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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— ethyl 2-ethylthio-1-methylpyrrolo[2,3-d]imidazole-5-carboxylate 191411-59-3 C11H15N3O2S
    ethyl 2-ethylthio-1-methylpyrrolo[2,3-d]imidazole-5-carboxylate
    —— 1-Methyl-2-methylsulfanyl-1,4-dihydro-pyrrolo[2,3-d]imidazole-5-carboxylic acid ethyl ester 191411-55-9 C10H13N3O2S
    1-Methyl-2-methylsulfanyl-1,4-dihydro-pyrrolo[2,3-d]imidazole-5-carboxylic acid ethyl ester
    —— (5Z)-6-iodo-6-[(4-methylphenyl)thio]-5-phenylhex-5-enenitrile 1353898-92-6 C19H18INS
    (5Z)-6-iodo-6-[(4-methylphenyl)thio]-5-phenylhex-5-enenitrile
    —— 3-(2-phenyl-[1,3]dithian-2-ylmethyl)-furan 881028-24-6 C15H16OS2
    3-(2-phenyl-[1,3]dithian-2-ylmethyl)-furan
    —— 3-Methylbenzo<b>thiophen-2(3H)-on 28800-51-3 C9H8OS
    3-Methylbenzo<b>thiophen-2(3H)-on
    —— 3-(4-hexylsulfanyl-isoxazol-3-yl)-1,2,5,6-tetrahydro-1-methylpyridine 1073551-46-8 C15H24N2OS
    3-(4-hexylsulfanyl-isoxazol-3-yl)-1,2,5,6-tetrahydro-1-methylpyridine
    —— 2-amino-6-methyl-5-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]-3,4-dihydro-4-oxo-7H-pyrrolo[2,3-d]pyrimidine 1224513-95-4 C15H12N6O2S
    2-amino-6-methyl-5-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]-3,4-dihydro-4-oxo-7H-pyrrolo[2,3-d]pyrimidine
    —— 2-oxo-3-(5-phenyl-[1,3,4]oxadiazol-2-ylsulfanyl)-propionic acid ethyl ester 475293-87-9 C13H12N2O4S
    2-oxo-3-(5-phenyl-[1,3,4]oxadiazol-2-ylsulfanyl)-propionic acid ethyl ester
    —— 1-(5-Phenyl-[1,3,4]oxadiazol-2-ylsulfanyl)-propan-2-one 81555-88-6 C11H10N2O2S
    1-(5-Phenyl-[1,3,4]oxadiazol-2-ylsulfanyl)-propan-2-one
    —— 4-methyl-5-((5-phenyl-1,3,4-oxadiazol-2-yl)thio)benzene-1,2-diol 1174331-73-7 C15H12N2O3S
    4-methyl-5-((5-phenyl-1,3,4-oxadiazol-2-yl)thio)benzene-1,2-diol
    —— 2-((4-chlorobenzyl)thio)-5-phenyl-1,3,4-oxadiazole 28923-55-9 C15H11ClN2OS
    2-((4-chlorobenzyl)thio)-5-phenyl-1,3,4-oxadiazole
    —— 4-(5-phenyl-1,3,4-oxadiazol-2-ylthio)benzene-1,2-diol 1174331-74-8 C14H10N2O3S
    4-(5-phenyl-1,3,4-oxadiazol-2-ylthio)benzene-1,2-diol
    —— 2-{[6-(4-Fluorophenyl)thieno[3,2-d]pyrimidin-4-yl]thio}-5-phenyl-1,3,4-oxadiazole 1610410-40-6 C20H11FN4OS2
    2-{[6-(4-Fluorophenyl)thieno[3,2-d]pyrimidin-4-yl]thio}-5-phenyl-1,3,4-oxadiazole
    —— 6,6-Dimethyl-8-phenyl-7-oxa-1,4-dithia-spiro[4.4]nonan-8-ol 74255-35-9 C14H18O2S2
    6,6-Dimethyl-8-phenyl-7-oxa-1,4-dithia-spiro[4.4]nonan-8-ol
    —— 2-(methylsulfonyl)ethylamine trifluoroacetate 1359970-22-1 C2HF3O2*C3H9NO2S
    2-(methylsulfonyl)ethylamine trifluoroacetate
    —— ethyl 2-(5-(3-amino-pyrazin-2-yl)-1,3,4-oxadiazol-2-ylthio)acetate 1402083-94-6 C10H11N5O3S
    ethyl 2-(5-(3-amino-pyrazin-2-yl)-1,3,4-oxadiazol-2-ylthio)acetate
    —— 2-(3-amino-pyrazin-2-yl)-5-methylthio-1,3,4-oxadiazole 1402083-93-5 C7H7N5OS
    2-(3-amino-pyrazin-2-yl)-5-methylthio-1,3,4-oxadiazole
    —— 1-methyl-2-p-chlorophenylmercaptoethylamine 53662-09-2 C9H12ClNS
    1-methyl-2-p-chlorophenylmercaptoethylamine
    —— t-butyl {[4-[5-chloro-4-[(4-chlorophenylthio)(2,5-difluorophenyl)methyl]pyridine-2-yl]morpholine-2-yl]methyl}carbamate 558465-42-2 C28H29Cl2F2N3O3S
    t-butyl {[4-[5-chloro-4-[(4-chlorophenylthio)(2,5-difluorophenyl)methyl]pyridine-2-yl]morpholine-2-yl]methyl}carbamate
    —— t-butyl 3-[[5-chloro-4-[(4-chlorophenylthio)-(2,5-difluorophenyl)methyl]pyridin-2-yl]amino]propylcarbamate 820224-71-3 C26H27Cl2F2N3O2S
    t-butyl 3-[[5-chloro-4-[(4-chlorophenylthio)-(2,5-difluorophenyl)methyl]pyridin-2-yl]amino]propylcarbamate
    —— Bis(ethylenediamine)(mercurictetrathiocyanato)copper 29471-80-5 C4H16CuN4*C4HgN4S4
    Bis(ethylenediamine)(mercurictetrathiocyanato)copper
    —— 3-(3-fluorophenylsulfanyl)-1-(5-phenylpentyl)quinolin-1-ium iodide 1299398-70-1 C26H25FNS*I
    3-(3-fluorophenylsulfanyl)-1-(5-phenylpentyl)quinolin-1-ium iodide
    —— 3-(4-fluorophenylsulfanyl)-1-(5-phenylpentyl)quinolin-1-ium iodide 1299398-72-3 C26H25FNS*I
    3-(4-fluorophenylsulfanyl)-1-(5-phenylpentyl)quinolin-1-ium iodide
    —— 2-benzothiazolyl 2-morpholino-4-phenyl-5-thiazolyl sulfide 141266-09-3 C20H17N3OS3
    2-benzothiazolyl 2-morpholino-4-phenyl-5-thiazolyl sulfide
    —— 3-(3-methoxyphenylsulfanyl)-1-(5-phenylpentyl)quinolin-1-ium iodide 1299398-75-6 C27H28NOS*I
    3-(3-methoxyphenylsulfanyl)-1-(5-phenylpentyl)quinolin-1-ium iodide
    —— 3-(2-fluorophenylsulfanyl)-1-(5-phenylpentyl)quinolin-1-ium iodide 1299398-68-7 C26H25FNS*I
    3-(2-fluorophenylsulfanyl)-1-(5-phenylpentyl)quinolin-1-ium iodide
    —— 3-(3-trifluoromethylphenylsulfanyl)-1-(5-phenylpentyl)quinolinium iodide 1299398-86-9 C27H25F3NS*I
    3-(3-trifluoromethylphenylsulfanyl)-1-(5-phenylpentyl)quinolinium iodide
    —— 1-(phenylpentyl)-3-(phenylthio)quinolinium iodide 1265087-24-8 C26H26NS*I
    1-(phenylpentyl)-3-(phenylthio)quinolinium iodide
    —— 3-(3-bromophenylthio)quinoline 1299398-52-9 C15H10BrNS
    3-(3-bromophenylthio)quinoline
    —— 3-(4-methoxyphenylsulfanyl)-1-(5-phenylpentyl)quinolin-1-ium iodide 1299398-77-8 C27H28NOS*I
    3-(4-methoxyphenylsulfanyl)-1-(5-phenylpentyl)quinolin-1-ium iodide
    —— 3-(2-bromophenylsulfanyl)-1-(5-phenylpentyl)quinolin-1-ium iodide 1299398-78-9 C26H25BrNS*I
    3-(2-bromophenylsulfanyl)-1-(5-phenylpentyl)quinolin-1-ium iodide
    —— 3-(2-methylphenylsulfanyl)-1-(5-phenylpentyl)quinolin-1-ium iodide 1299398-90-5 C27H28NS*I
    3-(2-methylphenylsulfanyl)-1-(5-phenylpentyl)quinolin-1-ium iodide
    —— 3-(3-trifluoromethylphenylthio)quinoline 1299398-36-9 C16H10F3NS
    3-(3-trifluoromethylphenylthio)quinoline
    —— 3-(4-trifluoromethylphenylsulfanyl)-1-(5-phenylpentyl)quinolin-1-ium iodide 1299398-88-1 C27H25F3NS*I
    3-(4-trifluoromethylphenylsulfanyl)-1-(5-phenylpentyl)quinolin-1-ium iodide
    —— 3-(3-bromophenylsulfanyl)-1-(5-phenylpentyl)quinolin-1-ium iodide 1299398-80-3 C26H25BrNS*I
    3-(3-bromophenylsulfanyl)-1-(5-phenylpentyl)quinolin-1-ium iodide
    —— 3-(4-bromophenylsulfanyl)-1-(5-phenylpentyl)quinolin-1-ium iodide 1299398-82-5 C26H25BrNS*I
    3-(4-bromophenylsulfanyl)-1-(5-phenylpentyl)quinolin-1-ium iodide
    —— 3-(2-methoxyphenylsulfanyl)-1-(5-phenylpentyl)quinolin-1-ium iodide 1299398-73-4 C27H28NOS*I
    3-(2-methoxyphenylsulfanyl)-1-(5-phenylpentyl)quinolin-1-ium iodide
    —— 3-(3-fluorophenylthio)quinoline 1299398-31-4 C15H10FNS
    3-(3-fluorophenylthio)quinoline
    —— 3-(4-methylphenylsulfanyl)-1-(5-phenylpentyl)quinolin-1-ium iodide 1299398-93-8 C27H28NS*I
    3-(4-methylphenylsulfanyl)-1-(5-phenylpentyl)quinolin-1-ium iodide
    —— 1-(2-aminoethyl)-4-[3-(phenylthio)propyl]piperazine 145708-17-4 C15H25N3S
    1-(2-aminoethyl)-4-[3-(phenylthio)propyl]piperazine
    —— 3-(3-aminopropyldisulfanyl)propan-1-amine;hydron;dichloride —— C6H18Cl2N2S2
    3-(3-aminopropyldisulfanyl)propan-1-amine;hydron;dichloride
    —— 6-methyl-2-methylthiocycloheptimidazole 118808-51-8 C10H10N2S
    6-methyl-2-methylthiocycloheptimidazole
    —— 2-methyl-3-methylsulfanyl-buta-1,3-diene 857954-76-8 C6H10S
    2-methyl-3-methylsulfanyl-buta-1,3-diene
    —— 4-Benzylmercapto-pyridin-1-oxid 3019-21-4 C12H11NOS
    4-Benzylmercapto-pyridin-1-oxid
    —— 2-Chloro-2-phenylsulfanyl-propionic acid ethyl ester 84938-90-9 C11H13ClO2S
    2-Chloro-2-phenylsulfanyl-propionic acid ethyl ester
    —— 6,12-dicyclohexylisothioquinanthrene 1021335-07-8 C30H30N2S2
    6,12-dicyclohexylisothioquinanthrene
    —— ethyl 2-(phenylthio)propanoate 209458-26-4 C11H14O2S
    ethyl 2-(phenylthio)propanoate
    —— N-(2-((4,6-dimethyl-2-morpholinopyrimidin-5-yl)thio)pyrimidin-4-yl)acrylamide 1268274-93-6 C17H20N6O2S
    N-(2-((4,6-dimethyl-2-morpholinopyrimidin-5-yl)thio)pyrimidin-4-yl)acrylamide
    —— 6-cyclohexylisothioquinanthrene 1021335-05-6 C24H20N2S2
    6-cyclohexylisothioquinanthrene
    —— <i>S</i>-(1-oxy-[4]pyridyl)-isothiourea; hydrochloride 106130-58-9 C6H7N3OS*ClH
    <i>S</i>-(1-oxy-[4]pyridyl)-isothiourea; hydrochloride