C8H2Br2N4S2
    1.6-Dibrom-dipyridazo<4,5-b;4,5-e>-1.4-dithiin
    —— 2-[(2,3,4,5,6-Pentafluorophenyl)methylsulfanyl]pyrimidine-4,5-diamine 124732-09-8 C11H7F5N4S
    2-[(2,3,4,5,6-Pentafluorophenyl)methylsulfanyl]pyrimidine-4,5-diamine
    —— 1.6-Dichlor-dipyridazo<4,5-b;4,5-e>-1.4-dithiin 13617-05-5 C8H2Cl2N4S2
    1.6-Dichlor-dipyridazo<4,5-b;4,5-e>-1.4-dithiin
    —— 1.6-Bis-benzylmercapto-dipyridazo<4,5-b;4,5-e>-1.4-dithiin 13616-26-7 C22H16N4S4
    1.6-Bis-benzylmercapto-dipyridazo<4,5-b;4,5-e>-1.4-dithiin
    —— 1.6-Bis-methylmercapto-dipyridazo<4,5-b;4,5-e>-1.4-dithiin 13616-27-8 C10H8N4S4
    1.6-Bis-methylmercapto-dipyridazo<4,5-b;4,5-e>-1.4-dithiin
    —— 2,2,2-trifluoroethoxy-4-cyano-5-ethylthioisothiazole 154846-66-9 C8H7F3N2OS2
    2,2,2-trifluoroethoxy-4-cyano-5-ethylthioisothiazole
    —— 2-[(4-Bromophenyl)methylsulfanyl]pyrimidine-4,5-diamine 124732-08-7 C11H11BrN4S
    2-[(4-Bromophenyl)methylsulfanyl]pyrimidine-4,5-diamine
    —— 2-Butylsulfanylpyrimidine-4,5-diamine 124732-01-0 C8H14N4S
    2-Butylsulfanylpyrimidine-4,5-diamine
    —— 2-[(4-Chlorophenyl)sulfanylmethylsulfanyl]pyrimidine-4,5-diamine 124732-11-2 C11H11ClN4S2
    2-[(4-Chlorophenyl)sulfanylmethylsulfanyl]pyrimidine-4,5-diamine
    —— 2-(Cyclopropylmethylsulfanyl)pyrimidine-4,5-diamine 124732-05-4 C8H12N4S
    2-(Cyclopropylmethylsulfanyl)pyrimidine-4,5-diamine
    —— 2-(4,5-Diaminopyrimidin-2-yl)sulfanylacetonitrile 124732-02-1 C6H7N5S
    2-(4,5-Diaminopyrimidin-2-yl)sulfanylacetonitrile
    —— 2-Prop-2-ynylsulfanylpyrimidine-4,5-diamine 124732-03-2 C7H8N4S
    2-Prop-2-ynylsulfanylpyrimidine-4,5-diamine
    —— 1,3-Diethyl-2-[hydroxy(methylamino)methyl]sulfanyl-6-oxopyrimidin-3-ium-4-olate 112977-66-9 C10H17N3O3S
    1,3-Diethyl-2-[hydroxy(methylamino)methyl]sulfanyl-6-oxopyrimidin-3-ium-4-olate
    —— 1,6,8-Trimethyl-3-phenyl-1H,8H-pyrimido[4,5-e][1,3,4]thiadiazine-5,7-dione 99261-95-7 C14H14N4O2S
    1,6,8-Trimethyl-3-phenyl-1H,8H-pyrimido[4,5-e][1,3,4]thiadiazine-5,7-dione
    —— 3-(Methylsulfanyl)pyrazino[2,3-e][1,2,4]triazine 831218-37-2 C6H5N5S
    3-(Methylsulfanyl)pyrazino[2,3-e][1,2,4]triazine
    —— 5,5-dideuterio-1,5-dihydro-3-methyl-10-thia-5-deazaflavin 69139-14-6 C12H10N2O2S
    5,5-dideuterio-1,5-dihydro-3-methyl-10-thia-5-deazaflavin
    —— 2-(2-Chloro-pyridin-3-ylsulfanyl)-3,5,6-trimethyl-phenol 103424-57-3 C14H14ClNOS
    2-(2-Chloro-pyridin-3-ylsulfanyl)-3,5,6-trimethyl-phenol
    —— Methyl 2,4-dioxo-3-phenylthiobutyrate 119493-28-6 C11H10O4S
    Methyl 2,4-dioxo-3-phenylthiobutyrate
    —— 5-ethylthio-3-methyl-4-nitrosoisothiazole 74840-89-4 C6H8N2OS2
    5-ethylthio-3-methyl-4-nitrosoisothiazole
    —— 2-n-propylthietane 1,1-dioxide 80324-93-2 C6H12O2S
    2-n-propylthietane 1,1-dioxide
    —— 4-n-propylthiete 1,1-dioxide 154012-37-0 C6H10O2S
    4-n-propylthiete 1,1-dioxide
    —— (Z)-4-Dimethylamino-3-phenylsulfanyl-1-(tetrahydro-pyran-2-yloxy)-but-3-en-2-one 115412-98-1 C17H23NO3S
    (Z)-4-Dimethylamino-3-phenylsulfanyl-1-(tetrahydro-pyran-2-yloxy)-but-3-en-2-one
    —— 5-Chloro-2H-1,3-benzodithiole 133532-83-9 C7H5ClS2
    5-Chloro-2H-1,3-benzodithiole
    —— <2α<Z(S<sup>*</sup>)>,3β>-2-<3-<3,3-bis(ethylthio)tetrahydro-2H-pyran-2-yl>-2-propenyl>tetrahydro-2-methyl-3-(tert-butyldimethylsiloxy)-2H-pyran 121620-35-7 C24H46O3S2Si
    <2α<Z(S<sup>*</sup>)>,3β>-2-<3-<3,3-bis(ethylthio)tetrahydro-2H-pyran-2-yl>-2-propenyl>tetrahydro-2-methyl-3-(tert-butyldimethylsiloxy)-2H-pyran
    —— <2α<Z(S<sup>*</sup>)>,3β>-2-<3-<3,3-bis(ethylthio)tetrahydro-2H-pyran-2-yl>-2-propenyl>tetrahydro-2-methyl-2H-pyran-3-ol 101696-65-5 C18H32O3S2
    <2α<Z(S<sup>*</sup>)>,3β>-2-<3-<3,3-bis(ethylthio)tetrahydro-2H-pyran-2-yl>-2-propenyl>tetrahydro-2-methyl-2H-pyran-3-ol
    —— 2-(4-Bromophenyl)-6-methyl-5-phenylsulfanyl-2,3-dihydropyran-4-one 129435-93-4 C18H15BrO2S
    2-(4-Bromophenyl)-6-methyl-5-phenylsulfanyl-2,3-dihydropyran-4-one
    —— 3-(2-phenylthio-3,3-dimethyl-1-butenyl)-2-pyridinol 142502-93-0 C17H19NOS
    3-(2-phenylthio-3,3-dimethyl-1-butenyl)-2-pyridinol
    —— Methyl <1-(Phenylthio)-3,3-dimethylbutylidene>hydrazinocarboxylate 114393-61-2 C14H20N2O2S
    Methyl <1-(Phenylthio)-3,3-dimethylbutylidene>hydrazinocarboxylate
    —— 4-n-Propylmercapto-2-methylpyridin 5613-23-0 C9H13NS
    4-n-Propylmercapto-2-methylpyridin
    —— cis-3-Methoxy-1-methylmercapto-prop-1-en 13168-92-8 C5H10OS
    cis-3-Methoxy-1-methylmercapto-prop-1-en
    —— 2-(3-Bromo-thien-2-ylthio)valeric acid 142578-09-4 C9H11BrO2S2
    2-(3-Bromo-thien-2-ylthio)valeric acid
    —— 2-tert-butyl-4-chloro-5-(4-n-propoxymethyl-cyclohexyl)methylthio-3(2H)-pyridazinone 141604-35-5 C19H31ClN2O2S
    2-tert-butyl-4-chloro-5-(4-n-propoxymethyl-cyclohexyl)methylthio-3(2H)-pyridazinone
    —— 2-(1,1,2,2-Tetrafluoro-ethylsulfanyl)-butane 68409-14-3 C6H10F4S
    2-(1,1,2,2-Tetrafluoro-ethylsulfanyl)-butane
    —— 2-tert-butyl-4-chloro-5-(4-cyclopropylmethoxymethyl-cyclohexyl)methylthio-3(2H)-pyridazinone 141604-34-4 C20H31ClN2O2S
    2-tert-butyl-4-chloro-5-(4-cyclopropylmethoxymethyl-cyclohexyl)methylthio-3(2H)-pyridazinone
    —— Dimethyl-2-(3-bromo-2-thienylthio)-2-methylglutarate 142578-01-6 C12H15BrO4S2
    Dimethyl-2-(3-bromo-2-thienylthio)-2-methylglutarate
    —— 2-tert-butyl-4-chloro-5-(4-n-hexyloxymethyl-cyclohexyl)methylthio-3(2H)-pyridazinone 141604-39-9 C22H37ClN2O2S
    2-tert-butyl-4-chloro-5-(4-n-hexyloxymethyl-cyclohexyl)methylthio-3(2H)-pyridazinone
    —— 2-(hexane-1-sulfonyl)-ethylamine 771574-30-2 C8H19NO2S
    2-(hexane-1-sulfonyl)-ethylamine
    —— 2-tert-butyl-4-chloro-5-(4-isobutylthiomethylcyclohexyl)methylthio-3(2H)-pyridazinone 141604-42-4 C20H33ClN2OS2
    2-tert-butyl-4-chloro-5-(4-isobutylthiomethylcyclohexyl)methylthio-3(2H)-pyridazinone
    —— 2-tert-butyl-4-chloro-5-(4-cyclohexyloxymethylcyclohexyl)methylthio-3(2H)-pyridazinone 141604-40-2 C22H35ClN2O2S
    2-tert-butyl-4-chloro-5-(4-cyclohexyloxymethylcyclohexyl)methylthio-3(2H)-pyridazinone
    —— 1-(1,1,2,2-Tetrafluoro-ethylsulfanyl)-butane 68409-10-9 C6H10F4S
    1-(1,1,2,2-Tetrafluoro-ethylsulfanyl)-butane