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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4-hydroxy-6-methyl-bis(3,5-phenylthiomethyl)-2-pyrone 106148-35-0 C20H18O3S2
    4-hydroxy-6-methyl-bis(3,5-phenylthiomethyl)-2-pyrone
    —— 6-[(1-methyl-1H-imidazol-2-yl)sulfanyl]-3-pyridinesulfonamide 96591-89-8 C9H10N4O2S2
    6-[(1-methyl-1H-imidazol-2-yl)sulfanyl]-3-pyridinesulfonamide
    —— 3,3,4,4-tetracyan-2-methylthio-2-octanoyltetrahydrothiophene 129206-09-3 C17H20N4OS2
    3,3,4,4-tetracyan-2-methylthio-2-octanoyltetrahydrothiophene
    —— 2-acetylamino-5-(1-methylimidazol-2-ylthio)thiazole 133691-64-2 C9H10N4OS2
    2-acetylamino-5-(1-methylimidazol-2-ylthio)thiazole
    —— 2-acetylamino-5-(4-methoxyphenylthio)thiazole 133691-85-7 C12H12N2O2S2
    2-acetylamino-5-(4-methoxyphenylthio)thiazole
    —— 2-amino-5-(1-methylimidazol-2-ylthio)thiazole 133691-65-3 C7H8N4S2
    2-amino-5-(1-methylimidazol-2-ylthio)thiazole
    —— 2-acetylamino-5-(pyridin-4-ylthio)thiazole 133691-52-8 C10H9N3OS2
    2-acetylamino-5-(pyridin-4-ylthio)thiazole
    —— 2[[4-(Trifluoromethyl)phenyl]thio]-1-methyl-1H-imidazole hydrochloride 133303-83-0 C11H9F3N2S*ClH
    2[[4-(Trifluoromethyl)phenyl]thio]-1-methyl-1H-imidazole hydrochloride
    —— 2-acetylamino-5-(1-methyl-1H-tetrazol-5-ylthio)thiazole 133691-89-1 C7H8N6OS2
    2-acetylamino-5-(1-methyl-1H-tetrazol-5-ylthio)thiazole
    —— 4-({3-Chloro-4-[(1-methyl-1H-imidazol-2-yl)thio]phenyl}amino)thieno[2,3-b]pyridine-5-carbonitrile 700844-38-8 C18H12ClN5S2
    4-({3-Chloro-4-[(1-methyl-1H-imidazol-2-yl)thio]phenyl}amino)thieno[2,3-b]pyridine-5-carbonitrile
    —— 2-amino-6-methyl-5-[(1-methylimidazol-2-yl)sulfanyl]-3,4-dihydro-4-oxo-7H-pyrrolo[2,3-d]pyrimidine 1224514-04-8 C11H12N6OS
    2-amino-6-methyl-5-[(1-methylimidazol-2-yl)sulfanyl]-3,4-dihydro-4-oxo-7H-pyrrolo[2,3-d]pyrimidine
    —— 1-(1-Methylimidazol-2-sulfenyl)methyl-5-chloropyrimidin-2-one 83768-24-5 C9H9ClN4OS
    1-(1-Methylimidazol-2-sulfenyl)methyl-5-chloropyrimidin-2-one
    —— 3-[N-methylimidazol-2-ylthio]benzo[b]selenophene-2-carboxylic acid ethyl ester 1314236-08-2 C15H14N2O2SSe
    3-[N-methylimidazol-2-ylthio]benzo[b]selenophene-2-carboxylic acid ethyl ester
    —— 1-[1-(4-chloro-phenyl)-cyclobutyl]-2-(1-methyl-1H-imidazol-2-ylsulfanyl)-ethanone 1185752-14-0 C16H17ClN2OS
    1-[1-(4-chloro-phenyl)-cyclobutyl]-2-(1-methyl-1H-imidazol-2-ylsulfanyl)-ethanone
    —— 1-[1-(4-chloro-phenyl)-cyclohexyl]-2-(1-methyl-1H-imidazol-2-ylsulfanyl)-ethanone 1185752-38-8 C18H21ClN2OS
    1-[1-(4-chloro-phenyl)-cyclohexyl]-2-(1-methyl-1H-imidazol-2-ylsulfanyl)-ethanone
    —— 6-[(1-methyl-1H-imidazol-2-yl)sulfanyl]pyridin-3-amine 96592-24-4 C9H10N4S
    6-[(1-methyl-1H-imidazol-2-yl)sulfanyl]pyridin-3-amine
    —— 5-[(1-methyl-1H-imidazol-2-yl)thio]-1H-indazole-3-amine 1093966-87-0 C11H11N5S
    5-[(1-methyl-1H-imidazol-2-yl)thio]-1H-indazole-3-amine
    —— 2,5-dimethyl-N-{6-[(1-methyl-1H-imidazol-2-yl)thio]imidazo[1,2-b]pyridazin-2-yl}-3-furamide 1005779-65-6 C17H16N6O2S
    2,5-dimethyl-N-{6-[(1-methyl-1H-imidazol-2-yl)thio]imidazo[1,2-b]pyridazin-2-yl}-3-furamide
    —— 2-chloro-4-nitrophenyl 1-methylimidazol-2-yl sulphide 133303-87-4 C10H8ClN3O2S
    2-chloro-4-nitrophenyl 1-methylimidazol-2-yl sulphide
    —— 2-((difluoromethyl)thio)-1-methyl-1H-imidazole 1355729-66-6 C5H6F2N2S
    2-((difluoromethyl)thio)-1-methyl-1H-imidazole
    —— 5-(1-methyl-1H-imidazol-2-ylthio)-4-fluoro-2-nitrobenzenamine 849236-50-6 C10H9FN4O2S
    5-(1-methyl-1H-imidazol-2-ylthio)-4-fluoro-2-nitrobenzenamine
    —— 2-(2-methoxyphenylsulfanyl)-N-methylimidazole 1032690-47-3 C11H12N2OS
    2-(2-methoxyphenylsulfanyl)-N-methylimidazole
    —— 1-[1-(4-chloro-phenyl)-cyclopropyl]-2-(pyridin-2-ylsulfanyl)-ethanone 1185751-95-4 C16H14ClNOS
    1-[1-(4-chloro-phenyl)-cyclopropyl]-2-(pyridin-2-ylsulfanyl)-ethanone
    —— 1-[1-(4-chloro-phenyl)-cyclohexyl]-2-(pyridin-2-ylsulfanyl)-ethanone 1185752-45-7 C19H20ClNOS
    1-[1-(4-chloro-phenyl)-cyclohexyl]-2-(pyridin-2-ylsulfanyl)-ethanone
    —— 1-(1-(4-chlorophenyl)cyclopropyl)-2-(4-methyl-4H-1,2,4-triazol-3-ylthio)ethanone 1185752-93-5 C14H14ClN3OS
    1-(1-(4-chlorophenyl)cyclopropyl)-2-(4-methyl-4H-1,2,4-triazol-3-ylthio)ethanone
    —— 1-[1-(4-chloro-phenyl)-cyclopentyl]-2-(1-methyl-1H-imidazol-2-ylsulfanyl)-ethanone 1185752-39-9 C17H19ClN2OS
    1-[1-(4-chloro-phenyl)-cyclopentyl]-2-(1-methyl-1H-imidazol-2-ylsulfanyl)-ethanone
    —— 1-[1-(4-chloro-phenyl)-cyclopropyl]-2-(1-methyl-1H-imidazol-2-ylsulfanyl)-ethanone 1185751-91-0 C15H15ClN2OS
    1-[1-(4-chloro-phenyl)-cyclopropyl]-2-(1-methyl-1H-imidazol-2-ylsulfanyl)-ethanone
    —— N,N-dibutyl-2,2,2-trifluoroethanethioamide 68506-68-3 C10H18F3NS
    N,N-dibutyl-2,2,2-trifluoroethanethioamide
    —— 4-methyl-2-methylthiopent-2-ene —— C7H14S
    4-methyl-2-methylthiopent-2-ene
    —— (1R,2S)-2-(tert-butylthio)-2-(2-pyridylthio)-1-(2,4,6-trimethylphenyl)ethanol 676328-60-2 C20H27NOS2
    (1R,2S)-2-(tert-butylthio)-2-(2-pyridylthio)-1-(2,4,6-trimethylphenyl)ethanol
    —— (1R,2S)-2-(tert-butylthio)-1-phenyl-2-(2-pyridylthio)ethanol 676328-56-6 C17H21NOS2
    (1R,2S)-2-(tert-butylthio)-1-phenyl-2-(2-pyridylthio)ethanol
    —— 2-{[(4-Aminophenyl)methyl]sulfanyl}aniline 74551-01-2 C13H14N2S
    2-{[(4-Aminophenyl)methyl]sulfanyl}aniline
    —— 5-amyl-5-butylthiotetrahydrofuran-2-one 120388-37-6 C13H24O2S
    5-amyl-5-butylthiotetrahydrofuran-2-one
    —— 7-chloro-3,4-dihydro-8-methyl-2H-1,5,2-benzo<f>dithiazepin-3-one 1,1-dioxide 220293-63-0 C9H8ClNO3S2
    7-chloro-3,4-dihydro-8-methyl-2H-1,5,2-benzo<f>dithiazepin-3-one 1,1-dioxide
    —— 3,4,5,6-tetrahydro-6-methyl-2-phenyl-2H-1,6-benzothiazocine 89569-12-0 C17H19NS
    3,4,5,6-tetrahydro-6-methyl-2-phenyl-2H-1,6-benzothiazocine
    —— 3,4,5,6-tetrahydro-2-phenyl-2H-1,6-benzothiazocine 56578-80-4 C16H17NS
    3,4,5,6-tetrahydro-2-phenyl-2H-1,6-benzothiazocine
    —— dodecyl vinyl sulfone 30719-66-5 C14H28O2S
    dodecyl vinyl sulfone
    —— 2-(acetoxymethyl)allyl phenylsulfide 182312-56-7 C12H14O2S
    2-(acetoxymethyl)allyl phenylsulfide
    —— 7-phenylsulfanyl-3,4-dihydro-2H-naphthalen-1-one 210972-10-4 C16H14OS
    7-phenylsulfanyl-3,4-dihydro-2H-naphthalen-1-one
    —— (Z)-3-methyl-1-(methylthio)-1-butene 102394-07-0 C6H12S
    (Z)-3-methyl-1-(methylthio)-1-butene
    —— 2-(dodecane-1-sulfonyl)-ethanol 24475-68-1 C14H30O3S
    2-(dodecane-1-sulfonyl)-ethanol
    —— <2-Chlor-aethyl>-dodecylsulfid 25543-42-4 C14H29ClS
    <2-Chlor-aethyl>-dodecylsulfid
    —— 7-Methylthio-2-phenyl-thiazolo<4,5-d>pyridazin 88469-79-8 C12H9N3S2
    7-Methylthio-2-phenyl-thiazolo<4,5-d>pyridazin
    —— 2-(3-chloro-4-methylsulfanylphenyl)-3-cyclopentylpropionic acid 300355-16-2 C15H19ClO2S
    2-(3-chloro-4-methylsulfanylphenyl)-3-cyclopentylpropionic acid
    —— 2-{[(4-chloro-2-ethylpyridin-3-yl)methyl]sulfanyl}-6-(trifluoromethyl)pyrimidin-4-ol 1256559-38-2 C13H11ClF3N3OS
    2-{[(4-chloro-2-ethylpyridin-3-yl)methyl]sulfanyl}-6-(trifluoromethyl)pyrimidin-4-ol
    —— 2-Izopropylthio-6-methyluracil 57200-30-3 C8H12N2OS
    2-Izopropylthio-6-methyluracil
    —— 2-{[(5-amino-2-chlorophenyl)methyl]sulfanyl}-6-methylpyrimidin-4-ol 1097809-33-0 C12H12ClN3OS
    2-{[(5-amino-2-chlorophenyl)methyl]sulfanyl}-6-methylpyrimidin-4-ol
    —— 2-({[4-chloro-2-(propan-2-yl)pyridin-3-yl]methyl}sulfanyl)-6-methylpyrimidin-4-ol hydrochloride 1256558-66-3 C14H16ClN3OS*ClH
    2-({[4-chloro-2-(propan-2-yl)pyridin-3-yl]methyl}sulfanyl)-6-methylpyrimidin-4-ol hydrochloride
    —— 2-{[(3-ethylpyridin-4-yl)methyl]sulfanyl}-6-methylpyrimidin-4-ol hydrochloride 1256558-80-1 C13H15N3OS*ClH
    2-{[(3-ethylpyridin-4-yl)methyl]sulfanyl}-6-methylpyrimidin-4-ol hydrochloride
    —— 2-{[(2,4-diethylpyridin-3-yl)methyl]sulfanyl}-6-methylpyrimidin-4-ol hydrochloride 1256558-69-6 C15H19N3OS*ClH
    2-{[(2,4-diethylpyridin-3-yl)methyl]sulfanyl}-6-methylpyrimidin-4-ol hydrochloride