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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (Z)-Ethyl 3-carboethoxy-6-phenylthio-2-hexenoate 141649-90-3 C17H22O4S
    (Z)-Ethyl 3-carboethoxy-6-phenylthio-2-hexenoate
    —— 4,4-bis[(4-fluorophenyl)sulfanyl]butanal 1432518-85-8 C16H14F2OS2
    4,4-bis[(4-fluorophenyl)sulfanyl]butanal
    —— 6-[[(3aR,5S,6R,6aR)-2,2-dimethyl-5-(phenylsulfanylmethyl)-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxol-6-yl]oxy]benzo[d][1,3,2]benzodioxaphosphepine 393869-36-8 C26H25O6PS
    6-[[(3aR,5S,6R,6aR)-2,2-dimethyl-5-(phenylsulfanylmethyl)-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxol-6-yl]oxy]benzo[d][1,3,2]benzodioxaphosphepine
    —— N-Phenylaethyl-p-chlorphenyl-mercapto-acetamid 14617-35-7 C16H16ClNOS
    N-Phenylaethyl-p-chlorphenyl-mercapto-acetamid
    —— (E)-Ethyl 6-Phenylthio-2-hexenoate 141649-89-0 C14H18O2S
    (E)-Ethyl 6-Phenylthio-2-hexenoate
    —— (4-Chloro-phenylsulfanyl)-acetic acid; compound with 2-(2-hydroxy-ethylamino)-ethanol 87298-92-8 C4H11NO2*C8H7ClO2S
    (4-Chloro-phenylsulfanyl)-acetic acid; compound with 2-(2-hydroxy-ethylamino)-ethanol
    —— (4-Chloro-phenylsulfanyl)-acetic acid; compound with 2-dimethylamino-ethanol 105892-09-9 C4H11NO*C8H7ClO2S
    (4-Chloro-phenylsulfanyl)-acetic acid; compound with 2-dimethylamino-ethanol
    —— (1-cyclohexyl-2-nitroethyl)(phenyl)sulfide 1131454-32-4 C14H19NO2S
    (1-cyclohexyl-2-nitroethyl)(phenyl)sulfide
    —— 1-Methylthio-2-((3-phenylthio)propyl)-1-hexene 141671-89-8 C16H24S2
    1-Methylthio-2-((3-phenylthio)propyl)-1-hexene
    —— (4-Chloro-phenylsulfanyl)-acetic acid; compound with 2-amino-ethanol 87298-91-7 C2H7NO*C8H7ClO2S
    (4-Chloro-phenylsulfanyl)-acetic acid; compound with 2-amino-ethanol
    —— 4-Phenyl-7-phenylthio-2-heptanone 141649-92-5 C19H22OS
    4-Phenyl-7-phenylthio-2-heptanone
    —— 4-(2-Oxo-cyclohexyl)-4-phenylsulfanyl-butyronitrile 95631-42-8 C16H19NOS
    4-(2-Oxo-cyclohexyl)-4-phenylsulfanyl-butyronitrile
    —— Allyl-N,N-dimethylthiolcarbamat 18283-54-0 C6H11NOS
    Allyl-N,N-dimethylthiolcarbamat
    —— 3-(3-Phenylthiopropyl)-2-cyclohexen-1-one 133188-98-4 C15H18OS
    3-(3-Phenylthiopropyl)-2-cyclohexen-1-one
    —— 3,4-Dihydro-3-hydroxy-2H-thiazino<3,2-a>pyridinium chloride 143746-34-3 C8H10NOS*Cl
    3,4-Dihydro-3-hydroxy-2H-thiazino<3,2-a>pyridinium chloride
    —— tert-Butyl (4-phenylthiobutyl) acrylate 133188-96-2 C17H24O2S
    tert-Butyl (4-phenylthiobutyl) acrylate
    —— S-3-(phenylthio)propyl-N,N-di-isopropylthiolcarbamate 62806-79-5 C16H25NOS2
    S-3-(phenylthio)propyl-N,N-di-isopropylthiolcarbamate
    —— 2-Phenyl-5-phenylthio-1-nitropentane 141649-91-4 C17H19NO2S
    2-Phenyl-5-phenylthio-1-nitropentane
    —— 2-(3-Chloro-1-phenylsulfanyl-propyl)-cyclohexanone 95631-38-2 C15H19ClOS
    2-(3-Chloro-1-phenylsulfanyl-propyl)-cyclohexanone
    —— 2-<(1-Chloro-2-hydroxy-3-propanyl)thio>pyridine 143746-31-0 C8H10ClNOS
    2-<(1-Chloro-2-hydroxy-3-propanyl)thio>pyridine
    —— S-3-(phenylthio)propyl-N,N-di-n-propylthiolcarbamate 62806-78-4 C16H25NOS2
    S-3-(phenylthio)propyl-N,N-di-n-propylthiolcarbamate
    —— 6,7-Dihydro-1,3,4,5,8,9-hexathia-cyclopenta[b]naphthalen-2-one 174091-26-0 C7H4OS6
    6,7-Dihydro-1,3,4,5,8,9-hexathia-cyclopenta[b]naphthalen-2-one
    —— dithiocarbonic acid <i>O</i>-ethyl ester-<i>S</i>-(2-methylsulfanyl-ethyl ester) 5344-19-4 C6H12OS3
    dithiocarbonic acid <i>O</i>-ethyl ester-<i>S</i>-(2-methylsulfanyl-ethyl ester)
    —— 1,3,5-Trimethyl-thiabenzol-1-oxid 32398-62-2 C8H12OS
    1,3,5-Trimethyl-thiabenzol-1-oxid
    —— 2,2-dimethyl-4-(2-phenylsulfanyl-but-3-enyl)-[1,3]dioxolane 792966-26-8 C15H20O2S
    2,2-dimethyl-4-(2-phenylsulfanyl-but-3-enyl)-[1,3]dioxolane
    —— benzotetrathiafulvalene 62921-51-1 C10H6S4
    benzotetrathiafulvalene
    —— 7-Benzylthio-2-methyloxazolo<5,4-d>pyrimidin 33360-27-9 C13H11N3OS
    7-Benzylthio-2-methyloxazolo<5,4-d>pyrimidin
    —— 1,2-bis(prop-1-en-1-ylthio)benzene 1204588-99-7 C12H14S2
    1,2-bis(prop-1-en-1-ylthio)benzene
    —— (1-cyclohexyl-2-nitroethyl)(p-tolyl)sulfide 1131454-33-5 C15H21NO2S
    (1-cyclohexyl-2-nitroethyl)(p-tolyl)sulfide
    —— 1-(4,6-bis-dimethylamino-[1,3,5]triazin-2-yl)-3-(3,5-dimethylisoxazol-4-yl-sulfanyl)-[1,2,4]triazole 1295576-24-7 C14H19N9OS
    1-(4,6-bis-dimethylamino-[1,3,5]triazin-2-yl)-3-(3,5-dimethylisoxazol-4-yl-sulfanyl)-[1,2,4]triazole
    —— (4-chlorophenyl)(1-cyclohexyl-2-nitroethyl)sulfide 1131454-34-6 C14H18ClNO2S
    (4-chlorophenyl)(1-cyclohexyl-2-nitroethyl)sulfide
    —— tris(N,N-diisopropyldithiocarbamato-S,S')bismuth(III) 90587-84-1 C21H42BiN3S6
    tris(N,N-diisopropyldithiocarbamato-S,S')bismuth(III)
    —— S-Allyl-O-methyl xanthate 6329-38-0 C5H8OS2
    S-Allyl-O-methyl xanthate
    —— 1-(4,6-bis-dimethylamino-[1,3,5]triazin-2-yl)-3-(1,3,5-trimethyl-1H-pyrazol-4-ylsulfanyl)-[1,2,4]triazole 1295576-28-1 C15H22N10S
    1-(4,6-bis-dimethylamino-[1,3,5]triazin-2-yl)-3-(1,3,5-trimethyl-1H-pyrazol-4-ylsulfanyl)-[1,2,4]triazole
    —— 3-(1,3,5-trimethyl-1H-pyrazol-4-ylsulfanyl)-1H-[1,2,4]triazole 157106-32-6 C8H11N5S
    3-(1,3,5-trimethyl-1H-pyrazol-4-ylsulfanyl)-1H-[1,2,4]triazole
    —— 3-(R)-amino-1,5-benzoxathiepine 470662-82-9 C9H11NOS
    3-(R)-amino-1,5-benzoxathiepine
    —— 2-(1H-indol-3-ylthio)-4-methoxyphenol 1448175-33-4 C15H13NO2S
    2-(1H-indol-3-ylthio)-4-methoxyphenol
    —— N-(2-Methylsulfanyl-6-oxo-1-phenyl-1,6-dihydro-pyrimidin-5-yl)-benzamide 127301-81-9 C18H15N3O2S
    N-(2-Methylsulfanyl-6-oxo-1-phenyl-1,6-dihydro-pyrimidin-5-yl)-benzamide
    —— triphenodithiazine 258-74-2 C18H10N2S2
    triphenodithiazine
    —— 3.5-Dihydroxy-6-<2-acetamino-1.3.4-thiadiazolyl-(5)-mercapto>-1.2.4-triazin 90110-04-6 C7H6N6O3S2
    3.5-Dihydroxy-6-<2-acetamino-1.3.4-thiadiazolyl-(5)-mercapto>-1.2.4-triazin
    —— 1-[4-(3,5-dimethylphenylsulfanyl)-5-iodo-2-methyl-6-oxo-1,6-dihydropyridin-3-ylmethyl]-1H-imidazole-2-carbonitrile 1185190-24-2 C19H17IN4OS
    1-[4-(3,5-dimethylphenylsulfanyl)-5-iodo-2-methyl-6-oxo-1,6-dihydropyridin-3-ylmethyl]-1H-imidazole-2-carbonitrile
    —— N-(8,8-Dimethyl-7,7-dioxido-7-thiabicyclo(4.2.0)oct-3-en-5-yl)-N,N-diethylamine 23430-95-7 C13H23NO2S
    N-(8,8-Dimethyl-7,7-dioxido-7-thiabicyclo(4.2.0)oct-3-en-5-yl)-N,N-diethylamine
    —— 4-[2,2-bis(phenylsulfanyl)ethyl]-2-methyl-7-phenylhept-1-ene 222547-32-2 C28H32S2
    4-[2,2-bis(phenylsulfanyl)ethyl]-2-methyl-7-phenylhept-1-ene
    —— 2-[(2-isobutylamino-6-methyl)benzylthio]imidazole 128936-36-7 C15H21N3S
    2-[(2-isobutylamino-6-methyl)benzylthio]imidazole
    —— 1.4-Bis-dodecylmercapto-butan 63347-83-1 C28H58S2
    1.4-Bis-dodecylmercapto-butan
    —— Phenylsulfanyl-acetic acid [1-(2-hydroxy-phenyl)-meth-(E)-ylidene]-hydrazide 152489-27-5 C15H14N2O2S
    Phenylsulfanyl-acetic acid [1-(2-hydroxy-phenyl)-meth-(E)-ylidene]-hydrazide
    —— DIOS-m-F 428862-62-8 C19H20F2O2S2
    DIOS-m-F
    —— 1,1-bis(ethylthio)-2-methylsulphinylprop-1-ene 89880-05-7 C8H16OS3
    1,1-bis(ethylthio)-2-methylsulphinylprop-1-ene
    —— 1,1-Bis-ethylsulfanyl-2-methanesulfinyl-ethene 83483-41-4 C7H14OS3
    1,1-Bis-ethylsulfanyl-2-methanesulfinyl-ethene
    —— (2S,3R)-3-(4-methylthiophenyl)-2-acetamido-1,3-propanediol 27348-43-2 C12H17NO3S
    (2S,3R)-3-(4-methylthiophenyl)-2-acetamido-1,3-propanediol