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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-oxo-3a, 4-dihydro-3H,6H-2-oxa-4-thia-1-aza-6a-azonio-3a-pentalenide 623565-40-2 C4H4N2O2S
    3-oxo-3a, 4-dihydro-3H,6H-2-oxa-4-thia-1-aza-6a-azonio-3a-pentalenide
    —— 2,2'-{Disulfanediylbis[(1,3,4-thiadiazole-5,2-diyl)sulfanediyl]}dipropanoic acid 820232-12-0 C10H10N4O4S6
    2,2'-{Disulfanediylbis[(1,3,4-thiadiazole-5,2-diyl)sulfanediyl]}dipropanoic acid
    —— 5-(2-aminophenylsulfanyl)-2-ethylthiazole-4-carboxylic acid ethyl ester 848555-56-6 C14H16N2O2S2
    5-(2-aminophenylsulfanyl)-2-ethylthiazole-4-carboxylic acid ethyl ester
    —— 3-amino-6-(2-methylbutan-2-yl)-4-methylsulfanyl-5,6,7,8-tetrahydro-1H-quinoline-2-thione 910308-62-2 C15H24N2S2
    3-amino-6-(2-methylbutan-2-yl)-4-methylsulfanyl-5,6,7,8-tetrahydro-1H-quinoline-2-thione
    —— Propanoic acid, 3-[(5-amino-1,3,4-thiadiazol-2-yl)thio]-2-hydroxy-2-methyl-, methyl ester 1340454-55-8 C7H11N3O3S2
    Propanoic acid, 3-[(5-amino-1,3,4-thiadiazol-2-yl)thio]-2-hydroxy-2-methyl-, methyl ester
    —— 3-(4-Bromophenyl)sulfanyl-2-hydroxy-2-methylpropanoic acid 1340369-37-0 C10H11BrO3S
    3-(4-Bromophenyl)sulfanyl-2-hydroxy-2-methylpropanoic acid
    —— (2R)-1-phenylsulfanylbut-3-en-2-amine 796099-15-5 C10H13NS
    (2R)-1-phenylsulfanylbut-3-en-2-amine
    —— 1-((Methylsulfonyl)methyl)cyclohexanecarboxylic acid 865459-89-8 C9H16O4S
    1-((Methylsulfonyl)methyl)cyclohexanecarboxylic acid
    —— tert-butyl N-[(1S,2R)-2-tert-butylsulfonylcyclohexyl]carbamate 865469-30-3 C15H29NO4S
    tert-butyl N-[(1S,2R)-2-tert-butylsulfonylcyclohexyl]carbamate
    —— Morpholine, 2-[[(3,4-dimethylphenyl)thio]methyl]- 1338967-81-9 C13H19NOS
    Morpholine, 2-[[(3,4-dimethylphenyl)thio]methyl]-
    —— 1-(1-Ethylpropyl)-5-methyl-3-(methylthio)-2 (1H)-pyrazinone 204856-54-2 C11H18N2OS
    1-(1-Ethylpropyl)-5-methyl-3-(methylthio)-2 (1H)-pyrazinone
    —— Benzeneethanimidamide, I+/--[[(3-methyl-1H-1,2,4-triazol-5-yl)thio]methyl]- 1468968-11-7 C12H15N5S
    Benzeneethanimidamide, I+/--[[(3-methyl-1H-1,2,4-triazol-5-yl)thio]methyl]-
    —— (2-methyl-3-oxo-pentane-2-sulfinyl)-acetic acid 853023-08-2 C8H14O4S
    (2-methyl-3-oxo-pentane-2-sulfinyl)-acetic acid
    —— (4-bromo-2-methyl-3-oxo-pentane-2-sulfonyl)-acetic acid 853023-10-6 C8H13BrO5S
    (4-bromo-2-methyl-3-oxo-pentane-2-sulfonyl)-acetic acid
    —— 2-Hydroxyethyl carbonotrithioate 87135-93-1 C3H5OS3-
    2-Hydroxyethyl carbonotrithioate
    —— bis(1H-inden-7-yl)sulfide 891865-43-3 C18H14S
    bis(1H-inden-7-yl)sulfide
    —— Acetic acid, 2-[[5-amino-4-(3-methylbutyl)-4H-1,2,4-triazol-3-yl]thio]- 1339128-48-1 C9H16N4O2S
    Acetic acid, 2-[[5-amino-4-(3-methylbutyl)-4H-1,2,4-triazol-3-yl]thio]-
    —— 5-Bromo-3-(2-methylsulfanylpyrimidin-4-yl)-2,1-benzoxazole 721448-46-0 C12H8BrN3OS
    5-Bromo-3-(2-methylsulfanylpyrimidin-4-yl)-2,1-benzoxazole
    —— bis(3-phenyl-1H-inden-7-yl)sulfide 891865-51-3 C30H22S
    bis(3-phenyl-1H-inden-7-yl)sulfide
    —— Cyclopropanemethanamine, I+/--[(propylthio)methyl]- 1339904-40-3 C8H17NS
    Cyclopropanemethanamine, I+/--[(propylthio)methyl]-
    —— Diphenyl[3-(phenylthio)phenyl]sulfonium 75482-19-8 C24H19S2+
    Diphenyl[3-(phenylthio)phenyl]sulfonium
    —— β-Phenylthioethyl-N,N-dimethyldithiocarbamat 27849-52-1 C11H15NS3
    β-Phenylthioethyl-N,N-dimethyldithiocarbamat
    —— 1-{5-[6-Cyano-7-(2-methoxyethoxy)quinolin-4-ylsulfanyl]thiophen-2-yl}-3-phenylurea 417715-67-4 C24H20N4O3S2
    1-{5-[6-Cyano-7-(2-methoxyethoxy)quinolin-4-ylsulfanyl]thiophen-2-yl}-3-phenylurea
    —— 1-{5-[6-Cyano-7-(2-methoxyethoxy)quinolin-4-ylsulfanyl]thiophen-2-yl}-3-cyclopropylurea 417715-65-2 C21H20N4O3S2
    1-{5-[6-Cyano-7-(2-methoxyethoxy)quinolin-4-ylsulfanyl]thiophen-2-yl}-3-cyclopropylurea
    —— 1-{5-[6-Cyano-7-(2-methoxyethoxy)quinolin-4-ylsulfanyl]thiophen-2-yl}-3-(para-tolyl)urea 417715-69-6 C25H22N4O3S2
    1-{5-[6-Cyano-7-(2-methoxyethoxy)quinolin-4-ylsulfanyl]thiophen-2-yl}-3-(para-tolyl)urea
    —— Benzenemethanamine, I+/--[[(3-chlorophenyl)thio]methyl]-N-ethyl-2-methyl- 1462237-18-8 C17H20ClNS
    Benzenemethanamine, I+/--[[(3-chlorophenyl)thio]methyl]-N-ethyl-2-methyl-
    —— 2-Butanamine, N-propyl-4-(2-pyrazinylthio)- 1343824-89-4 C11H19N3S
    2-Butanamine, N-propyl-4-(2-pyrazinylthio)-
    —— 1,2-Butanediamine, N1,N1,3-trimethyl-N2-[1-methyl-2-(methylsulfonyl)ethyl]- 1341367-70-1 C11H26N2O2S
    1,2-Butanediamine, N1,N1,3-trimethyl-N2-[1-methyl-2-(methylsulfonyl)ethyl]-
    —— 2-Propanamine, N-ethyl-1-[(1-methyl-1H-pyrazol-4-yl)thio]- 1339660-97-7 C9H17N3S
    2-Propanamine, N-ethyl-1-[(1-methyl-1H-pyrazol-4-yl)thio]-
    —— Ethyl 2-(4-propylsulfanylphenyl)acetate 15560-16-4 C13H18O2S
    Ethyl 2-(4-propylsulfanylphenyl)acetate
    —— Cyclopropanemethanamine, I+/--[[(3,4-dimethylphenyl)thio]methyl]-N-methyl- 1342385-24-3 C14H21NS
    Cyclopropanemethanamine, I+/--[[(3,4-dimethylphenyl)thio]methyl]-N-methyl-
    —— 2-Butanamine, 3,3-dimethyl-1-[(1-methylpropyl)sulfonyl]- 1342150-57-5 C10H23NO2S
    2-Butanamine, 3,3-dimethyl-1-[(1-methylpropyl)sulfonyl]-
    —— 1-Propanamine, N-(1,1-dimethylethyl)-3-(methylsulfinyl)- 1344275-69-9 C8H19NOS
    1-Propanamine, N-(1,1-dimethylethyl)-3-(methylsulfinyl)-
    —— 2-Butanamine, 1-[(1,1-dimethylethyl)sulfonyl]-N-ethyl- 1339479-28-5 C10H23NO2S
    2-Butanamine, 1-[(1,1-dimethylethyl)sulfonyl]-N-ethyl-
    —— 2-Butanamine, 3,3-dimethyl-1-(propylsulfinyl)- 1340346-17-9 C9H21NOS
    2-Butanamine, 3,3-dimethyl-1-(propylsulfinyl)-
    —— 3-Pentanamine, N-propyl-2-(2-pyrimidinylthio)- 1344015-80-0 C12H21N3S
    3-Pentanamine, N-propyl-2-(2-pyrimidinylthio)-
    —— N-t-butoxycarbonyl-(4-fluoro-2-(methylthio)phenyl)methanamine 869591-73-1 C13H18FNO2S
    N-t-butoxycarbonyl-(4-fluoro-2-(methylthio)phenyl)methanamine
    —— 1-[3-(n-Pentylthio)phenyl]ethanol 1443304-46-8 C13H20OS
    1-[3-(n-Pentylthio)phenyl]ethanol
    —— Acetamide, 2-[[3-(1-hydroxyethyl)phenyl]thio]-N-(1-methylbutyl)- 1378381-42-0 C15H23NO2S
    Acetamide, 2-[[3-(1-hydroxyethyl)phenyl]thio]-N-(1-methylbutyl)-
    —— 1-Propanamine, 3-(cyclohexylsulfonyl)-N-propyl- 1342742-35-1 C12H25NO2S
    1-Propanamine, 3-(cyclohexylsulfonyl)-N-propyl-
    —— 2-methyl-6-(4-methylphenyl)-sulfanylnicotinic acid 888022-55-7 C14H13NO2S
    2-methyl-6-(4-methylphenyl)-sulfanylnicotinic acid
    —— 2-(3-chloro-4-methylsulfanylphenyl)-3-[(3R)-8,8-dimethyl-6,10-dioxaspiro[4.5]decan-3-yl]propanoic acid 952517-41-8 C20H27ClO4S
    2-(3-chloro-4-methylsulfanylphenyl)-3-[(3R)-8,8-dimethyl-6,10-dioxaspiro[4.5]decan-3-yl]propanoic acid
    —— Methyl 4-(n-pentylthio)phenyl sulfide 1443345-26-3 C12H18S2
    Methyl 4-(n-pentylthio)phenyl sulfide
    —— Cyclohexanamine, 3-[(3-chloro-2-pyridinyl)thio]-N-methyl- 1340283-23-9 C12H17ClN2S
    Cyclohexanamine, 3-[(3-chloro-2-pyridinyl)thio]-N-methyl-
    —— Cyclopentanamine, N-methyl-3-[(4-methyl-4H-1,2,4-triazol-3-yl)thio]- 1339208-95-5 C9H16N4S
    Cyclopentanamine, N-methyl-3-[(4-methyl-4H-1,2,4-triazol-3-yl)thio]-
    —— (2R)-2-[(2R)-2-methyl-3-phenylsulfanylpropyl]-2,3-dihydropyran-4-one 1373398-06-1 C15H18O2S
    (2R)-2-[(2R)-2-methyl-3-phenylsulfanylpropyl]-2,3-dihydropyran-4-one
    —— 4-benzylsulfanyl-2-methyl-1,3-thiazole 1382676-17-6 C11H11NS2
    4-benzylsulfanyl-2-methyl-1,3-thiazole
    —— Cyclopentanamine, 3-[(3-bromo-2-pyridinyl)thio]- 1343158-96-2 C10H13BrN2S
    Cyclopentanamine, 3-[(3-bromo-2-pyridinyl)thio]-
    —— (2R,4S)-2-[(2R)-2-methyl-3-phenylsulfanylpropyl]-3,4-dihydro-2H-pyran-4-ol 1373398-07-2 C15H20O2S
    (2R,4S)-2-[(2R)-2-methyl-3-phenylsulfanylpropyl]-3,4-dihydro-2H-pyran-4-ol
    —— (3R)-3-methyl-4-phenylsulfanylbutanal 1373398-04-9 C11H14OS
    (3R)-3-methyl-4-phenylsulfanylbutanal