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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 5-methylthio-imidazo[2,1-b][1,3,5]benzothiadiazepine hydrochloride 87011-04-9 C11H9N3S2*ClH
    5-methylthio-imidazo[2,1-b][1,3,5]benzothiadiazepine hydrochloride
    —— 2-(4,4-difluorobut-3-enylthio)-5-methylthiazole 172933-14-1 C8H9F2NS2
    2-(4,4-difluorobut-3-enylthio)-5-methylthiazole
    —— 6-[(4-fluorophenyl)sulfanyl)-N-(5-methyl-1,3-thiazol-2-yl)-3-(4H-1,2,4-triazol-3-ylsulfanyl)pyrazine-2-carboxamide 1093382-47-8 C17H12FN7OS3
    6-[(4-fluorophenyl)sulfanyl)-N-(5-methyl-1,3-thiazol-2-yl)-3-(4H-1,2,4-triazol-3-ylsulfanyl)pyrazine-2-carboxamide
    —— 3-[(4-fluorophenyl)sulfanyl]-N-(5-methyl-1,3-thiazol-2-yl)-6-[(6-oxopyridazin-1(6H)-yl)methyl]pyrazine-2-carboxamide 1093383-06-2 C20H15FN6O2S2
    3-[(4-fluorophenyl)sulfanyl]-N-(5-methyl-1,3-thiazol-2-yl)-6-[(6-oxopyridazin-1(6H)-yl)methyl]pyrazine-2-carboxamide
    —— 2-ethanesulfinyl-1,1-dimethoxy-ethane 71185-73-4 C6H14O3S
    2-ethanesulfinyl-1,1-dimethoxy-ethane
    —— 2-(2,2-dimethoxy-ethanesulfinyl)-propane 71185-75-6 C7H16O3S
    2-(2,2-dimethoxy-ethanesulfinyl)-propane
    —— 5-methyl-6-(1-naphthylmethyl)-2-[(thiophen-2-yl)thio]pyrimidin-4(3H)-one 1075181-61-1 C20H16N2OS2
    5-methyl-6-(1-naphthylmethyl)-2-[(thiophen-2-yl)thio]pyrimidin-4(3H)-one
    —— 2-chloro-4-hexamethyleneimino-8-methylthio-pyrimido[5,4-d]pyrimidine 101850-56-0 C13H16ClN5S
    2-chloro-4-hexamethyleneimino-8-methylthio-pyrimido[5,4-d]pyrimidine
    —— Nonanoic acid (2-nonanoylamino-ethyl)-(2-phenylsulfanyl-ethyl)-amide 61797-83-9 C28H48N2O2S
    Nonanoic acid (2-nonanoylamino-ethyl)-(2-phenylsulfanyl-ethyl)-amide
    —— (4S,5S)-5-formylamino-2,2-dimethyl-4-[4-(methylthio)phenyl]-1,3-dioxane 845728-43-0 C14H19NO3S
    (4S,5S)-5-formylamino-2,2-dimethyl-4-[4-(methylthio)phenyl]-1,3-dioxane
    —— 2-(3-Phenylsulfanyl-propyl)-cyclohexanone 77516-33-7 C15H20OS
    2-(3-Phenylsulfanyl-propyl)-cyclohexanone
    —— α-<5-(2-Furyl)-1,2,4-triazol-3-ylthio>acethydrazid 30502-39-7 C8H9N5O2S
    α-<5-(2-Furyl)-1,2,4-triazol-3-ylthio>acethydrazid
    —— 6-(3-Phenylsulfanyl-propyl)-1,4-dioxa-spiro[4.5]decane 200860-45-3 C17H24O2S
    6-(3-Phenylsulfanyl-propyl)-1,4-dioxa-spiro[4.5]decane
    —— methyl 1-(3-phenylsulfanylpropyl)-2-oxocyclopentanecarboxylate 1010832-60-6 C16H20O3S
    methyl 1-(3-phenylsulfanylpropyl)-2-oxocyclopentanecarboxylate
    —— (5-furan-2-yl-1<i>H</i>-[1,2,4]triazol-3-ylsulfanyl)-acetic acid ethyl ester 30452-53-0 C10H11N3O3S
    (5-furan-2-yl-1<i>H</i>-[1,2,4]triazol-3-ylsulfanyl)-acetic acid ethyl ester
    —— Allylthiocarbaminsaeure-pentylester 90477-98-8 C9H17NOS
    Allylthiocarbaminsaeure-pentylester
    —— 6-cyclopentyl-N-[2-[2-(6-cyclopentylhexylamino)ethyldisulfanyl]ethyl]hexan-1-amine;hydron;dichloride —— C26H54Cl2N2S2
    6-cyclopentyl-N-[2-[2-(6-cyclopentylhexylamino)ethyldisulfanyl]ethyl]hexan-1-amine;hydron;dichloride
    —— ethyl 4-[[4-[2-[(trifluoroacetyl)amino]ethyl]phenyl]thio]-2-pyridinecarboxylate 699013-02-0 C18H17F3N2O3S
    ethyl 4-[[4-[2-[(trifluoroacetyl)amino]ethyl]phenyl]thio]-2-pyridinecarboxylate
    —— 5-cyclooctyloxy-N-[2-[2-(5-cyclooctyloxypentylamino)ethyldisulfanyl]ethyl]pentan-1-amine;hydron;dichloride —— C30H62Cl2N2O2S2
    5-cyclooctyloxy-N-[2-[2-(5-cyclooctyloxypentylamino)ethyldisulfanyl]ethyl]pentan-1-amine;hydron;dichloride
    —— methyl 12-hydroxy-13,13-propylenedithio-15,16-dinorlabda-8(17)-en-19-oate 501004-59-7 C22H36O3S2
    methyl 12-hydroxy-13,13-propylenedithio-15,16-dinorlabda-8(17)-en-19-oate
    —— 4-cyclohexyl-N-[2-[2-(4-cyclohexylpentylamino)ethyldisulfanyl]ethyl]pentan-1-amine;hydron;dichloride —— C26H54Cl2N2S2
    4-cyclohexyl-N-[2-[2-(4-cyclohexylpentylamino)ethyldisulfanyl]ethyl]pentan-1-amine;hydron;dichloride
    —— 4-(p-chlorothiophenoxy)-1-methyl-1,4,5,6-tetrahydropyridine-3-carbonitrile 94008-36-3 C13H13ClN2S
    4-(p-chlorothiophenoxy)-1-methyl-1,4,5,6-tetrahydropyridine-3-carbonitrile
    —— Allylthiocarbaminsaeure-hexylester 91016-52-3 C10H19NOS
    Allylthiocarbaminsaeure-hexylester
    —— 6-benzenesulfanyl-2-(3-phenyl-1-propyl)-3,4-dihydro-2H-pyran 553670-78-3 C20H22OS
    6-benzenesulfanyl-2-(3-phenyl-1-propyl)-3,4-dihydro-2H-pyran
    —— 3,9-dioxa-6-thiacyclodecan-1-ol-6,6-dioxide 1067244-39-6 C7H14O5S
    3,9-dioxa-6-thiacyclodecan-1-ol-6,6-dioxide
    —— 2,6-Dimethyl-2,3-dihydro-thiazolo[3,2-a]thieno[3,4-d]pyrimidin-5-one 120079-36-9 C10H10N2OS2
    2,6-Dimethyl-2,3-dihydro-thiazolo[3,2-a]thieno[3,4-d]pyrimidin-5-one
    —— 3-(benzyloxy)-N-(4-methylthiazol-2-yl)-5-(methylthio)pyridin-2-amine hydrochloride 936245-10-2 C17H17N3OS2*ClH
    3-(benzyloxy)-N-(4-methylthiazol-2-yl)-5-(methylthio)pyridin-2-amine hydrochloride
    —— 1-methyl-2-azathiabenzene 1-oxide 88628-88-0 C5H7NOS
    1-methyl-2-azathiabenzene 1-oxide
    —— 4-fluoro-α-[[(2-fluorophenyl)thio]methyl]-benzeneacetic acid 131210-55-4 C15H12F2O2S
    4-fluoro-α-[[(2-fluorophenyl)thio]methyl]-benzeneacetic acid
    —— 2-(2-carbamimidoylsulfanylethoxy)ethyl carbamimidothioate;hydron;dichloride —— C6H16Cl2N4OS2
    2-(2-carbamimidoylsulfanylethoxy)ethyl carbamimidothioate;hydron;dichloride
    —— 2,2,8-Trimethyl-2,3-dihydro-thiazolo[3,2-a]thieno[3,4-d]pyrimidin-5-one 126636-79-1 C11H12N2OS2
    2,2,8-Trimethyl-2,3-dihydro-thiazolo[3,2-a]thieno[3,4-d]pyrimidin-5-one
    —— 4-carboxy-1-methyl-2-azathiabenzene 1-oxide 88628-87-9 C6H7NO3S
    4-carboxy-1-methyl-2-azathiabenzene 1-oxide
    —— 3-(4-methylsulfanyl-1H-pyrazol-3-yl)-1,2,5,6-tetrahydro-1-methylpyridine 1073551-34-4 C10H15N3S
    3-(4-methylsulfanyl-1H-pyrazol-3-yl)-1,2,5,6-tetrahydro-1-methylpyridine
    —— 2,6,8-Trimethyl-2,3-dihydro-thiazolo[3,2-a]thieno[3,4-d]pyrimidin-5-one 120079-37-0 C11H12N2OS2
    2,6,8-Trimethyl-2,3-dihydro-thiazolo[3,2-a]thieno[3,4-d]pyrimidin-5-one
    —— (4-Cyclohexyl-pentyl)-{2-[2-(4-cyclohexyl-pentylamino)-ethyldisulfanyl]-ethyl}-amine 90378-83-9 C26H52N2S2
    (4-Cyclohexyl-pentyl)-{2-[2-(4-cyclohexyl-pentylamino)-ethyldisulfanyl]-ethyl}-amine
    —— (Methylcarbonylthio)(methylsulfonyl)methane 89986-83-4 C4H8O3S2
    (Methylcarbonylthio)(methylsulfonyl)methane
    —— 5-methylthio-2-furonitrile 106240-49-7 C6H5NOS
    5-methylthio-2-furonitrile
    —— 8-Ethyl-2-methyl-2,3-dihydro-thiazolo[3,2-a]thieno[3,4-d]pyrimidin-5-one 120079-38-1 C11H12N2OS2
    8-Ethyl-2-methyl-2,3-dihydro-thiazolo[3,2-a]thieno[3,4-d]pyrimidin-5-one
    —— 2,8-Dimethyl-2,3-dihydro-thiazolo[3,2-a]thieno[3,4-d]pyrimidin-5-one 120079-35-8 C10H10N2OS2
    2,8-Dimethyl-2,3-dihydro-thiazolo[3,2-a]thieno[3,4-d]pyrimidin-5-one
    —— <i>N</i>-allyl-<i>N</i>'-isobutyl-thiourea 23328-50-9 C8H16N2S
    <i>N</i>-allyl-<i>N</i>'-isobutyl-thiourea
    —— 3,3'-bis(phenylthio)<2>staffane 115092-69-8 C22H22S2
    3,3'-bis(phenylthio)<2>staffane
    —— 5-(methylmercapto)-2-pyrimidinone 75670-14-3 C5H6N2OS
    5-(methylmercapto)-2-pyrimidinone
    —— (3,3-Dimethyl-2-phenylsulfanyl-but-1-enylidene)-p-tolyl-amine 160976-82-9 C19H21NS
    (3,3-Dimethyl-2-phenylsulfanyl-but-1-enylidene)-p-tolyl-amine
    —— (2-fluoro-4-(methylsulfanyl)benzyl)carbamic acid tert-butyl ester 1570084-49-9 C13H18FNO2S
    (2-fluoro-4-(methylsulfanyl)benzyl)carbamic acid tert-butyl ester
    —— <i>N</i>-allyl-<i>N</i>'-octadecyl-thiourea 7460-25-5 C22H44N2S
    <i>N</i>-allyl-<i>N</i>'-octadecyl-thiourea
    —— 5-(6-chloro-pyridin-3-ylmethyl)-2-methylsulfanyl-1H-pyrimidin-4-one 1380430-99-8 C11H10ClN3OS
    5-(6-chloro-pyridin-3-ylmethyl)-2-methylsulfanyl-1H-pyrimidin-4-one
    —— 1,10-Di-(ethylsulphinyl)-decan 28242-23-1 C14H30O2S2
    1,10-Di-(ethylsulphinyl)-decan
    —— [4-chloro-6-(4-chloro-benzylamino)-5-methyl-pyrimidin-2-ylsulfanyl]-acetic acid ethyl ester 50892-46-1 C16H17Cl2N3O2S
    [4-chloro-6-(4-chloro-benzylamino)-5-methyl-pyrimidin-2-ylsulfanyl]-acetic acid ethyl ester
    —— [4-chloro-6-(4-chloro-benzylamino)-pyrimidin-2-ylsulfanyl]-acetic acid ethyl ester 50892-25-6 C15H15Cl2N3O2S
    [4-chloro-6-(4-chloro-benzylamino)-pyrimidin-2-ylsulfanyl]-acetic acid ethyl ester
    —— [4-(4-chloro-benzylamino)-pyrimidin-2-ylsulfanyl]-acetic acid ethyl ester 50892-43-8 C15H16ClN3O2S
    [4-(4-chloro-benzylamino)-pyrimidin-2-ylsulfanyl]-acetic acid ethyl ester