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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4-Pyrimidinamine, 6-ethenyl-N,N-dimethyl-2-(methylthio)- 920490-06-8 C9H13N3S
    4-Pyrimidinamine, 6-ethenyl-N,N-dimethyl-2-(methylthio)-
    —— 3-deoxy-D-arabino-2-heptulose diethyl dithioketal 1251928-36-5 C11H24O5S2
    3-deoxy-D-arabino-2-heptulose diethyl dithioketal
    —— (Z)-5-[tert-butyl(dimethyl)silyl]oxy-2-phenylsulfanylpent-2-enal 1256796-55-0 C17H26O2SSi
    (Z)-5-[tert-butyl(dimethyl)silyl]oxy-2-phenylsulfanylpent-2-enal
    —— 14,15-dihydro-13H-14-(4-methoxyphenyl)dipyrido[1,2-a:1',2'-a']thiopyrano[2",3"-d:6",5"-d']dipyrimidine-13,15-dione 1262236-98-5 C24H16N4O3S
    14,15-dihydro-13H-14-(4-methoxyphenyl)dipyrido[1,2-a:1',2'-a']thiopyrano[2",3"-d:6",5"-d']dipyrimidine-13,15-dione
    —— (6Z)-9-(tert-butyldimethylsilyloxy)-6-phenylthio-1-trimethylsilylnon-6-ene-1,3-diyn-5-ol 1256796-56-1 C24H36O2SSi2
    (6Z)-9-(tert-butyldimethylsilyloxy)-6-phenylthio-1-trimethylsilylnon-6-ene-1,3-diyn-5-ol
    —— 14,15-dihydro-13H-14-([1,3]benzodioxol-5-yl)dipyrido[1,2-a:1',2'-a']thiopyrano[2",3"-d:6",5"-d']dipyrimidine-13,15-dione 1262237-02-4 C24H14N4O4S
    14,15-dihydro-13H-14-([1,3]benzodioxol-5-yl)dipyrido[1,2-a:1',2'-a']thiopyrano[2",3"-d:6",5"-d']dipyrimidine-13,15-dione
    —— (6Z)-9-(tert-butyldimethylsilyloxy)-6-phenylthio-1-trimethylsilyl-non-6-ene-1,3-diyn-5-one 1256796-57-2 C24H34O2SSi2
    (6Z)-9-(tert-butyldimethylsilyloxy)-6-phenylthio-1-trimethylsilyl-non-6-ene-1,3-diyn-5-one
    —— (5R,6Z)-9-(tert-butyldimethylsilyloxy)-6-phenylthio-1-trimethylsilylnon-6-ene-1,3-diyn-5-ol 1256796-76-5 C24H36O2SSi2
    (5R,6Z)-9-(tert-butyldimethylsilyloxy)-6-phenylthio-1-trimethylsilylnon-6-ene-1,3-diyn-5-ol
    —— 14,15-dihydro-13H-14-(3,4-dimethoxyphenyl)dipyrido[1,2-a:1',2'-a']thiopyrano[2",3"-d:6",5"-d']dipyrimidine-13,15-dione 1262237-01-3 C25H18N4O4S
    14,15-dihydro-13H-14-(3,4-dimethoxyphenyl)dipyrido[1,2-a:1',2'-a']thiopyrano[2",3"-d:6",5"-d']dipyrimidine-13,15-dione
    —— 14,15-dihydro-13H-14-(4-methylphenyl)dipyrido[1,2-a:1',2'-a']thiopyrano[2",3"-d:6",5"-d']dipyrimidine-13,15-dione 1262237-00-2 C24H16N4O2S
    14,15-dihydro-13H-14-(4-methylphenyl)dipyrido[1,2-a:1',2'-a']thiopyrano[2",3"-d:6",5"-d']dipyrimidine-13,15-dione
    —— 3-hydroxy-2-methylene-4-[methyl[2-(phenylthio)acetyl]amino]butanoic acid methyl ester 1251855-54-5 C15H19NO4S
    3-hydroxy-2-methylene-4-[methyl[2-(phenylthio)acetyl]amino]butanoic acid methyl ester
    —— N-methyl-N-(2-oxoethyl)-2-(phenylthio)acetamide 1251855-53-4 C11H13NO2S
    N-methyl-N-(2-oxoethyl)-2-(phenylthio)acetamide
    —— S-(5-cyanopentyl)isothiourea 1256463-79-2 C7H13N3S
    S-(5-cyanopentyl)isothiourea
    —— 6-Chloro-2-ethylsulfanyl-3-methyl-3H-pyrimidin-4-one 1239759-41-1 C7H9ClN2OS
    6-Chloro-2-ethylsulfanyl-3-methyl-3H-pyrimidin-4-one
    —— tert-butyl N-(8-methyl-4-methylsulfanyl-5-oxoindeno[1,2-d]pyrimidin-2-yl)-N-[(2-methylpropan-2-yl)oxycarbonyl]carbamate 1228035-29-7 C23H27N3O5S
    tert-butyl N-(8-methyl-4-methylsulfanyl-5-oxoindeno[1,2-d]pyrimidin-2-yl)-N-[(2-methylpropan-2-yl)oxycarbonyl]carbamate
    —— 2-[[5-(1-Adamantyl)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoic acid 1257344-20-9 C15H20N2O2S2
    2-[[5-(1-Adamantyl)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoic acid
    —— 2-(1-Adamantyl)-5-[(4-fluorophenyl)methylsulfanyl]-1,3,4-thiadiazole 1257344-13-0 C19H21FN2S2
    2-(1-Adamantyl)-5-[(4-fluorophenyl)methylsulfanyl]-1,3,4-thiadiazole
    —— Ethyl 2-[[5-(1-adamantyl)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoate 1257344-26-5 C17H24N2O2S2
    Ethyl 2-[[5-(1-adamantyl)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoate
    —— 2-[[5-(1-Adamantyl)-1,3,4-thiadiazol-2-yl]sulfanyl]acetic acid 1257344-19-6 C14H18N2O2S2
    2-[[5-(1-Adamantyl)-1,3,4-thiadiazol-2-yl]sulfanyl]acetic acid
    —— Ethyl 2-[[5-(1-adamantyl)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate 1257344-27-6 C16H22N2O2S2
    Ethyl 2-[[5-(1-adamantyl)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate
    —— 3-[[5-(1-Adamantyl)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoic acid 1257344-21-0 C15H20N2O2S2
    3-[[5-(1-Adamantyl)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoic acid
    —— 2-(1-Adamantyl)-5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazole 1257344-14-1 C19H21ClN2S2
    2-(1-Adamantyl)-5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazole
    —— 4-[(6-methoxy-1H-benzimidazol-2-yl)sulfanyl]phenol 1257314-77-4 C14H12N2O2S
    4-[(6-methoxy-1H-benzimidazol-2-yl)sulfanyl]phenol
    —— 2-amino-(4-benzo[1,3]dioxol-5-yl)-6-(5-methoxy-1H-benzoimidazol-2-ylsulfanyl)-4H-chromene-3-carboxylic acid ethyl ester 1257314-63-8 C27H23N3O6S
    2-amino-(4-benzo[1,3]dioxol-5-yl)-6-(5-methoxy-1H-benzoimidazol-2-ylsulfanyl)-4H-chromene-3-carboxylic acid ethyl ester
    —— 2-amino-6-(5-methoxy-1H-benzoimidazol-2-ylsulfanyl)-4-thiophen-2-yl-4H-chromene-3-carboxylic acid ethyl ester 1257314-60-5 C24H21N3O4S2
    2-amino-6-(5-methoxy-1H-benzoimidazol-2-ylsulfanyl)-4-thiophen-2-yl-4H-chromene-3-carboxylic acid ethyl ester
    —— 2-amino-6-[(6-methoxy-1H-benzimidazol-2-yl)sulfanyl]-4-thiophen-2-yl-4H-chromene-3-carbonitrile 1257314-62-7 C22H16N4O2S2
    2-amino-6-[(6-methoxy-1H-benzimidazol-2-yl)sulfanyl]-4-thiophen-2-yl-4H-chromene-3-carbonitrile
    —— N-[5-(4-trifluoromethyl-phenyl-sulfanyl)-1,3,4-thiadiazol-2-yl]benzamide 1095155-02-4 C16H10F3N3OS2
    N-[5-(4-trifluoromethyl-phenyl-sulfanyl)-1,3,4-thiadiazol-2-yl]benzamide
    —— N-[5-(4-bromo-phenyl-sulfanyl)-1,3,4-thiadiazol-2-yl]benzamide 1095155-04-6 C15H10BrN3OS2
    N-[5-(4-bromo-phenyl-sulfanyl)-1,3,4-thiadiazol-2-yl]benzamide
    —— 4-[(2,4-diamino-5-methyl-7H-pyrrolo[2,3-d]pyrimidin-6-yl)sulfanyl]-N-(pyridin-3-ylmethyl)benzamide 1258401-03-4 C20H19N7OS
    4-[(2,4-diamino-5-methyl-7H-pyrrolo[2,3-d]pyrimidin-6-yl)sulfanyl]-N-(pyridin-3-ylmethyl)benzamide
    —— 3-[(4-Methylphenyl)sulfanylmethyl]pyridine;hydrochloride 88594-64-3 C13H14ClNS
    3-[(4-Methylphenyl)sulfanylmethyl]pyridine;hydrochloride
    —— 9-[4-[1-[2-[2-[2-[2-[2-[2-[2-[4-[4-[6-Amino-8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]purin-9-yl]butyl]triazol-1-yl]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethyl]triazol-4-yl]butyl]-8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]purin-6-amine 1243536-46-0 C50H60Br2N16O10S2
    9-[4-[1-[2-[2-[2-[2-[2-[2-[2-[4-[4-[6-Amino-8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]purin-9-yl]butyl]triazol-1-yl]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethyl]triazol-4-yl]butyl]-8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]purin-6-amine
    —— 9-[3-[1-[2-[2-[2-[2-[2-[2-[2-[4-[3-[6-Amino-8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]purin-9-yl]propyl]triazol-1-yl]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethyl]triazol-4-yl]propyl]-8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]purin-6-amine 1243536-45-9 C48H56Br2N16O10S2
    9-[3-[1-[2-[2-[2-[2-[2-[2-[2-[4-[3-[6-Amino-8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]purin-9-yl]propyl]triazol-1-yl]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethyl]triazol-4-yl]propyl]-8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]purin-6-amine
    —— (5S)-3-{(R)-2-[(tert-butyldimethylsilyl)oxy]tetradec-13-en-1-yl}-5-methyl-3-(phenylthio)dihydrofuran-2(3H)-one 1258303-45-5 C31H52O3SSi
    (5S)-3-{(R)-2-[(tert-butyldimethylsilyl)oxy]tetradec-13-en-1-yl}-5-methyl-3-(phenylthio)dihydrofuran-2(3H)-one
    —— (Z)-5-(3-Nitro-4-(p-tolylthio)benzylidene)thiazolidine-2,4-dione 3 1489294-32-7 C17H12N2O4S2
    (Z)-5-(3-Nitro-4-(p-tolylthio)benzylidene)thiazolidine-2,4-dione 3
    —— N-Carbamothioyl-N-[(methylamino)methyl]formamide 688299-61-8 C4H9N3OS
    N-Carbamothioyl-N-[(methylamino)methyl]formamide
    —— 2-amino-5-(methylmercapto)pyrimidine 7367-94-4 C5H7N3S
    2-amino-5-(methylmercapto)pyrimidine
    —— {[4-(5-bromo-6-chloro-pyridine-3-sulfonyl)-5-methylsulfanyl-thiophen-2-yl]-imino-methyl}-carbamic acid tert-butyl ester 631910-38-8 C16H17BrClN3O4S3
    {[4-(5-bromo-6-chloro-pyridine-3-sulfonyl)-5-methylsulfanyl-thiophen-2-yl]-imino-methyl}-carbamic acid tert-butyl ester
    —— tert-butyl imino{[(mesitylthio)acetyl]amino}methylcarbamate 1356959-30-2 C17H25N3O3S
    tert-butyl imino{[(mesitylthio)acetyl]amino}methylcarbamate
    —— [Nd(S2CNEt2)3] 22557-98-8 C15H30N3NdS6
    [Nd(S2CNEt2)3]
    —— 1.3-Bis-ethylmercapto-butan 90952-37-7 C8H18S2
    1.3-Bis-ethylmercapto-butan
    —— 3-Pyridinecarboxamide, N-[4-[5-[(acetylamino)methyl]-2-furanyl]-2-thiazolyl]-2-(phenylthio)- 1147294-75-4 C22H18N4O3S2
    3-Pyridinecarboxamide, N-[4-[5-[(acetylamino)methyl]-2-furanyl]-2-thiazolyl]-2-(phenylthio)-
    —— 3-Phenylthio-2-chlorbut-2-en-4-olid 62674-17-3 C10H7ClO2S
    3-Phenylthio-2-chlorbut-2-en-4-olid
    —— 2-(Isobutylsulfonyl)ethanamine 1092280-20-0 C6H15NO2S
    2-(Isobutylsulfonyl)ethanamine
    —— 4-(dimethylamino)-2-methylsulfanyl-1,4-diazabuta-1,3-diene 1112998-77-2 C5H11N3S
    4-(dimethylamino)-2-methylsulfanyl-1,4-diazabuta-1,3-diene
    —— 2-(5-cyano-6-methyl-2-phenylpyrimidin-4-yl)sulfanyl-N-(furan-2-ylmethyl)acetamide 915185-90-9 C19H16N4O2S
    2-(5-cyano-6-methyl-2-phenylpyrimidin-4-yl)sulfanyl-N-(furan-2-ylmethyl)acetamide
    —— Methyl(methylsulfanyl)sulfanium 90827-83-1 C2H7S2
    Methyl(methylsulfanyl)sulfanium
    —— N-{4-amino-6-[(4-chlorophenyl)sulfanyl]-2-phenylpyrimidin-5-yl}benzamide 898520-02-0 C23H17ClN4OS
    N-{4-amino-6-[(4-chlorophenyl)sulfanyl]-2-phenylpyrimidin-5-yl}benzamide
    —— 2-[(4-Methyl-5-sulfanylidene-4,5-dihydro-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide 834899-94-4 C5H7N3OS3
    2-[(4-Methyl-5-sulfanylidene-4,5-dihydro-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— 2-Acetyl-7-methyl-1-benzothiophen-3(2H)-one 562085-66-9 C11H10O2S
    2-Acetyl-7-methyl-1-benzothiophen-3(2H)-one
    —— Cyclopentanecarbodithioic acid 35329-07-8 C6H10S2
    Cyclopentanecarbodithioic acid