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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (+)-(1S,2R)-2-amino-1-<4-(methylthio)phenyl>-1,3-propanediol 27348-48-7 C10H15NO2S
    (+)-(1S,2R)-2-amino-1-<4-(methylthio)phenyl>-1,3-propanediol
    —— (4S,5S)-5-(4-methylthiophenyl)-4-hydroxymethyl-2,2-dimethyl-1,3-oxazolidine 135204-38-5 C13H19NO2S
    (4S,5S)-5-(4-methylthiophenyl)-4-hydroxymethyl-2,2-dimethyl-1,3-oxazolidine
    —— (4S,5S)-3-acetyl-2,2-dimethyl-4-formyl-5-<4-(methylthio)phenyl>-1,3-oxazolidine 135204-36-3 C15H19NO3S
    (4S,5S)-3-acetyl-2,2-dimethyl-4-formyl-5-<4-(methylthio)phenyl>-1,3-oxazolidine
    —— 4-(4-amino-2-(6-iodobenzo[d][1,3]dioxol-5-ylthio)-1H-imidazo[4,5-c]pyridin-1-yl)butanamide 1061318-00-0 C17H16IN5O3S
    4-(4-amino-2-(6-iodobenzo[d][1,3]dioxol-5-ylthio)-1H-imidazo[4,5-c]pyridin-1-yl)butanamide
    —— (2-ethyl-2-methyl-[1,3]oxathiolan-5-yl)-methanol 24606-77-7 C7H14O2S
    (2-ethyl-2-methyl-[1,3]oxathiolan-5-yl)-methanol
    —— Bis-<2,5-dimethoxy-phenyl>-sulfid 93006-86-1 C16H18O4S
    Bis-<2,5-dimethoxy-phenyl>-sulfid
    —— N-Phenyl-N-(3-phenylsulfanyl-1H-indol-2-ylmethyl)-acetamide 171618-54-5 C23H20N2OS
    N-Phenyl-N-(3-phenylsulfanyl-1H-indol-2-ylmethyl)-acetamide
    —— (1-Benzenesulfonyl-3-phenylsulfanyl-1H-indol-2-ylmethyl)-phenyl-amine 171618-47-6 C27H22N2O2S2
    (1-Benzenesulfonyl-3-phenylsulfanyl-1H-indol-2-ylmethyl)-phenyl-amine
    —— 1-Ethyl-1-ethylmercapto-propadien-1,2 89942-02-9 C7H12S
    1-Ethyl-1-ethylmercapto-propadien-1,2
    —— 2-bromo-3-(2-cyanoethylsulfanyl)thiophene 499793-74-7 C7H6BrNS2
    2-bromo-3-(2-cyanoethylsulfanyl)thiophene
    —— 2-bromo-3-(2-trimethylsilylethylsulfanyl)thiophene 1310380-03-0 C9H15BrS2Si
    2-bromo-3-(2-trimethylsilylethylsulfanyl)thiophene
    —— (cyclohexylidenemethyl)(2-methylbutyl)sulfane 1332526-10-9 C12H22S
    (cyclohexylidenemethyl)(2-methylbutyl)sulfane
    —— 3,3-Dimethyl-2-phenylsulfanyl-butan-1-ol 54441-95-1 C12H18OS
    3,3-Dimethyl-2-phenylsulfanyl-butan-1-ol
    —— S-<Guanyl-aethyl-1>-isothioharnstoff 88526-36-7 C4H10N4S
    S-<Guanyl-aethyl-1>-isothioharnstoff
    —— 3,3-Dimethyl-2-methylsulfanyl-butan-1-ol 111661-09-7 C7H16OS
    3,3-Dimethyl-2-methylsulfanyl-butan-1-ol
    —— 4-[(4-bromophenyl)thio]butanoic acid 15115-76-1 C10H11BrO2S
    4-[(4-bromophenyl)thio]butanoic acid
    —— (E)-6,6-Dimethyl-5-phenylsulfanyl-hept-3-en-2-one 173200-93-6 C15H20OS
    (E)-6,6-Dimethyl-5-phenylsulfanyl-hept-3-en-2-one
    —— (E)-5,5-Dimethyl-4-phenylsulfanyl-hex-2-enal 711028-77-2 C14H18OS
    (E)-5,5-Dimethyl-4-phenylsulfanyl-hex-2-enal
    —— 2-Adamantan-1-yl-isothiourea 30771-94-9 C11H18N2S
    2-Adamantan-1-yl-isothiourea
    —— 1-methylsulfinyl-4,4-dimethylheptan-2-one 109902-08-1 C10H20O2S
    1-methylsulfinyl-4,4-dimethylheptan-2-one
    —— (E)-5-Methanesulfonyl-6,6-dimethyl-hept-3-en-2-one 711028-71-6 C10H18O3S
    (E)-5-Methanesulfonyl-6,6-dimethyl-hept-3-en-2-one
    —— 3,3-dimethyl-2-methylsulfanyl-butyraldehyde 69769-61-5 C7H14OS
    3,3-dimethyl-2-methylsulfanyl-butyraldehyde
    —— bis-<2,2-bis(ethylthio)vinyl> sulphide 89880-17-1 C12H22S5
    bis-<2,2-bis(ethylthio)vinyl> sulphide
    —— 1-((E)-2-Ethylsulfanyl-2-methylsulfanyl-ethenesulfinyl)-pentan-2-ol 89880-10-4 C10H20O2S3
    1-((E)-2-Ethylsulfanyl-2-methylsulfanyl-ethenesulfinyl)-pentan-2-ol
    —— bis-<2,2-bis(ethylthio)vinyl> sulphoxide 83483-49-2 C12H22OS5
    bis-<2,2-bis(ethylthio)vinyl> sulphoxide
    —— bis<ethylene<4-(methylthio)-2,6-pyridindiyl>-5,5'-bis<thiophene>-2,2'-dicarboxylate> 82093-99-0 C36H26N2O8S6
    bis<ethylene<4-(methylthio)-2,6-pyridindiyl>-5,5'-bis<thiophene>-2,2'-dicarboxylate>
    —— 2-[1-(2-Amino-1-methyl-ethylsulfanyl)-1-pentyl-hexylsulfanyl]-propylamine 91485-96-0 C17H38N2S2
    2-[1-(2-Amino-1-methyl-ethylsulfanyl)-1-pentyl-hexylsulfanyl]-propylamine
    —— 1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluoro-8-methanesulfinyloctane 357604-64-9 C9H7F13OS
    1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluoro-8-methanesulfinyloctane
    —— (Z)-1-(2-hydroxyphenyl)-2-phenylthio-oct-1-ene 104971-00-8 C20H24OS
    (Z)-1-(2-hydroxyphenyl)-2-phenylthio-oct-1-ene
    —— 2'-(Perfluorhexyl)-ethyl-4-mercaptobutyl-sulfid 36097-07-1 C12H13F13S2
    2'-(Perfluorhexyl)-ethyl-4-mercaptobutyl-sulfid
    —— 2,2,5-Trimethyl-[1,3]oxathiolan 38384-74-6 C6H12OS
    2,2,5-Trimethyl-[1,3]oxathiolan
    —— 2-Mercapto-2-methyl-butylamin 99741-24-9 C5H13NS
    2-Mercapto-2-methyl-butylamin
    —— 1-Aethyl-2-phenylmercapto-propylamin 91341-39-8 C11H17NS
    1-Aethyl-2-phenylmercapto-propylamin
    —— (2-Methyl-4-phenylsulfanylbut-3-en-2-yl)sulfanylbenzene 60040-04-2 C17H18S2
    (2-Methyl-4-phenylsulfanylbut-3-en-2-yl)sulfanylbenzene
    —— 1-chloro-4-methylamino-3-(2-chloro-phenylsulfanyl)-benzene 289686-72-2 C13H11Cl2NS
    1-chloro-4-methylamino-3-(2-chloro-phenylsulfanyl)-benzene
    —— 5-Ethoxy-2,2-dimethyl-6-phenylsulfanyl-hexan-3-one 89113-77-9 C16H24O2S
    5-Ethoxy-2,2-dimethyl-6-phenylsulfanyl-hexan-3-one
    —— methyl 3-methyl-3-(2-oxocyclohexyl)propanedithioate 91388-77-1 C11H18OS2
    methyl 3-methyl-3-(2-oxocyclohexyl)propanedithioate
    —— di(1-methylallyl) sulfide 53926-81-1 C8H14S
    di(1-methylallyl) sulfide
    —— 5-Ethoxy-2,2-dimethyl-7-phenylsulfanyl-hept-6-yn-3-one 183435-06-5 C17H22O2S
    5-Ethoxy-2,2-dimethyl-7-phenylsulfanyl-hept-6-yn-3-one
    —— 1,1-diisopropoxy-2-(phenylthio)propane 145866-88-2 C15H24O2S
    1,1-diisopropoxy-2-(phenylthio)propane
    —— (E)-2,2-dimethyl-5-phenyl-8-phenylthio-6-octen-3-one 137346-15-7 C22H26OS
    (E)-2,2-dimethyl-5-phenyl-8-phenylthio-6-octen-3-one
    —— Trihydroxy(oxo)-lambda5-chlorane;1,2,3-tris(ethylsulfanyl)cyclopropene 53202-77-0 C9H19ClO4S3 ——
    —— 17-Phenyl-8,16-dithia-6,14,17-triazatetracyclo[7.7.1.0~2,7~.0~10,15~]heptadeca-2,4,6,10,12,14-hexaene 72397-25-2 C18H13N3S2
    17-Phenyl-8,16-dithia-6,14,17-triazatetracyclo[7.7.1.0~2,7~.0~10,15~]heptadeca-2,4,6,10,12,14-hexaene
    —— 5-[1-(2-tert-butyldimethylsiloxy-3,4-dimethoxyphenyl)methyl]-4-[1-hydroxy-1-(4-methoxyphenyl)methyl]-1-methyl-2-phenylthio-1H-imidazole 445474-75-9 C33H42N2O5SSi
    5-[1-(2-tert-butyldimethylsiloxy-3,4-dimethoxyphenyl)methyl]-4-[1-hydroxy-1-(4-methoxyphenyl)methyl]-1-methyl-2-phenylthio-1H-imidazole
    —— 5-[1-tert-butyldimethylsiloxy-1-(4-methoxymethoxyphenyl)methyl]-1-methyl-2-phenylthio-1H-imidazole 304442-81-7 C25H34N2O3SSi
    5-[1-tert-butyldimethylsiloxy-1-(4-methoxymethoxyphenyl)methyl]-1-methyl-2-phenylthio-1H-imidazole
    —— (E)-1,1-dimethoxy-2-(phenylthio)-3-pentene 145866-42-8 C13H18O2S
    (E)-1,1-dimethoxy-2-(phenylthio)-3-pentene
    —— 5-[1-hydroxy-1-(2-tert-butyldimethylsiloxy-3,4-dimethoxyphenyl)methyl]-1-methyl-2-phenylthio-1H-imidazole 445474-69-1 C25H34N2O4SSi
    5-[1-hydroxy-1-(2-tert-butyldimethylsiloxy-3,4-dimethoxyphenyl)methyl]-1-methyl-2-phenylthio-1H-imidazole
    —— 5-[1-hydroxy-1-(4-methoxymethoxyphenyl)methyl]-4-[1-hydroxy-1-(4-methoxyphenyl)methyl]-1-methyl-2-phenylthio-1H-imidazole 304442-84-0 C27H28N2O5S
    5-[1-hydroxy-1-(4-methoxymethoxyphenyl)methyl]-4-[1-hydroxy-1-(4-methoxyphenyl)methyl]-1-methyl-2-phenylthio-1H-imidazole
    —— 3,3-Dimethyl-1-(3-phenylsulfanyl-tetrahydro-furan-2-yl)-butan-2-one 89113-93-9 C16H22O2S
    3,3-Dimethyl-1-(3-phenylsulfanyl-tetrahydro-furan-2-yl)-butan-2-one
    —— (3,4-Dimethoxy-2-methoxymethoxy-phenyl)-(3-methyl-2-phenylsulfanyl-3H-imidazol-4-yl)-methanol 171780-60-2 C21H24N2O5S
    (3,4-Dimethoxy-2-methoxymethoxy-phenyl)-(3-methyl-2-phenylsulfanyl-3H-imidazol-4-yl)-methanol