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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— Sodium;4-(4-sulfophenyl)sulfanylbenzenesulfonic acid 6966-19-4 C12H10NaO6S3+
    Sodium;4-(4-sulfophenyl)sulfanylbenzenesulfonic acid
    —— Decane-1,10-diyl dicarbamimidothioate--hydrogen bromide (1/1) 63498-30-6 C12H27BrN4S2
    Decane-1,10-diyl dicarbamimidothioate--hydrogen bromide (1/1)
    —— 2-Chloroethyl carbamimidothioate;hydrochloride 7250-13-7 C3H8Cl2N2S
    2-Chloroethyl carbamimidothioate;hydrochloride
    —— Methyl propanimidothioate;hydrochloride 5415-96-3 C4H10ClNS
    Methyl propanimidothioate;hydrochloride
    —— N-butyl-N-[2-(2,3,4,5,6-pentachlorophenyl)sulfanylethyl]butan-1-amine;hydrochloride 93047-36-0 C16H23Cl6NS
    N-butyl-N-[2-(2,3,4,5,6-pentachlorophenyl)sulfanylethyl]butan-1-amine;hydrochloride
    —— 2-Pyridinecarboximidamide, 4-(3-oxetanylthio)- 1427368-30-6 C9H11N3OS
    2-Pyridinecarboximidamide, 4-(3-oxetanylthio)-
    —— Acetic acid, 2-[[4-[(1,3,5-trimethyl-1H-pyrazol-4-yl)methyl]-4H-1,2,4-triazol-3-yl]thio]- 1519622-90-2 C11H15N5O2S
    Acetic acid, 2-[[4-[(1,3,5-trimethyl-1H-pyrazol-4-yl)methyl]-4H-1,2,4-triazol-3-yl]thio]-
    —— sodium 5-chloro-1-<α-(4-chlorophenylsulfenyl)>benzyl-2-oxo-1,2,3,4-tetrahydropyrimidine-4-sulfonate 100944-69-2 C17H13Cl2N2O4S2*Na
    sodium 5-chloro-1-<α-(4-chlorophenylsulfenyl)>benzyl-2-oxo-1,2,3,4-tetrahydropyrimidine-4-sulfonate
    —— benzene-1,2-dithiolate;2,3-dihydro-1,4-benzodithiine;(Z)-1,1,1,4,4,4-hexafluorobut-2-ene-2,3-dithiolate;molybdenum(4+) 959921-85-8 C18H12F6MoS6
    benzene-1,2-dithiolate;2,3-dihydro-1,4-benzodithiine;(Z)-1,1,1,4,4,4-hexafluorobut-2-ene-2,3-dithiolate;molybdenum(4+)
    —— 2,3-Dichloro-4-(2-propan-2-ylphenyl)sulfanylbenzaldehyde 387873-65-6 C16H14Cl2OS
    2,3-Dichloro-4-(2-propan-2-ylphenyl)sulfanylbenzaldehyde
    —— 1H-Pyrazole-3-methanamine, 1-[(2,3-dihydrobenzo[b]thien-2-yl)methyl]- 1518881-19-0 C13H15N3S
    1H-Pyrazole-3-methanamine, 1-[(2,3-dihydrobenzo[b]thien-2-yl)methyl]-
    —— 1-(Propylsulfanyl)undecane 66826-84-4 C14H30S
    1-(Propylsulfanyl)undecane
    —— Benzo[b]thiophene, 3-[2-(chloromethyl)-3-(2-methylphenyl)propyl]-2,3-dihydro- 1520424-52-5 C19H21ClS
    Benzo[b]thiophene, 3-[2-(chloromethyl)-3-(2-methylphenyl)propyl]-2,3-dihydro-
    —— 1,1-Di(ethenesulfonyl)-3-methoxypropane 84782-44-5 C8H14O5S2
    1,1-Di(ethenesulfonyl)-3-methoxypropane
    —— p-Tolyl-2,5-dimethyl-phenyl-sulfid 16704-44-2 C15H16S
    p-Tolyl-2,5-dimethyl-phenyl-sulfid
    —— Dichloro(diisothiocyanato)phosphanium 86860-16-4 C2Cl2N2PS2
    Dichloro(diisothiocyanato)phosphanium
    —— Tetraisothiocyanatophosphanium 56633-41-1 C4N4PS4
    Tetraisothiocyanatophosphanium
    —— 2-(3-cyano-4-methyl-6-trifluoromethanesulfonylpyridin-2-ylmercapto)acetamide 635732-65-9 C10H8F3N3O4S2
    2-(3-cyano-4-methyl-6-trifluoromethanesulfonylpyridin-2-ylmercapto)acetamide
    —— 2H-1,3-Oxathiepine 15599-76-5 C5H6OS
    2H-1,3-Oxathiepine
    —— 4-amino-3-cyano-4'-methoxy-diphenylsulphide 51124-45-9 C14H12N2OS
    4-amino-3-cyano-4'-methoxy-diphenylsulphide
    —— 2-[2-({2-[(Prop-2-en-1-yl)sulfanyl]ethyl}sulfanyl)ethoxy]butane 88627-50-3 C11H22OS2
    2-[2-({2-[(Prop-2-en-1-yl)sulfanyl]ethyl}sulfanyl)ethoxy]butane
    —— 3-{[2-({2-[(Propan-2-yl)oxy]ethyl}sulfanyl)ethyl]sulfanyl}prop-1-ene 88627-48-9 C10H20OS2
    3-{[2-({2-[(Propan-2-yl)oxy]ethyl}sulfanyl)ethyl]sulfanyl}prop-1-ene
    —— 2,2,6,6-Tetramethyl-4,4-bis(ethylsulfonyl)piperidine 58981-21-8 C13H27NO4S2
    2,2,6,6-Tetramethyl-4,4-bis(ethylsulfonyl)piperidine
    —— trans-2,6-dibutylsulfonyl-1,4-dithiafulvene 74057-78-6 C12H20O4S4
    trans-2,6-dibutylsulfonyl-1,4-dithiafulvene
    —— 3-({2-[(2-tert-Butoxyethyl)sulfanyl]ethyl}sulfanyl)prop-1-ene 88627-51-4 C11H22OS2
    3-({2-[(2-tert-Butoxyethyl)sulfanyl]ethyl}sulfanyl)prop-1-ene
    —— 3-[(2-{[2-(2,2,2-Trifluoroethoxy)ethyl]sulfanyl}ethyl)sulfanyl]prop-1-ene 88627-47-8 C9H15F3OS2
    3-[(2-{[2-(2,2,2-Trifluoroethoxy)ethyl]sulfanyl}ethyl)sulfanyl]prop-1-ene
    —— (2-Phenylsulfanyl-ethyl)-(2-tripropylsilanyl-ethyl)-amine 65575-51-1 C19H35NSSi
    (2-Phenylsulfanyl-ethyl)-(2-tripropylsilanyl-ethyl)-amine
    —— 5-Methylsulfanyl-1,2,4-benzotriazin-3-amine 1-oxide 763131-41-5 C8H8N4OS
    5-Methylsulfanyl-1,2,4-benzotriazin-3-amine 1-oxide
    —— 2-amino-(2-hydroxyethylamino)-8-methylthiopyrimido<4,5-d>pyridazine 126226-30-0 C9H12N6OS
    2-amino-(2-hydroxyethylamino)-8-methylthiopyrimido<4,5-d>pyridazine
    —— phenyl 2-chlorodifluoromethyl-2-deoxy-1-thio-α-D-arabinopyranoside 581099-64-1 C12H13ClF2O3S
    phenyl 2-chlorodifluoromethyl-2-deoxy-1-thio-α-D-arabinopyranoside
    —— 4,4'-Sulfanediylbis(2-hexylphenol) 89520-08-1 C24H34O2S
    4,4'-Sulfanediylbis(2-hexylphenol)
    —— 4-amino-6-<i>sec</i>-butyl-3-methylsulfanyl-4<i>H</i>-[1,2,4]triazin-5-one 57989-68-1 C8H14N4OS
    4-amino-6-<i>sec</i>-butyl-3-methylsulfanyl-4<i>H</i>-[1,2,4]triazin-5-one
    —— 5-ethylthio-3-hydroxymethyl-4-isobutyl-4H-1,2,4-triazole 497855-04-6 C9H17N3OS
    5-ethylthio-3-hydroxymethyl-4-isobutyl-4H-1,2,4-triazole
    —— {[5-(Trifluoromethyl)-1,3,4-thiadiazol-2-yl]thio}acetic acid 62616-87-9 C5H3F3N2O2S2
    {[5-(Trifluoromethyl)-1,3,4-thiadiazol-2-yl]thio}acetic acid
    —— 2-cyano-N-nonylthioacetamide 501333-98-8 C12H22N2S
    2-cyano-N-nonylthioacetamide
    —— 5-(Methylsulfonyl)pentanal 558466-08-3 C6H12O3S
    5-(Methylsulfonyl)pentanal
    —— N,N-dihexylcarbamodithioate 22296-19-1 C13H26NS2
    N,N-dihexylcarbamodithioate
    —— 4-(Cyclopentylsulfanyl)phenylboronic acid 1107580-37-9 C11H15BO2S
    4-(Cyclopentylsulfanyl)phenylboronic acid
    —— N-(5-(6,7-Dimethoxyquinolin-4-ylsulfanyl)thiophen-2-yl)-N'-phenylurea 417715-22-1 C22H19N3O3S2
    N-(5-(6,7-Dimethoxyquinolin-4-ylsulfanyl)thiophen-2-yl)-N'-phenylurea
    —— 2-(4-methyl-2-phenylsulfanylthiazol-5-yl)ethyl methanesulfonate 477533-74-7 C13H15NO3S3
    2-(4-methyl-2-phenylsulfanylthiazol-5-yl)ethyl methanesulfonate
    —— (2S,4R)-4-(tert-butyldimethylsilyloxy)2-methyl-4-[3-(1-methyl-2-oxo-1,2,3,4-tetrahydroquinazolin-6-ylthio)phenyl]tetrahydropyran 166883-35-8 C27H38N2O3SSi
    (2S,4R)-4-(tert-butyldimethylsilyloxy)2-methyl-4-[3-(1-methyl-2-oxo-1,2,3,4-tetrahydroquinazolin-6-ylthio)phenyl]tetrahydropyran
    —— Acetic acid, 2-[(5-bromo-2-chloro-4-pyrimidinyl)thio]-, ethyl ester 1515466-73-5 C8H8BrClN2O2S
    Acetic acid, 2-[(5-bromo-2-chloro-4-pyrimidinyl)thio]-, ethyl ester
    —— 3-Chloro-6-(2-piperidin-1-yl-ethylsulfanyl)-pyridazine 65612-24-0 C11H16ClN3S
    3-Chloro-6-(2-piperidin-1-yl-ethylsulfanyl)-pyridazine
    —— N,N-dimethyl-2-(phenylthio)propane-1,3-diamine 406234-04-6 C11H18N2S
    N,N-dimethyl-2-(phenylthio)propane-1,3-diamine
    —— 2-(1,4-benzoxathian-2-yl)-acetic acid 62591-01-9 C10H10O3S
    2-(1,4-benzoxathian-2-yl)-acetic acid
    —— 4-(p-chlorophenylthio)butyl methyl ether 61016-65-7 C11H15ClOS
    4-(p-chlorophenylthio)butyl methyl ether
    —— 6-chloro-3-(phenylsulfanyl)-2-pyrazinecarbonitrile 356783-25-0 C11H6ClN3S
    6-chloro-3-(phenylsulfanyl)-2-pyrazinecarbonitrile
    —— N-[(3-Chloro-5-trifluoromethyl-2-pyridyl)methyl]-2-phenylthiopropanamide 326816-59-5 C16H14ClF3N2OS
    N-[(3-Chloro-5-trifluoromethyl-2-pyridyl)methyl]-2-phenylthiopropanamide
    —— 2-methylsulphanyl-5-trimethylstannanyl-pyridine 188879-13-2 C9H15NSSn
    2-methylsulphanyl-5-trimethylstannanyl-pyridine
    —— N-methyl-N-[2-(methylsulfonyl)ethyl]amine hydrochloride 202197-60-2 C4H11NO2S*ClH
    N-methyl-N-[2-(methylsulfonyl)ethyl]amine hydrochloride