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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-amino-4-methyl-6-oxopyrimidin-2-ylthioacetic acid hydrazide 143424-50-4 C7H11N5O2S
    1-amino-4-methyl-6-oxopyrimidin-2-ylthioacetic acid hydrazide
    —— 1-methyl-7-phenylthio-2-trimethylsilylindole 82053-03-0 C18H21NSSi
    1-methyl-7-phenylthio-2-trimethylsilylindole
    —— 1-amino-4-methyl-6-oxopyrimidin-2-ylthioacetic acid 143424-41-3 C7H9N3O3S
    1-amino-4-methyl-6-oxopyrimidin-2-ylthioacetic acid
    —— Ethyl 2-(1-amino-4-methyl-6-oxopyrimidin-2-yl)sulfanylacetate 143424-46-8 C9H13N3O3S
    Ethyl 2-(1-amino-4-methyl-6-oxopyrimidin-2-yl)sulfanylacetate
    —— Ethyl 7-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]heptanoate 40107-52-6 C13H21NO2S2
    Ethyl 7-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]heptanoate
    —— 2-(4-aminophenylthio)-quinoline 190331-31-8 C15H12N2S
    2-(4-aminophenylthio)-quinoline
    —— 1,7-dithiaspiro<5.5>undecane 59871-44-2 C9H16S2
    1,7-dithiaspiro<5.5>undecane
    —— 3-Methyl-4-phenylsulfanylbut-3-en-2-ol 112449-88-4 C11H14OS
    3-Methyl-4-phenylsulfanylbut-3-en-2-ol
    —— 3-formyl-2,2,5,5-tetramethyl-4-phenylthio-2,5-dihydro-1H-pyrrol-1-yloxyl radical 215956-73-3 C15H18NO2S
    3-formyl-2,2,5,5-tetramethyl-4-phenylthio-2,5-dihydro-1H-pyrrol-1-yloxyl radical
    —— 2-Ethylhexyl 2-cyano-2-[2-[1-cyano-2-(2-ethylhexoxy)-2-oxoethylidene]-4,8-dihydroxy-[1,3]dithiolo[4,5-f][1,3]benzodithiol-6-ylidene]acetate 1118625-27-6 C30H36N2O6S4
    2-Ethylhexyl 2-cyano-2-[2-[1-cyano-2-(2-ethylhexoxy)-2-oxoethylidene]-4,8-dihydroxy-[1,3]dithiolo[4,5-f][1,3]benzodithiol-6-ylidene]acetate
    —— 3-(hydroxymethyl)-2,2,5,5-tetramethyl-4-phenylthio-2,5-dihydro-1H-pyrrol-1-yloxyl radical 215956-75-5 C15H20NO2S
    3-(hydroxymethyl)-2,2,5,5-tetramethyl-4-phenylthio-2,5-dihydro-1H-pyrrol-1-yloxyl radical
    —— 1-[(5-benzyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-(cyclohexylamino)propan-2-ol 134744-85-7 C18H26N4OS
    1-[(5-benzyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-(cyclohexylamino)propan-2-ol
    —— 2-[2-(4-Fluorophenyl)ethenyl]-3-phenylsulfanylquinoxaline 366018-63-5 C22H15FN2S
    2-[2-(4-Fluorophenyl)ethenyl]-3-phenylsulfanylquinoxaline
    —— phenyl 2-deoxy-4-O-(4'-N'-monodemethyl-N'-trichloroethoxycarbamoyl-β-D-forosaminyl)-2-N-methyl-N-trichloroethoxycarbamoyl-1-thio-α-D-xylopyranoside 1342295-18-4 C25H32Cl6N2O8S
    phenyl 2-deoxy-4-O-(4'-N'-monodemethyl-N'-trichloroethoxycarbamoyl-β-D-forosaminyl)-2-N-methyl-N-trichloroethoxycarbamoyl-1-thio-α-D-xylopyranoside
    —— 2,3-Dihydro-3-methylbenzothiophene-2-carboxylic acid 230293-45-5 C10H10O2S
    2,3-Dihydro-3-methylbenzothiophene-2-carboxylic acid
    —— 5-methyl-3-(phenylthio)-4,5-dihydrothiophene 1,1-dioxide 104664-91-7 C11H12O2S2
    5-methyl-3-(phenylthio)-4,5-dihydrothiophene 1,1-dioxide
    —— 2-methyl-4-(phenylthio)-4,5-dihydrothiophene 1,1-dioxide 104664-87-1 C11H12O2S2
    2-methyl-4-(phenylthio)-4,5-dihydrothiophene 1,1-dioxide
    —— phenyl 2-deoxy-2-N-methyl-N-trichloroethoxycarbamoyl-1-thio-α-D-xylopyranoside 1342295-14-0 C15H18Cl3NO5S
    phenyl 2-deoxy-2-N-methyl-N-trichloroethoxycarbamoyl-1-thio-α-D-xylopyranoside
    —— phenyl 2-azido-2-deoxy-3,4-di-O-diethylisopropylsilyl-1-thio-α-D-xylopyranoside 1342295-10-6 C25H45N3O3SSi2
    phenyl 2-azido-2-deoxy-3,4-di-O-diethylisopropylsilyl-1-thio-α-D-xylopyranoside
    —— 2-[2-(Carboxymethyl)phenyl]sulfanyl-2-methylpropanoic acid 81549-12-4 C12H14O4S
    2-[2-(Carboxymethyl)phenyl]sulfanyl-2-methylpropanoic acid
    —— 6-(2,4-difluorophenyl)-3-methyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine 832737-52-7 C11H8F2N4S
    6-(2,4-difluorophenyl)-3-methyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— 4,4-dimethyl-5-<(phenylthio)methyl>-1,3-dioxane 146668-34-0 C13H18O2S
    4,4-dimethyl-5-<(phenylthio)methyl>-1,3-dioxane
    —— 5-[(4-Bromophenyl)sulfanyl]-2-thiophenecarbaldehyde 886361-55-3 C11H7BrOS2
    5-[(4-Bromophenyl)sulfanyl]-2-thiophenecarbaldehyde
    —— 2-oxo-3-(4-pyridylthio)propane 172287-75-1 C8H9NOS
    2-oxo-3-(4-pyridylthio)propane
    —— (R)-(+)-1-(4-pyridylthio)propan-2-yl acetate 464934-57-4 C10H13NO2S
    (R)-(+)-1-(4-pyridylthio)propan-2-yl acetate
    —— 1-(2-Methyl-1,3-dithian-2-yl)propan-2-ol 1131229-39-4 C8H16OS2
    1-(2-Methyl-1,3-dithian-2-yl)propan-2-ol
    —— 4-((6-((6-bromo-[1,2,4]triazolo[4,3-a]pyridin-3-yl)thio)quinolin-3-yl)methyl)morpholine 1427474-77-8 C20H18BrN5OS
    4-((6-((6-bromo-[1,2,4]triazolo[4,3-a]pyridin-3-yl)thio)quinolin-3-yl)methyl)morpholine
    —— methyl (2-phenylthioethyl)carbamate 91012-35-0 C10H13NO2S
    methyl (2-phenylthioethyl)carbamate
    —— 4-((6-((6-(1-ethoxyvinyl)-[1,2,4]triazolo[4,3-a]pyridin-3-yl)thio)quinolin-3-yl)methyl)morpholine 1427474-78-9 C24H25N5O2S
    4-((6-((6-(1-ethoxyvinyl)-[1,2,4]triazolo[4,3-a]pyridin-3-yl)thio)quinolin-3-yl)methyl)morpholine
    —— 2,4-bis-methylsulfanyl-aniline 57946-71-1 C8H11NS2
    2,4-bis-methylsulfanyl-aniline
    —— 4-(1-ethoxyvinyl)-2-methylsulfanylpyrimidine 521092-40-0 C9H12N2OS
    4-(1-ethoxyvinyl)-2-methylsulfanylpyrimidine
    —— methyl (E)-4-(4-dimethylaminophenylsulfanyl)-2-methyl-2-pentenoate 875737-07-8 C15H21NO2S
    methyl (E)-4-(4-dimethylaminophenylsulfanyl)-2-methyl-2-pentenoate
    —— (2E,4E)-ethyl 6-(4-dimethylaminophenylsulfanyl)-4-methyl-2,4-heptadienoate 698387-93-8 C18H25NO2S
    (2E,4E)-ethyl 6-(4-dimethylaminophenylsulfanyl)-4-methyl-2,4-heptadienoate
    —— (E)-4-(4-dimethylaminophenylsulfanyl)-2-methyl-2-penten-1-ol 875737-08-9 C14H21NOS
    (E)-4-(4-dimethylaminophenylsulfanyl)-2-methyl-2-penten-1-ol
    —— Allylthiocarbaminsaeure-butylester 90204-55-0 C8H15NOS
    Allylthiocarbaminsaeure-butylester
    —— Ethyl 2-((4-cyclopropyl-6-(difluoromethyl)pyrimidin-2-yl)thio)acetate 886498-18-6 C12H14F2N2O2S
    Ethyl 2-((4-cyclopropyl-6-(difluoromethyl)pyrimidin-2-yl)thio)acetate
    —— S-(2,3-dihydrothieno[3,4-b][1,4]oxathiin-3-yl)-methyl 4,4,5,5,5-pentafluoropentanethioate 1333236-78-4 C12H11F5O2S3
    S-(2,3-dihydrothieno[3,4-b][1,4]oxathiin-3-yl)-methyl 4,4,5,5,5-pentafluoropentanethioate
    —— <2-(1-propynyl)cyclohexen-1-yl>thioacetic acid 77416-32-1 C11H14O2S
    <2-(1-propynyl)cyclohexen-1-yl>thioacetic acid
    —— 7-((phenyl)thio)-3,5-dihydro-4H-pyrrolo[3,2-d]pyrimidin-4-one 266347-91-5 C12H9N3OS
    7-((phenyl)thio)-3,5-dihydro-4H-pyrrolo[3,2-d]pyrimidin-4-one
    —— (4aR)-4a,5-dimethyl-1-(phenylsulfanylmethyl)-3,4,7,8-tetrahydronaphthalen-2-one 196709-87-2 C19H22OS
    (4aR)-4a,5-dimethyl-1-(phenylsulfanylmethyl)-3,4,7,8-tetrahydronaphthalen-2-one
    —— 2-[(5-Amino-1,3,4-thiadiazol-2-YL)thio]-N-cyclopropylacetamide 876532-11-5 C7H10N4OS2
    2-[(5-Amino-1,3,4-thiadiazol-2-YL)thio]-N-cyclopropylacetamide
    —— α-(phenylthio)-β-vinylbutyrolactone 81470-06-6 C12H12O2S
    α-(phenylthio)-β-vinylbutyrolactone
    —— 2-(2-chloro-benzylidene)-benzo[<i>b</i>]thiophen-3-one 93986-77-7 C15H9ClOS
    2-(2-chloro-benzylidene)-benzo[<i>b</i>]thiophen-3-one
    —— 2-[(5-Amino-1,3,4-thiadiazol-2-yl)thio]-N-(1-ethylpropyl)acetamide 875911-70-9 C9H16N4OS2
    2-[(5-Amino-1,3,4-thiadiazol-2-yl)thio]-N-(1-ethylpropyl)acetamide
    —— 2-(4-chloro-benzylidene)-benzo[<i>b</i>]thiophen-3-one 3139-46-6 C15H9ClOS
    2-(4-chloro-benzylidene)-benzo[<i>b</i>]thiophen-3-one
    —— 2-(4-methyl-benzylidene)-benzo[<i>b</i>]thiophen-3-one 3139-43-3 C16H12OS
    2-(4-methyl-benzylidene)-benzo[<i>b</i>]thiophen-3-one
    —— JFD 00191 357163-75-8 C15H9FOS
    JFD 00191
    —— 2-[2-methyl-4-(phenylthio)-5,6,7,8-tetrahydro[1]benzothieno[2,3-b]pyridin-3-yl]-2-tert-butoxyacetic acid 1256256-80-0 C24H27NO3S2
    2-[2-methyl-4-(phenylthio)-5,6,7,8-tetrahydro[1]benzothieno[2,3-b]pyridin-3-yl]-2-tert-butoxyacetic acid
    —— methyl 2-[2-methyl-4-(phenylthio)-5,6,7,8-tetrahydro[1]benzothieno[2,3-b]pyridin-3-yl]-2-tert-butoxyacetate 1256256-78-6 C25H29NO3S2
    methyl 2-[2-methyl-4-(phenylthio)-5,6,7,8-tetrahydro[1]benzothieno[2,3-b]pyridin-3-yl]-2-tert-butoxyacetate
    —— N-[[2-(acetamidomethylsulfanylmethyl)-3-hydroxypropyl]sulfanylmethyl]acetamide 1056901-07-5 C10H20N2O3S2
    N-[[2-(acetamidomethylsulfanylmethyl)-3-hydroxypropyl]sulfanylmethyl]acetamide