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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-[4-(methylthio)phenyl]propionitrile 672952-68-0 C10H11NS
    3-[4-(methylthio)phenyl]propionitrile
    —— N~2~,N~2~-Diphenyl-6-(phenylsulfanyl)-1,3,5-triazine-2,4-diamine 30360-87-3 C21H17N5S
    N~2~,N~2~-Diphenyl-6-(phenylsulfanyl)-1,3,5-triazine-2,4-diamine
    —— 3H-1,2,4-Oxadithiine 290-73-3 C3H4OS2
    3H-1,2,4-Oxadithiine
    —— 1,6-Dithia-3,8-diazaspiro[4.4]nonane-4,9-dione 26933-64-2 C5H6N2O2S2
    1,6-Dithia-3,8-diazaspiro[4.4]nonane-4,9-dione
    —— 1,3,4-Oxadithiolane 24987-50-6 C2H4OS2
    1,3,4-Oxadithiolane
    —— p-Dithiino(2.3-b)pyrazin-2.3-dicarbonitril 50869-11-9 C8H2N4S2
    p-Dithiino(2.3-b)pyrazin-2.3-dicarbonitril
    —— 2H,6H-1,5-Oxathiocine 292-96-6 C6H8OS
    2H,6H-1,5-Oxathiocine
    —— Tricyclo[3.3.1.1~3,7~]decane-1,3-dithiol 607741-81-1 C10H16S2
    Tricyclo[3.3.1.1~3,7~]decane-1,3-dithiol
    —— 1,10-Dithia-8-aza-(2,2)-metacyclophan 20044-82-0 C13H11NS2
    1,10-Dithia-8-aza-(2,2)-metacyclophan
    —— 1-Ethylsulfanylundecane 66577-30-8 C13H28S
    1-Ethylsulfanylundecane
    —— 1,3-Dichloro-6-[(4,6-dichlorohexyl)sulfanyl]hexane 114811-35-7 C12H22Cl4S
    1,3-Dichloro-6-[(4,6-dichlorohexyl)sulfanyl]hexane
    —— 2-pyridin-2-yl-3-(3,4,5-trimethoxyphenyl)sulfanyl-1H-indole 1337932-95-2 C22H20N2O3S
    2-pyridin-2-yl-3-(3,4,5-trimethoxyphenyl)sulfanyl-1H-indole
    —— 2-[3-(3,4,5-trimethoxyphenyl)sulfanyl-1H-indol-2-yl]-4,5-dihydro-1,3-oxazole 1416576-29-8 C20H20N2O4S
    2-[3-(3,4,5-trimethoxyphenyl)sulfanyl-1H-indol-2-yl]-4,5-dihydro-1,3-oxazole
    —— 2-(1H-indol-5-yl)-3-(3,4,5-trimethoxyphenyl)sulfanyl-1H-indole 1337933-00-2 C25H22N2O3S
    2-(1H-indol-5-yl)-3-(3,4,5-trimethoxyphenyl)sulfanyl-1H-indole
    —— 2-pyridin-3-yl-3-(3,4,5-trimethoxyphenyl)sulfanyl-1H-indole 1337932-98-5 C22H20N2O3S
    2-pyridin-3-yl-3-(3,4,5-trimethoxyphenyl)sulfanyl-1H-indole
    —— 2-[3-(3,4,5-trimethoxyphenyl)sulfanyl-1H-indol-2-yl]-1,3-thiazole 1337932-90-7 C20H18N2O3S2
    2-[3-(3,4,5-trimethoxyphenyl)sulfanyl-1H-indol-2-yl]-1,3-thiazole
    —— 6-[3-(3,4,5-trimethoxyphenyl)sulfanyl-1H-indol-2-yl]quinoline 1337933-01-3 C26H22N2O3S
    6-[3-(3,4,5-trimethoxyphenyl)sulfanyl-1H-indol-2-yl]quinoline
    —— Spiro[bicyclo[2.2.2]octane-2,2'-[1,3]dithiolane] 702-52-3 C10H16S2
    Spiro[bicyclo[2.2.2]octane-2,2'-[1,3]dithiolane]
    —— S-(Methylthiomethyl) 2-methylpropanethioate 77974-85-7 C6H12OS2
    S-(Methylthiomethyl) 2-methylpropanethioate
    —— 2-Chloro-2-(phenylsulfanyl)acetamide 7519-04-2 C8H8ClNOS
    2-Chloro-2-(phenylsulfanyl)acetamide
    —— Trimethyl-(2-phenylsulfanyl-1,3-thiazol-5-yl)silane 1319212-47-9 C12H15NS2Si
    Trimethyl-(2-phenylsulfanyl-1,3-thiazol-5-yl)silane
    —— Ethyl 4-(2-phenylsulfanyl-1,3-thiazol-4-yl)benzoate 1319212-64-0 C18H15NO2S2
    Ethyl 4-(2-phenylsulfanyl-1,3-thiazol-4-yl)benzoate
    —— Ethyl 4-(2-phenylsulfanyl-5-trimethylsilyl-1,3-thiazol-4-yl)benzoate 1319212-59-3 C21H23NO2S2Si
    Ethyl 4-(2-phenylsulfanyl-5-trimethylsilyl-1,3-thiazol-4-yl)benzoate
    —— Ethyl 4-(5-chloro-2-phenylsulfanyl-1,3-thiazol-4-yl)benzoate 1319212-62-8 C18H14ClNO2S2
    Ethyl 4-(5-chloro-2-phenylsulfanyl-1,3-thiazol-4-yl)benzoate
    —— 2-chloro-5-methoxy-4-(phenylthio)aniline 1303613-74-2 C13H12ClNOS
    2-chloro-5-methoxy-4-(phenylthio)aniline
    —— 4-(4-Chlorophenyl)sulfanyl-2-(trichloromethyl)quinazoline 1336930-54-1 C15H8Cl4N2S
    4-(4-Chlorophenyl)sulfanyl-2-(trichloromethyl)quinazoline
    —— THP-protected 3-fluorothiophenol 1316276-95-5 C11H13FOS
    THP-protected 3-fluorothiophenol
    —— 1-(Azetidin-1-yl)-2-(methanesulfonyl)ethan-1-one 1162262-03-4 C6H11NO3S
    1-(Azetidin-1-yl)-2-(methanesulfonyl)ethan-1-one
    —— 4,4,5,5-Tetramethyl-2-(2-(2,2,2-trifluoroethylthio)phenyl)-1,3,2-dioxaborolane 1026797-05-6 C14H18BF3O2S
    4,4,5,5-Tetramethyl-2-(2-(2,2,2-trifluoroethylthio)phenyl)-1,3,2-dioxaborolane
    —— 4,4,5,5-Tetramethyl-2-(4-(2,2,2-trifluoroethylthio)phenyl)-1,3,2-dioxaborolane 1026797-09-0 C14H18BF3O2S
    4,4,5,5-Tetramethyl-2-(4-(2,2,2-trifluoroethylthio)phenyl)-1,3,2-dioxaborolane
    —— (R)-1-(4-(Methylthio)phenyl)ethanamine hydrochloride 1217456-30-8 C9H14ClNS
    (R)-1-(4-(Methylthio)phenyl)ethanamine hydrochloride
    —— 1,4-Dithia-7-azaspiro[4.4]nonan-7-amine;hydrochloride 1261999-19-2 C6H13ClN2S2
    1,4-Dithia-7-azaspiro[4.4]nonan-7-amine;hydrochloride
    —— (3xi)-3,5-Di-O-acetyl-N-{[5-cyano-6-(phenylsulfanyl)pyridine-3-carbonyl]carbamoyl}-2-deoxy-beta-D-glycero-pentofuranosylamine 1207756-46-4 C23H22N4O7S
    (3xi)-3,5-Di-O-acetyl-N-{[5-cyano-6-(phenylsulfanyl)pyridine-3-carbonyl]carbamoyl}-2-deoxy-beta-D-glycero-pentofuranosylamine
    —— (3xi)-3,5-Di-O-acetyl-N-({5-cyano-6-[(4-fluorophenyl)sulfanyl]pyridine-3-carbonyl}carbamoyl)-2-deoxy-beta-D-glycero-pentofuranosylamine 1207756-58-8 C23H21FN4O7S
    (3xi)-3,5-Di-O-acetyl-N-({5-cyano-6-[(4-fluorophenyl)sulfanyl]pyridine-3-carbonyl}carbamoyl)-2-deoxy-beta-D-glycero-pentofuranosylamine
    —— 2-(m-Tolylthio)-6-chloropyridine 1242241-04-8 C12H10ClNS
    2-(m-Tolylthio)-6-chloropyridine
    —— (3xi)-N-({5-Cyano-6-[(4-fluorophenyl)sulfanyl]pyridine-3-carbonyl}carbamoyl)-2-deoxy-beta-D-glycero-pentofuranosylamine 1207756-61-3 C19H17FN4O5S
    (3xi)-N-({5-Cyano-6-[(4-fluorophenyl)sulfanyl]pyridine-3-carbonyl}carbamoyl)-2-deoxy-beta-D-glycero-pentofuranosylamine
    —— (3xi)-3,5-Di-O-acetyl-N-({5-cyano-6-[(4-methylphenyl)sulfanyl]pyridine-3-carbonyl}carbamoyl)-2-deoxy-beta-D-glycero-pentofuranosylamine 1207756-50-0 C24H24N4O7S
    (3xi)-3,5-Di-O-acetyl-N-({5-cyano-6-[(4-methylphenyl)sulfanyl]pyridine-3-carbonyl}carbamoyl)-2-deoxy-beta-D-glycero-pentofuranosylamine
    —— (3xi)-N-({5-Cyano-6-[(4-methylphenyl)sulfanyl]pyridine-3-carbonyl}carbamoyl)-2-deoxy-beta-D-glycero-pentofuranosylamine 1207756-52-2 C20H20N4O5S
    (3xi)-N-({5-Cyano-6-[(4-methylphenyl)sulfanyl]pyridine-3-carbonyl}carbamoyl)-2-deoxy-beta-D-glycero-pentofuranosylamine
    —— (3xi)-N-{[5-Cyano-6-(phenylsulfanyl)pyridine-3-carbonyl]carbamoyl}-2-deoxy-beta-D-glycero-pentofuranosylamine 1207756-48-6 C19H18N4O5S
    (3xi)-N-{[5-Cyano-6-(phenylsulfanyl)pyridine-3-carbonyl]carbamoyl}-2-deoxy-beta-D-glycero-pentofuranosylamine
    —— N-carbamoyl-5-cyano-6-(phenylthio)nicotinamide 1207756-66-8 C14H10N4O2S
    N-carbamoyl-5-cyano-6-(phenylthio)nicotinamide
    —— (3xi)-3,5-Di-O-acetyl-N-({6-[(4-chlorophenyl)sulfanyl]-5-cyanopyridine-3-carbonyl}carbamoyl)-2-deoxy-beta-D-glycero-pentofuranosylamine 1214729-09-5 C23H21ClN4O7S
    (3xi)-3,5-Di-O-acetyl-N-({6-[(4-chlorophenyl)sulfanyl]-5-cyanopyridine-3-carbonyl}carbamoyl)-2-deoxy-beta-D-glycero-pentofuranosylamine
    —— (3xi)-N-({6-[(4-Chlorophenyl)sulfanyl]-5-cyanopyridine-3-carbonyl}carbamoyl)-2-deoxy-beta-D-glycero-pentofuranosylamine 1214729-12-0 C19H17ClN4O5S
    (3xi)-N-({6-[(4-Chlorophenyl)sulfanyl]-5-cyanopyridine-3-carbonyl}carbamoyl)-2-deoxy-beta-D-glycero-pentofuranosylamine
    —— N~8~-(Cyclopropylmethyl)-2-(2,6-Diazaspiro[3.3]hept-2-Yl)-N~4~-[2-(Methylsulfanyl)phenyl]pyrimido[5,4-D]pyrimidine-4,8-Diamine 1303470-34-9 C22H26N8S
    N~8~-(Cyclopropylmethyl)-2-(2,6-Diazaspiro[3.3]hept-2-Yl)-N~4~-[2-(Methylsulfanyl)phenyl]pyrimido[5,4-D]pyrimidine-4,8-Diamine
    —— Carbamic acid, [5-[(phenylmethyl)thio]-1,3,4-thiadiazol-2-yl]-, ethyl ester 157369-89-6 C12H13N3O2S2
    Carbamic acid, [5-[(phenylmethyl)thio]-1,3,4-thiadiazol-2-yl]-, ethyl ester
    —— N-{2-[(2,3-difluorobenzyl)thio]-6-methoxypyrimidin-4-yl}-4-morpholin-4-ylpiperidine-1-sulfonamide 878388-22-8 C21H27F2N5O4S2
    N-{2-[(2,3-difluorobenzyl)thio]-6-methoxypyrimidin-4-yl}-4-morpholin-4-ylpiperidine-1-sulfonamide
    —— 4-(cyclopropylamino)-N-{2-[(2,3-difluorobenzyl)thio]-6-methoxypyrimidin-4-yl}piperidine-1-sulfonamide 878388-29-5 C20H25F2N5O3S2
    4-(cyclopropylamino)-N-{2-[(2,3-difluorobenzyl)thio]-6-methoxypyrimidin-4-yl}piperidine-1-sulfonamide
    —— 3-sulfinylhexane 133619-40-6 C6H12OS
    3-sulfinylhexane
    —— N-(2-hydroxyethyl)propanethioamide 77706-73-1 C5H11NOS
    N-(2-hydroxyethyl)propanethioamide
    —— 2-[(Dimethylamino)(phenyl)methylidene]-1-benzothiophen-3(2H)-one 77946-59-9 C17H15NOS
    2-[(Dimethylamino)(phenyl)methylidene]-1-benzothiophen-3(2H)-one
    —— methyl N-[N-methoxycarbonyl-N'-[2-(pentanoylamino)-4-phenylsulfanylphenyl]carbamimidoyl]carbamate 73857-17-7 C22H26N4O5S
    methyl N-[N-methoxycarbonyl-N'-[2-(pentanoylamino)-4-phenylsulfanylphenyl]carbamimidoyl]carbamate