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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(3-bromophenylthio)-3-(4-(pyridin-3-yl)butoxy)pyridine 263390-98-3 C20H19BrN2OS
    2-(3-bromophenylthio)-3-(4-(pyridin-3-yl)butoxy)pyridine
    —— 2-(3-bromophenylthio)-3-(3-(pyridin-3-yl)propoxy)pyridine 263390-85-8 C19H17BrN2OS
    2-(3-bromophenylthio)-3-(3-(pyridin-3-yl)propoxy)pyridine
    —— 2-(3-bromophenylthio)-3-(2-(pyridin-4-yl)ethoxy)pyridine 263390-87-0 C18H15BrN2OS
    2-(3-bromophenylthio)-3-(2-(pyridin-4-yl)ethoxy)pyridine
    —— 2-(3-bromophenylthio)-3-(2-(pyridin-3-yl)ethoxy)pyridine 263390-86-9 C18H15BrN2OS
    2-(3-bromophenylthio)-3-(2-(pyridin-3-yl)ethoxy)pyridine
    —— (2E)-penta-2,4-diene-1-thiol 1133951-72-0 C5H8S
    (2E)-penta-2,4-diene-1-thiol
    —— 4-chloro-2-fluoro-5-cyclopentyloxycarbonylmethylthiophenylisothiocyanate 125318-61-8 C14H13ClFNO2S2
    4-chloro-2-fluoro-5-cyclopentyloxycarbonylmethylthiophenylisothiocyanate
    —— 1-<(2-azidoethoxy)methyl>-6-(phenylthio)thymine 132774-42-6 C14H15N5O3S
    1-<(2-azidoethoxy)methyl>-6-(phenylthio)thymine
    —— 2-methypropane-1,3-bis(2-hydroxyethyl sulfide) 1385790-58-8 C8H18O2S2
    2-methypropane-1,3-bis(2-hydroxyethyl sulfide)
    —— 1-(2-Amino-ethoxymethyl)-5-methyl-6-phenylsulfanyl-1H-pyrimidine-2,4-dione 189637-33-0 C14H17N3O3S
    1-(2-Amino-ethoxymethyl)-5-methyl-6-phenylsulfanyl-1H-pyrimidine-2,4-dione
    —— 2,2-bis(2'-hydroxyethyl)-1,3-dithiolane 126300-43-4 C7H14O2S2
    2,2-bis(2'-hydroxyethyl)-1,3-dithiolane
    —— 3-oxo 2-phenylthiomethyl methyl cyclopentane carboxylate 90380-03-3 C14H16O3S
    3-oxo 2-phenylthiomethyl methyl cyclopentane carboxylate
    —— 2-(phenylthio)pyridin-3-ol 263390-51-8 C11H9NOS
    2-(phenylthio)pyridin-3-ol
    —— 3-hydroxy-2-pyridyl n-octyl sulfide 1062541-47-2 C13H21NOS
    3-hydroxy-2-pyridyl n-octyl sulfide
    —— 1-{2-[Dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-ethoxymethyl}-5-methyl-6-(pyridin-2-ylsulfanyl)-1H-pyrimidine-2,4-dione 189637-40-9 C21H33N3O4SSi
    1-{2-[Dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-ethoxymethyl}-5-methyl-6-(pyridin-2-ylsulfanyl)-1H-pyrimidine-2,4-dione
    —— 2-Methyl-5-amino-phenylthiopropionsaeure 54246-53-6 C10H13NO2S
    2-Methyl-5-amino-phenylthiopropionsaeure
    —— 5-{[3-{(Bis-methanesulfonyl)amino}phenyl]thio}-3-methyl-1-(2-methylpropyl)-6-(1-naphthalenylmethyl)thieno[2,3-d]pyrimidine-2,4-(1H, 3H)-dione 216685-54-0 C30H31N3O6S4
    5-{[3-{(Bis-methanesulfonyl)amino}phenyl]thio}-3-methyl-1-(2-methylpropyl)-6-(1-naphthalenylmethyl)thieno[2,3-d]pyrimidine-2,4-(1H, 3H)-dione
    —— 5-[(3-Aminophenyl)thio]-3-methyl-1-(2-methylpropyl)-6-(1-naphthalenylmethyl)thieno[2,3-d]pyrimidine-2,4-(1H, 3H)-dione 216685-53-9 C28H27N3O2S2
    5-[(3-Aminophenyl)thio]-3-methyl-1-(2-methylpropyl)-6-(1-naphthalenylmethyl)thieno[2,3-d]pyrimidine-2,4-(1H, 3H)-dione
    —— 5-benzylthio-3-chloro-1-methyl-4-(5-methyl-5H,6H-1,4,2-dioxazin-3-yl)pyrazole 868681-02-1 C15H16ClN3O2S
    5-benzylthio-3-chloro-1-methyl-4-(5-methyl-5H,6H-1,4,2-dioxazin-3-yl)pyrazole
    —— 3-[(Z)-1-fluoro-2-{4-[(trifluoromethyl)sulphanyl]phenyl}vinyl]-5-methyl-1-(4-methylbenzyl)-1H-pyrazole 1418295-64-3 C21H18F4N2S
    3-[(Z)-1-fluoro-2-{4-[(trifluoromethyl)sulphanyl]phenyl}vinyl]-5-methyl-1-(4-methylbenzyl)-1H-pyrazole
    —— 8-Chloro-7-methyl-imidazo[1,2-b][1,4,2]benzodithiazine 5,5-dioxide 198694-52-9 C10H7ClN2O2S2
    8-Chloro-7-methyl-imidazo[1,2-b][1,4,2]benzodithiazine 5,5-dioxide
    —— dimethyl-[1-methyl-2-(2-trifluoromethyl-6,11-dihydro-dibenzo[<i>b</i>,<i>f</i>][1,4]thiazocin-12-yl)-ethyl]-amine 37071-45-7 C20H23F3N2S
    dimethyl-[1-methyl-2-(2-trifluoromethyl-6,11-dihydro-dibenzo[<i>b</i>,<i>f</i>][1,4]thiazocin-12-yl)-ethyl]-amine
    —— Bis(3-bromo-1,2,4-thiadiazol-5-ylthio)methane 444791-14-4 C5H2Br2N4S4
    Bis(3-bromo-1,2,4-thiadiazol-5-ylthio)methane
    —— 4-methyl-pent-2-ene-3-thiol 25946-15-0 C6H12S
    4-methyl-pent-2-ene-3-thiol
    —— 2-methyl-pent-2-ene-3-thiol 25946-14-9 C6H12S
    2-methyl-pent-2-ene-3-thiol
    —— 2-trifluoromethyl-6,11-dihydro-dibenzo[<i>b</i>,<i>f</i>][1,4]thiazocine-12-carboxylic acid amide 24084-38-6 C16H13F3N2OS
    2-trifluoromethyl-6,11-dihydro-dibenzo[<i>b</i>,<i>f</i>][1,4]thiazocine-12-carboxylic acid amide
    —— 2-trifluoromethyl-6,11-dihydro-dibenzo[<i>b</i>,<i>f</i>][1,4]thiazocine-12-carbonyl chloride 851-76-3 C16H11ClF3NOS
    2-trifluoromethyl-6,11-dihydro-dibenzo[<i>b</i>,<i>f</i>][1,4]thiazocine-12-carbonyl chloride
    —— 2-Pentyl thiocyanate 61735-43-1 C6H11NS
    2-Pentyl thiocyanate
    —— 5-isopropyl-6-(3,5-dimethylphenylthio)-2,4-pyrimidinedione 171048-62-7 C15H18N2O2S
    5-isopropyl-6-(3,5-dimethylphenylthio)-2,4-pyrimidinedione
    —— 2-(2-amino-4-(trifluoromethyl)phenylthio)benzylamine 258875-17-1 C14H13F3N2S
    2-(2-amino-4-(trifluoromethyl)phenylthio)benzylamine
    —— 1-Methylthio-hexa-1,3-diin 58890-30-5 C7H8S
    1-Methylthio-hexa-1,3-diin
    —— 3-Bromo-2-methylsulfanylbut-2-enenitrile 206005-51-8 C5H6BrNS
    3-Bromo-2-methylsulfanylbut-2-enenitrile
    —— N-methyl-2-(2-amino-4-(trifluoromethyl)phenylthio)benzylamine 258875-16-0 C15H15F3N2S
    N-methyl-2-(2-amino-4-(trifluoromethyl)phenylthio)benzylamine
    —— N-(4-chlorobenzyl)-2-[2-(6,7-dimethoxyquinazolin-4-ylthio)-4-methylthiazol-5-yl]acetamide 1234579-24-8 C23H21ClN4O3S2
    N-(4-chlorobenzyl)-2-[2-(6,7-dimethoxyquinazolin-4-ylthio)-4-methylthiazol-5-yl]acetamide
    —— 2-[2-(6,7-dimethoxyquinazolin-4-ylthio)-4-methylthiazol-5-yl]-N-[3-(trifluoromethyl)phenyl]acetamide 1234579-22-6 C23H19F3N4O3S2
    2-[2-(6,7-dimethoxyquinazolin-4-ylthio)-4-methylthiazol-5-yl]-N-[3-(trifluoromethyl)phenyl]acetamide
    —— N-(3,5-dichlorophenyl)-2-[2-(6,7-dimethoxyquinazolin-4-ylthio)-4-methylthiazol-5-yl]acetamide 1234579-25-9 C22H18Cl2N4O3S2
    N-(3,5-dichlorophenyl)-2-[2-(6,7-dimethoxyquinazolin-4-ylthio)-4-methylthiazol-5-yl]acetamide
    —— 1-(3-(6,7-dimethoxyquinazolin-4-ylthio)phenyl)-3-(5-(1-(trifluoromethyl)cyclopropyl)isoxazol-3-yl)urea 1188920-81-1 C24H20F3N5O4S
    1-(3-(6,7-dimethoxyquinazolin-4-ylthio)phenyl)-3-(5-(1-(trifluoromethyl)cyclopropyl)isoxazol-3-yl)urea
    —— 1-(3-(6,7-dimethoxyquinazolin-4-ylthio)phenyl)-3-(5-(1,1,1-trifluoro-2-methylpropan-2-yl)isoxazol-3-yl)urea 1188911-79-6 C24H22F3N5O4S
    1-(3-(6,7-dimethoxyquinazolin-4-ylthio)phenyl)-3-(5-(1,1,1-trifluoro-2-methylpropan-2-yl)isoxazol-3-yl)urea
    —— N-(3-chlorophenyl)-2-[2-(6,7-dimethoxyquinazolin-4-ylthio)-4-methylthiazol-5-yl]acetamide 1234579-21-5 C22H19ClN4O3S2
    N-(3-chlorophenyl)-2-[2-(6,7-dimethoxyquinazolin-4-ylthio)-4-methylthiazol-5-yl]acetamide
    —— 1-(3-(6,7-imethoxyquinazolin-4-ylthio)phenyl)-3-(3-(2-fluoropropan-2-yl)isoxazol-5-yl)urea 1188909-90-1 C23H22FN5O4S
    1-(3-(6,7-imethoxyquinazolin-4-ylthio)phenyl)-3-(3-(2-fluoropropan-2-yl)isoxazol-5-yl)urea
    —— trans-1-methyl-2-(phenylthio)cyclopentanol 101704-30-7 C12H16OS
    trans-1-methyl-2-(phenylthio)cyclopentanol
    —— 2-(4,4-Dimethylpent-2-ynylsulfanyl)pyridine 1000854-40-9 C12H15NS
    2-(4,4-Dimethylpent-2-ynylsulfanyl)pyridine
    —— 2-chloromethyl-5-(3,5-dimethyl-4-nitrophenylthio)-3-methyl-3H-imidazo[4,5-b]pyridine 301548-48-1 C16H15ClN4O2S
    2-chloromethyl-5-(3,5-dimethyl-4-nitrophenylthio)-3-methyl-3H-imidazo[4,5-b]pyridine
    —— 5-benzylamino-3-methylthio-as-triazine 84582-96-7 C11H13N5S
    5-benzylamino-3-methylthio-as-triazine
    —— 1,4-dihydro-2-(1-methylethyl)-6-(methylthio)-4-oxo-5-pyrimidinecarbonitrile 96823-92-6 C9H11N3OS
    1,4-dihydro-2-(1-methylethyl)-6-(methylthio)-4-oxo-5-pyrimidinecarbonitrile
    —— 12-(3-chloro-propyl)-2-trifluoromethyl-11,12-dihydro-6<i>H</i>-dibenzo[<i>b</i>,<i>f</i>][1,4]thiazocine 37075-10-8 C18H17ClF3NS
    12-(3-chloro-propyl)-2-trifluoromethyl-11,12-dihydro-6<i>H</i>-dibenzo[<i>b</i>,<i>f</i>][1,4]thiazocine
    —— dimethyl-[3-(2-trifluoromethyl-6,11-dihydro-dibenzo[<i>b</i>,<i>f</i>][1,4]thiazocin-12-yl)-propyl]-amine 37123-77-6 C20H23F3N2S
    dimethyl-[3-(2-trifluoromethyl-6,11-dihydro-dibenzo[<i>b</i>,<i>f</i>][1,4]thiazocin-12-yl)-propyl]-amine
    —— 12-[3-(4-methyl-piperazin-1-yl)-propyl]-2-trifluoromethyl-11,12-dihydro-6<i>H</i>-dibenzo[<i>b</i>,<i>f</i>][1,4]thiazocine 37071-47-9 C23H28F3N3S
    12-[3-(4-methyl-piperazin-1-yl)-propyl]-2-trifluoromethyl-11,12-dihydro-6<i>H</i>-dibenzo[<i>b</i>,<i>f</i>][1,4]thiazocine
    —— 1,1-Bis-ethanesulfonyl-2,2-bis-ethylsulfanyl-ethene 90127-78-9 C10H20O4S4
    1,1-Bis-ethanesulfonyl-2,2-bis-ethylsulfanyl-ethene
    —— 12-(3-chloro-propionyl)-2-trifluoromethyl-11,12-dihydro-6<i>H</i>-dibenzo[<i>b</i>,<i>f</i>][1,4]thiazocine 37075-09-5 C18H15ClF3NOS
    12-(3-chloro-propionyl)-2-trifluoromethyl-11,12-dihydro-6<i>H</i>-dibenzo[<i>b</i>,<i>f</i>][1,4]thiazocine
    —— 1,1,2-Tris-ethanesulfonyl-2-ethylsulfanyl-ethene 90127-75-6 C10H20O6S4
    1,1,2-Tris-ethanesulfonyl-2-ethylsulfanyl-ethene