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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4-(3-fluoro-4-methoxyphenylthio)benzaldehyde 1173658-46-2 C14H11FO2S
    4-(3-fluoro-4-methoxyphenylthio)benzaldehyde
    —— 4-phenylthiophenylhydroxylamine 21229-99-2 C12H11NOS
    4-phenylthiophenylhydroxylamine
    —— 4-[4-(3-fluoro-4-methoxy-phenylsulfanyl)-phenyl]-6-methyl-2-oxo-1,2,3,4-tetrahydro-pyrimidine-5-carboxylic acid ethyl ester 1173658-61-1 C21H21FN2O4S
    4-[4-(3-fluoro-4-methoxy-phenylsulfanyl)-phenyl]-6-methyl-2-oxo-1,2,3,4-tetrahydro-pyrimidine-5-carboxylic acid ethyl ester
    —— 6-methyl-2-thioxo-4-(4-p-tolylsulfanyl-phenyl)-1,2,3,4-tetrahydro-pyrimidine-5-carboxylic acid ethyl ester 1173658-65-5 C21H22N2O2S2
    6-methyl-2-thioxo-4-(4-p-tolylsulfanyl-phenyl)-1,2,3,4-tetrahydro-pyrimidine-5-carboxylic acid ethyl ester
    —— 5H,7H-dibenzo<b,g><1,5>dithiocin 60418-10-2 C14H12S2
    5H,7H-dibenzo<b,g><1,5>dithiocin
    —— 5-acetyl-6-methyl-4-(4-phenylsulfanyl-phenyl)-3,4-dihydro-1H-pyrimidin-2-one 1173658-48-4 C19H18N2O2S
    5-acetyl-6-methyl-4-(4-phenylsulfanyl-phenyl)-3,4-dihydro-1H-pyrimidin-2-one
    —— 1-[6-methyl-2-thioxo-4-(4-p-tolylsulfanyl-phenyl)-1,2,3,4-tetrahydro-pyrimidin-5-yl]-ethanone 1173658-66-6 C20H20N2OS2
    1-[6-methyl-2-thioxo-4-(4-p-tolylsulfanyl-phenyl)-1,2,3,4-tetrahydro-pyrimidin-5-yl]-ethanone
    —— 5-acetyl-6-methyl-4-(4-p-tolylsulfanyl-phenyl)-3,4-dihydro-1H-pyrimidin-2-one 1173658-50-8 C20H20N2O2S
    5-acetyl-6-methyl-4-(4-p-tolylsulfanyl-phenyl)-3,4-dihydro-1H-pyrimidin-2-one
    —— 5-acetyl-4-[4-(3-fluoro-4-methoxy-phenylsulfanyl)-phenyl]-6-methyl-2-oxo-3,4-dihydro-1H-pyrimidine-2-one 1173658-62-2 C20H19FN2O3S
    5-acetyl-4-[4-(3-fluoro-4-methoxy-phenylsulfanyl)-phenyl]-6-methyl-2-oxo-3,4-dihydro-1H-pyrimidine-2-one
    —— 4-[4-(2-chloro-6-methyl-phenylsulfanyl)-phenyl]-6-methyl-2-oxo-1,2,3,4-tetrahydro-pyrimidine-5-carboxylic acid ethyl ester 1173658-59-7 C21H21ClN2O3S
    4-[4-(2-chloro-6-methyl-phenylsulfanyl)-phenyl]-6-methyl-2-oxo-1,2,3,4-tetrahydro-pyrimidine-5-carboxylic acid ethyl ester
    —— 4-methyl-3-thiophenesulfonyl isocyanate 81417-53-0 C6H5NO3S2
    4-methyl-3-thiophenesulfonyl isocyanate
    —— 2,3-bis(3-carbomethoxypyridyl-2-thio)indole 242491-41-4 C22H17N3O4S2
    2,3-bis(3-carbomethoxypyridyl-2-thio)indole
    —— 5-acetyl-4-[4-(2-chloro-6-methyl-phenylsulfanyl)-phenyl]-6-methyl-3,4-dihydro-1H-pyrimidin-2-one 1173658-60-0 C20H19ClN2O2S
    5-acetyl-4-[4-(2-chloro-6-methyl-phenylsulfanyl)-phenyl]-6-methyl-3,4-dihydro-1H-pyrimidin-2-one
    —— 2-chloro-n-prop-1-yl-sulfonyl isocyanate 4794-12-1 C4H6ClNO3S
    2-chloro-n-prop-1-yl-sulfonyl isocyanate
    —— 5,5'-bis(mesitylthio)-2,2'-bithiophene 291308-72-0 C26H26S4
    5,5'-bis(mesitylthio)-2,2'-bithiophene
    —— 3-((pyridin-4-ylmethyl)thio)-5,6-di-p-tolyl-1,2,4-triazine 1478982-08-9 C23H20N4S
    3-((pyridin-4-ylmethyl)thio)-5,6-di-p-tolyl-1,2,4-triazine
    —— (3aS,7aS)-5-methyl-7a-phenylsulfanyl-3,3a,4,7-tetrahydro-2H-inden-1-one 75781-77-0 C16H18OS
    (3aS,7aS)-5-methyl-7a-phenylsulfanyl-3,3a,4,7-tetrahydro-2H-inden-1-one
    —— bis(acetylthio)methane 2506-35-6 C5H8O2S2
    bis(acetylthio)methane
    —— 4-chloro-6-(3,5-dimethyl-1H-1,2,4-triazol-1-yl)-2-(methylthio)pyrimidine 1429634-94-5 C9H10ClN5S
    4-chloro-6-(3,5-dimethyl-1H-1,2,4-triazol-1-yl)-2-(methylthio)pyrimidine
    —— 6-(4-ethyl-2-thiazolylthio)-5-nitro-3H-isobenzofuran-1-one 181485-51-8 C13H10N2O4S2
    6-(4-ethyl-2-thiazolylthio)-5-nitro-3H-isobenzofuran-1-one
    —— 2-methyl-2-(phenylthio)-1,3-cyclopentanedione 72302-65-9 C12H12O2S
    2-methyl-2-(phenylthio)-1,3-cyclopentanedione
    —— Methyl (2E)-2-(4-methylpentan-2-ylidene)hydrazine-1-carbodithioate 60273-80-5 C8H16N2S2
    Methyl (2E)-2-(4-methylpentan-2-ylidene)hydrazine-1-carbodithioate
    —— (S)-S-1-formyl-4-methylcyclohex-3-enyl diisopropylcarbamothioate 1379479-90-9 C15H25NO2S
    (S)-S-1-formyl-4-methylcyclohex-3-enyl diisopropylcarbamothioate
    —— 5-Amino-6-(4-ethyl-2-thiazolylthio)-3H-isobenzofuran-1-one 181485-52-9 C13H12N2O2S2
    5-Amino-6-(4-ethyl-2-thiazolylthio)-3H-isobenzofuran-1-one
    —— N-[6-[(4-ethyl-1,3-thiazol-2-yl)sulfanyl]-1-oxo-3H-2-benzofuran-5-yl]-N-methylsulfonylmethanesulfonamide 181485-53-0 C15H16N2O6S4
    N-[6-[(4-ethyl-1,3-thiazol-2-yl)sulfanyl]-1-oxo-3H-2-benzofuran-5-yl]-N-methylsulfonylmethanesulfonamide
    —— (E,E)-3,4-diisothiocyanatohexa-2,4-diene 137768-90-2 C8H8N2S2
    (E,E)-3,4-diisothiocyanatohexa-2,4-diene
    —— [(3,4-Dimethylpent-3-EN-1-YL)sulfanyl]benzene 260548-20-7 C13H18S
    [(3,4-Dimethylpent-3-EN-1-YL)sulfanyl]benzene
    —— cis-Pt(Me2SO)2Br2 61586-51-4 C4H12Br2O2PtS2
    cis-Pt(Me2SO)2Br2
    —— 1-(n-hexylguanyl)thiourea 101189-94-0 C8H18N4S
    1-(n-hexylguanyl)thiourea
    —— 2,3,5,6-tetramethyl-4-oxo-1-phenylthiocyclohexa-2,5-dienyl acetate 194720-36-0 C18H20O3S
    2,3,5,6-tetramethyl-4-oxo-1-phenylthiocyclohexa-2,5-dienyl acetate
    —— (4-methoxy-2,6-dimethylphenyl)(phenyl)sulfane 108125-21-9 C15H16OS
    (4-methoxy-2,6-dimethylphenyl)(phenyl)sulfane
    —— 1-Bromo-2-[2-(2-bromophenyl)sulfanylethylsulfanyl]benzene 1221446-32-7 C14H12Br2S2
    1-Bromo-2-[2-(2-bromophenyl)sulfanylethylsulfanyl]benzene
    —— 1,10-diaza-5,6,15,17-tetrathia-2,3:8,9:12,13,18:19-tetrabenzocyclododeca-10,20-diene 21620-34-8 C30H26N2S4
    1,10-diaza-5,6,15,17-tetrathia-2,3:8,9:12,13,18:19-tetrabenzocyclododeca-10,20-diene
    —— <i>N</i>-methyl-hydrazinecarbodithioic acid 95792-14-6 C2H6N2S2
    <i>N</i>-methyl-hydrazinecarbodithioic acid
    —— trans-α-Methyl-β-phenylthioacrylic acid 77199-25-8 C10H10O2S
    trans-α-Methyl-β-phenylthioacrylic acid
    —— 3,3,6-trimethyl-4-methylthiohepta-1,5-diene 40754-52-7 C11H20S
    3,3,6-trimethyl-4-methylthiohepta-1,5-diene
    —— 2,3,5,6-tetrafluoro-4-(isopropylthio)pyridine 67644-48-8 C8H7F4NS
    2,3,5,6-tetrafluoro-4-(isopropylthio)pyridine
    —— 2-methyl-3-(phenylthio)acrylic acid 49667-38-1 C10H10O2S
    2-methyl-3-(phenylthio)acrylic acid
    —— 3-Phenylthio-3-methoxy-2-hydroxy-propan 42919-47-1 C10H14O2S
    3-Phenylthio-3-methoxy-2-hydroxy-propan
    —— 3-<1'-(phenylthio)prop-2'-enyl>butan-4-olide 113460-72-3 C13H14O2S
    3-<1'-(phenylthio)prop-2'-enyl>butan-4-olide
    —— (E)-3-<3'-(phenylthio)prop-1'-enyl>butan-4-olide 113460-74-5 C13H14O2S
    (E)-3-<3'-(phenylthio)prop-1'-enyl>butan-4-olide
    —— 1-butanethiol 27482-27-5 C4H8S
    1-butanethiol
    —— MeCSPh(CO2Et)SO2Me 1214319-99-9 C12H16O4S2
    MeCSPh(CO2Et)SO2Me
    —— 5,6-dimethyl-2-methylsulfanyl-pyrimidin-4-ylamine 14394-63-9 C7H11N3S
    5,6-dimethyl-2-methylsulfanyl-pyrimidin-4-ylamine
    —— 6-Ethyl-5-methyl-2-methylsulfanylpyrimidin-4-amine 77786-99-3 C8H13N3S
    6-Ethyl-5-methyl-2-methylsulfanylpyrimidin-4-amine
    —— 5,6-Dihydro-thiazolo[3,2-d][1,4,2]diazaphopsphole-3-carboxylic acid methyl ester 138404-48-5 C6H7N2O2PS
    5,6-Dihydro-thiazolo[3,2-d][1,4,2]diazaphopsphole-3-carboxylic acid methyl ester
    —— 2-(4-chlorophenylsulfanyl)-3,4,6-trimethyl-benzoic acid methyl ester 1190220-05-3 C17H17ClO2S
    2-(4-chlorophenylsulfanyl)-3,4,6-trimethyl-benzoic acid methyl ester
    —— (2,4-dinitro-phenyl)-(3-nitro-phenyl)-sulfide 1657-86-9 C12H7N3O6S
    (2,4-dinitro-phenyl)-(3-nitro-phenyl)-sulfide
    —— 1-(5,6-dihydro-2-methyl-6-(phenylthio)-1,4-oxathiin-3-yl)ethanone 170469-82-6 C13H14O2S2
    1-(5,6-dihydro-2-methyl-6-(phenylthio)-1,4-oxathiin-3-yl)ethanone
    —— (E)-Butyl(3,3-dimethyl-1-butenyl)sulfid 70127-58-1 C10H20S
    (E)-Butyl(3,3-dimethyl-1-butenyl)sulfid