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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4-methylsulfanyl-1-phenylpyrimidine-2(1H)-thione 872492-84-7 C11H10N2S2
    4-methylsulfanyl-1-phenylpyrimidine-2(1H)-thione
    —— 3-(benzyloxymethyl)-1-[(Z)-2,3-di-O-(tert-butyldimethylsilyl)-4,5-dehydro-5-phenylthio-β-D-ribopentofuranosyl]uracil 1354938-99-0 C35H50N2O6SSi2
    3-(benzyloxymethyl)-1-[(Z)-2,3-di-O-(tert-butyldimethylsilyl)-4,5-dehydro-5-phenylthio-β-D-ribopentofuranosyl]uracil
    —— 2-Methyl-m-dithiane-2-carboxaldehyde O-(methylcarbamoyl)oxime 26419-72-7 C8H14N2O2S2
    2-Methyl-m-dithiane-2-carboxaldehyde O-(methylcarbamoyl)oxime
    —— [1,1,1,5,5,5-Hexafluoro-2,4-bis(trifluoromethyl)pent-2-en-3-yl]sulfanylbenzene 38091-65-5 C13H6F12S
    [1,1,1,5,5,5-Hexafluoro-2,4-bis(trifluoromethyl)pent-2-en-3-yl]sulfanylbenzene
    —— 3-ethylsulfanyl-1,1,1,5,5,5-hexafluoro-2,4-bis-trifluoromethyl-pent-2-ene 38091-64-4 C9H6F12S
    3-ethylsulfanyl-1,1,1,5,5,5-hexafluoro-2,4-bis-trifluoromethyl-pent-2-ene
    —— 2-(Morpholinoimino)-4'-(phenylthio)acetophenone 25561-45-9 C18H18N2O2S
    2-(Morpholinoimino)-4'-(phenylthio)acetophenone
    —— (2-bromoethyl)(5-(difluoromethyl)selenophen-2-yl)sulfane 1297906-71-8 C7H7BrF2SSe
    (2-bromoethyl)(5-(difluoromethyl)selenophen-2-yl)sulfane
    —— diisopropyl 2-(2-bromoethylthio)thiophen-3-ylphosphonate 1297906-74-1 C12H20BrO3PS2
    diisopropyl 2-(2-bromoethylthio)thiophen-3-ylphosphonate
    —— α-phenylsulfanyl-isobutyric acid amide 857809-74-6 C10H13NOS
    α-phenylsulfanyl-isobutyric acid amide
    —— 2-(2-bromoethylthio)furan 1297906-67-2 C6H7BrOS
    2-(2-bromoethylthio)furan
    —— 5-(2-bromoethylthio)selenophene-2-carbonitrile 1297906-72-9 C7H6BrNSSe
    5-(2-bromoethylthio)selenophene-2-carbonitrile
    —— 2-chloroethyl cycloheptyl sulfide 333782-91-5 C9H17ClS
    2-chloroethyl cycloheptyl sulfide
    —— 2-(3-fluorophenylthio)ethyl chloride 333782-56-2 C8H8ClFS
    2-(3-fluorophenylthio)ethyl chloride
    —— N-{(E)-[4-(methylsulfanyl)phenyl]methylidene}-2-phenylethanesulfonamide —— C16H17NO2S2
    N-{(E)-[4-(methylsulfanyl)phenyl]methylidene}-2-phenylethanesulfonamide
    —— 2-(4-methylthiophenyl)-4-(2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-henicosafluorodecyl)-[1,3,2]dioxaborolane 884844-91-1 C20H12BF21O2S
    2-(4-methylthiophenyl)-4-(2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-henicosafluorodecyl)-[1,3,2]dioxaborolane
    —— 1,3-Dithiolane-2-carboxaldehyde, 2-methyl-, O-((methylamino)carbonyl)oxime 26419-69-2 C7H12N2O2S2
    1,3-Dithiolane-2-carboxaldehyde, 2-methyl-, O-((methylamino)carbonyl)oxime
    —— 2-Methyl-2-(methylthio)propanal O-((dibutylaminosulfenyl)(methyl)carbamoyl)oxime 69784-43-6 C15H31N3O2S2
    2-Methyl-2-(methylthio)propanal O-((dibutylaminosulfenyl)(methyl)carbamoyl)oxime
    —— 2,4,8-Trimethyl-5-oxo-6-oxa-3,9-dithia-2,4,7-triazadec-7-enoic acid 1-methylethyl ester 65907-51-9 C10H19N3O4S2
    2,4,8-Trimethyl-5-oxo-6-oxa-3,9-dithia-2,4,7-triazadec-7-enoic acid 1-methylethyl ester
    —— 5-chloro-1-methyl-3-(2-cyanoethylthio)-2(1H)-pyrazinone 107363-58-6 C8H8ClN3OS
    5-chloro-1-methyl-3-(2-cyanoethylthio)-2(1H)-pyrazinone
    —— 5-chloro-1-phenyl-3-(2-cyanoethylthio)-2(1H)-pyrazinone 107363-59-7 C13H10ClN3OS
    5-chloro-1-phenyl-3-(2-cyanoethylthio)-2(1H)-pyrazinone
    —— allyl vinyl sulfide 41049-25-6 C5H8S
    allyl vinyl sulfide
    —— 2-Ethyl-4,8-dimethyl-5-oxo-6-oxa-3,9-dithia-2,4,7-triazadec-7-enoic acid hexyl ester 65907-53-1 C14H27N3O4S2
    2-Ethyl-4,8-dimethyl-5-oxo-6-oxa-3,9-dithia-2,4,7-triazadec-7-enoic acid hexyl ester
    —— 2,4,9,9-Tetramethyl-5-oxo-6-oxa-3,10-dithia-2,4,7-triazaundec-7-enoic acid decyl ester 65907-43-9 C19H37N3O4S2
    2,4,9,9-Tetramethyl-5-oxo-6-oxa-3,10-dithia-2,4,7-triazaundec-7-enoic acid decyl ester
    —— 2,4,8-Trimethyl-5-oxo-6-oxa-3,9-dithia-2,4,7-triazadec-7-enoic acid propyl ester 65907-50-8 C10H19N3O4S2
    2,4,8-Trimethyl-5-oxo-6-oxa-3,9-dithia-2,4,7-triazadec-7-enoic acid propyl ester
    —— N,N-diethyl-2-[(Z)-[(5-ethyl-1,3-thiazol-2-yl)-[3-(trifluoromethylsulfanyl)phenyl]methylidene]amino]oxypropan-1-amine;hydron;chloride —— C20H27ClF3N3OS2
    N,N-diethyl-2-[(Z)-[(5-ethyl-1,3-thiazol-2-yl)-[3-(trifluoromethylsulfanyl)phenyl]methylidene]amino]oxypropan-1-amine;hydron;chloride
    —— 1-methyl-5-(3-cyclohexylcarbonylpropyl)thio-1,2,3,4-tetrazole 80087-21-4 C12H20N4OS
    1-methyl-5-(3-cyclohexylcarbonylpropyl)thio-1,2,3,4-tetrazole
    —— 5-<2-Amino-phenylmercapto>-4-chlor-3(2H)-pyridazinon 2843-05-2 C10H8ClN3OS
    5-<2-Amino-phenylmercapto>-4-chlor-3(2H)-pyridazinon
    —— 12-mercapto-1-dodecanol 131215-93-5 C12H26OS
    12-mercapto-1-dodecanol
    —— 3-(3-Phenylsulfanylpropyl)cyclohexan-1-one 133188-97-3 C15H20OS
    3-(3-Phenylsulfanylpropyl)cyclohexan-1-one
    —— (2R)-4,4-bis(ethylthio)oct-5-yn-2-ol 333347-46-9 C12H22OS2
    (2R)-4,4-bis(ethylthio)oct-5-yn-2-ol
    —— 9-(3,5-dihydro-2H-1,4-benzodioxepin-3-yl)-6-phenylsulfanylpurine 1020397-72-1 C20H16N4O2S
    9-(3,5-dihydro-2H-1,4-benzodioxepin-3-yl)-6-phenylsulfanylpurine
    —— 9-(3,5-dihydro-2H-1,4-benzodioxepin-3-yl)-6-(4-fluorophenyl)sulfanylpurine 1020397-75-4 C20H15FN4O2S
    9-(3,5-dihydro-2H-1,4-benzodioxepin-3-yl)-6-(4-fluorophenyl)sulfanylpurine
    —— 7-(3,5-dihydro-2H-1,4-benzodioxepin-3-yl)-6-(4-fluorophenyl)sulfanylpurine 1020397-91-4 C20H15FN4O2S
    7-(3,5-dihydro-2H-1,4-benzodioxepin-3-yl)-6-(4-fluorophenyl)sulfanylpurine
    —— 6-(2,4-dichlorophenyl)sulfanyl-9-(3,5-dihydro-2H-1,4-benzodioxepin-3-yl)purine 1020397-68-5 C20H14Cl2N4O2S
    6-(2,4-dichlorophenyl)sulfanyl-9-(3,5-dihydro-2H-1,4-benzodioxepin-3-yl)purine
    —— 6-(2,4-dichlorophenyl)sulfanyl-7-(3,5-dihydro-2H-1,4-benzodioxepin-3-yl)purine 1020397-84-5 C20H14Cl2N4O2S
    6-(2,4-dichlorophenyl)sulfanyl-7-(3,5-dihydro-2H-1,4-benzodioxepin-3-yl)purine
    —— 7-(3,5-dihydro-2H-1,4-benzodioxepin-3-yl)-6-phenylsulfanylpurine 1020397-89-0 C20H16N4O2S
    7-(3,5-dihydro-2H-1,4-benzodioxepin-3-yl)-6-phenylsulfanylpurine
    —— (2R)-1-(2-but-1-ynyl-1,3-dithian-2-yl)propan-2-ol 333347-44-7 C11H18OS2
    (2R)-1-(2-but-1-ynyl-1,3-dithian-2-yl)propan-2-ol
    —— chlordimethylmercaptomethan 62999-77-3 C3H7ClS2
    chlordimethylmercaptomethan
    —— 1,1-bis-ethylsulfanyl-pent-2-yne 22230-76-8 C9H16S2
    1,1-bis-ethylsulfanyl-pent-2-yne
    —— 2-[(R)-2-(2-hydroxypropyl)-1,3-dithian-2-yl]phenol 475644-99-6 C13H18O2S2
    2-[(R)-2-(2-hydroxypropyl)-1,3-dithian-2-yl]phenol
    —— (2R)-4-(phenylthio)oct-5-yn-2-ol 333347-42-5 C14H18OS
    (2R)-4-(phenylthio)oct-5-yn-2-ol
    —— Aldicarb oxime sulfoxide 7635-32-7 C5H11NO2S
    Aldicarb oxime sulfoxide
    —— 3-(R)-2-hydroxypropylthiophenylboronic acid 956388-64-0 C9H13BO3S
    3-(R)-2-hydroxypropylthiophenylboronic acid
    —— 3-(3-mercaptopropyl)cyclohexene 63715-29-7 C9H16S
    3-(3-mercaptopropyl)cyclohexene
    —— 2,8-bis(trifluoromethyl)-4-quinolyl p-tolylsulphide 177092-30-7 C18H11F6NS
    2,8-bis(trifluoromethyl)-4-quinolyl p-tolylsulphide
    —— 2-(4-amino-5-cyano-6-methylsulfanyl-pyrimidin-2-yl)-1,1-diethyl-3-phenyl-isothiourea 72367-49-8 C17H20N6S2
    2-(4-amino-5-cyano-6-methylsulfanyl-pyrimidin-2-yl)-1,1-diethyl-3-phenyl-isothiourea
    —— N-(3-Chlorophenyl)-N'-(2-(6,7-dimethoxyquinolin-4-ylsulfanyl)thiazol-5-yl)urea 417715-39-0 C21H17ClN4O3S2
    N-(3-Chlorophenyl)-N'-(2-(6,7-dimethoxyquinolin-4-ylsulfanyl)thiazol-5-yl)urea
    —— 3-phenylmercapto-2-chloro-4,4-ethylenedioxycyclopent-2-en-1-one 677308-56-4 C13H11ClO3S
    3-phenylmercapto-2-chloro-4,4-ethylenedioxycyclopent-2-en-1-one
    —— 2-(3-bromophenylthio)-3-(3-(pyridin-2-yl)propoxy)pyridine 263390-88-1 C19H17BrN2OS
    2-(3-bromophenylthio)-3-(3-(pyridin-2-yl)propoxy)pyridine
    —— (+)-2,2-dicyclohexyl-5-[(dimethylamino)methyl]-1,3-oxathiolane methiodide 101990-82-3 C19H36NOS*I
    (+)-2,2-dicyclohexyl-5-[(dimethylamino)methyl]-1,3-oxathiolane methiodide