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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4-Methyl-1-[(4-methylphenyl)sulfanyl]pentan-2-one 477761-13-0 C13H18OS
    4-Methyl-1-[(4-methylphenyl)sulfanyl]pentan-2-one
    —— (S)-(+)-1-(p-tolylsulfanyl)-4-methyl-2-pentanol 477761-27-6 C13H20OS
    (S)-(+)-1-(p-tolylsulfanyl)-4-methyl-2-pentanol
    —— 3-(2-chlorophenyl)-7-methylthio-1-phenyl-3,4-dihydropyrimido[4,5-d]-pyrimidin-2(1H)-one 335653-82-2 C19H15ClN4OS
    3-(2-chlorophenyl)-7-methylthio-1-phenyl-3,4-dihydropyrimido[4,5-d]-pyrimidin-2(1H)-one
    —— 5-(2-chlorophenyl)aminomethyl-4-phenylamino-2-methylthiopyrimidine 335653-81-1 C18H17ClN4S
    5-(2-chlorophenyl)aminomethyl-4-phenylamino-2-methylthiopyrimidine
    —— pyrimidin-4-ylsulfanyl-acetic acid methyl ester 64679-74-9 C7H8N2O2S
    pyrimidin-4-ylsulfanyl-acetic acid methyl ester
    —— [[2-(2,6-Dimethylheptyl)-1-cyclobutenyl]thio]benzene 63048-82-8 C19H28S
    [[2-(2,6-Dimethylheptyl)-1-cyclobutenyl]thio]benzene
    —— 1-<4-(p-hydroxyphenylthio)butyl>piperidinium hydrochloride 57055-93-3 C15H23NOS*ClH
    1-<4-(p-hydroxyphenylthio)butyl>piperidinium hydrochloride
    —— 2-(3-chloro-2-hydroxyphenyl)sulfanyl-N,N-diethylacetamide 681123-07-9 C12H16ClNO2S
    2-(3-chloro-2-hydroxyphenyl)sulfanyl-N,N-diethylacetamide
    —— 2-methyl-5-(2-(methylthio)phenyl)thiophene 1360610-85-0 C12H12S2
    2-methyl-5-(2-(methylthio)phenyl)thiophene
    —— 3-[(1R,2R)-2-(2,4-difluorophenyl)-2-hydroxy-1-methyl-3-(1,2,4-triazol-1-yl)propyl]-7-phenylsulfanyl-quinazolin-4-one 187949-61-7 C26H21F2N5O2S
    3-[(1R,2R)-2-(2,4-difluorophenyl)-2-hydroxy-1-methyl-3-(1,2,4-triazol-1-yl)propyl]-7-phenylsulfanyl-quinazolin-4-one
    —— 2-[2'-(methylsulfanyl)phenyl]-1,3-dithiane 765292-66-8 C11H14S3
    2-[2'-(methylsulfanyl)phenyl]-1,3-dithiane
    —— cis-(RS,SR)-γ-hydroxy-β-methyl-γ-<2-(methylthio)phenyl>butanoic acid lactone 133101-61-8 C12H14O2S
    cis-(RS,SR)-γ-hydroxy-β-methyl-γ-<2-(methylthio)phenyl>butanoic acid lactone
    —— N-((2-(methylsulfanyl)phenyl)([1,3]thiazolo[5,4-b]pyridin-2-yl)methyl)-3,4-dihydro-2H-1,5-benzodioxepine-7-sulfonamide 1402607-94-6 C23H21N3O4S3
    N-((2-(methylsulfanyl)phenyl)([1,3]thiazolo[5,4-b]pyridin-2-yl)methyl)-3,4-dihydro-2H-1,5-benzodioxepine-7-sulfonamide
    —— o-methylthiostyrene oxide 67764-86-7 C9H10OS
    o-methylthiostyrene oxide
    —— (2R,3S)-1-Chloro-1,1-difluoro-3-<(4-methylphenyl)thio>hept-6-en-2-ol 136310-16-2 C14H17ClF2OS
    (2R,3S)-1-Chloro-1,1-difluoro-3-<(4-methylphenyl)thio>hept-6-en-2-ol
    —— (R)-(+)-2-methyl-2,3-dihydrobenzo[b]thiophene 129388-08-5 C9H10S
    (R)-(+)-2-methyl-2,3-dihydrobenzo[b]thiophene
    —— 2-Methylmercpto-benzaldoxim 67764-84-5 C8H9NOS
    2-Methylmercpto-benzaldoxim
    —— 6-(2-(methylthio)phenyl)-3,4-dihydro-2H-pyran 1362860-32-9 C12H14OS
    6-(2-(methylthio)phenyl)-3,4-dihydro-2H-pyran
    —— (2S,3S)-1-Chloro-1,1-difluoro-3-<(4-methylphenyl)thio>hept-6-en-2-ol 136310-15-1 C14H17ClF2OS
    (2S,3S)-1-Chloro-1,1-difluoro-3-<(4-methylphenyl)thio>hept-6-en-2-ol
    —— (2S,3R)-1-Chloro-1,1-difluoro-3-<(4-methylphenyl)thio>hept-6-en-2-ol 156483-95-3 C14H17ClF2OS
    (2S,3R)-1-Chloro-1,1-difluoro-3-<(4-methylphenyl)thio>hept-6-en-2-ol
    —— (2R,3R)-1-Chloro-1,1-difluoro-3-<(4-methylphenyl)thio>hept-6-en-2-ol 136310-14-0 C14H17ClF2OS
    (2R,3R)-1-Chloro-1,1-difluoro-3-<(4-methylphenyl)thio>hept-6-en-2-ol
    —— (+)-2-methyl-cis-2,3-dihydroxy-2,3-dihydrobenzo[ b]thiophene 183812-29-5 C9H10O2S
    (+)-2-methyl-cis-2,3-dihydroxy-2,3-dihydrobenzo[ b]thiophene
    —— N-[4-[[4-(2-hydroxyethylamino)-6-[(5-methyl-1,3-thiazol-2-yl)amino]-1,3,5-triazin-2-yl]sulfanyl]phenyl]cyclopropanecarboxamide 1258423-53-8 C19H21N7O2S2
    N-[4-[[4-(2-hydroxyethylamino)-6-[(5-methyl-1,3-thiazol-2-yl)amino]-1,3,5-triazin-2-yl]sulfanyl]phenyl]cyclopropanecarboxamide
    —— N-[4-[[4-(butylamino)-6-[(5-methyl-1,3-thiazol-2-yl)amino]-1,3,5-triazin-2-yl]sulfanyl]phenyl]cyclopropanecarboxamide 1258423-63-0 C21H25N7OS2
    N-[4-[[4-(butylamino)-6-[(5-methyl-1,3-thiazol-2-yl)amino]-1,3,5-triazin-2-yl]sulfanyl]phenyl]cyclopropanecarboxamide
    —— N-[4-[[4-[2-(dimethylamino)ethyl-methylamino]-6-[(5-methyl-1,3-thiazol-2-yl)amino]-1,3,5-triazin-2-yl]sulfanyl]phenyl]cyclopropanecarboxamide 1258423-62-9 C22H28N8OS2
    N-[4-[[4-[2-(dimethylamino)ethyl-methylamino]-6-[(5-methyl-1,3-thiazol-2-yl)amino]-1,3,5-triazin-2-yl]sulfanyl]phenyl]cyclopropanecarboxamide
    —— N-[4-[[4-[(5-methyl-1,3-thiazol-2-yl)amino]-6-piperidin-1-yl-1,3,5-triazin-2-yl]sulfanyl]phenyl]cyclopropanecarboxamide 1258423-66-3 C22H25N7OS2
    N-[4-[[4-[(5-methyl-1,3-thiazol-2-yl)amino]-6-piperidin-1-yl-1,3,5-triazin-2-yl]sulfanyl]phenyl]cyclopropanecarboxamide
    —— N-[4-[[4-(diethylamino)-6-[(5-methyl-1,3-thiazol-2-yl)amino]-1,3,5-triazin-2-yl]sulfanyl]phenyl]cyclopropanecarboxamide 1258423-64-1 C21H25N7OS2
    N-[4-[[4-(diethylamino)-6-[(5-methyl-1,3-thiazol-2-yl)amino]-1,3,5-triazin-2-yl]sulfanyl]phenyl]cyclopropanecarboxamide
    —— N-[4-[[4-[(5-methyl-1,3-thiazol-2-yl)amino]-6-morpholin-4-yl-1,3,5-triazin-2-yl]sulfanyl]phenyl]cyclopropanecarboxamide 1258423-51-6 C21H23N7O2S2
    N-[4-[[4-[(5-methyl-1,3-thiazol-2-yl)amino]-6-morpholin-4-yl-1,3,5-triazin-2-yl]sulfanyl]phenyl]cyclopropanecarboxamide
    —— N-[4-[[4-(cyclopropylamino)-6-[(5-methyl-1,3-thiazol-2-yl)amino]-1,3,5-triazin-2-yl]sulfanyl]phenyl]cyclopropanecarboxamide 1258423-65-2 C20H21N7OS2
    N-[4-[[4-(cyclopropylamino)-6-[(5-methyl-1,3-thiazol-2-yl)amino]-1,3,5-triazin-2-yl]sulfanyl]phenyl]cyclopropanecarboxamide
    —— dinitro-5,5' dipyrimidyl-2,2' sulfure 96592-13-1 C8H4N6O4S
    dinitro-5,5' dipyrimidyl-2,2' sulfure
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(E)-(5-iodo-2-methylsulfanylthiophen-3-yl)methylideneamino]-5-methyltriazole-4-carboxamide —— C12H11IN8O2S2
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(E)-(5-iodo-2-methylsulfanylthiophen-3-yl)methylideneamino]-5-methyltriazole-4-carboxamide
    —— 2-butylthio-4,6-dichloro-5-phenylazopyrimidine 1415583-62-8 C14H14Cl2N4S
    2-butylthio-4,6-dichloro-5-phenylazopyrimidine
    —— 2-Methyl-3-tert.-butyl-thiopropanol-1 62296-19-9 C8H18OS
    2-Methyl-3-tert.-butyl-thiopropanol-1
    —— (E)-(3-deutero-3-hexylnon-1-en-1-yl)(phenyl)sulfane 1393672-48-4 C21H34S
    (E)-(3-deutero-3-hexylnon-1-en-1-yl)(phenyl)sulfane
    —— (2-Isopropylphenyl)(4-bromo-2-cyanophenyl)sulfide 280752-61-6 C16H14BrNS
    (2-Isopropylphenyl)(4-bromo-2-cyanophenyl)sulfide
    —— 7-Chloro-4-(3,5-dimethylpyrazol-1-yl)-2-(2-picolylthio)imidazo<4,5-d>pyridazine 85732-90-7 C16H14ClN7S
    7-Chloro-4-(3,5-dimethylpyrazol-1-yl)-2-(2-picolylthio)imidazo<4,5-d>pyridazine
    —— 5,5'-Bis{[(pyridin-2-yl)methyl]sulfanyl}-2,2'-bi-1,3,4-thiadiazole 650636-37-6 C16H12N6S4
    5,5'-Bis{[(pyridin-2-yl)methyl]sulfanyl}-2,2'-bi-1,3,4-thiadiazole
    —— 2-pyridylmethyl 2'-(4-methylpyrimidyl) sulfide 854375-22-7 C11H11N3S
    2-pyridylmethyl 2'-(4-methylpyrimidyl) sulfide
    —— 4-(3,5-Dimethylpyrazol-1-yl)-2-(2-picolylthio)imidazo<4,5-d>pyridazine 85732-99-6 C16H15N7S
    4-(3,5-Dimethylpyrazol-1-yl)-2-(2-picolylthio)imidazo<4,5-d>pyridazine
    —— 4-Phenyl-5-ethylthio-3H-1,2-dithiole-3-thione 19940-65-9 C11H10S4
    4-Phenyl-5-ethylthio-3H-1,2-dithiole-3-thione
    —— 5-((4-methoxyphenyl)thio)pyrimidine 1308660-20-9 C11H10N2OS
    5-((4-methoxyphenyl)thio)pyrimidine
    —— 5-[2-(tert-butyl-dimethylsilanyloxymethyl)phenylsulfanyl]pyrimidine 1161865-52-6 C17H24N2OSSi
    5-[2-(tert-butyl-dimethylsilanyloxymethyl)phenylsulfanyl]pyrimidine
    —— iso-butyl methyl sulfone 70385-68-1 C5H12O2S
    iso-butyl methyl sulfone
    —— isobutyl (methylthio)methyl sulfoxide 69977-55-5 C6H14OS2
    isobutyl (methylthio)methyl sulfoxide
    —— 3-[(E)-4-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]but-2-enyl]sulfanyl-5,6-diphenyl-1,2,4-triazine —— C34H26N6S2
    3-[(E)-4-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]but-2-enyl]sulfanyl-5,6-diphenyl-1,2,4-triazine
    —— 3-[3-(benzylsulfanyl)pyridin-4-yl]-5,6-dihydro-1,4,2-dioxazine 1253052-76-4 C15H14N2O2S
    3-[3-(benzylsulfanyl)pyridin-4-yl]-5,6-dihydro-1,4,2-dioxazine
    —— 2-methoxy-N-[(E)-(5-pyridin-2-ylsulfanylfuran-2-yl)methylideneamino]acetamide —— C13H13N3O3S
    2-methoxy-N-[(E)-(5-pyridin-2-ylsulfanylfuran-2-yl)methylideneamino]acetamide
    —— 4-[3,6-Bis(2-methylpropyl)pyrazin-2-yl]sulfanylbutan-1-ol 1283166-96-0 C16H28N2OS
    4-[3,6-Bis(2-methylpropyl)pyrazin-2-yl]sulfanylbutan-1-ol
    —— 2-[(6-Nitro-1,3-benzothiazol-2-yl)sulfanyl]-1,3-benzothiazol-6-amine 5964-03-4 C14H8N4O2S3
    2-[(6-Nitro-1,3-benzothiazol-2-yl)sulfanyl]-1,3-benzothiazol-6-amine
    —— 2,4,4-trimethyl-8-(phenylthiomethyl)cyclohex-2-en-1-ol 288302-94-3 C16H22OS
    2,4,4-trimethyl-8-(phenylthiomethyl)cyclohex-2-en-1-ol