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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-amino-5-[(3,5-dichlorophenyl)sulfanyl]-6-ethylthieno[2,3-d]pyrimidin-4(3H)-one 1178542-69-2 C14H11Cl2N3OS2
    2-amino-5-[(3,5-dichlorophenyl)sulfanyl]-6-ethylthieno[2,3-d]pyrimidin-4(3H)-one
    —— 2-amino-5-[(2,5-dimethoxyphenyl)sulfanyl]-6-ethylthieno[2,3-d]pyrimidin-4(3H)-one 1178542-67-0 C16H17N3O3S2
    2-amino-5-[(2,5-dimethoxyphenyl)sulfanyl]-6-ethylthieno[2,3-d]pyrimidin-4(3H)-one
    —— 2-amino-5-[(3,5-dimethoxyphenyl)sulfanyl]-6-ethylthieno[2,3-d]pyrimidin-4(3H)-one 1178542-76-1 C16H17N3O3S2
    2-amino-5-[(3,5-dimethoxyphenyl)sulfanyl]-6-ethylthieno[2,3-d]pyrimidin-4(3H)-one
    —— 2-amino-6-ethyl-5-(pyridin-4-ylsulfanyl)thieno[2,3-d]pyrimidin-4(3H)-one 1178542-71-6 C13H12N4OS2
    2-amino-6-ethyl-5-(pyridin-4-ylsulfanyl)thieno[2,3-d]pyrimidin-4(3H)-one
    —— 2-amino-6-ethyl-5-(phenylsulfanyl)thieno[2,3-d]pyrimidin-4(3H)-one 1178542-64-7 C14H13N3OS2
    2-amino-6-ethyl-5-(phenylsulfanyl)thieno[2,3-d]pyrimidin-4(3H)-one
    —— 2-amino-5-[(4-bromophenyl)sulfanyl]-6-ethylthieno[2,3-d]pyrimidin-4(3H)-one 1178542-74-9 C14H12BrN3OS2
    2-amino-5-[(4-bromophenyl)sulfanyl]-6-ethylthieno[2,3-d]pyrimidin-4(3H)-one
    —— N-(3-(6-amino-8-((6-ethynylbenzo[d][1,3]dioxol-5-yl)thio)-9H-purin-9-yl)propyl)pivalamide 1402546-48-8 C22H24N6O3S
    N-(3-(6-amino-8-((6-ethynylbenzo[d][1,3]dioxol-5-yl)thio)-9H-purin-9-yl)propyl)pivalamide
    —— (4-methylsulfanyl-phenyl)-arsonic acid 5410-38-8 C7H9AsO3S
    (4-methylsulfanyl-phenyl)-arsonic acid
    —— N,N,N',N'-Tetrabutylthiourea 2422-89-1 C17H36N2S
    N,N,N',N'-Tetrabutylthiourea
    —— α-Formyl-α-<4-chlor-phenylmercapto>-essigsaeure-aethylester 78090-21-8 C11H11ClO3S
    α-Formyl-α-<4-chlor-phenylmercapto>-essigsaeure-aethylester
    —— 2-(4-chlorophenyl)sulfanyl-N-methyl-N-propan-2-ylacetamide 5429-15-2 C12H16ClNOS
    2-(4-chlorophenyl)sulfanyl-N-methyl-N-propan-2-ylacetamide
    —— (Pyridin-2-ylsulfanyl)-acetic acid [1-(2-hydroxy-phenyl)-meth-(Z)-ylidene]-hydrazide 132371-32-5 C14H13N3O2S
    (Pyridin-2-ylsulfanyl)-acetic acid [1-(2-hydroxy-phenyl)-meth-(Z)-ylidene]-hydrazide
    —— (Pyridin-2-ylsulfanyl)-acetic acid hydrazide 104496-91-5 C7H9N3OS
    (Pyridin-2-ylsulfanyl)-acetic acid hydrazide
    —— 2-(2-methyl-1,3-dithiolan-2-yl)propanal 1413945-58-0 C7H12OS2
    2-(2-methyl-1,3-dithiolan-2-yl)propanal
    —— (3-Chloro-4-phenylsulfanylphenyl)methanol 1260497-64-0 C13H11ClOS
    (3-Chloro-4-phenylsulfanylphenyl)methanol
    —— (o-Chlorphenylthio)-acetamid 101080-59-5 C8H8ClNOS
    (o-Chlorphenylthio)-acetamid
    —— (3R,5R)-3-[(R)-(6S)-1,4-dioxa-8-thiaspiro[4.5]dec-6-yl-(methoxymethoxy)methyl]-5-[(1R,2S)-2-(2-methyl-1,3-dithiolan-2-yl)-1-hydroxypropyl]tetrahydro-4H-thiopyran-4-one 1413946-03-8 C22H36O6S4
    (3R,5R)-3-[(R)-(6S)-1,4-dioxa-8-thiaspiro[4.5]dec-6-yl-(methoxymethoxy)methyl]-5-[(1R,2S)-2-(2-methyl-1,3-dithiolan-2-yl)-1-hydroxypropyl]tetrahydro-4H-thiopyran-4-one
    —— (3R,5R)-3-[(R)-(6S)-1,4-dioxa-8-thiaspiro[4.5]dec-6-yl-(methoxymethoxy)methyl]-5-[(1S,2R)-2-(2-methyl-1,3-dithiolan-2-yl)-1-hydroxypropyl]tetrahydro-4H-thiopyran-4-one 1413945-86-4 C22H36O6S4
    (3R,5R)-3-[(R)-(6S)-1,4-dioxa-8-thiaspiro[4.5]dec-6-yl-(methoxymethoxy)methyl]-5-[(1S,2R)-2-(2-methyl-1,3-dithiolan-2-yl)-1-hydroxypropyl]tetrahydro-4H-thiopyran-4-one
    —— 2-(3-chlorophenylthio)propanehydrazide 1255526-61-4 C9H11ClN2OS
    2-(3-chlorophenylthio)propanehydrazide
    —— μ-disulfido-1,2-dithio-dicarbonic acid bis-(2-hydroxy-ethylamide) 94023-51-5 C6H12N2O2S4
    μ-disulfido-1,2-dithio-dicarbonic acid bis-(2-hydroxy-ethylamide)
    —— 3-Bromo-4-(phenylthio)-benzonitrile 869854-58-0 C13H8BrNS
    3-Bromo-4-(phenylthio)-benzonitrile
    —— N1,N1,N4,N4-Tetracyclohexyl-1,4-tetrasulfanedicarbothioamide 5439-79-2 C26H44N2S6
    N1,N1,N4,N4-Tetracyclohexyl-1,4-tetrasulfanedicarbothioamide
    —— o-Ethyl o-pentyl dithiodicarbonate 5439-65-6 C9H16O3S2
    o-Ethyl o-pentyl dithiodicarbonate
    —— 1,1'-Trithiobis(N,N-dicyclohexylmethanethioamide 6317-83-5 C26H44N2S5
    1,1'-Trithiobis(N,N-dicyclohexylmethanethioamide
    —— Carbonic acid, (dicyclohexylamino)thioxomethyl ethyl ester 5439-73-6 C16H27NO3S
    Carbonic acid, (dicyclohexylamino)thioxomethyl ethyl ester
    —— isopropyl 2-chloro-2-phenylthioacetate 255876-18-7 C11H13ClO2S
    isopropyl 2-chloro-2-phenylthioacetate
    —— dicyclohexylcarbamothioyl N,N-dicyclohexylcarbamodithioate 5439-78-1 C26H44N2S3
    dicyclohexylcarbamothioyl N,N-dicyclohexylcarbamodithioate
    —— 3-(Methoxycarbonyl)-2-(2-(phenylthio)ethyl)-4,5-dihydrofuran 131905-83-4 C14H16O3S
    3-(Methoxycarbonyl)-2-(2-(phenylthio)ethyl)-4,5-dihydrofuran
    —— (2R)-2-[3-chloro-4-(methylsulfanyl)phenyl]-3-cyclopentylpropanoic acid 588940-80-1 C15H19ClO2S
    (2R)-2-[3-chloro-4-(methylsulfanyl)phenyl]-3-cyclopentylpropanoic acid
    —— 4-(o-aminophenythio)-N-butyl-4-phenylbutyramide 89569-11-9 C20H26N2OS
    4-(o-aminophenythio)-N-butyl-4-phenylbutyramide
    —— 6-(5-isoquinolylsulfanyl)-7-nitroquinoxaline 203338-87-8 C17H10N4O2S
    6-(5-isoquinolylsulfanyl)-7-nitroquinoxaline
    —— tert.-Butyl(2-nitro-5-(phenylthio)phenyl)acetate 89278-19-3 C18H19NO4S
    tert.-Butyl(2-nitro-5-(phenylthio)phenyl)acetate
    —— 2-(5-chloro-2-nitrophenylthio)aniline 105837-12-5 C12H9ClN2O2S
    2-(5-chloro-2-nitrophenylthio)aniline
    —— O,O'-Dimethyl S,S'-methylene biscarbonodithioate 89364-30-7 C5H8O2S4
    O,O'-Dimethyl S,S'-methylene biscarbonodithioate
    —— 5-(3,5-Dichlorophenylthio)-1,2-bis-(2-carbamoyloxyethyl)-4-isopropyl-1H-imidazole 178980-42-2 C18H22Cl2N4O4S
    5-(3,5-Dichlorophenylthio)-1,2-bis-(2-carbamoyloxyethyl)-4-isopropyl-1H-imidazole
    —— 5-(3,5-Dichlorophenylthio)-1-(2-carbamoyloxyethyl)-2-(3-carbamoyloxypropyl)-4-isopropyl-1H-imidazole 178980-46-6 C19H24Cl2N4O4S
    5-(3,5-Dichlorophenylthio)-1-(2-carbamoyloxyethyl)-2-(3-carbamoyloxypropyl)-4-isopropyl-1H-imidazole
    —— (4-chloromethyl-phenyl)-(4-nitro-phenyl)-sulfide 100398-42-3 C13H10ClNO2S
    (4-chloromethyl-phenyl)-(4-nitro-phenyl)-sulfide
    —— 4,4'-Bis-(phenylthio)-azoxybenzol 5333-73-3 C24H18N2OS2
    4,4'-Bis-(phenylthio)-azoxybenzol
    —— 5,6-dihydro-6-phenyl-4H-s-triazolo<3,4-e><1,6>benzothiazocine 89569-01-7 C17H15N3S
    5,6-dihydro-6-phenyl-4H-s-triazolo<3,4-e><1,6>benzothiazocine
    —— 2-(Propylsulfonyl)cyclohexanon 85058-04-4 C9H16O3S
    2-(Propylsulfonyl)cyclohexanon
    —— 5,6-dimethyl-3-(phenylthio)pyridazine-4-carbonitrile 93824-73-8 C13H11N3S
    5,6-dimethyl-3-(phenylthio)pyridazine-4-carbonitrile
    —— 5-Methyl-2-(phenylthio)hexyl-phenylsulfid 66164-98-5 C19H24S2
    5-Methyl-2-(phenylthio)hexyl-phenylsulfid
    —— 5-Methyl-2-(phenylthio)hexan-1-ol 61829-50-3 C13H20OS
    5-Methyl-2-(phenylthio)hexan-1-ol
    —— 5-Methyl-2-phenylthiohexanal 66332-73-8 C13H18OS
    5-Methyl-2-phenylthiohexanal
    —— 2-(3-Butenylsulfonyl)-1-cyclohexanon 89730-09-6 C10H16O3S
    2-(3-Butenylsulfonyl)-1-cyclohexanon
    —— 2-(Hexylsulfonyl)-1-cyclohexanon 89729-99-7 C12H22O3S
    2-(Hexylsulfonyl)-1-cyclohexanon
    —— 3-methyl-5-(pyridin-2-ylsulfanyl)-3H-imidazole-4-carbaldehyde 1258283-09-8 C10H9N3OS
    3-methyl-5-(pyridin-2-ylsulfanyl)-3H-imidazole-4-carbaldehyde
    —— 3-tert-butylthio-4-hydroxy-6-methyl-2-pyrone 53603-44-4 C10H14O3S
    3-tert-butylthio-4-hydroxy-6-methyl-2-pyrone
    —— 2-methylthio-4,6-pyrimidinyl ditriflate 154499-78-2 C7H4F6N2O6S3
    2-methylthio-4,6-pyrimidinyl ditriflate
    —— phenyl 2-deoxy-2-fluoro-1-thio-α-D-mannopyranoside 931095-45-3 C12H15FO4S
    phenyl 2-deoxy-2-fluoro-1-thio-α-D-mannopyranoside