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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(3-Methylphenyl)-5-prop-2-ynylsulfanyl-1,3,4-oxadiazole 892446-26-3 C12H10N2OS
    2-(3-Methylphenyl)-5-prop-2-ynylsulfanyl-1,3,4-oxadiazole
    —— N-(4-methylsulfanyl-3-propan-2-yloxadiazol-3-ium-5-yl)ethanimidate 1217515-98-4 C8H13N3O2S
    N-(4-methylsulfanyl-3-propan-2-yloxadiazol-3-ium-5-yl)ethanimidate
    —— N-[3-(dimethylamino)-4-methylsulfanyloxadiazol-3-ium-5-yl]benzenecarboximidate 1217515-96-2 C12H14N4O2S
    N-[3-(dimethylamino)-4-methylsulfanyloxadiazol-3-ium-5-yl]benzenecarboximidate
    —— N-(4-benzylsulfanyl-3-propan-2-yloxadiazol-3-ium-5-yl)benzenecarboximidate 1217516-02-3 C19H19N3O2S
    N-(4-benzylsulfanyl-3-propan-2-yloxadiazol-3-ium-5-yl)benzenecarboximidate
    —— methyl 2-((2-(4-bromophenylthio)quinolin-3-yl)(hydroxy)methyl)acrylate 1309389-08-9 C20H16BrNO3S
    methyl 2-((2-(4-bromophenylthio)quinolin-3-yl)(hydroxy)methyl)acrylate
    —— 1-Chloro-3-[4-[4-(3-chloro-2-hydroxypropoxy)phenyl]sulfanylphenoxy]propan-2-ol 1314090-45-3 C18H20Cl2O4S
    1-Chloro-3-[4-[4-(3-chloro-2-hydroxypropoxy)phenyl]sulfanylphenoxy]propan-2-ol
    —— (2-(1-methoxycyclohex-2-enyl)ethynyl)(phenyl)sulfane 1298087-12-3 C15H16OS
    (2-(1-methoxycyclohex-2-enyl)ethynyl)(phenyl)sulfane
    —— 5-((4-bromophenylthio)methyl)-1H-pyrazol-3(2H)-one 1227692-39-8 C10H9BrN2OS
    5-((4-bromophenylthio)methyl)-1H-pyrazol-3(2H)-one
    —— 1-methyl-3-(phenylthio)quinolinium iodide 1265087-21-5 C16H14NS*I
    1-methyl-3-(phenylthio)quinolinium iodide
    —— 2,2'-bis[(S)-4-benzylimidazolin-2-yl]diphenyl sulfide 1265177-57-8 C32H30N4S
    2,2'-bis[(S)-4-benzylimidazolin-2-yl]diphenyl sulfide
    —— 3-(Butylthio)phenylboronic acid 884868-03-5 C10H15BO2S
    3-(Butylthio)phenylboronic acid
    —— 5-bromo-2-(4-(3-trifluoromethyl-diazirin-3-yl)phenylthio)thiazole 1270931-18-4 C11H5BrF3N3S2
    5-bromo-2-(4-(3-trifluoromethyl-diazirin-3-yl)phenylthio)thiazole
    —— 2,2'-bis[(S)-1-(1-methylethyl)-4-benzylimidazolin-2-yl]diphenyl sulfide 1265177-59-0 C38H42N4S
    2,2'-bis[(S)-1-(1-methylethyl)-4-benzylimidazolin-2-yl]diphenyl sulfide
    —— 3-(Cyclohexylsulfanyl)-6-hydrazinylpyridazine 1334490-68-4 C10H16N4S
    3-(Cyclohexylsulfanyl)-6-hydrazinylpyridazine
    —— 5-(4-methoxytetrahydropyran-4-yl)-2-(4-(3-trifluoromethyl-diazirin-3-yl)phenylthio)thiazole 1270931-12-8 C17H16F3N3O2S2
    5-(4-methoxytetrahydropyran-4-yl)-2-(4-(3-trifluoromethyl-diazirin-3-yl)phenylthio)thiazole
    —— N-i-propyl-3,3-dimethoxy-2-(phenylthio)propanamide 1294897-38-3 C14H21NO3S
    N-i-propyl-3,3-dimethoxy-2-(phenylthio)propanamide
    —— 5-(4-Methoxyoxan-4-yl)-2-[4-[3-(trifluoromethyl)diazirin-3-yl]phenyl]sulfanyl-4-tritio-1,3-thiazole 1270931-13-9 C17H16F3N3O2S2
    5-(4-Methoxyoxan-4-yl)-2-[4-[3-(trifluoromethyl)diazirin-3-yl]phenyl]sulfanyl-4-tritio-1,3-thiazole
    —— N-i-propyl-3-(morpholin-4-yl)-2-(phenylthio)propenamide 1294897-03-2 C16H22N2O2S
    N-i-propyl-3-(morpholin-4-yl)-2-(phenylthio)propenamide
    —— 4-bromo-5-(4-methoxytetrahydropyran-4-yl)-2-(4-(3-trifluoromethyl-diazirin-3-yl)phenylthio)thiazole 1270931-15-1 C17H15BrF3N3O2S2
    4-bromo-5-(4-methoxytetrahydropyran-4-yl)-2-(4-(3-trifluoromethyl-diazirin-3-yl)phenylthio)thiazole
    —— N-benzyl-2-[(4R,5R)-4,5-dimethyl-1,3-dioxolan-2-yl]-2-phenylsulfanylacetamide 1294897-66-7 C20H23NO3S
    N-benzyl-2-[(4R,5R)-4,5-dimethyl-1,3-dioxolan-2-yl]-2-phenylsulfanylacetamide
    —— 4-Deuterio-5-(4-methoxyoxan-4-yl)-2-[4-[3-(trifluoromethyl)diazirin-3-yl]phenyl]sulfanyl-1,3-thiazole 1270931-21-9 C17H16F3N3O2S2
    4-Deuterio-5-(4-methoxyoxan-4-yl)-2-[4-[3-(trifluoromethyl)diazirin-3-yl]phenyl]sulfanyl-1,3-thiazole
    —— N-benzyl-2-[(4S,5S)-4,5-dimethyl-1,3-dioxolan-2-yl]-2-phenylsulfanylacetamide 1296255-11-2 C20H23NO3S
    N-benzyl-2-[(4S,5S)-4,5-dimethyl-1,3-dioxolan-2-yl]-2-phenylsulfanylacetamide
    —— 2-[(4R,5R)-4,5-dimethyl-1,3-dioxolan-2-yl]-2-phenylsulfanylacetamide 1294897-71-4 C13H17NO3S
    2-[(4R,5R)-4,5-dimethyl-1,3-dioxolan-2-yl]-2-phenylsulfanylacetamide
    —— 2-[(4R,5R)-4,5-dimethyl-1,3-dioxolan-2-yl]-N-[(1S)-1-phenylethyl]-2-phenylsulfanylacetamide 1294897-65-6 C21H25NO3S
    2-[(4R,5R)-4,5-dimethyl-1,3-dioxolan-2-yl]-N-[(1S)-1-phenylethyl]-2-phenylsulfanylacetamide
    —— diethyl (4R,5R)-2-[2-(benzylamino)-2-oxo-1-phenylsulfanylethyl]-1,3-dioxolane-4,5-dicarboxylate 1294897-68-9 C24H27NO7S
    diethyl (4R,5R)-2-[2-(benzylamino)-2-oxo-1-phenylsulfanylethyl]-1,3-dioxolane-4,5-dicarboxylate
    —— 2-[(4R,6R)-4,6-dimethyl-1,3-dioxan-2-yl]-2-phenylsulfanylacetamide 1294897-72-5 C14H19NO3S
    2-[(4R,6R)-4,6-dimethyl-1,3-dioxan-2-yl]-2-phenylsulfanylacetamide
    —— N-benzyl-2-[(4R,6R)-4,6-dimethyl-1,3-dioxan-2-yl]-2-phenylsulfanylacetamide 1294897-67-8 C21H25NO3S
    N-benzyl-2-[(4R,6R)-4,6-dimethyl-1,3-dioxan-2-yl]-2-phenylsulfanylacetamide
    —— (Z)-2-(phenylthio)-2-butenamide 1294896-93-7 C10H11NOS
    (Z)-2-(phenylthio)-2-butenamide
    —— N,N-dimethyl-3-(morpholin4-yl)-2-(phenylthio)propenamide 1294897-02-1 C15H20N2O2S
    N,N-dimethyl-3-(morpholin4-yl)-2-(phenylthio)propenamide
    —— 3,3-dimethoxy-2-(phenylthio)propanamide 1294897-41-8 C11H15NO3S
    3,3-dimethoxy-2-(phenylthio)propanamide
    —— 3-(N-tert-butoxycarbonyl)amino-4-phenylsulfanyl-(2R,3R)-butane-1,2-diol 1345532-30-0 C15H23NO4S
    3-(N-tert-butoxycarbonyl)amino-4-phenylsulfanyl-(2R,3R)-butane-1,2-diol
    —— 4-(6-Methylsulfanylpyridin-2-yl)piperidine-4-carbonitrile 1312679-47-2 C12H15N3S
    4-(6-Methylsulfanylpyridin-2-yl)piperidine-4-carbonitrile
    —— 3-(3-cyanophenylthio)-5-methyl[1,2,4]triazine 1313039-56-3 C11H8N4S
    3-(3-cyanophenylthio)-5-methyl[1,2,4]triazine
    —— 3-(3-chlorobenzylthio)-5-methyl[1,2,4]triazine 1313039-65-4 C11H10ClN3S
    3-(3-chlorobenzylthio)-5-methyl[1,2,4]triazine
    —— 3-(3-bromophenylthio)-5-methyl[1,2,4]triazine 1313039-54-1 C10H8BrN3S
    3-(3-bromophenylthio)-5-methyl[1,2,4]triazine
    —— Ethyl 3-(4-chlorophenyl)sulfanyl-2-methylbut-3-enoate 1308656-53-2 C13H15ClO2S
    Ethyl 3-(4-chlorophenyl)sulfanyl-2-methylbut-3-enoate
    —— 3-(3-bromobenzylthio)-5-methyl[1,2,4]triazine 1313039-66-5 C11H10BrN3S
    3-(3-bromobenzylthio)-5-methyl[1,2,4]triazine
    —— 2-Bromomethyl-3-methylsulfanyl-pyrazine 1289385-55-2 C6H7BrN2S
    2-Bromomethyl-3-methylsulfanyl-pyrazine
    —— ethyl 2-oxo-7-(phenylthio)bicyclo[3.2.0]hept-6-ene-1-carboxylate 1312205-37-0 C16H16O3S
    ethyl 2-oxo-7-(phenylthio)bicyclo[3.2.0]hept-6-ene-1-carboxylate
    —— Ethyl 3-[(4-bromophenyl)sulfanyl]-2-cyano-3-(methylsulfanyl)prop-2-enoate 214330-98-0 C13H12BrNO2S2
    Ethyl 3-[(4-bromophenyl)sulfanyl]-2-cyano-3-(methylsulfanyl)prop-2-enoate
    —— Ethyl 3-[(4-chlorophenyl)sulfanyl]-2-cyano-3-(methylsulfanyl)prop-2-enoate 214330-97-9 C13H12ClNO2S2
    Ethyl 3-[(4-chlorophenyl)sulfanyl]-2-cyano-3-(methylsulfanyl)prop-2-enoate
    —— 3-[2-(Ethylsulfanyl)pyrimidin-5-yl]prop-2-enoic acid 915921-69-6 C9H10N2O2S
    3-[2-(Ethylsulfanyl)pyrimidin-5-yl]prop-2-enoic acid
    —— (2E)-3-[2-(Methylthio)pyrimidin-5-YL]acrylic acid 915924-30-0 C8H8N2O2S
    (2E)-3-[2-(Methylthio)pyrimidin-5-YL]acrylic acid
    —— Ethyl 2-[2-(aminocarbonyl)hydrazinylidene]-3-[(4-chlorophenyl)thio]propanoate 886361-57-5 C12H14ClN3O3S
    Ethyl 2-[2-(aminocarbonyl)hydrazinylidene]-3-[(4-chlorophenyl)thio]propanoate
    —— 2-(Chloroethylsulfonyl)ethanol dihydrochloride 85739-74-8 C4H11Cl3O3S
    2-(Chloroethylsulfonyl)ethanol dihydrochloride
    —— 1-(2-(Methylthio)-1H-imidazol-4-yl)ethanone 944898-42-4 C6H8N2OS
    1-(2-(Methylthio)-1H-imidazol-4-yl)ethanone
    —— 5-(Chloromethyl)-2-(methylthio)-1H-imidazole 944905-27-5 C5H7ClN2S
    5-(Chloromethyl)-2-(methylthio)-1H-imidazole
    —— 3-Fluoro-2-methylphenyl methyl sulfide 134646-04-1 C8H9FS
    3-Fluoro-2-methylphenyl methyl sulfide
    —— Ethyl 3-{4-[(trifluoromethyl)sulfanyl]phenyl}propanoate 910654-45-4 C12H13F3O2S
    Ethyl 3-{4-[(trifluoromethyl)sulfanyl]phenyl}propanoate
    —— 1-(Propylsulfanyl)tridecane 66271-55-4 C16H34S
    1-(Propylsulfanyl)tridecane