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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3,5-bis(phenylthio)acetanilide 131195-89-6 C20H17NOS2
    3,5-bis(phenylthio)acetanilide
    —— 5-(pyridin-2-ylthio)pyridin-2-amine 68559-45-5 C10H9N3S
    5-(pyridin-2-ylthio)pyridin-2-amine
    —— N-ethylacetothioacetamide 69583-04-6 C6H11NOS
    N-ethylacetothioacetamide
    —— 5-(4-chloro-phenylsulfanyl)-pyridin-2-ylamine 64064-93-3 C11H9ClN2S
    5-(4-chloro-phenylsulfanyl)-pyridin-2-ylamine
    —— (R)-1-(2-methyl-2-oxiranylmethyl)-4-nitro-2-(4-nitrophenylthio)imidazole 683276-51-9 C13H12N4O5S
    (R)-1-(2-methyl-2-oxiranylmethyl)-4-nitro-2-(4-nitrophenylthio)imidazole
    —— 2-(4-Phenylsulfanyl-phenylamino)-ethanol 51026-08-5 C14H15NOS
    2-(4-Phenylsulfanyl-phenylamino)-ethanol
    —— 6,8-Dimethyl-3-phenyl-1H,8H-pyrimido[4,5-e][1,3,4]thiadiazine-5,7-dione 99261-94-6 C13H12N4O2S
    6,8-Dimethyl-3-phenyl-1H,8H-pyrimido[4,5-e][1,3,4]thiadiazine-5,7-dione
    —— tert.-Butyl-<1,3-dimethyl-but-2-enyl>-disulfid 91009-93-7 C10H20S2
    tert.-Butyl-<1,3-dimethyl-but-2-enyl>-disulfid
    —— 1-n-Butylthio-2-methyl-aethin 18212-33-4 C7H12S
    1-n-Butylthio-2-methyl-aethin
    —— 4-nitro-2-(4-nitrophenylthio)-imidazole 683276-48-4 C9H6N4O4S
    4-nitro-2-(4-nitrophenylthio)-imidazole
    —— Pyridinium, 1,1'-(oxydimethylene)bis(4-(methylthio)-, dichloride 51276-93-8 C14H18Cl2N2OS2
    Pyridinium, 1,1'-(oxydimethylene)bis(4-(methylthio)-, dichloride
    —— 1-[4-(Phenylsulfanyl)but-1-EN-1-YL]pyrrolidine 113541-81-4 C14H19NS
    1-[4-(Phenylsulfanyl)but-1-EN-1-YL]pyrrolidine
    —— 3,7-dibromo-2H,6H-benzo<1,2-b:4,5-b'>dithiophene-2,6-dione 87522-80-3 C10H2Br2O2S2
    3,7-dibromo-2H,6H-benzo<1,2-b:4,5-b'>dithiophene-2,6-dione
    —— 3-Methyl-5-methylsulfanyl-1,3,4-thiadiazol-3-ium-2-amine;iodide —— C4H8IN3S2
    3-Methyl-5-methylsulfanyl-1,3,4-thiadiazol-3-ium-2-amine;iodide
    —— 1-Methoxy-1,5-bis-phenylsulfanyl-pentan-2-one 89171-39-1 C18H20O2S2
    1-Methoxy-1,5-bis-phenylsulfanyl-pentan-2-one
    —— 1-Methoxy-6-methyl-1-phenylsulfanyl-hept-5-en-2-one 89171-38-0 C15H20O2S
    1-Methoxy-6-methyl-1-phenylsulfanyl-hept-5-en-2-one
    —— (R)-2-Phenylsulfanyl-propionaldehyde 125660-37-9 C9H10OS
    (R)-2-Phenylsulfanyl-propionaldehyde
    —— 1-[1-Butylsulfanyl-meth-(E)-ylidene]-3-methyl-2-methylene-cyclohexane 65839-84-1 C13H22S
    1-[1-Butylsulfanyl-meth-(E)-ylidene]-3-methyl-2-methylene-cyclohexane
    —— 5-chloro-2,3-dihydro-3-phenylbenzo[b]thiophene 147620-09-5 C14H11ClS
    5-chloro-2,3-dihydro-3-phenylbenzo[b]thiophene
    —— 5-chloro-2,3-dihydro-2-phenylbenzo[b]thiophene 147620-10-8 C14H11ClS
    5-chloro-2,3-dihydro-2-phenylbenzo[b]thiophene
    —— S-[(3R)-hex-1-en-3-yl] N-butylcarbamothioate 1228454-00-9 C11H21NOS
    S-[(3R)-hex-1-en-3-yl] N-butylcarbamothioate
    —— 1,1-bis(phenylthio)-2-butylcyclopropane 100045-90-7 C19H22S2
    1,1-bis(phenylthio)-2-butylcyclopropane
    —— (2R<sup>*</sup>,2'S<sup>*</sup>)-2-<1-(phenylthio)propyl>-2,3-dihydro-4H-pyran-4-one 140928-69-4 C14H16O2S
    (2R<sup>*</sup>,2'S<sup>*</sup>)-2-<1-(phenylthio)propyl>-2,3-dihydro-4H-pyran-4-one
    —— (2R<sup>*</sup>,2'S<sup>*</sup>)-2-<2-methyl-1-(phenylthio)propyl>-2,3-dihydro-4H-pyran-4-one 140928-73-0 C15H18O2S
    (2R<sup>*</sup>,2'S<sup>*</sup>)-2-<2-methyl-1-(phenylthio)propyl>-2,3-dihydro-4H-pyran-4-one
    —— 4-chloro-6-methyl-5-(1-methylethyl)-2-(methylthio)pyrimidine 1379580-86-5 C9H13ClN2S
    4-chloro-6-methyl-5-(1-methylethyl)-2-(methylthio)pyrimidine
    —— 2,4-Bis-methylsulfanyl-6-thiazol-2-yl-pyrimidine 116137-72-5 C9H9N3S3
    2,4-Bis-methylsulfanyl-6-thiazol-2-yl-pyrimidine
    —— 1-(Phenylthio)-1,5-hexadien-3-ol 63540-13-6 C12H14OS
    1-(Phenylthio)-1,5-hexadien-3-ol
    —— 3-(Methanesulfonyl-methylsulfanyl-methyl)-hept-1-ene 81236-46-6 C10H20O2S2
    3-(Methanesulfonyl-methylsulfanyl-methyl)-hept-1-ene
    —— (3-(5-(2-(methylthio)-4-pyrimidinyl)-1,3-thiazol-4-yl)phenyl)amine 1160624-79-2 C14H12N4S2
    (3-(5-(2-(methylthio)-4-pyrimidinyl)-1,3-thiazol-4-yl)phenyl)amine
    —— O-methylthiomethyl-(S)-lactal 172703-58-1 C5H10O2S
    O-methylthiomethyl-(S)-lactal
    —— 3,3-Difluoro-2-phenyl-4-phenylsulfanyl-pent-4-en-2-ol 221557-79-5 C17H16F2OS
    3,3-Difluoro-2-phenyl-4-phenylsulfanyl-pent-4-en-2-ol
    —— (E)-5-Methyl-1-phenylsulfanyl-hexa-1,5-dien-3-ol 63540-15-8 C13H16OS
    (E)-5-Methyl-1-phenylsulfanyl-hexa-1,5-dien-3-ol
    —— 4-(difluoromethylthio)-2-fluoro-N-methylaniline 935440-64-5 C8H8F3NS
    4-(difluoromethylthio)-2-fluoro-N-methylaniline
    —— N-ethyl-2-fluoro-4-(trifluoromethylthio)-aniline 935440-21-4 C9H9F4NS
    N-ethyl-2-fluoro-4-(trifluoromethylthio)-aniline
    —— (E)-1-octenyl bromomethyl sulfone 86823-63-4 C9H17BrO2S
    (E)-1-octenyl bromomethyl sulfone
    —— 5-tert-Butyl-3-phenylsulfanyl-5H-furan-2-one 127459-06-7 C14H16O2S
    5-tert-Butyl-3-phenylsulfanyl-5H-furan-2-one
    —— 1,2-bis(phenylthio)cyclopentene 123558-55-4 C17H16S2
    1,2-bis(phenylthio)cyclopentene
    —— 2,6-difluoro-N-[(6-phenylsulfanylpyridazin-3-yl)carbamoyl]benzamide 1173149-91-1 C18H12F2N4O2S
    2,6-difluoro-N-[(6-phenylsulfanylpyridazin-3-yl)carbamoyl]benzamide
    —— N-methyl-4-(1,1,2,2-tetrafluoroethylthio)-aniline 935440-59-8 C9H9F4NS
    N-methyl-4-(1,1,2,2-tetrafluoroethylthio)-aniline
    —— 2-chloro-N-methyl-4-(1,1,2,2-tetrafluoroethylthio)-aniline 935441-02-4 C9H8ClF4NS
    2-chloro-N-methyl-4-(1,1,2,2-tetrafluoroethylthio)-aniline
    —— 2-methyl-N-methyl-4-(1,1,2,2-tetrafluoroethylthio)-aniline 935441-03-5 C10H11F4NS
    2-methyl-N-methyl-4-(1,1,2,2-tetrafluoroethylthio)-aniline
    —— 2,5-difluoro-N-methyl-4-(trifluoromethylthio)-aniline 935440-57-6 C8H6F5NS
    2,5-difluoro-N-methyl-4-(trifluoromethylthio)-aniline
    —— 2-[(3,4-difluorobenzyl)thio]-5-fluoro-6-{[(1R)-2-hydroxy-1-methylethyl]amino}pyrimidin-4-ol 666753-00-0 C14H14F3N3O2S
    2-[(3,4-difluorobenzyl)thio]-5-fluoro-6-{[(1R)-2-hydroxy-1-methylethyl]amino}pyrimidin-4-ol
    —— 2-chloro-4-(difluoromethylthio)-N-methylaniline 935440-66-7 C8H8ClF2NS
    2-chloro-4-(difluoromethylthio)-N-methylaniline
    —— 2-fluoro-N-(3-methylthiopropyl)-4-(trifluoromethylthio)aniline 939038-32-1 C11H13F4NS2
    2-fluoro-N-(3-methylthiopropyl)-4-(trifluoromethylthio)aniline
    —— N-methyl-2-methyl-4-(trifluoromethylthio)aniline 935440-55-4 C9H10F3NS
    N-methyl-2-methyl-4-(trifluoromethylthio)aniline
    —— 2-fluoro-N-methyl-4-(1,1,2,2,2-pentafluoroethylthio)-aniline 935440-95-2 C9H7F6NS
    2-fluoro-N-methyl-4-(1,1,2,2,2-pentafluoroethylthio)-aniline
    —— 2-fluoro-N-(2-methoxyethyl)-4-(trifluoromethylthio)aniline 939037-89-5 C10H11F4NOS
    2-fluoro-N-(2-methoxyethyl)-4-(trifluoromethylthio)aniline
    —— 2,6-difluoro-N-methyl-4-(trifluoromethylthio)-aniline 935440-58-7 C8H6F5NS
    2,6-difluoro-N-methyl-4-(trifluoromethylthio)-aniline
    —— 2-chloro-N-methyl-4-(pentafluoroethylthio)-aniline 935440-62-3 C9H7ClF5NS
    2-chloro-N-methyl-4-(pentafluoroethylthio)-aniline