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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-Propanamine, N-methyl-3-(2-(phenylthio)phenoxy)-, hydrochloride 62232-59-1 C16H20ClNOS
    1-Propanamine, N-methyl-3-(2-(phenylthio)phenoxy)-, hydrochloride
    —— 1-<(2-hydroxyethoxy)methyl>-6-<(2-methylphenyl)thio>thymine 125056-57-7 C15H18N2O4S
    1-<(2-hydroxyethoxy)methyl>-6-<(2-methylphenyl)thio>thymine
    —— 1-bromo-10-(pentylsulfonyl)decane 177584-01-9 C15H31BrO2S
    1-bromo-10-(pentylsulfonyl)decane
    —— 6-phenyl-4-(phenylthio)hex-2-ene 147330-97-0 C18H20S
    6-phenyl-4-(phenylthio)hex-2-ene
    —— (2R,3S,6R)-2-Hydroxymethyl-6-((Z)-2-phenylsulfanyl-2-triethylsilanyl-vinyl)-tetrahydro-pyran-3-ol 175673-09-3 C20H32O3SSi
    (2R,3S,6R)-2-Hydroxymethyl-6-((Z)-2-phenylsulfanyl-2-triethylsilanyl-vinyl)-tetrahydro-pyran-3-ol
    —— ethyl 2-benzyl-4-phenylthiobut-2-enoate 86895-85-4 C19H20O2S
    ethyl 2-benzyl-4-phenylthiobut-2-enoate
    —— 2-(2-chloro-phenylsulfanyl)-butyric acid 103038-50-2 C10H11ClO2S
    2-(2-chloro-phenylsulfanyl)-butyric acid
    —— ethyl 2-(phenylthio)-2-butenoate 109542-31-6 C12H14O2S
    ethyl 2-(phenylthio)-2-butenoate
    —— ethyl 2-benzyl-2-phenylthiobut-3-enoate 86895-76-3 C19H20O2S
    ethyl 2-benzyl-2-phenylthiobut-3-enoate
    —— 2-((4-Chlorophenyl)thio)-alpha-(2-(dimethylamino)ethyl)benzeneacetonitrile hydrochloride 62674-72-0 C18H20Cl2N2S
    2-((4-Chlorophenyl)thio)-alpha-(2-(dimethylamino)ethyl)benzeneacetonitrile hydrochloride
    —— 6-[(2,6-difluorophenyl)ethyl]-5-ethyl-2-butylthiopyrimidin-4(3H)-one 1613669-25-2 C18H22F2N2OS
    6-[(2,6-difluorophenyl)ethyl]-5-ethyl-2-butylthiopyrimidin-4(3H)-one
    —— 6-[(2,6-difluorophenyl)ethyl]-5-ethyl-2-isopropylthiopyrimidin-4(3H)-one 1613669-22-9 C17H20F2N2OS
    6-[(2,6-difluorophenyl)ethyl]-5-ethyl-2-isopropylthiopyrimidin-4(3H)-one
    —— 6-[(2,6-difluorophenyl)ethyl]-5-methyl-2-propylthiopyrimidin-4(3H)-one 1613669-21-8 C16H18F2N2OS
    6-[(2,6-difluorophenyl)ethyl]-5-methyl-2-propylthiopyrimidin-4(3H)-one
    —— ethyl β,γ-bis(phenylthio)butyrate 77316-67-7 C18H20O2S2
    ethyl β,γ-bis(phenylthio)butyrate
    —— 6-[(2,6-difluorophenyl)ethyl]-5-ethyl-2-cyclopentylthiopyrimidin-4(3H)-one 1613669-26-3 C19H22F2N2OS
    6-[(2,6-difluorophenyl)ethyl]-5-ethyl-2-cyclopentylthiopyrimidin-4(3H)-one
    —— 6-(2,6-Difluoro-benzyl)-2-isopropylsulfanyl-3H-pyrimidin-4-one 221122-02-7 C14H14F2N2OS
    6-(2,6-Difluoro-benzyl)-2-isopropylsulfanyl-3H-pyrimidin-4-one
    —— 6-[(2,6-difluorophenyl)ethyl]-5-ethyl-2-sec-butylthiopyrimidin-4(3H)-one 1613669-24-1 C18H22F2N2OS
    6-[(2,6-difluorophenyl)ethyl]-5-ethyl-2-sec-butylthiopyrimidin-4(3H)-one
    —— 6-[(2,6-difluorophenyl)ethyl]-5-ethyl-2-propylthiopyrimidin-4(3H)-one 1613669-23-0 C17H20F2N2OS
    6-[(2,6-difluorophenyl)ethyl]-5-ethyl-2-propylthiopyrimidin-4(3H)-one
    —— 2-Butylsulfanyl-6-(2,6-difluoro-benzyl)-3H-pyrimidin-4-one 221122-03-8 C15H16F2N2OS
    2-Butylsulfanyl-6-(2,6-difluoro-benzyl)-3H-pyrimidin-4-one
    —— 2-Cyclohexylsulfanyl-6-(2,6-difluoro-benzyl)-3H-pyrimidin-4-one 221122-07-2 C17H18F2N2OS
    2-Cyclohexylsulfanyl-6-(2,6-difluoro-benzyl)-3H-pyrimidin-4-one
    —— 2-(4-(2-aminothiazol-4-ylthio)phenyl)-1,1,1-trifluoropropan-2-ol 869854-29-5 C12H11F3N2OS2
    2-(4-(2-aminothiazol-4-ylthio)phenyl)-1,1,1-trifluoropropan-2-ol
    —— N,N-dimethyl-2-(3-hydroxy-4-methoxyphenylthio)benzylamine 134987-20-5 C16H19NO2S
    N,N-dimethyl-2-(3-hydroxy-4-methoxyphenylthio)benzylamine
    —— 2-(3-benzyloxy-4-methoxyphenylthio)benzoic acid 134987-28-3 C21H18O4S
    2-(3-benzyloxy-4-methoxyphenylthio)benzoic acid
    —— 2-Methyl-5-propylsulfanyl-furan 116394-88-8 C8H12OS
    2-Methyl-5-propylsulfanyl-furan
    —— 5-ethyl-1-benzyloxymethyl-6-(3,5-dimethylphenylthio)-2-thiouracil 136105-78-7 C22H24N2O2S2
    5-ethyl-1-benzyloxymethyl-6-(3,5-dimethylphenylthio)-2-thiouracil
    —— 5-ethyl-1-hydroxyethoxymethyl-6-(3,5-dimethylphenylthio)-2-thiouracil 136105-77-6 C17H22N2O3S2
    5-ethyl-1-hydroxyethoxymethyl-6-(3,5-dimethylphenylthio)-2-thiouracil
    —— 6-<(3,5-dimethylphenyl)thio>-1-<(2-hydroxyethoxy)methyl>-2-thiothymine 137897-73-5 C16H20N2O3S2
    6-<(3,5-dimethylphenyl)thio>-1-<(2-hydroxyethoxy)methyl>-2-thiothymine
    —— 5-ethyl-1-ethoxymethyl-6-(3,5-dimethylphenylthio)-2-thiouracil 136011-45-5 C17H22N2O2S2
    5-ethyl-1-ethoxymethyl-6-(3,5-dimethylphenylthio)-2-thiouracil
    —— benzyl(3,5-dimethylphenyl)sulfide 1227376-32-0 C15H16S
    benzyl(3,5-dimethylphenyl)sulfide
    —— 2-Methyl-2-propyl-1,3-propandithiol-dicarbamat 13044-77-4 C9H18N2O2S2
    2-Methyl-2-propyl-1,3-propandithiol-dicarbamat
    —— 3-Methyl-pentan-3-thiol-carbamat 90048-35-4 C7H15NOS
    3-Methyl-pentan-3-thiol-carbamat
    —— [Amino(2-azaniumylethylsulfanyl)methylidene]azanium;diiodide 63680-12-6 C3H11I2N3S
    [Amino(2-azaniumylethylsulfanyl)methylidene]azanium;diiodide
    —— 4-[2-(2-Amino-propyl)-phenylsulfanyl]-phenol 128959-32-0 C15H17NOS
    4-[2-(2-Amino-propyl)-phenylsulfanyl]-phenol
    —— 1-[2-(4-Methoxyphenyl)sulfanylphenyl]-2,2-dimethylbut-3-en-1-ol 1052737-79-7 C19H22O2S
    1-[2-(4-Methoxyphenyl)sulfanylphenyl]-2,2-dimethylbut-3-en-1-ol
    —— 9,10-Dihydro-6-phenyl-5H,8H,16H-dibenzo<d,h><1,6,10,2>oxadithiaphosphacyclotridecin-6-oxid 122278-88-0 C23H23O2PS2
    9,10-Dihydro-6-phenyl-5H,8H,16H-dibenzo<d,h><1,6,10,2>oxadithiaphosphacyclotridecin-6-oxid
    —— 5-<Furyl-(2)>-2-methylmercapto-1,3,4-oxdiazol 89795-60-8 C7H6N2O2S
    5-<Furyl-(2)>-2-methylmercapto-1,3,4-oxdiazol
    —— 3-amino-1H-1-(3-phenylpropyl)-5-methylsulfanyl-4-[3-(2-furyl)-1,2,4-triazol-5-yl]pyrazole 512846-00-3 C19H20N6OS
    3-amino-1H-1-(3-phenylpropyl)-5-methylsulfanyl-4-[3-(2-furyl)-1,2,4-triazol-5-yl]pyrazole
    —— Acetyl-[amino(2-azaniumylethylsulfanyl)methylidene]azanium;dichloride 63679-53-8 C5H13Cl2N3OS
    Acetyl-[amino(2-azaniumylethylsulfanyl)methylidene]azanium;dichloride
    —— 1,4-bis[5-(N,N-diethylcarbamoyl)thio-4-cyclohexyl-1,2,4-triazol-3-yl]butane 1266399-79-4 C30H50N8O2S2
    1,4-bis[5-(N,N-diethylcarbamoyl)thio-4-cyclohexyl-1,2,4-triazol-3-yl]butane
    —— S-methylisothiosulfate hemisulfate 26365-03-7 CH5N3S
    S-methylisothiosulfate hemisulfate
    —— 3-(2-Hydroxyphenyl)-7-methylsulfanyl-5-oxo-[1,3]thiazolo[3,2-a]pyrimidine-6-carbonitrile 1223515-77-2 C14H9N3O2S2
    3-(2-Hydroxyphenyl)-7-methylsulfanyl-5-oxo-[1,3]thiazolo[3,2-a]pyrimidine-6-carbonitrile
    —— Acetyl-[amino(2-aminoethylsulfanyl)methylidene]azanium;acetate 63679-55-0 C7H15N3O3S
    Acetyl-[amino(2-aminoethylsulfanyl)methylidene]azanium;acetate
    —— (8aS)-albicanyl phenyl sulfide 1041006-64-7 C21H30S
    (8aS)-albicanyl phenyl sulfide
    —— [Amino(2-azaniumylethylsulfanyl)methylidene]azanium;diacetate 63680-10-4 C7H17N3O4S
    [Amino(2-azaniumylethylsulfanyl)methylidene]azanium;diacetate
    —— S-(((4-Chlorophenyl)thio)methyl) O-ethyl phosphonodithioate 63869-31-8 C11H16ClOPS3
    S-(((4-Chlorophenyl)thio)methyl) O-ethyl phosphonodithioate
    —— 6-phenyl-4-methyl-3-methylmercapto-4,5-dihydro-5-oxo-1,2,4-triazine 22943-30-2 C11H11N3OS
    6-phenyl-4-methyl-3-methylmercapto-4,5-dihydro-5-oxo-1,2,4-triazine
    —— Di(propan-2-yl)-[2-(pyrido[3,2-b][1,4]benzothiazine-10-carbonyloxy)propyl]azanium;chloride —— C21H28ClN3O2S
    Di(propan-2-yl)-[2-(pyrido[3,2-b][1,4]benzothiazine-10-carbonyloxy)propyl]azanium;chloride
    —— hydron;S-(3-piperidin-1-ylpropyl) pyrido[3,2-b][1,4]benzothiazine-10-carbothioate;chloride —— C20H24ClN3OS2
    hydron;S-(3-piperidin-1-ylpropyl) pyrido[3,2-b][1,4]benzothiazine-10-carbothioate;chloride
    —— Diethyl-[3-(pyrido[3,2-b][1,4]benzothiazine-10-carbonyloxy)propyl]azanium;chloride —— C19H24ClN3O2S
    Diethyl-[3-(pyrido[3,2-b][1,4]benzothiazine-10-carbonyloxy)propyl]azanium;chloride
    —— 2-[2-[di(propan-2-yl)amino]ethylsulfanyl]ethyl pyrido[3,2-b][1,4]benzothiazine-10-carboxylate;hydron;chloride —— C22H30ClN3O2S2
    2-[2-[di(propan-2-yl)amino]ethylsulfanyl]ethyl pyrido[3,2-b][1,4]benzothiazine-10-carboxylate;hydron;chloride