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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— phenyl thiophene-2-carbimidothioate hydrobromide 659743-43-8 BrH*C11H9NS2
    phenyl thiophene-2-carbimidothioate hydrobromide
    —— 9(R)-6,6-ethylenedithio-9-methyl-9-nonanolide 138332-44-2 C12H20O2S2
    9(R)-6,6-ethylenedithio-9-methyl-9-nonanolide
    —— 1-Acetoxy-1-(triphenylsilyloxy)-2-phenylthioethane 123541-68-4 C28H26O3SSi
    1-Acetoxy-1-(triphenylsilyloxy)-2-phenylthioethane
    —— 2-Phenylsulfanyl-1-tri(propan-2-yl)silylethanol 162247-37-2 C17H30OSSi
    2-Phenylsulfanyl-1-tri(propan-2-yl)silylethanol
    —— E-1-(tri-n-butylstannyl)-1-(phenylthio)-2-phenylethene 198219-71-5 C26H38SSn
    E-1-(tri-n-butylstannyl)-1-(phenylthio)-2-phenylethene
    —— (5S,2'R)-3-[2'-(t-butyldimethylsilanyloxy)-hex-6-enyl]-5-methyl-3-phenylsulfanyldihydrofuran-2-one 909270-36-6 C23H36O3SSi
    (5S,2'R)-3-[2'-(t-butyldimethylsilanyloxy)-hex-6-enyl]-5-methyl-3-phenylsulfanyldihydrofuran-2-one
    —— N-(2-Phenylmercapto-1,1-dimethyl-ethyl)-benzamid 1155-29-9 C17H19NOS
    N-(2-Phenylmercapto-1,1-dimethyl-ethyl)-benzamid
    —— tert-butyl 2-[4-(methylsulfanyl)benzyl]acrylate 942298-95-5 C15H20O2S
    tert-butyl 2-[4-(methylsulfanyl)benzyl]acrylate
    —— 2-tributylstannyl-1,3-benzodithiole 155127-03-0 C19H32S2Sn
    2-tributylstannyl-1,3-benzodithiole
    —— 2-(methoxycarbonylamino) 6-(p-hydroxyphenylthio) imidazo [1,2-a] pyridine 76911-42-7 C15H13N3O3S
    2-(methoxycarbonylamino) 6-(p-hydroxyphenylthio) imidazo [1,2-a] pyridine
    —— 2-[(4-trifluoromethyl-2-nitrophenyl)thio]aniline 322-71-4 C13H9F3N2O2S
    2-[(4-trifluoromethyl-2-nitrophenyl)thio]aniline
    —— 2,2-dimethyl-5-(4-(methylthio)benzyl)-1,3-dioxane-4,6-dione 154317-91-6 C14H16O4S
    2,2-dimethyl-5-(4-(methylthio)benzyl)-1,3-dioxane-4,6-dione
    —— 1-Dimethylaminomethyl-4-hydroxy-7-phenylsulfanyl-isoquinoline-3-carboxylic acid butyl ester 808120-25-4 C23H26N2O3S
    1-Dimethylaminomethyl-4-hydroxy-7-phenylsulfanyl-isoquinoline-3-carboxylic acid butyl ester
    —— 4-[4-(4-bromo-2,6-dimethylphenylsulfanyl)pyrimidin-2-ylamino]benzonitrile 374067-83-1 C19H15BrN4S
    4-[4-(4-bromo-2,6-dimethylphenylsulfanyl)pyrimidin-2-ylamino]benzonitrile
    —— 3-(2-trifluoromethylphenylsulfanyl)-1-(5-phenylpentyl)quinolin-1-ium iodide 1299398-83-6 C27H25F3NS*I
    3-(2-trifluoromethylphenylsulfanyl)-1-(5-phenylpentyl)quinolin-1-ium iodide
    —— (2S)-2-[(2S)-2-(methoxymethoxy)-4-phenylsulfanylbutyl]oxirane 197520-82-4 C14H20O3S
    (2S)-2-[(2S)-2-(methoxymethoxy)-4-phenylsulfanylbutyl]oxirane
    —— 2-phenylthio-1-phenylethylamine 140372-83-4 C14H15NS
    2-phenylthio-1-phenylethylamine
    —— Cyclobutyl-heptyl-sulfid 10394-45-3 C11H22S
    Cyclobutyl-heptyl-sulfid
    —— (E)-3-methyl-1-(methylsulfonyl)-1-butene 286376-75-8 C6H12O2S
    (E)-3-methyl-1-(methylsulfonyl)-1-butene
    —— n-3-thiadecanal 1174747-14-8 C9H18OS
    n-3-thiadecanal
    —— 4-Pyridinecarbothioamide, 2-(heptylthio)- 180791-11-1 C13H20N2S2
    4-Pyridinecarbothioamide, 2-(heptylthio)-
    —— (E)-5-(4-cyanobut-3-enyl)-2,3-dihydro-1,4-benzoxathiin 261633-80-1 C13H13NOS
    (E)-5-(4-cyanobut-3-enyl)-2,3-dihydro-1,4-benzoxathiin
    —— methylheptyl disulfide 70869-29-3 C8H18S2
    methylheptyl disulfide
    —— (5S)-3-[(2R)-2-[tert-butyl(dimethyl)silyl]oxyundec-10-enyl]-5-methyl-3-phenylsulfanyloxolan-2-one 862603-29-0 C28H46O3SSi
    (5S)-3-[(2R)-2-[tert-butyl(dimethyl)silyl]oxyundec-10-enyl]-5-methyl-3-phenylsulfanyloxolan-2-one
    —— Phenyl 1,2,2-trifluoroethyl sulfide 136370-27-9 C8H7F3S
    Phenyl 1,2,2-trifluoroethyl sulfide
    —— 4,6-dimethyl-2-(prop-2-en-1-ylsulfanyl)pyrimidine 55749-32-1 C9H12N2S
    4,6-dimethyl-2-(prop-2-en-1-ylsulfanyl)pyrimidine
    —— 5-acetyl-5,6,11,12-tetrahydro-8-bromo-2-methylthiodibenz[b,f]azocine 1446113-94-5 C18H18BrNOS
    5-acetyl-5,6,11,12-tetrahydro-8-bromo-2-methylthiodibenz[b,f]azocine
    —— 1-(3,5-dimethyl-1H-pyrazol-1-yl)-2-phenyl-1-(phenylthio)ethane 122606-08-0 C19H20N2S
    1-(3,5-dimethyl-1H-pyrazol-1-yl)-2-phenyl-1-(phenylthio)ethane
    —— 4-{[(1-methyl-1H-imidazol-5-yl)methyl]sulfanyl}aniline 497853-77-7 C11H13N3S
    4-{[(1-methyl-1H-imidazol-5-yl)methyl]sulfanyl}aniline
    —— 4-chloro-N-(3-methylsulfanylphenyl)pyrimidin-2-amine 945396-91-8 C11H10ClN3S
    4-chloro-N-(3-methylsulfanylphenyl)pyrimidin-2-amine
    —— 8-Methylthio-1-azaphenothiazin 117000-77-8 C12H10N2S2
    8-Methylthio-1-azaphenothiazin
    —— (3-methylsulfanyl-phenyl)-pyridin-2-yl-amine 106167-23-1 C12H12N2S
    (3-methylsulfanyl-phenyl)-pyridin-2-yl-amine
    —— 2-(3'-Methylthioanilinium)-5-methyl-5-nitro-1,3,2-dioxaphosphorinan 2-oxid 20926-64-1 C11H15N2O5PS
    2-(3'-Methylthioanilinium)-5-methyl-5-nitro-1,3,2-dioxaphosphorinan 2-oxid
    —— 1,1'-(5,5'-disulfanediylbis(2-chloro-5,1-phenylene))bis(3-methyl-3-(3-(methylthio)phenyl)guanidine) 1349064-27-2 C30H30Cl2N6S4
    1,1'-(5,5'-disulfanediylbis(2-chloro-5,1-phenylene))bis(3-methyl-3-(3-(methylthio)phenyl)guanidine)
    —— N-(5-benzylthio-2-chlorophenyl)-N'-(3-methylthiophenyl)-N'-methyl-guanidine hydrochloride 917894-08-7 C22H22ClN3S2*ClH
    N-(5-benzylthio-2-chlorophenyl)-N'-(3-methylthiophenyl)-N'-methyl-guanidine hydrochloride
    —— 2-benzyl-8-(4-chlorophenylthio)-6-phenylimidazo[1,2-a]pyrazin-3(7H)-one 1262118-00-2 C25H18ClN3OS
    2-benzyl-8-(4-chlorophenylthio)-6-phenylimidazo[1,2-a]pyrazin-3(7H)-one
    —— 2-benzyl-8-(4-chlorophenylthio)-6-(4-hydroxyphenyl)imidazo[1,2-a]pyrazin-3(7H)-one 1262117-95-2 C25H18ClN3O2S
    2-benzyl-8-(4-chlorophenylthio)-6-(4-hydroxyphenyl)imidazo[1,2-a]pyrazin-3(7H)-one
    —— methyl n-octanesulphonylacetate 221119-53-5 C11H22O4S
    methyl n-octanesulphonylacetate
    —— 3-(2-chloro-5-((2-(18)fluoroethyl)thio)phenyl)-1-methyl-1-(3-(methylthio)phenyl)guanidine 917894-12-3 C17H19ClFN3S2
    3-(2-chloro-5-((2-(18)fluoroethyl)thio)phenyl)-1-methyl-1-(3-(methylthio)phenyl)guanidine
    —— (Z)-2-(5-bromo-1H-indol-yl)-3-(4-(phenylthio)pyridin-3-yl)acrylonitrile 1613334-42-1 C22H14BrN3S
    (Z)-2-(5-bromo-1H-indol-yl)-3-(4-(phenylthio)pyridin-3-yl)acrylonitrile
    —— 3-(2-chloro-5-(2-fluoroethylthio)phenyl)-N'-methyl-N'-(3-(methylthio)phenyl)guanidine 917894-11-2 C17H19ClFN3S2
    3-(2-chloro-5-(2-fluoroethylthio)phenyl)-N'-methyl-N'-(3-(methylthio)phenyl)guanidine
    —— pyridine-4-carboxaldehyde (3-methylthiophenyl)imine 165806-93-9 C13H12N2S
    pyridine-4-carboxaldehyde (3-methylthiophenyl)imine
    —— 1-(3,5-dimethyl-1H-pyrazol-1-yl)-1-(phenylthio)ethane 122606-09-1 C13H16N2S
    1-(3,5-dimethyl-1H-pyrazol-1-yl)-1-(phenylthio)ethane
    —— 2-(3,5-dimethyl-1H-pyrazol-1-yl)-1-(4-methylphenyl)-2-(phenylthio)ethanol 122606-12-6 C20H22N2OS
    2-(3,5-dimethyl-1H-pyrazol-1-yl)-1-(4-methylphenyl)-2-(phenylthio)ethanol
    —— 1-Methylspiro(piperidine-4,6'-dibenz<b,e>-1,4-oxathiepin) 98796-28-2 C18H19NOS
    1-Methylspiro(piperidine-4,6'-dibenz<b,e>-1,4-oxathiepin)
    —— 2-[5-Chloro-2-(2-fluorophenyl)sulfanylphenyl]acetic acid 73129-27-8 C14H10ClFO2S
    2-[5-Chloro-2-(2-fluorophenyl)sulfanylphenyl]acetic acid
    —— (R)-N-[2-fluoro-4-(2-fluorophenylthio)phenyl]-2-hydroxy-2-methyl-3,3,3-trifluoropropanamide 252016-86-7 C16H12F5NO2S
    (R)-N-[2-fluoro-4-(2-fluorophenylthio)phenyl]-2-hydroxy-2-methyl-3,3,3-trifluoropropanamide
    —— 6-(3-Piperidinopropyl)-6H-dibenz<b,e>-1,4-oxathiepin 83193-49-1 C21H25NOS
    6-(3-Piperidinopropyl)-6H-dibenz<b,e>-1,4-oxathiepin
    —— S-Methyl-S'-(2'-bromphenyl)-3-acetamido-dithio-hydrochinon 5166-81-4 C15H14BrNOS2
    S-Methyl-S'-(2'-bromphenyl)-3-acetamido-dithio-hydrochinon
    —— 4,4'-Diisocyanato-diphenylsulfid 14353-02-7 C14H8N2O2S
    4,4'-Diisocyanato-diphenylsulfid