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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2,6-Dimethyl-4-(methylthio)imidazo<4,5-d>pyridazine 76756-68-8 C8H10N4S
    2,6-Dimethyl-4-(methylthio)imidazo<4,5-d>pyridazine
    —— 1<i>c</i>-ethylsulfanyl-3,3-dimethyl-but-1-ene 64707-11-5 C8H16S
    1<i>c</i>-ethylsulfanyl-3,3-dimethyl-but-1-ene
    —— (Z)-β-Ethylmercapto-methacrylnitril 28976-84-3 C6H9NS
    (Z)-β-Ethylmercapto-methacrylnitril
    —— 3,3'-Dicyano-4,4'-diamino-diphenylsulfid 61382-02-3 C14H10N4S
    3,3'-Dicyano-4,4'-diamino-diphenylsulfid
    —— 2-(4'-tert-butylthiophenyl)thiophene 756899-88-4 C14H16S2
    2-(4'-tert-butylthiophenyl)thiophene
    —— 1-(7-Methyl-1,5-dithia-spiro[5.5]undec-8-en-8-yl)-ethanone 76160-01-5 C12H18OS2
    1-(7-Methyl-1,5-dithia-spiro[5.5]undec-8-en-8-yl)-ethanone
    —— Decanedithioic acid ethyl ester 81066-69-5 C12H24S2
    Decanedithioic acid ethyl ester
    —— N-Benzyl-2,2,2-trifluoro-N-((2S,3S)-2-fluoromethyl-2-hydroxy-3-p-tolylsulfanyl-butyl)-acetamide 214957-00-3 C21H23F4NO2S
    N-Benzyl-2,2,2-trifluoro-N-((2S,3S)-2-fluoromethyl-2-hydroxy-3-p-tolylsulfanyl-butyl)-acetamide
    —— 4,5-diisopropylthio-1,2-dithiole-3-thione 233685-26-2 C9H14S5
    4,5-diisopropylthio-1,2-dithiole-3-thione
    —— 3-(2-aminophenylthio)-1-(2-tienyl)prop-1-yne 260803-78-9 C13H11NS2
    3-(2-aminophenylthio)-1-(2-tienyl)prop-1-yne
    —— methyl 4-[4-(2-[2,2,2-trifluoroethyl]guanidino)pyrimid-2-ylthio]butyrimidate 84406-42-8 C12H17F3N6OS
    methyl 4-[4-(2-[2,2,2-trifluoroethyl]guanidino)pyrimid-2-ylthio]butyrimidate
    —— S-[2-{N-3'-(2-thienyl)prop-2'-ynyl}aminophenyl]-N,N-dimethylthiocarbamate 352556-31-1 C16H16N2OS2
    S-[2-{N-3'-(2-thienyl)prop-2'-ynyl}aminophenyl]-N,N-dimethylthiocarbamate
    —— 6-methylidenespiro[1,2,3a,4,5,6a-hexahydropentalene-3,2'-1,3-dithiolane] 142981-43-9 C11H16S2
    6-methylidenespiro[1,2,3a,4,5,6a-hexahydropentalene-3,2'-1,3-dithiolane]
    —— 2-[3-(4-[2-(2,2,2-trifluoroethyl)guanidino]pyrimid-2-ylthio)propyl]-1-imidazoline 84406-86-0 C13H18F3N7S
    2-[3-(4-[2-(2,2,2-trifluoroethyl)guanidino]pyrimid-2-ylthio)propyl]-1-imidazoline
    —— (E)-1-phenyl-2-(phenylthio)but-1-ene 66164-65-6 C16H16S
    (E)-1-phenyl-2-(phenylthio)but-1-ene
    —— 1-(4-chlorophenylamino)-4-(pyridin-4-ylthio)phthalazine 852989-59-4 C19H13ClN4S
    1-(4-chlorophenylamino)-4-(pyridin-4-ylthio)phthalazine
    —— (E)-1-bromo-1-phenyl-2-(phenylthio)but-1-ene 152959-18-7 C16H15BrS
    (E)-1-bromo-1-phenyl-2-(phenylthio)but-1-ene
    —— (Z)-1-phenyl-2-(phenylthio)but-1-ene 66164-53-2 C16H16S
    (Z)-1-phenyl-2-(phenylthio)but-1-ene
    —— 5,7-diamino-3-phenyl-2-(3,4-dimethoxyphenylthio)quinoxaline 958797-40-5 C22H20N4O2S
    5,7-diamino-3-phenyl-2-(3,4-dimethoxyphenylthio)quinoxaline
    —— 1-Bromo-5-ethylsulfanyl-pentane 115412-79-8 C7H15BrS
    1-Bromo-5-ethylsulfanyl-pentane
    —— 2-Methyldithiobenzoesaeurephenylester 112291-35-7 C14H12S2
    2-Methyldithiobenzoesaeurephenylester
    —— 2-(1-Methyl-3-phenylsulfanyl-prop-2-ynyl)-3-oxo-hexanoic acid methyl ester 199919-22-7 C17H20O3S
    2-(1-Methyl-3-phenylsulfanyl-prop-2-ynyl)-3-oxo-hexanoic acid methyl ester
    —— (Z)-4-(dimethyl(phenyl)silyl)-4-(phenylthio)but-3-en-2-ol 1622445-75-3 C18H22OSSi
    (Z)-4-(dimethyl(phenyl)silyl)-4-(phenylthio)but-3-en-2-ol
    —— Butadiyl-(1,4)-bis-(aethyl-sulfon) 92099-02-0 C8H18O4S2
    Butadiyl-(1,4)-bis-(aethyl-sulfon)
    —— N-(4-((4-((((Amino(imino)methyl)amino)(imino)methyl)amino)phenyl)thio)phenyl)dicarbonimidoic diamide/imido 5440-96-0 C16H20N10S
    N-(4-((4-((((Amino(imino)methyl)amino)(imino)methyl)amino)phenyl)thio)phenyl)dicarbonimidoic diamide/imido
    —— (R)-2-tert-butoxycarbonylamino-N-ethyl-thiopropionimidic acid 944705-55-9 C10H20N2O2S
    (R)-2-tert-butoxycarbonylamino-N-ethyl-thiopropionimidic acid
    —— 4-[4-Hydroxy-3-(2,4,4-trimethylpentan-2-yl)phenyl]sulfanyl-2-(2,4,4-trimethylpentan-2-yl)phenol 951403-93-3 C28H42O2S
    4-[4-Hydroxy-3-(2,4,4-trimethylpentan-2-yl)phenyl]sulfanyl-2-(2,4,4-trimethylpentan-2-yl)phenol
    —— 3-morpholino-1-(4-phenylsulfanyl-phenyl)-propan-1-ol 6317-79-9 C19H23NO2S
    3-morpholino-1-(4-phenylsulfanyl-phenyl)-propan-1-ol
    —— 6,6-dimethyl-1-(4-methylsulfanyl-phenyl)-1,6-dihydro-[1,3,5]triazine-2,4-diamine 90-07-3 C12H17N5S
    6,6-dimethyl-1-(4-methylsulfanyl-phenyl)-1,6-dihydro-[1,3,5]triazine-2,4-diamine
    —— S-sec.-Butyl-thiuronium 44648-64-8 C5H12N2S
    S-sec.-Butyl-thiuronium
    —— <(oxo-2 cyclopentyl)-1 ethyl>-2 pentene-4 dithioate de methyle 119755-99-6 C13H20OS2
    <(oxo-2 cyclopentyl)-1 ethyl>-2 pentene-4 dithioate de methyle
    —— (4S,5S)-3-(tert-butoxycarbonyl)-4-(cyclohexylmethyl)-2,2-dimethyl-5-<2-(2-pyridylthio)ethyl>oxazolidine 143122-20-7 C24H38N2O3S
    (4S,5S)-3-(tert-butoxycarbonyl)-4-(cyclohexylmethyl)-2,2-dimethyl-5-<2-(2-pyridylthio)ethyl>oxazolidine
    —— (4S,5S)-3-(tert-butoxycarbonyl)-4-(cyclohexylmethyl)-2,2-dimethyl-5-<2-<(1-methyl-1H-tetrazol-5-yl)thio>ethyl>oxazolidine 143122-26-3 C21H37N5O3S
    (4S,5S)-3-(tert-butoxycarbonyl)-4-(cyclohexylmethyl)-2,2-dimethyl-5-<2-<(1-methyl-1H-tetrazol-5-yl)thio>ethyl>oxazolidine
    —— (4S,5S)-3-(tert-butoxycarbonyl)-4-(cyclohexylmethyl)-2,2-dimethyl-5-<3-(2-pyridylthio)propyl>oxazolidine 143122-16-1 C25H40N2O3S
    (4S,5S)-3-(tert-butoxycarbonyl)-4-(cyclohexylmethyl)-2,2-dimethyl-5-<3-(2-pyridylthio)propyl>oxazolidine
    —— 2-Amino-5-phenyl-4,6-di-(benzylmercapto)-pyrimidin 6299-80-5 C24H21N3S2
    2-Amino-5-phenyl-4,6-di-(benzylmercapto)-pyrimidin
    —— l-5-(hydroxymethyl)-3-[4-(methylthio)phenyl]-2-oxazolidinone 64589-90-8 C11H13NO3S
    l-5-(hydroxymethyl)-3-[4-(methylthio)phenyl]-2-oxazolidinone
    —— 2-Amino-5-phenyl-4,6-di-(o-chlorbenzylmercapto)-pyrimidin 6299-79-2 C24H19Cl2N3S2
    2-Amino-5-phenyl-4,6-di-(o-chlorbenzylmercapto)-pyrimidin
    —— (4S,5S)-3-(tert-butoxycarbonyl)-4-(cyclohexylmethyl)-2,2-dimethyl-5-<2-(4-pyridylthio)ethyl>oxazolidine 143122-22-9 C24H38N2O3S
    (4S,5S)-3-(tert-butoxycarbonyl)-4-(cyclohexylmethyl)-2,2-dimethyl-5-<2-(4-pyridylthio)ethyl>oxazolidine
    —— Benzyl-dimethyl-(phenylsulfanylmethyl)azanium 7154-02-1 C16H20NS+
    Benzyl-dimethyl-(phenylsulfanylmethyl)azanium
    —— 4.5-Bis-(3-fluor-benzylmercapto)-2-phenyl-3-oxo-2.3-dihydro-pyridazin 5376-24-9 C24H18F2N2OS2
    4.5-Bis-(3-fluor-benzylmercapto)-2-phenyl-3-oxo-2.3-dihydro-pyridazin
    —— 1,4-bis(vinylthio)benzene 86199-22-6 C10H10S2
    1,4-bis(vinylthio)benzene
    —— 4.5-Bis-(2-chlor-benzylmercapto)-2-phenyl-3-oxo-2.3-dihydro-pyridazin 5273-34-7 C24H18Cl2N2OS2
    4.5-Bis-(2-chlor-benzylmercapto)-2-phenyl-3-oxo-2.3-dihydro-pyridazin
    —— Isopropan-α-thiosulfonsaeure-S-aethylester 2043-80-3 C5H12O2S2
    Isopropan-α-thiosulfonsaeure-S-aethylester
    —— 4.5-Bis-(2-fluor-benzylmercapto)-2-phenyl-3-oxo-2.3-dihydro-pyridazin 5273-36-9 C24H18F2N2OS2
    4.5-Bis-(2-fluor-benzylmercapto)-2-phenyl-3-oxo-2.3-dihydro-pyridazin
    —— t-butyl 3-methyl-4-phenylthiohept-2(E)-enoate 208582-32-5 C18H26O2S
    t-butyl 3-methyl-4-phenylthiohept-2(E)-enoate
    —— methyl (2RS,3RS)-2,3-dimethyl-4,4-bis(phenylthio)heptanoate 128098-99-7 C22H28O2S2
    methyl (2RS,3RS)-2,3-dimethyl-4,4-bis(phenylthio)heptanoate
    —— 4.5-Bis-(4-fluor-benzylmercapto)-2-phenyl-3-oxo-2.3-dihydro-pyridazin 5273-37-0 C24H18F2N2OS2
    4.5-Bis-(4-fluor-benzylmercapto)-2-phenyl-3-oxo-2.3-dihydro-pyridazin
    —— Dicyclopropylcarbinyl-phenylsulfid 59277-51-9 C13H16S
    Dicyclopropylcarbinyl-phenylsulfid
    —— S-(2-Aminooxy-propyl)-isothioharnstoff 90642-24-3 C4H11N3OS
    S-(2-Aminooxy-propyl)-isothioharnstoff
    —— 4.5-Bis-(4-brom-benzylmercapto)-2-phenyl-3-oxo-2.3-dihydro-pyridazin 5273-33-6 C24H18Br2N2OS2
    4.5-Bis-(4-brom-benzylmercapto)-2-phenyl-3-oxo-2.3-dihydro-pyridazin