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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (1,1-difluoro-2-phenyl-1-phenylsulfanylpropan-2-oxy)trimethylsilane 899820-55-4 C18H22F2OSSi
    (1,1-difluoro-2-phenyl-1-phenylsulfanylpropan-2-oxy)trimethylsilane
    —— 2,2-difluoro-1-(4-bromophenyl)-2-phenylsulfanyl-1-trimethoxysiloxyethane 899820-47-4 C17H19BrF2OSSi
    2,2-difluoro-1-(4-bromophenyl)-2-phenylsulfanyl-1-trimethoxysiloxyethane
    —— 2-((5-((2-(Dimethylamino)-1-methylethyl)thio)-1,3,4-thiadiazol-2-yl)thio)-N,N-dimethyl-1-propanamine 6292-05-3 C12H24N4S3
    2-((5-((2-(Dimethylamino)-1-methylethyl)thio)-1,3,4-thiadiazol-2-yl)thio)-N,N-dimethyl-1-propanamine
    —— 4-({4-[(2-amino-6-ethyl-4-pyrimidinyl)amino]phenyl}sulfanyl)phenol 569658-12-4 C18H18N4OS
    4-({4-[(2-amino-6-ethyl-4-pyrimidinyl)amino]phenyl}sulfanyl)phenol
    —— 6-ethyl-N4-[3-fluoro-4-(4-pyridinylsulfanyl)phenyl]-2,4-pyrimidinediamine 570415-02-0 C17H16FN5S
    6-ethyl-N4-[3-fluoro-4-(4-pyridinylsulfanyl)phenyl]-2,4-pyrimidinediamine
    —— 2-Chlor-3-methylsulfonyl-propionamid 10568-98-6 C4H8ClNO3S
    2-Chlor-3-methylsulfonyl-propionamid
    —— 2,5-bis[2'-(5'-chlorothienyl)sulfanyl]thiophene 1211374-98-9 C12H6Cl2S5
    2,5-bis[2'-(5'-chlorothienyl)sulfanyl]thiophene
    —— 3-acetamidothiopropionamide 76275-89-3 C5H10N2OS
    3-acetamidothiopropionamide
    —— [3-(1-Phenylsulfanylethyl)phenyl]boronic acid 1332344-51-0 C14H15BO2S
    [3-(1-Phenylsulfanylethyl)phenyl]boronic acid
    —— 1-[4-[(4-Chlorophenyl)methylsulfanyl]phenyl]-2,3-dicyclohexyl-guanidine 1314034-04-2 C26H34ClN3S
    1-[4-[(4-Chlorophenyl)methylsulfanyl]phenyl]-2,3-dicyclohexyl-guanidine
    —— 1-[4-[(4-Chlorophenyl)methylsulfanyl]phenyl]guanidine 1314034-03-1 C14H14ClN3S
    1-[4-[(4-Chlorophenyl)methylsulfanyl]phenyl]guanidine
    —— 4-<(3,6-Dichlor-2-pyridinyl)-methylthio>-benzolamin 58803-97-7 C12H10Cl2N2S
    4-<(3,6-Dichlor-2-pyridinyl)-methylthio>-benzolamin
    —— N-(4-(4-chloro-6-(3-methyl-1H-pyrazol-5-ylamino)pyrimidin-2-ylthio)phenyl)-3,3,3-trifluoropropanamide 1061682-24-3 C17H14ClF3N6OS
    N-(4-(4-chloro-6-(3-methyl-1H-pyrazol-5-ylamino)pyrimidin-2-ylthio)phenyl)-3,3,3-trifluoropropanamide
    —— 2-(4-aminophenylthio)-6-methoxyquinoline 190331-35-2 C16H14N2OS
    2-(4-aminophenylthio)-6-methoxyquinoline
    —— 1-[4-[(3,5-Dibromophenyl)methylsulfanyl]phenyl]guanidine 1314034-12-2 C14H13Br2N3S
    1-[4-[(3,5-Dibromophenyl)methylsulfanyl]phenyl]guanidine
    —— S-dimethylcarbamoyl-p-aminothiophenol 112308-01-7 C9H12N2OS
    S-dimethylcarbamoyl-p-aminothiophenol
    —— 4-Carboxymethylthio-5H-pyrimido <4.5-b>-thiazin-6(7H)-on 65247-65-6 C8H7N3O3S2
    4-Carboxymethylthio-5H-pyrimido <4.5-b>-thiazin-6(7H)-on
    —— methanesulfonic acid 3-{4-[4-(3-methanesulfonyloxy-propyl)-2-trifluoromethyl-phenylsulfanyl]-3-trifluoromethyl-phenyl}-propyl ester 719294-09-4 C22H24F6O6S3
    methanesulfonic acid 3-{4-[4-(3-methanesulfonyloxy-propyl)-2-trifluoromethyl-phenylsulfanyl]-3-trifluoromethyl-phenyl}-propyl ester
    —— 2,5-bis{2'-[5'-(4''-aminophenyl)sulfanyl]thienyl}thiophene 1211374-99-0 C24H18N2S7
    2,5-bis{2'-[5'-(4''-aminophenyl)sulfanyl]thienyl}thiophene
    —— 2-(2'-propyl)-5,6-dihydro-1,4-dithiin-1,1,4,4-tetroxide 68090-31-3 C7H12O4S2
    2-(2'-propyl)-5,6-dihydro-1,4-dithiin-1,1,4,4-tetroxide
    —— 5-(4-Dimethylsulfamoyl-phenylsulfanyl)-thiophene-2-sulfonic acid amide 63032-35-9 C12H14N2O4S4
    5-(4-Dimethylsulfamoyl-phenylsulfanyl)-thiophene-2-sulfonic acid amide
    —— 6-(4-aminophenylthio)-8-methyl-3-phenethylthiomethylimidazo[1,2-a]pyridine 1076691-21-8 C23H23N3S2
    6-(4-aminophenylthio)-8-methyl-3-phenethylthiomethylimidazo[1,2-a]pyridine
    —— 2-(4-Aminophenyl)sulfanyl-2-phenylethanol 1260243-59-1 C14H15NOS
    2-(4-Aminophenyl)sulfanyl-2-phenylethanol
    —— 4-((2-(2-chlorophenyl)thiazol-4-yl)methylthio)aniline 1048364-13-1 C16H13ClN2S2
    4-((2-(2-chlorophenyl)thiazol-4-yl)methylthio)aniline
    —— 3-{4-[4-(3-Hydroxy-propyl)-2-trifluoromethyl-phenylsulfanyl]-3-trifluoromethyl-phenyl)-propan-1-ol 719293-96-6 C20H20F6O2S
    3-{4-[4-(3-Hydroxy-propyl)-2-trifluoromethyl-phenylsulfanyl]-3-trifluoromethyl-phenyl)-propan-1-ol
    —— 2-methyl-5-(2-thienylmethyl)-4-(phenylsulfanyl)thiazole 1167412-47-6 C15H13NS3
    2-methyl-5-(2-thienylmethyl)-4-(phenylsulfanyl)thiazole
    —— (5-Brompentyl)-(4-bromphenyl)-sulfid 16181-16-1 C11H14Br2S
    (5-Brompentyl)-(4-bromphenyl)-sulfid
    —— 5-(4-Amino-phenylsulfanyl)-thiophene-2-sulfonic acid amide 63031-88-9 C10H10N2O2S3
    5-(4-Amino-phenylsulfanyl)-thiophene-2-sulfonic acid amide
    —— 1-(4-aminophenylthio)naphthalene 76180-77-3 C16H13NS
    1-(4-aminophenylthio)naphthalene
    —— 2,2-bis(phenylthio)-1-methylcyclopropanecarbonitrile 100082-43-7 C17H15NS2
    2,2-bis(phenylthio)-1-methylcyclopropanecarbonitrile
    —— 4-[[(4-propyl-4H-1,2,4-triazol-3-yl)methyl]sulfanyl]aniline 742100-94-3 C12H16N4S
    4-[[(4-propyl-4H-1,2,4-triazol-3-yl)methyl]sulfanyl]aniline
    —— 2-(2-hydroxymethyl-1-pyrrolidinyl)-4-phenylthio-5-[N-(2-pyrimidylmethyl)carbamoyl]pyrimidine 330786-26-0 C21H22N6O2S
    2-(2-hydroxymethyl-1-pyrrolidinyl)-4-phenylthio-5-[N-(2-pyrimidylmethyl)carbamoyl]pyrimidine
    —— 1-(3-Methylsulfanyl-phenyl)-cyclohexylamine 125802-13-3 C13H19NS
    1-(3-Methylsulfanyl-phenyl)-cyclohexylamine
    —— (2-allylsulfanyl-benzyl)-carbamic acid tert-butyl ester 857499-95-7 C15H21NO2S
    (2-allylsulfanyl-benzyl)-carbamic acid tert-butyl ester
    —— Tris(methyldisulfanyl)methane 5418-89-3 C4H10S6
    Tris(methyldisulfanyl)methane
    —— 1-(2-methylisopropylsulfonyl)-2-butene 120454-02-6 C8H16O2S
    1-(2-methylisopropylsulfonyl)-2-butene
    —— diethyl 5,5'-thiobis(2-aminobenzoate) 907964-68-5 C18H20N2O4S
    diethyl 5,5'-thiobis(2-aminobenzoate)
    —— 2-(3-chlorophenylthio)acetohydrazide 1255527-45-7 C8H9ClN2OS
    2-(3-chlorophenylthio)acetohydrazide
    —— 5-[6-(3-Fluorophenyl)sulfanyl-[1,2,4]triazolo[4,3-b]pyridazin-3-yl]-1,3-thiazole 1428566-10-2 C14H8FN5S2
    5-[6-(3-Fluorophenyl)sulfanyl-[1,2,4]triazolo[4,3-b]pyridazin-3-yl]-1,3-thiazole
    —— 5-[6-(3-Bromophenyl)sulfanyl-[1,2,4]triazolo[4,3-b]pyridazin-3-yl]-1,3-thiazole 1428566-06-6 C14H8BrN5S2
    5-[6-(3-Bromophenyl)sulfanyl-[1,2,4]triazolo[4,3-b]pyridazin-3-yl]-1,3-thiazole
    —— 5-(6-Phenylsulfanyl-[1,2,4]triazolo[4,3-b]pyridazin-3-yl)-1,3-thiazole 1428566-22-6 C14H9N5S2
    5-(6-Phenylsulfanyl-[1,2,4]triazolo[4,3-b]pyridazin-3-yl)-1,3-thiazole
    —— 5-[6-[3-(Trifluoromethyl)phenyl]sulfanyl-[1,2,4]triazolo[4,3-b]pyridazin-3-yl]-1,3-thiazole 1428565-70-1 C15H8F3N5S2
    5-[6-[3-(Trifluoromethyl)phenyl]sulfanyl-[1,2,4]triazolo[4,3-b]pyridazin-3-yl]-1,3-thiazole
    —— 5-[6-(3-Tert-butylphenyl)sulfanyl-[1,2,4]triazolo[4,3-b]pyridazin-3-yl]-1,3-thiazole 1428566-14-6 C18H17N5S2
    5-[6-(3-Tert-butylphenyl)sulfanyl-[1,2,4]triazolo[4,3-b]pyridazin-3-yl]-1,3-thiazole
    —— 2-(4-chlorophenyl)sulfanyl-N,N-dipentylacetamide 5431-58-3 C18H28ClNOS
    2-(4-chlorophenyl)sulfanyl-N,N-dipentylacetamide
    —— 5-[6-[3-(Trifluoromethoxy)phenyl]sulfanyl-[1,2,4]triazolo[4,3-b]pyridazin-3-yl]-1,3-thiazole 1428566-16-8 C15H8F3N5OS2
    5-[6-[3-(Trifluoromethoxy)phenyl]sulfanyl-[1,2,4]triazolo[4,3-b]pyridazin-3-yl]-1,3-thiazole
    —— 2-(4-aminophenylthio)-6-(azetidin-1-yl)-N-(3-methyl-1H-pyrazol-5-yl)pyrimidin-4-amine 936848-90-7 C17H19N7S
    2-(4-aminophenylthio)-6-(azetidin-1-yl)-N-(3-methyl-1H-pyrazol-5-yl)pyrimidin-4-amine
    —— 2-(5-Methoxy-1H-benzimidazol-2-yl thio) benzenamine 112903-29-4 C14H13N3OS
    2-(5-Methoxy-1H-benzimidazol-2-yl thio) benzenamine
    —— N-[6-Chloro-3-(4-chloro-phenylsulfanyl)-imidazo[1,2-a]pyridin-2-yl]-2,2,2-trifluoro-acetamide 209971-52-8 C15H8Cl2F3N3OS
    N-[6-Chloro-3-(4-chloro-phenylsulfanyl)-imidazo[1,2-a]pyridin-2-yl]-2,2,2-trifluoro-acetamide
    —— 2-Cyclopropylsulfanyl-pyridine 127878-53-9 C8H9NS
    2-Cyclopropylsulfanyl-pyridine
    —— 1-ethyl-4-(methylsulfanyl)pyrimidin-2(1H)-one 25855-36-1 C7H10N2OS
    1-ethyl-4-(methylsulfanyl)pyrimidin-2(1H)-one