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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N.N'-Dicyclohexyl-S-ethyl-isothioharnstoff 14170-80-0 C15H28N2S
    N.N'-Dicyclohexyl-S-ethyl-isothioharnstoff
    —— 3-[2-Hydroxy-8-(oxan-2-yloxy)oct-3-ynyl]-1-(4-methoxybutyl)-3-phenylsulfanylpiperidin-2-one 159599-65-2 C29H43NO5S
    3-[2-Hydroxy-8-(oxan-2-yloxy)oct-3-ynyl]-1-(4-methoxybutyl)-3-phenylsulfanylpiperidin-2-one
    —— 2-(2-(phenylthio)phenyl)ethylamine 127876-59-9 C14H15NS
    2-(2-(phenylthio)phenyl)ethylamine
    —— N,N-dimethyl-2-(2-(phenylthio)phenyl)ethylamine 127876-62-4 C16H19NS
    N,N-dimethyl-2-(2-(phenylthio)phenyl)ethylamine
    —— N,N-dimethyl-1-(2-(phenylthio)phenyl)-2-propylamine 127876-69-1 C17H21NS
    N,N-dimethyl-1-(2-(phenylthio)phenyl)-2-propylamine
    —— 2-(4-Methylphenyl)sulfanylethylazanium 42404-23-9 C9H14NS+
    2-(4-Methylphenyl)sulfanylethylazanium
    —— 2-Phenylsulfenyldimedon 72117-61-4 C14H16O2S
    2-Phenylsulfenyldimedon
    —— 2-Methyl-2-[(phenylsulfanyl)methyl]oxepane 114218-78-9 C14H20OS
    2-Methyl-2-[(phenylsulfanyl)methyl]oxepane
    —— 2-But-3-enyl-4-phenylsulfanyl-2,5-dihydrothiophene 1,1-dioxide 197862-42-3 C14H16O2S2
    2-But-3-enyl-4-phenylsulfanyl-2,5-dihydrothiophene 1,1-dioxide
    —— 2-[(3-chlorobenzyl)thio]-5-fluoro-6-{[(1R)-2-hydroxy-1-methylethyl]amino}-4-pyrimidinol 666752-58-5 C14H15ClFN3O2S
    2-[(3-chlorobenzyl)thio]-5-fluoro-6-{[(1R)-2-hydroxy-1-methylethyl]amino}-4-pyrimidinol
    —— 2,2-difluoro-1-phenyl-2-(phenylsulfanyl)ethanol 351195-17-0 C14H12F2OS
    2,2-difluoro-1-phenyl-2-(phenylsulfanyl)ethanol
    —— 5-chloro-2-[(3-chlorobenzyl)thio]-6-{[(1R)-2-hydroxy-1-methylethyl]amino}-4-pyrimidinol 666752-54-1 C14H15Cl2N3O2S
    5-chloro-2-[(3-chlorobenzyl)thio]-6-{[(1R)-2-hydroxy-1-methylethyl]amino}-4-pyrimidinol
    —— N-(2-[(3-chlorobenzyl)thio]-4-hydroxy-6-{[(1R)-2-hydroxy-1-methylethyl]amino}-5-pyrimidinyl)methanesulfonamide 666752-56-3 C15H19ClN4O4S2
    N-(2-[(3-chlorobenzyl)thio]-4-hydroxy-6-{[(1R)-2-hydroxy-1-methylethyl]amino}-5-pyrimidinyl)methanesulfonamide
    —— 2-[(3-chlorobenzyl)thio]-6-{[(1R)-2-hydroxy-1-methylethyl]amino}-5-[(methylsulfon-yl)amino]-4-pyrimidinyl methanesulfonate 666752-57-4 C16H21ClN4O6S3
    2-[(3-chlorobenzyl)thio]-6-{[(1R)-2-hydroxy-1-methylethyl]amino}-5-[(methylsulfon-yl)amino]-4-pyrimidinyl methanesulfonate
    —— 1-[2-(morpholin-4-yl)ethyl]-3-[6-([1,2,4]triazolo[4,3-a]pyridin-3-ylsulphanyl)-1,3-benzothiazol-2-yl]urea 1205853-07-1 C20H21N7O2S2
    1-[2-(morpholin-4-yl)ethyl]-3-[6-([1,2,4]triazolo[4,3-a]pyridin-3-ylsulphanyl)-1,3-benzothiazol-2-yl]urea
    —— 4-([1,2,4]triazolo[4,3-a]pyridin-3-ylsulphanyl)aniline 1205852-96-5 C12H10N4S
    4-([1,2,4]triazolo[4,3-a]pyridin-3-ylsulphanyl)aniline
    —— N-[6-([1,2,4]triazolo[4,3-a]pyridin-3-ylsulphanyl)-1,3-benzothiazol-2-yl]cyclopropanecarboxamide 1205852-98-7 C17H13N5OS2
    N-[6-([1,2,4]triazolo[4,3-a]pyridin-3-ylsulphanyl)-1,3-benzothiazol-2-yl]cyclopropanecarboxamide
    —— di-2-quinolyl sulfide 52159-96-3 C18H12N2S
    di-2-quinolyl sulfide
    —— 3-(2-Fluorophenyl)sulfanylpropanoate 21243-09-4 C9H8FO2S-
    3-(2-Fluorophenyl)sulfanylpropanoate
    —— 6-([1,2,4]triazolo[4,3-a]pyridin-3-ylsulphanyl)-1,3-benzothiazol-2-amine 1205852-93-2 C13H9N5S2
    6-([1,2,4]triazolo[4,3-a]pyridin-3-ylsulphanyl)-1,3-benzothiazol-2-amine
    —— 3-(Phenylsulfanyl)-1-[tri(propan-2-yl)silyl]-1H-pyrrole 90971-73-6 C19H29NSSi
    3-(Phenylsulfanyl)-1-[tri(propan-2-yl)silyl]-1H-pyrrole
    —— N-methyl-1-(2-(4-methoxyphenylthio)phenyl)-2-propylamine 128959-05-7 C17H21NOS
    N-methyl-1-(2-(4-methoxyphenylthio)phenyl)-2-propylamine
    —— N,N-dimethyl-1-(2-(4-methoxyphenylthio)phenyl)-2-propylamine 128959-08-0 C18H23NOS
    N,N-dimethyl-1-(2-(4-methoxyphenylthio)phenyl)-2-propylamine
    —— 3-(6-cyano-2-methyl-1H-indol-3-ylsulfanyl)-benzoic acid methyl ester 1359982-73-2 C18H14N2O2S
    3-(6-cyano-2-methyl-1H-indol-3-ylsulfanyl)-benzoic acid methyl ester
    —— 5-(6-Chloro-2-methyl-1H-indol-3-ylsulfanyl)-2-fluoro-benzoic acid methyl ester 1359981-79-5 C17H13ClFNO2S
    5-(6-Chloro-2-methyl-1H-indol-3-ylsulfanyl)-2-fluoro-benzoic acid methyl ester
    —— 2-cyanoethyl 2-(methylamino)phenyl sulfide 37845-64-0 C10H12N2S
    2-cyanoethyl 2-(methylamino)phenyl sulfide
    —— 3-(1-benzyl-6-bromo-2-methyl-1H-indol-3-ylsulfanyl)-benzoic acid methyl ester 1359979-85-3 C24H20BrNO2S
    3-(1-benzyl-6-bromo-2-methyl-1H-indol-3-ylsulfanyl)-benzoic acid methyl ester
    —— 3-(2-Fluorphenylthio)-propionitril 51932-76-4 C9H8FNS
    3-(2-Fluorphenylthio)-propionitril
    —— 4-({2-[2-(Dimethylamino)propyl]phenyl}sulfanyl)phenol 128959-39-7 C17H21NOS
    4-({2-[2-(Dimethylamino)propyl]phenyl}sulfanyl)phenol
    —— 4-(2-chloro-5-fluorobenzyl)-6-methyl-3-(methylthio)-1,2,4-triazin-5(4H)-one 1312954-63-4 C12H11ClFN3OS
    4-(2-chloro-5-fluorobenzyl)-6-methyl-3-(methylthio)-1,2,4-triazin-5(4H)-one
    —— 1-(2-(4-methoxyphenylthio)phenyl)-2-propylamine 128958-99-6 C16H19NOS
    1-(2-(4-methoxyphenylthio)phenyl)-2-propylamine
    —— 2-[[5-(2-Fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetate 436087-03-5 C10H6FN2O3S-
    2-[[5-(2-Fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetate
    —— 3-(1-benzyl-6-bromo-2-methyl-1H-indol-3-ylsulfanyl)-benzoic acid 1359979-82-0 C23H18BrNO2S
    3-(1-benzyl-6-bromo-2-methyl-1H-indol-3-ylsulfanyl)-benzoic acid
    —— 3-(3-bromo-4-fluoro-phenylsulfanyl)-6-chloro-2-methyl-1H-indole 1359981-77-3 C15H10BrClFNS
    3-(3-bromo-4-fluoro-phenylsulfanyl)-6-chloro-2-methyl-1H-indole
    —— 3-(1-benzyl-2-methyl-6-phenyl-1H-indol-3-ylsulfanyl)-benzoic acid methyl ester 1359979-87-5 C30H25NO2S
    3-(1-benzyl-2-methyl-6-phenyl-1H-indol-3-ylsulfanyl)-benzoic acid methyl ester
    —— N-{3-[6-chloro-1-(1-ethyl-1H-pyrazol-4-yl)-7-fluoro-2-methyl-1H-indol-3-ylsulfanyl]-benzoyl}-methanesulfonamide 1359982-68-5 C22H20ClFN4O3S2
    N-{3-[6-chloro-1-(1-ethyl-1H-pyrazol-4-yl)-7-fluoro-2-methyl-1H-indol-3-ylsulfanyl]-benzoyl}-methanesulfonamide
    —— 2-[(2-Amino-1,3-thiazol-5-yl)sulfanyl]-3-benzyl-6-methylquinazolin-4-one 1443205-02-4 C19H16N4OS2
    2-[(2-Amino-1,3-thiazol-5-yl)sulfanyl]-3-benzyl-6-methylquinazolin-4-one
    —— Ethyl 2-amino-5-(3-benzyl-6-methyl-4-oxoquinazolin-2-yl)sulfanyl-1,3-thiazole-4-carboxylate 1443205-14-8 C22H20N4O3S2
    Ethyl 2-amino-5-(3-benzyl-6-methyl-4-oxoquinazolin-2-yl)sulfanyl-1,3-thiazole-4-carboxylate
    —— Ethyl 2-amino-5-(6-methyl-4-oxo-3-phenylquinazolin-2-yl)sulfanyl-1,3-thiazole-4-carboxylate 1443205-13-7 C21H18N4O3S2
    Ethyl 2-amino-5-(6-methyl-4-oxo-3-phenylquinazolin-2-yl)sulfanyl-1,3-thiazole-4-carboxylate
    —— 2-[(2-Amino-1,3-thiazol-5-yl)sulfanyl]-6-methyl-3-phenylquinazolin-4-one 1443205-01-3 C18H14N4OS2
    2-[(2-Amino-1,3-thiazol-5-yl)sulfanyl]-6-methyl-3-phenylquinazolin-4-one
    —— 2,8-Dimethylbenzo[c][1,5]benzodithiocine-6,12-dione 77149-15-6 C16H12O2S2
    2,8-Dimethylbenzo[c][1,5]benzodithiocine-6,12-dione
    —— 2,5-dimethyl-3,4-dithiocyanopyrrole 18519-26-1 C8H7N3S2
    2,5-dimethyl-3,4-dithiocyanopyrrole
    —— bis(2,5-dimethyl-N-tert-butoxycarbonylpyrrolo<3,4-d>)tetrathiafulvalene 117559-74-7 C24H30N2O4S4
    bis(2,5-dimethyl-N-tert-butoxycarbonylpyrrolo<3,4-d>)tetrathiafulvalene
    —— 3-(N-benzylcarbamoylmethyl)-6-methyl-2-methylthiopyrimidin-4(3H)-one 109389-00-6 C15H17N3O2S
    3-(N-benzylcarbamoylmethyl)-6-methyl-2-methylthiopyrimidin-4(3H)-one
    —— (E)-1,4-Bis(2-aminoethyldithio)-2-butene 111238-64-3 C8H18N2S4
    (E)-1,4-Bis(2-aminoethyldithio)-2-butene
    —— 2-{4-[3-(t-butyldimethylsilanyloxy)propyl]-3-cyano-6-oxo-1,6-dihydropyridin-2-ylsulfanyl}-acetamide 635732-33-1 C17H27N3O3SSi
    2-{4-[3-(t-butyldimethylsilanyloxy)propyl]-3-cyano-6-oxo-1,6-dihydropyridin-2-ylsulfanyl}-acetamide
    —— 2-(3,4,4-trifluoro-3-butenylthio)oxazole 359631-01-9 C7H6F3NOS
    2-(3,4,4-trifluoro-3-butenylthio)oxazole
    —— tert-butyl ({4-(2-fluorophenyl)-5-[(3-formylphenyl)thio]-1,3-thiazol-2-yl}methyl)methylcarbamate 1138035-51-4 C23H23FN2O3S2
    tert-butyl ({4-(2-fluorophenyl)-5-[(3-formylphenyl)thio]-1,3-thiazol-2-yl}methyl)methylcarbamate
    —— cis-6-(Ethoxycarbonyl)-5-(trimethylsilyl)bicyclo<4.4.0>dec-1-en-3-one 3-(ethylene dithioacetal) 121143-18-8 C18H30O2S2Si
    cis-6-(Ethoxycarbonyl)-5-(trimethylsilyl)bicyclo<4.4.0>dec-1-en-3-one 3-(ethylene dithioacetal)
    —— rac-(4'R,4a'S)-4'-(tert-butyl)-4a'-methyl-4',4a',5',6',7',8'-hexahydro-3'H-spiro[cyclopentane-1,2'-naphthalene] 122723-22-2 C15H26S2Si
    rac-(4'R,4a'S)-4'-(tert-butyl)-4a'-methyl-4',4a',5',6',7',8'-hexahydro-3'H-spiro[cyclopentane-1,2'-naphthalene]