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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— ethyl 2-(4,6-dihydroxypyrimidin-2-ylthio)butanoate 916482-21-8 C10H14N2O4S
    ethyl 2-(4,6-dihydroxypyrimidin-2-ylthio)butanoate
    —— ethyl [6-(methylsulfanyl)pyridin-3-yl]acetate 1080060-39-4 C10H13NO2S
    ethyl [6-(methylsulfanyl)pyridin-3-yl]acetate
    —— Ethyl-2-chloro-2-[1,3-dihydro-pyrido(2,3-b)(1,4)thiazine-2-ilidene]acetate 103089-91-4 C11H11ClN2O2S
    Ethyl-2-chloro-2-[1,3-dihydro-pyrido(2,3-b)(1,4)thiazine-2-ilidene]acetate
    —— 2-Bromo-3-(phenylsulfanylmethyl)pyridine 1207736-72-8 C12H10BrNS
    2-Bromo-3-(phenylsulfanylmethyl)pyridine
    —— (3,4,5-trifluorophenyl)-4-hydroxyphenylsulfide 1229514-40-2 C12H7F3OS
    (3,4,5-trifluorophenyl)-4-hydroxyphenylsulfide
    —— 3,5,3',5'-tetramethyl-2,2'-sulfanediyl-di-phenol 17074-66-7 C16H18O2S
    3,5,3',5'-tetramethyl-2,2'-sulfanediyl-di-phenol
    —— 2-hydroxypropyl methanethiolsulfonate 30388-01-3 C4H10O3S2
    2-hydroxypropyl methanethiolsulfonate
    —— bis(2-hydroxyisopropyl) disulfide 33179-12-3 C6H14O2S2
    bis(2-hydroxyisopropyl) disulfide
    —— n-hexyl methyl sulfoxide 1561-73-5 C7H16OS
    n-hexyl methyl sulfoxide
    —— methyl hexyl sulfone 89851-52-5 C7H16O2S
    methyl hexyl sulfone
    —— 1-methoxycarbonylsulfanyl-hexane 17659-15-3 C8H16O2S
    1-methoxycarbonylsulfanyl-hexane
    —— azocane-1-carbothioic acid amide 68881-67-4 C8H16N2S
    azocane-1-carbothioic acid amide
    —— cyclohexyl-(5-ethylsulfanyl-[1,3,4]thiadiazol-2-yl)-amine 73311-13-4 C10H17N3S2
    cyclohexyl-(5-ethylsulfanyl-[1,3,4]thiadiazol-2-yl)-amine
    —— 2-(methylthio)-3-allylpyrimidin-4(3H)-one 94731-94-9 C8H10N2OS
    2-(methylthio)-3-allylpyrimidin-4(3H)-one
    —— 4(1H)-Pyrimidinone, 5-methyl-2-(2-propenylthio)- 94731-76-7 C8H10N2OS
    4(1H)-Pyrimidinone, 5-methyl-2-(2-propenylthio)-
    —— 1-(5-ethyl-2-ethylmercapto-[3]thienyl)-ethanone 103386-04-5 C10H14OS2
    1-(5-ethyl-2-ethylmercapto-[3]thienyl)-ethanone
    —— 1-Methyl-4-(2-(phenylthio)benzyl)piperazine maleate 37652-48-5 C22H26N2O4S
    1-Methyl-4-(2-(phenylthio)benzyl)piperazine maleate
    —— bis(tert-butylthio)cyclopropenone 19307-77-8 C11H18OS2
    bis(tert-butylthio)cyclopropenone
    —— 5-bromo-1-(4-fluorophenylsulfenyl)methyl-2(1H)-pyrimidinone 83768-18-7 C11H8BrFN2OS
    5-bromo-1-(4-fluorophenylsulfenyl)methyl-2(1H)-pyrimidinone
    —— 5-bromo-2-(4-fluorophenylsulfenyl)methyloxypyrimidine 83768-17-6 C11H8BrFN2OS
    5-bromo-2-(4-fluorophenylsulfenyl)methyloxypyrimidine
    —— 2-amino-9-(2-isopropoxy-ethyl)-8-(2-chloro-3,4,5-trimethoxy-phenylsulfanyl)adenine 852030-68-3 C19H25ClN6O4S
    2-amino-9-(2-isopropoxy-ethyl)-8-(2-chloro-3,4,5-trimethoxy-phenylsulfanyl)adenine
    —— 2-Fluoro-9-pent-4-ynyl-8-(3,4,5-trimethoxy-phenylsulfanyl)-9H-purin-6-ylamine 852030-55-8 C19H20FN5O3S
    2-Fluoro-9-pent-4-ynyl-8-(3,4,5-trimethoxy-phenylsulfanyl)-9H-purin-6-ylamine
    —— N-tricyclo[3.3.1.0-3,7-]non-3-ylthiourea 870707-54-3 C10H16N2S
    N-tricyclo[3.3.1.0-3,7-]non-3-ylthiourea
    —— 2-amino-9-butyl-8-(2-chloro-3,4,5-trimethoxy-phenylsulfanyl)adenine 852030-67-2 C18H23ClN6O3S
    2-amino-9-butyl-8-(2-chloro-3,4,5-trimethoxy-phenylsulfanyl)adenine
    —— 2-amino-9-(2-isopropoxy-ethyl)-8-(3,4,5-trimethoxy-phenylsulfanyl)adenine 852030-66-1 C19H26N6O4S
    2-amino-9-(2-isopropoxy-ethyl)-8-(3,4,5-trimethoxy-phenylsulfanyl)adenine
    —— 1-(4-chloro-phenylsulfanyl)-cyclobutanecarboxylic acid ethyl ester 1004769-98-5 C13H15ClO2S
    1-(4-chloro-phenylsulfanyl)-cyclobutanecarboxylic acid ethyl ester
    —— 2-fluoro-8-(3,4,5-trimethoxy-phenylsulfanyl)adenine 852030-69-4 C14H14FN5O3S
    2-fluoro-8-(3,4,5-trimethoxy-phenylsulfanyl)adenine
    —— pyridazine-3,6-diylbissulfanyl-bis-acetic acid 89977-20-8 C8H8N2O4S2
    pyridazine-3,6-diylbissulfanyl-bis-acetic acid
    —— 10H-Pyrido(3,2-b)(1,4)benzothiazine-10-carbothioic acid, 8-fluoro-, S-(2-(diisopropylamino)ethyl) ester, maleate 63885-97-2 C44H52F2N6O6S4
    10H-Pyrido(3,2-b)(1,4)benzothiazine-10-carbothioic acid, 8-fluoro-, S-(2-(diisopropylamino)ethyl) ester, maleate
    —— 4-((2-((Dimethylamino)methyl)phenyl)thio)phenol (Z)-2-butenedioate (1:1) (salt) 127906-27-8 C19H21NO5S
    4-((2-((Dimethylamino)methyl)phenyl)thio)phenol (Z)-2-butenedioate (1:1) (salt)
    —— 2-((2,5-Dimethoxyphenyl)thio)benzenemethanamine (Z)-2-butenedioate (1:1) 127906-02-9 C19H21NO6S
    2-((2,5-Dimethoxyphenyl)thio)benzenemethanamine (Z)-2-butenedioate (1:1)
    —— (1S)-1-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]-3,3-bis(phenylsulfanyl)propan-1-ol 323582-35-0 C20H24O3S2
    (1S)-1-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]-3,3-bis(phenylsulfanyl)propan-1-ol
    —— 1-(1-Imino-2-(2-(phenylthio)phenyl)ethyl)-4-methylpiperazine dimaleate hydrate 117596-43-7 C27H31N3O8S
    1-(1-Imino-2-(2-(phenylthio)phenyl)ethyl)-4-methylpiperazine dimaleate hydrate
    —— 3-((2-((Methylamino)methyl)phenyl)thio)phenol (Z)-2-butenedioate (1:1) (salt) 127906-38-1 C18H19NO5S
    3-((2-((Methylamino)methyl)phenyl)thio)phenol (Z)-2-butenedioate (1:1) (salt)
    —— 2-<Bis(methylthio)methyl>cyclopent-1-one 103381-84-6 C8H14OS2
    2-<Bis(methylthio)methyl>cyclopent-1-one
    —— N,N-Dimethyl-2-(5-bromo-2-thienylthio)benzylamine maleate 134478-68-5 C17H18BrNO4S2
    N,N-Dimethyl-2-(5-bromo-2-thienylthio)benzylamine maleate
    —— 2-isopropyl-2-(2-formylethynyl)-1,3-dithiolane 1072800-71-5 C9H12OS2
    2-isopropyl-2-(2-formylethynyl)-1,3-dithiolane
    —— isopropyl (3-cyano-6-methyl-4-oxo-1,4-dihydro-2-pyridinyl)thioacetate 942895-04-7 C12H14N2O3S
    isopropyl (3-cyano-6-methyl-4-oxo-1,4-dihydro-2-pyridinyl)thioacetate
    —— methyl (6-methyl-2-piperidin-1-yl-pyrimidin-4-yl)-sulfanylacetate 347846-67-7 C13H19N3O2S
    methyl (6-methyl-2-piperidin-1-yl-pyrimidin-4-yl)-sulfanylacetate
    —— 1-bromo-3-(2-methyl-propane-2-sulfonyl)-propane 5755-80-6 C7H15BrO2S
    1-bromo-3-(2-methyl-propane-2-sulfonyl)-propane
    —— 7,8,16,17-bisbenzo-10,14-diaza-1,6-dithia-cycloheptadecane 1228649-25-9 C21H28N2S2
    7,8,16,17-bisbenzo-10,14-diaza-1,6-dithia-cycloheptadecane
    —— ethyl (3-cyano-6-methyl-4-oxo-1,4-dihydro-2-pyridinyl)thioacetate 942857-10-5 C11H12N2O3S
    ethyl (3-cyano-6-methyl-4-oxo-1,4-dihydro-2-pyridinyl)thioacetate
    —— 2-(6-Methyl-2-piperidin-1-ylpyrimidin-4-yl)sulfanylacetohydrazide 807621-17-6 C12H19N5OS
    2-(6-Methyl-2-piperidin-1-ylpyrimidin-4-yl)sulfanylacetohydrazide
    —— β,β'-dichlorodipropyl sulfone 86240-76-8 C6H12Cl2O2S
    β,β'-dichlorodipropyl sulfone
    —— bis-(3-chloro-propyl) sulfone 7767-78-4 C6H12Cl2O2S
    bis-(3-chloro-propyl) sulfone
    —— 3-(2-isopropyl-1,3-dithiolan-2-yl)prop-2-yn-1-ol 1072800-31-7 C9H14OS2
    3-(2-isopropyl-1,3-dithiolan-2-yl)prop-2-yn-1-ol
    —— 6-<<2-(N-methylamino)phenyl>thio>uracil 164029-06-5 C11H11N3O2S
    6-<<2-(N-methylamino)phenyl>thio>uracil
    —— 5-[(6-methyl-2-piperidin-1-ylpyrimidin-4-yl)sulfanylmethyl]-3H-1,3,4-oxadiazole-2-thione 347846-75-7 C13H17N5OS2
    5-[(6-methyl-2-piperidin-1-ylpyrimidin-4-yl)sulfanylmethyl]-3H-1,3,4-oxadiazole-2-thione
    —— 4-chloro-6-((R)-1-((S)-2,2-dimethyl-1,3-dioxolan-4-yl)ethoxy)-2-(4-fluorobenzylthio)pyrimidine 1418112-79-4 C18H20ClFN2O3S
    4-chloro-6-((R)-1-((S)-2,2-dimethyl-1,3-dioxolan-4-yl)ethoxy)-2-(4-fluorobenzylthio)pyrimidine
    —— N-(6-((R)-1-((S)-2,2-dimethyl-1,3-dioxolan-4-yl)ethoxy)-2-(4-fluorobenzyl-thio)pyrimidin-4-yl)-3-methylazetidine-1-sulfonamide 1418112-80-7 C22H29FN4O5S2
    N-(6-((R)-1-((S)-2,2-dimethyl-1,3-dioxolan-4-yl)ethoxy)-2-(4-fluorobenzyl-thio)pyrimidin-4-yl)-3-methylazetidine-1-sulfonamide